Alcohols Phenols Ehos

Paga
Date
Page

AMcohal R-OH An’ Jarup

An - 0H
SbenzeN CHg
R-0-R

Dat-2s/0g/23 alcahal

Phene
#Clasigcatag OE alahol -OH attobed to sp²
to anamaha

1 Ncaghydio dbyd

: OH
(5) VinyLic alcohgl
1
grupdiecy atacked ta
OH

CH OH
OH

Clausihcahan Ehen

(a)
Poinanyaday 1. Sinaple yeticel.
both
- CH;OH -CHOH
CH- 0- CH
3)
alcohol
aup atached o Sp Canban hith in
tuno isatached to inad nsynaefaical ctherz (R-oR')
amarny AIyio
CH, CH -CH, OH
 Date
Page

pote
Page

Alcohol

Aaning paly hydaie panet

whiten
alkane nct dzoppld - CH-CH,- CH-L
CH- CH
diol
Ch,-oH

R-metyl Gyclopentanol
()

- CH - GH
2,2 -Dinatayl papanal CH- CHs
CHa
2-150proPyl pentanL
MO Hhanol

22.3 Tnimethylpeatand
cH,

S) CH- CH -'CH Papan-2-0! (soproryl alcana) NOMenclatuns OE Ethers Phenals

CH3

CCH) C- OH 2-methylpapan 2-01

(tert buty! atconot)
) CH, OH - CH OH) - CH, OH pnpane -12 3 -triol
tm-CresOL)
reta

Bn

Hex- en3-0L
3achlaHaphenol
OH
Nomonclatue cthens

.4,6-initophenal
NO,

Diathyletham.

2.6-dimkalphenel CHa0GaHs

OH

Benzeng -1,2-d0T
(Catechol
IUPAC Name

7 ianqest cicaaia
Benzen-3-dnl
OH ChesHCina)
1.

Methnethane

3
Phenayheazene
Chnisole

beazent 1,4-diot Phenetole)

Cquina)
Chydzoguicaas)
 Pru

than H
hedal De The tanlesthe The STRUCTURE
C-0-C
Dueto
to (Alcaka)
MethanolWhy
atom
bord uonancein
TIONAL
ELNC OF

tetsahudlangl bord

inCO
Chanart CPhana)
Dhenol pheral in GROUP

apulsian
 Anechanium
Data
Name Heac'
Page
Prte Dale
276/23 Pace

Step-3 Da-potonaton to foYm alcohol

XX
H
G) 0m alkens OE akon
H+

IuPAC padut tocaed

7Dibatane Heacts Hh Kene to

aa addi Hon panduct Ahich on ouid

aohal

Nole Hae add Oe koans to oubl ord takes place

Chene) to Eoxm allahol n uch a u/ hat bonon
Of alkne
double konded

(hydronim ion)

H BH

Xy CH-CHCH
X

Carbo catoo
CH,-CH ECH
Step-2 NNclaaphlit atack Carbo Cahan 3H, ,aq.NOH
get pattonated aleahol 3CH CH CH,De
Thi alkyl hanaae
-r-6A HO H-C-c-O-4
H

Protenae aleoha
 R
Buutar-0 Budanal
Butaoal reducion
of Catalytil
hdteuct pndut oE nam fupAc. tuctune.
and Give
Torynea
X -Mù=0t
-R
ram
Cady adducd fVes
an up
yl Onhick Heageat
to iagnand o£Nuclapiia
ade
P
d rabd" cleaphii, machaaism
fot white OHCH, CHa Pt
Adekyd
alcobal
ed
H
alcohel nLauch0n ketone
>-CHaoH -CHD
age Ginignand ede
()Fx0m
alohol
alahal aid
Clcolol
R-ch, RCO0
R' R'oH RCoOH
t
Ha/Pl
Naau
ethanic ketone
CHCHOH
HeducHon
Of
Dote Page
DaBe
 Dal
Dole
Page
Pags

Adduct
Ohanol
(ronasthyde Lalechal Prepanahan of Phenol -

H-CHÖ # DOw's proCeRy reFong to preu. Chapterr

benzano
3° alohol ConvemE Beo zenl to phenal
’ BeazenL iL Aaphonaked with olen CHs, 0,) to
Beazene delphmic acd Which 4eet whan
dy ehor traatditth aat Slum pheaaside
ahich on

