Ketres 1Data

Page
Date

Date
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Nomenclature oE aohyde& hetones

TUPAC adahyde
Ketons- one'
Adhyde R

ketone Nole The Dames Ok Cnpausd Qu giuen by thlin

nam

Sinpleat aamatic

OLher Subshtuted aomahc

kenzatyde
1eC HO Methaal.
(aznaldahyde)
(aataldelhgd)
3. CH,CHa CHO
y.
5. ÇHO 2-mthydpzpaaal CH- CH-CHO

Estor CRCOR') gctopvopnt tobatrtbhgde

CHO
otopentane Cavdatdetyde
CHO
Noe:

CHO
Cenzaldohyde
NH,
OH
2- hydnoy benxalelehde
Notei When CO
zup )8 Otachad to
halicle
4-oitno heozaldebyde
 Dats
Page
Dolg
Page

2-Pheayleitanal
fu. 22.Cuco CuyCHg Butane-2-0ne

Pentane -2-0ne
1.
-3one

12.
CHO
3-nthyl Gyclohenanh, candaldelyde
rols Cyclohe nanone
43 2

26
Pantanal C
acerptenene)

Prop-2-enal I2
I5 CH, : CH CHO
tPeylpuapaaane
Peot-2 enal
6.CHa- CH - CH =CH - CHD
Pentane -2g4-dione.
2

Qutane - 23- dione

4-Gomo-3-mhyl heptanal
18 3 2

CHO ben1en -11 icanbaldehyde 30CH cH, CoCHe CHO 3-00pentanal

31
Diphenye mehanone (Bnopro
y-&nomo benzalde hydo
32. OHC- CH, - CH - CHa CHO
CH=CHCHO 3-
Punyl ap- 2- enal

21 CH, C0CH
Propaen pnopaone
 Bute

Chy-Cy-CHo
Ciha ny prapibnadhydl Pupanabon OE dibyde kelon24
02C -CH, Comman mithod
3-lydnou,kudanal ÇHO

4- OoopenBanal
CH, -Ch Cho aldilyde
cocHs
-aho! kafong

y- Eluoreace tophinane

OH kMal,/H

STRUCTUREOE ARAO NyL ARAp

ogtoidised
Bond angle : 120 CHOH
F0

CHoH

kotone
aldlahyde
hycracankoa
dipolar From alkenes 0Z0nolysis f alkeres
4ag C-0 hond ik20lari sed due ta hiqken alcAno
AIKene heduc
Jaugluin neutial s a di-palan
doukle hondedCin alkene ContiA
Noe
Chnduanyllanbon aldebyde phodeuct
Mclesphile
 DaBe
Page

4.
CEvon aachande).
Acid chlosides

Basay
2

CH,-CotL

EIthaglhanide
Zn dust /H, 0

Pd - Aaua HCU
t H

Zh dust /H0 benseytetotide

H, CH -eHgtocta R- -0R

heacti nn
Gtephen
Sncla t ucl DlsAL-H.
By bydsakinn ALH Ci-Aa
audenyd DIBAL-H diso huy Aluminium

tautonoute
CH CHQ with
Nibalea anl teduced to atnekpogclinq imine
Qlich
tastabte
(ero) Fautone
adelyde
Hg'/4*
CH -G =CH + H,0 im'n
eno ACeHn

ReHO
 CN geduted CHO
Data

CH,-CzN Gncl, t HCL CHtycHO.

thart natle.

Beneontrue

HHa0
DIBaL- H/Ha0 , CH CCH)a, CHO

Noek Ananah. aldsbydea ane pxepanad foom anomatit

aydhucankang
Jame
26) Etard hea

kezldebyde with

Cromit e chonide cmiiseaMe

ChHomium Camp lo Mhich On

CS.

Ct Comp len
Gu) by side chaun chlaninalianO Taluntfouauwld by
CH

Cl

Cd) Gaterman- koch..

ohenbenzen
OnSdeuisatiuesistolacd uith
vLbon maroid54cL in pxesunckanhqAlCly
Oh. Cupu(euclg itgiuehaLalduhyale
GHO
-Go-y-Het

Cadmiun0n0cd chlotide

NOLe neac ocadnium. chlanide wth aignand

nagut-leAialuyl Cadmiun
 Dote

GH,-CH,-c N dy esen

cOC35
Asqahon.
ahy. AlGlg

anhy AICl3
3.

