ORGANIC CHEMISTRY Preparation and Properties of alkanes MIND MAP

GMP GR
H , Ni
(1) R–C  CH 2  (1) X , h or UV light or 400 C
2         
 RX
200300C
or
R–CH=CH2 Sabatier senderens Nitration
(2)  R-N
reaction

(2) R–X 

Zn Cu  HCl
 Sulphonation H S O
Re d P Hi, LiAlH 4 (3) 2
       2
7  Alkyl Sulphonic acid

(3) R–Mg–X 

HOH or ROH
  
or NH3 or RNH 2 Reed reaction
(4) SO2 + Cl2    RSO2Cl
h
Na , dry ether
(4) RX   
Wurtz reaction R–H
AlCl / HCl
Zn or (5) 3  branched alkanes
(5) RX    
 Isomerisation
Frankland's reaction R–R
or
R  C  Cl or ROH CnH2n+2 (6) Pyrolysis
Re
d
(6) P / Hi 
||  500 700 C
Alkenes + CH4 or C2H6
O
or Cr or Mo or V oxide
   
R CR or RCHO (7)  Al 2O3 500C Aromatic compound
||
O
CH N
22
(8)   Higher alkane
R CR step up reaction
Zn Hg / Conc . HCl
(7) ||     

O Clemension 's reduction
O
2
(9) 
 CO2 + H2O
R C  O 
H 2 N  NH 2
(8) |   
 Combustion
R Wolf / Kishner reduction

or
(RCH2CH2)3B H O
 2

(9) RCOONa NaOH  CaO

  

(10) RCOONa Kolbe

's electrolytic synthesis
 
ORGANIC CHEMISTRY Preparation and Properties of alkenes MIND MAP
ORGANIC CHEMISTRY Preparation and Properties of alkynes MIND MAP