Oleum
Segt -NaaH
ONa OH

dy eher,
Eom Cumene

to

CH, -cH-OH + ytepesonle Whichdo teatmtAt

AJiH dlute acd
CH,
HC- C-0-0-H

TuPAC ame H*/H,0

Cumene

dry ehen
bom nilone

Nacl OH

+ NaNo, + HCL Q13-213 k

t HCL
 Dale
Page
Data
Page

24

eher why?
theznl Sbong inten malecutas H
n BCaz
Bp Aandig
R-0-- H--Q-- H-0
H

No4e

anpisd Caxbasayti c oid > aleahal Kelone)

CH - CH = CH,

oH,--0-CH, NabHy CH, -CO0-CHa

Solubilihy
ohetone i3 edued 1St. Soluble in aten
NaBH,
alcohol phenol
CH-CH,- CH -CHO Can H- bond oit aate
CH-CH, - CH- CH, OH
CH
B.P.
Butan- 1-0
Paapaa - 1-0l me thanol

CO Boiting poist methaol ehanol Popan -1- 0L < Btan-1-00

Nole
Pentan -1-02
Nanderuauk
0- butane Pentan1-0 pentanal
dofe
incKease in D-butane <le thomy ethane< pen tanal KDentan t-o
decxease n 8uface ea
 Date

Chital prplnhl5nPhenou
NaaH

phenals.
Phauda
abucleaphiles - ashenalHOact wh Nach which c a base
I Alcohals

alahas doadt eact

act
nucteaphulee
6AICahols
mechansm
QH

Nuclenphle

O-H
bond Es1eriGation

mtaU
netal to give

Aicoluols phenalA heact with

’ 2R- ONa beid chinzile n aid anhydideia as0ca

etiancate

o+ aNa IuPAC. lada wi th Qate

aylaaaaeQate Celiea)

alminium tent butonida

 duys aoalagesic uces
Ha CH CHCH
CH- HatcHa cH-CH, CHy-
Dapit poduca acidSalicylic Acattainn
OH
Aaylain
lker& Halo
halide
- ymith Aac 1
bond.
anuDlNing heac EtamplA
on
HCL CoCL CH,- t+
chloside acid with Phenol
aleonal
fokaed HcLDPLbxale
hol alco nat Proto
R-CH, ete4
ehlaide acid heact pheael
uith
Step'I
kaken (C-ois mechanilm theEaplain
eetophile as
AlCohals I
ebanoate
aypiin CH,CO N
+
COoH OH
H
Page
Date
Page
Date
 3
acohol pate
Page

dshinguish
tur h
-H¡ CH;- CH= CHa t H,0

iotue CHe- -O)

CH,

aleana
mmediate
kusaidiny
the mechandsm on acd catalyted hybah
ashangl
n e minute
Sec. 41cohol
SAep1
H

H- c- c - H
H c - C- 0 -H H
T
H H

Pro onatd alcohol

d. lRpacton ith phesphXAS halide thonie ch oh.
(SOclg) Step :2
hucen thaln-allones - Slowe t SteD hate

3ehyaio H
H
Slow

3 Canto-cahon 8 MOSt Stable

H
Conc. Hy sy H-C= C-H

H
 Date
Poge
Dale
Page

Ooudaton AMcohols aleohol

formaka0
Ctl, CH OH CH, - Co04
O-H C-H berd

a CHa CH, 0H PCC CH CHO

H-Ç-0tH
Mehanal
(Frmaldehyde)) Cu,CH CHO

are aluo callud dehydkagenairn

4 CHa - CH CH CH OH PC ’ CH- CH 5 CH CHO

Lsed
addic Cu/s73K

Pcc ’ Pundininchlanocimamate 2 acohal

1 CH- CH CHy uC-CH

CH,- - OHt H-a

ashol
(o) - CH -CH Pcc /Cala CHC
alcnkal PccCnlg,Cusi 3 CH, - CH -CHa
OH
2alahel aleael
CHg CHa
+ Ha0
alcohol Pcc /Cnls, Cu/s72K
keare CHa CHs
3° al Cohol Culs34
 Date
Pag
Dat
Page
Cas be used
Ooiolahon rec QPoedict themajth. paduck oE cid
etyyclahenanalcatalued
alconol

kyeatin.
CH OH CH

Sal.
HCI- Znc,
CHeMICAL PLOPERT es PHEN
1 OE phenal uith ioc dust

SOcLe
+ Zn
4.

