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  • Reaction of Aldehydes

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    Joko Susilo
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    This document summarizes several common reactions of aldehydes: 1. Aldehydes react with Tollens' reagent or Fehling's solution to form silver mirrors or copper(I) oxide precipitates, indicating the presence of the carbonyl group. 2. Oxidation of aldehydes with acidified dichromate forms carboxylic acids, while reaction with iodine forms alkyl iodides. 3. Aldehydes undergo reduction by sodium borohydride or lithium aluminum hydride to form primary alcohols, or hydrogenation to form hydrocarbons. 4. Reaction with 2,4-dinitrophenylhydrazine

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    This document summarizes several common reactions of aldehydes: 1. Aldehydes react with Tollens' reagent or Fehling's solution to form silver mirrors or copper(I) oxide precipitates, indicating the presence of the carbonyl group. 2. Oxidation of aldehydes with acidified dichromate forms carboxylic acids, while reaction with iodine forms alkyl iodides. 3. Aldehydes undergo reduction by sodium borohydride or lithium aluminum hydride to form primary alcohols, or hydrogenation to form hydrocarbons. 4. Reaction with 2,4-dinitrophenylhydrazine

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    © All Rights Reserved
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    23 views1 page

    Reaction of Aldehydes

    Uploaded by

    Joko Susilo
    This document summarizes several common reactions of aldehydes: 1. Aldehydes react with Tollens' reagent or Fehling's solution to form silver mirrors or copper(I) oxide precipitates, indicating the presence of the carbonyl group. 2. Oxidation of aldehydes with acidified dichromate forms carboxylic acids, while reaction with iodine forms alkyl iodides. 3. Aldehydes undergo reduction by sodium borohydride or lithium aluminum hydride to form primary alcohols, or hydrogenation to form hydrocarbons. 4. Reaction with 2,4-dinitrophenylhydrazine

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    © All Rights Reserved
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    Reaction of Aldehydes - Must know reaction

    O H 3C C O OH

    H C O – Na +
    KMnO4 or K2Cr2O7 O
    I2
    dilute HCl
    CHI3 (s) NaOH (aq) heat or reflux H3C C O –
    warm

    Fehling’s solution or
    Tollen’s reagent warm
    H2
    K2Cr2O7, dilute H2SO4 C
    OH
    reflux with immediate distillation
    H 3C C H H 3C C H
    H
    NaBH4 (aq), r.t.
    or 1. LiAlH4, dry ether
    HCN 2. H2O, r.t.
    trace NaCN or or H2 (g), Pt, heat
    2,4-DNPH trace NaOH
    r.t
    10-20oC

    O2N
    H3 OH
    C
    H H 3C C H OH
    H C N N NO2
    CN H3C C H
    H

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