ALCOnOLS

PRERE PARA TLON OF ALcOHOLS

h a Kon
CHCH, - CA
CM-CH tC2
OH
HsOyC-CH-CH

CHy-C = C2
oMDM Ch-M -C
-CA
O
P on HBO
REO C-C C-OM
1 / alk. calk KMnoy
Bayens Raapet
CM- CH-C2
CM-CU = CH
o OH

OH
RCOOOH
CH CH,
-On

MCPBA
-C0-0- H.
C-0-0-H

CL
meta- chWoso peroxybenzoic Acid
 ay. KOH
R OH S as

fro Gben Co

LAHy
>CM- OHH

m Aid

R-CooM Li R-UH,-OM

rom GRIGNARDS REAGGE NT

RMaX

RM
-ox
R

| HO
C-OM++M on

1.RgX X
R CH -OM
2 HO
ARc

CH-OH 2 Alc.
K
c-6 C =0 - C-OM Mc.
R

ee

- oR

C OR OR'
-C=O
R R
R
K
C-o RMa OR

C-OM

-OR Krgx RA
H- CH-OH (2ALc)
2 ,O

R - OR
C-OH
(M)
ep ep xide

oyX
Me Me Me C CH- R
Me
Me Me
 Me R

Me Me

Popecties of ALcohol

R-O-H Zo

H, Me
-

RO
,K = t

- (5.S
+H K = lo
CHOM
 67 2 > 1> ? > S

CH
2 CH O

* CH OH 77 CH-C"2 OH> CH-CM -Ou

3NM

Me
Me C CH
SHE CH
Me
HCOOH

CMCoo * Peente of
gCns-0H te t ecrease te acidicc

Phensl s mane acidie than alip Latic

On AL
o Ht

nOOC CH
CHO
OCCH CHOH
2 mal. of
MCEC NoNH
MCEC
O
 R -0-M

Cn--OH

C CH O
 - H
DO on
R- C - OH
R C O R- C On

. 182
R -0H
H
R -C o-R

* Reartiity Aid
CHCo0H
CoOH
HCOot> CM -
 C

C-COOH,
CM

*Reattivm Alcohsl

M
C - H - B0H > le-c-o
H CM-1-on>
Me

Baed upon
Nuleopilieity,
 Me

Me Me
Propercties of ALahol -

R-OH
RO H, Me ,k =10- to

-O K IO

- (5.S

o H

* £steifictim (Net in
iead)
ROH +RCooM R'CooR +

ROM +RCooM

8
R-C on+ HloR R - c-o'R

Mech
- R-
R-C-0on R-C+OM,

18
R C -R
 e yla-titn D

R CH+ C-Ph R-0 C -

Ph
11

O
C - CA

Acyltim

R-O C-R
+ R
R -O
-

H
R

R C- C

Rta ttn Canb o o + OR

R-CAD 2 ROk R CH Acetl
H
C0 + 2 ROH Ketrl
OR
Reac wth Giuard_leeget

+ R-H +Ma
RaX R '

Ren due eledage of R-¢ on

Noll+H2s0y
R-

A Zn U2
R-On C. HCA R-

PCA S0d2
R-

Oxidati afAlcslusls-

str O.A

KMO,Ht
 11
R C - On R -HO p-Coon

R-CR
C - OM

R
C-OM No Real".

Mid O. A
Usi X2 /OH

2 Collen's Reaget

PCC

R-CHO
R Cn,On

R
n-0bM =0

No Reac".
R C-oH
 CatDeydkagengtio
Ree Cu/3ooC
CH--

C
Cy-H

C +M2O
Ch -OH

cHy
ekydatio,

On

CH2-C -
C
TEST OF ALCOnOLS-
TEST
R-OH Na RONa H

CAN
R- OM
Cennic Am
Reolauh
Nibate

Dis-tinetim ,2 S Alc
LLAs eaet
Studied in ALkyl haltdes
 Victor Moy
*
st
Pes
2/s Ale. Et BJu e

3/T A
RBC

R CH2 -OM P+T2

R - £

ANO
R M,- NO2
Tauto e

R - CH N=o
R-C = N- 0H
-

NQ HO/so)

- H -N- R C H - N=6

NO N 0'

Red Colsus Non

R C -N O
N -0H

(Nithelie Actd)
R n DM > -u-T Ag
R

NO

R C= N 0H

K-C N 0VV
HoNo
|-Ho

N O
Blue olsun,
R C NoOH

A O
-I R-CN=

ReaRea tim Vicind Di-ol

Oxidacbism
HIO, (Peiodie acid) ov P& (04)

CH,-b
O

CH-bM
*NoTE OND. xidatio b HIOG
2 C OH
Atleast 2 oH
o ould dya cet Cabon
e

OH OH

2 C d + CM
CH -0 H

=0 + HCE0
2 h

C =O

CH6M
avieaumanzi

C - 0M

On VoLe o 4CH-
C - ON

X
CH O CH,-on
on
CM -O1

HCHO
Ques

On

2HCH6
CM 6
HLO
On
on
3 C +

3nLOOn
C -0H - OH
OM
H OH
C-O

Pinacole- -

Picalone R e a a z e n-et.
O CMa
C. M, So4
Ch CH C-l-(
CHs
inacole Pinacaleme

HAy> Aky.

Mech OH
O
H

CM C C
H CM H C
CH-C C-tn C - CH-

- H
CM -
C- CM- Cn- C- CH-CH
1

D OM

Ph Ph C C-Ph
Ph-C
Me
Me

2
On O
CH C -Me
Me - C C Me Me
t

3 O
Me
Ayog Me C -CH
Ph-C1 C Me
Ph
Me

C-O
L
oM
on

ma