NO eas
HcL- Zocla . Convert phenol
CH CH¡CH, CH, Okt
to ben Zene

Lucw
Onidation Phenol
’ CH,CH, CH, CH, BA t Ho

2- methulhutan - 2-0L
CH4
HCI-Zrds CHa C- CHa - CH a anjugattd diketon
t3. Kolbe's Aeacton -
CHo
2phepaakon Eram phenol

Pheaol hoa treakd wito Sediun hydooe Sodium

phenoaide. foMLd Whico ohea
 Dais
Date
Page

Cool Reac 1nPhenol -

G)CO,
t Naor G)

Ans esOnanco Stchwe phenel)

[azbon dioruce Why tauc tul thena
ion teatdoitt
densiy at pana Posiilns
phnwsida ion beng atack
Conpanid t phenelheachve touandu electaphius
Substiton reac

1. Bomí Naion

Phenal 1Oth Bromina L2ates

/Pate
10/3 oder

to tae For Of 24G tribtona phenal

Rieme Tieman0. Reach0n
(Suugldelye OH

t 8r/H,o

kenzgl clhlaside ie pnduad tohitePt

OH Na
Phenol lhen txeatkd uoith Ghanaing in preseace or
CHC, ag, Na NaoH
On CHcl4
are Obtaised.
&ub benzal chlorido
OH
Ccly /Cs / cHCs

Majoa
 lewis Ocd ’ e pain ocep tor
bose e pai ono
ochvaing Date
Poge
Date

takel plaei the OF_ACahel Phena

6
Liu's acd Cashy AICly ths aciia Chanaclen, o
2muoc" to prave
phendl.

R.Ntaton. Conc. HNO to

Phenal heactk
OH nletat

ND,
aleahalPheal act Aran ted acid
Picrc tt
CH'done)

3 base.

isome&_OE
Q3.Cnplain the OE phena
hittphenal
epanated by stea
H
distlato0
moeculan H-bonding hile pana i ey alalile
inten saoleaLanHlondin
*OH

(it
 Dat
dornating CI)
Psge
Date
Page

Which. as hy ale idic that phenal

tesanan Stabilized H clLolCde ion

whichI not esonance sfabilized

hyteidsed + HH
alkoidejn
Cak phunal hch n
LOhenea Phenaic ia neoraa Stabil zod
0f plånal o phunamide
n incned ionilaticn
Lnalcokal Hhe e
denaing
onlbaton
t H
Oyglo atim hich mLans
OH botd motc dieiCalt
$0 alkdal hae
Phenoide lon
Rosonance St tnl
XX

Date

Lkoioe
6.
Why phena Tide ik mote stable hantee ian
Ans

phencidi

kases than
kodium eHhaoide i aa ctengea base tan lodiun
ha' yaoide ?
 S0y HaConc Cdcease)
d
H¡ lant with heated alakal
is When
turg inWkth bond CH E
Pate
1>2)3
SOME NIEE
S
phenlOrhanitno band OH
danatig
eaal yataphiaal 3ysdini QcakolL
Phenal phual
<Ythyl -al Papaa
uerkKA alcohok
ater han
pheel thiaitro incteai!.
24
-10l Pipane
anacte acid Onden
cE H,0 R-
OH t OHA-
PKa
7
) Pkaflog
 Data

Page. Date
Page

Wiliansons Synthesil
holide with
&odium alcomide
ConC HasO,

Subshate Nuclanpile
tbase

eliminatnn halidea ane

huaachagaa

alkeat
alehel Jodica
ehana Stng Aulenphile 50 iminatln paaminates
RhstittnA alkenlA fae Product

CHa I t Cah 0N.

protenak alcalaal
(CH Co No t CH, Brn

lec ond alu to.

PcH
H

Prupanaten
Oihan san's Syattela
H
 Date

(aniiole)

astong aucaghila
baeso liminakan 2edarvasal ubebtu?

Piysical popenhes ehen

iaten-puollaulan H-bnndiog

Q.eHhen i misg ble waten

te eisabeheacfon tepdepa
Lthen