ttt-tpagimgtang e
3

NO,

CHa- N

pt
Boiling paint
 Poge

in decreasing
Uhden bp GHCMICAL. Proporie

OniteMOchanit fon

+ N

ane owen. than

Steng niaunalecudlar Hkanding i3presea) s'n alcah
thanke tanes to oand
hucleaphilit add?
than
S4enic hindoranc. Poh the nuclenple o atal
Dutoeak mOLcutan aocaho
out DF diplle dipole. Aterachon

ane miscible
H-CN adods to aldehyde kotone to faam
OH
CH -C=0 + HcA
CN
acotaloeye)
Qlhanal famahydnia

cceone yanalyddn)
 pate
Dete 3/1
/02

ANOE Sadun bislphk. (Na HSO) Ketal:

ketal
50, Na

O-CH
CHa
O-CH,
C QceLone)
Ng HS0
CH So Na eaylere

alealaa! Nane oF ammonia FOrmula

deri vatve

Ketang4 NH-0H Couine

3.
Hy drazine NH- NHa yaaz
CACHL Ketal hnation
y 2,4- DioitnoPhny
yaazine
NO,

inbsdiate 2llD hemiarall thon Semi Gaxkaide Semicaba2ne

gediaa lanpaund Calod aetal

2oten.molecute
H
Conpauade

0C,Ha
ethanal ouime
erhounal
 Date
Date
Peqe

CH, N-OH

CHa

NH NH HN= C-NH- NH.

prapannt
X

NH NH
CH, = N- NH
MCHØ tNN
H+

H
CH, CHâ + N-NH CÇtts
H
1.
NO
HC HO +NÂ NH-oNO cHq N- NH
2,u- Drp C6orss heagent -NHO NO,
H*
NO

R- CH CH - CHD t NH CO NH A K-C4 CH-CH

NNH CONH

t CH CH, NH¡ CHa

gemicanhazite but
the fon of Semi caLko zOne1
Hhe Complnda in inoeaing ondar OE
Ann Semicanbazite One oe NH atachec ta ouande uclephilied heac.
i in Volued in tos0nsACe ths e
Notel! than kataaek tanandd&

AA

deoeases
 Date

Poge

Analekyde,dlyk Pitbokorotdhydo

Likenane(Ptolualdelyd CHacoCHa

Aaduchan Adehade letonet

ILaidatioo.
kotonet ta alcohal
Cpasia alzaka)
AWh
adekyde
alcaknl
Qid nth
Caidakion gues Cankrnylit
lami D0O

CHglH) KM,/H
23
ytndcanson caxkenuylic
in aldohyde e etanek acidith less C atom Han the
panent Ketone.

aenrmenlon Reduchon -
aldhyde ketne with ine Me thanpt Qçd
amalgan HcL
kmal, H*
CH - CHy tH0 C Ca
ethano
CHy GOCHg CHocoo4
Propan CHCH coaN
Cea,on)
 pzodu)

ld ooidainy

Tallens Heagent0

HalOFOHn niachan

Aidhyde ketna Caniaiaing

Eeling's A
Camepandg Caskanydie Dcid kauieg tCato
Given
Toddfoa Date
Date
Page
Poge.

Halooum
iS Convenled to OAcetophenane. Ben zo phenane
CHCL,
Sadurn hyocAarude
PoMDate
CH Chg
’CHI, t GaH Coo Na

Pentan-2-0n2 Pentane-3-one

CH,- (0Ct, CH, CHy + Na0I

CHaCHO CHIg t

CHa CocH, t Na OI ( Ethanal Propenat

Ch, CHcHO
4NO

CHacHot Na0I

blw
Proparal t Prypanene

CHO CUO
 -3
CH
heac
CH
-CO CH
-c= CH,
ptce Candise
in ydagen Alhali
dilte Condene
adabyde
atllast Cacdnsation Auo
ryl
Carbonion
ao dit.
=CHCH,- CH
Canbanion
al tosdse
be
Can 4held isd-H Thereae
C-H, (CH,-cH, declaleA bond
Fom wihdnaus
e inthn d-C The
NaoH. dil.
bond
efxom
Canpand
being
CHO Ch, + HC- -CH,
paaduct alclol Seif- Callad
ct heo Caclen aldol Ln ased is Camousd
H H
tone Noe Cnplaàn
tha
anpand asdanyt
watlr lose Mdol The
(23
19/10
Page age Date
Date
Dote
 Date
Poge

di', Nao

- co-O
- cH -COcH

Nok COss - Alsol Conceasalin

Munroducks e dbtaney
Ada onensatiDD

-CHO CHa
dian CHa-Ch =CH JUf aldo

+ CH,CH, CHo CH, CHa -CR=C -CHO oduct

Electnophili'e Shsitukion Boa.

eH, G-CH- CHO
eleuophilies
CHCH,- bH- CH-CHO produc
0H
CHO CHU

+ ConC. HNO, t Cnc. HS

CaniLz ano
idekydeskich dac' H CAReOXyLIC AC ID - Oic Qc u2AC
Concaatoale
alkati
 Date
Poge
Dals

HCOOH MethQunoaacid CFaxoicacd) |u.

(acenc aid) CHhanaic Qud. 16

-COO H

CH-G-C;cCO3-matalbudancic aeid.
16
ocoM
4- Amin bdania Qad
COo

COOH
Dae Aer Puiavocaha
Lpaialic acia)
19. Ph- CHCH Co0H

o.CHy-ÇH -CoOH. ylaay-apaaic aid

3-diucthyl butaneic aid
ap- 2-esic acd

CHCH cH CoOH But - 2 - enoic aid 2- methyl Gyclo pertana caboytie

4. CaHo CH CH CooH. SPheaylpup- 2-enaic Qcd
23
COOH
Iaand 10. aid acid
HC sC -CoaH

14. H00G Cthane -12-dioicaid 24 Coan - CH, GH (CooH) H, CoOH

(onaic acd)
2
12.HEO0G - CH Co0H popane -13- dioio aid 1,2,3 ticathusuylie acid
Propano - 1,2 3 -

CH- CooH
13. peatae 15- diosc acd
5
CH¡- c00H
 Date
Poga
AL eabove
STRUCTURE CEGARBOXL DE GROP On
iVenason. KOH
Why i Cakonyi. Cankon_les claeinaphiiG. tsan. Qid a puoduct SH0 dil NaoH
Cavtony Canban

Cantaauylie cid then to

Canbonuyuc Canton Canton
CH, coN H
EHonoi bile
EHanamido CH,CoQH +NH
CN

Benzo nitale Benzuic. aicl

t NH

Canbon nutnlileL dho

HO
CH, Co NHa
Ethan amide

PrepanakOn -Etnaayl chaude

CooH
1alcool 2Ce CoOH
9alcahol tentoG

KMO, /H*
GçHCH,o4 Cate Coc t OH H,0 CaH CoDH! HCL
8 Bentoy! Chuo ride
CHy CCH), CH,oH CnO- H, s0,
Ben zoic ethanic
-ahybide
Fom itilee Acid halde
(Cyaniole amide

ajd anbydu de ester

(R-coR')
 Date
Poge_
CHS CEO
Pons
KMAQ, oH
Acd hydaolykic OE ester gvet cavkonuyic acid
dinachly
Dhich on aadhcaton
From
Gougoaed eageat
Dae
Sio123
Carbon dioudain
Na OH adeitoo paduct wich on
CHyCH CH, Coo Na Cid.
CH,CHaaH, CooH +COH

3 alKyl ben tene :

CHa- C -0H+ MoH)87r
Anomatic Caxbaaylis Qod is epaned by
olkalinL. KMaly Mehod i used fon

Atehalide
Q. Convent BHoMAe hse paapanaic
KM,Ou -kat
dry ethen

try etmer

KMao, oH
 decxeaei
qmup haligeA bw
distance the A3
aidity
Ha
aeicihy he
iocxeasel
Qidi thiDALALeA
e CODH n bOnd O-H
alaual Capanad
to
e
alcohol than
H
phase apoun indiniei ar ab
eoist It
naleculn
H nto Ston
goa Boilang
1.
ae
phenol maaidic
than sCOoH
PKe cuw dry Mg+
Qid the Snmalen
value
ka cE the GAlater NOte
homdbenzene
to
Convert
H,0 RCoD benzoic
Date Page
Date
 t4eald. ith auca
qives.m kaisk
hich ded in each pain id shong
SECahendlcide
CH, CO,t. CHCOOH_t..auco
CH, FCO, H On ClaCA CO, H
CHcmCM,C0,H Beaciontinvaugcuaag,aand
Esterificatioo
id t
CooH
CH -

CooH is heaed
asaabydaide is asaud
Raacionining chaua
2Cta CooNa t H, ‘

hali

NH,DH
Canbanyic eid peact ith
Beac cith Cankengte &kicaxtonat Pcla to aud chloide
 Dote
Poge
CH, CoOH
CH CH,04
CHC004t SOCkg
CHC00H pclg

o alkane
aid

amonin salt hich on heating lnace a naolacale

Amethad to CoNert CooH to akana with 1C

CHaCaOH t NHa
-elharide Convent thaNgio aid to Mohane

-NH
Benzaido aoH(a

Hvz GHel volhard

taiacid

dhala Cankaylil
Phthalimide henenas FOnmula
amide
red PhasateACH CoOk

5. ucHion
Reuckon cankanylie ad
rud P, Ho
CHa CoOK tCL
aleahol
 Date
Page Date

CoOH CH,0H
CH,CoOH
andto
-COOH

3-NitobHomobenzere t0
puduct 3-ito benzoic acld
dty ehor

CAS heoc ? H,0

CnOM den't wndergo Luidee NO

bon dod to coOH

CO0H

CocHa

Niakon COOH
Conc. HNDa + GH CoOH
conc HS0,

Sulphondtion

CoaH

COAent A) butang-1-ol to batanaic acld.

CHa r CHa -CHy-cH, -OH

Bulanal to butanalc aid
cHs-CHs-CH- CHO
CH-ct, -cH c00H