to Bromo-4-make

pent-2-yue

C -

4 = C-Ch
I
le
Br
 C
C4= - CH -

X B zo

*
L Allys Halide Benul Valid

-- CHO
Vine halide
-

L
- X
Los
I 23 4

2-Bromobutque

- Dichlorobenzen
2 ,

3 Chloro prop-tee Br
I
↳ CH
CH5-Cn-Cn2 Ch
I 26
,
 I I 3

CH2 =
CU-C4-Br
3-Bromo prop-1-24

at a
C-D
2- (Trichloromethe)
-

⑭
C
-hepta
-

- 2, 7, I 2 3 33
T , , ,

S Chloro propore .

9
-
 6 -+ >
-

Peroxide
CHjc C=
Pu (2 + H By >
-
-

A M R

·
: .

s
L

Chy-CH2-CV2-CH , O + NaO
-Br

*
accor CUs-CU -C4-CR-I
.

R-OH + SOU >

- R-C

·
+ VR + SOL
*
r (g)
T
96

because in this
reaction alkys
halide found
along with two
gaseous product which
are easily escabable
 ① es
Peroxid
CHy-CH=CU, + HBV -
CHy-CH-Cl
Br
·
- +
Ne
O
<

CHy-CH-Cl -
-I
E
· Br
&
[H1-(ks
x-
BV2 -- CH-C y

Los -
(C ②

an UV
list o No
,

cus-isMr + e

dus Bu
I

CUyoCU2 -
C ~
C
jus
Loke <I
i
-

p-isomer of haloarenes have

highest mot became

of their

symmetrical str and better

close
packing In crystal lattice

=> its
valogen abow become of
-
effect has some tender
to withdraw
eo from benzene
sing as a result bensee
some what gets deactivated
How are Electrophilic Seb Roy
.
 -

E + c
*H +uc
right

SN2 -
less steric Hindrance
↳ 19720730

2-Bromopenta S1 Bru -

De
S C
I
C-C-CC-C Garc-CfBr CofEC
&

Bu i
-
2 Bromo-2-methys <2-Brome 4 I-Bruno
butane pantal pentas

Br
iMgBr
Mg
-

Mg
-

-
L -
T
L
H OU
Wo
>
- # +
dry ther
 At ortho position , higher steric
hindrance is there hence
para isomer is major
product
-

⑭ C

-so
I I
CH
y e C-C-CUs
-e

°
-

⑫
°
-

->
-
-=>
-
"Ins
-

T2-Methy proparal 2- 01] -

 Ruloromethas has highes dipole moment -

of fluore
Due to smaller size the

dipole moment of fluorometer is comparatively

lesser
#
C CH -f
Ch -
,
 I +
NaoUcag) >
- No RyY

e clizon
I
Noon
L) + cas)
-
E
Benrys chloride is hydrolused easily
became bene carbocation fored
is more Stable

on the other Chlorobenzene

doesn't undergo nucleophilic
sub .
Reachor
,
became C-c
bonel have partial double
bord character due to
Resonance
vertig Haloavnere doesn't undergo Nucleophilic
Sub .
Row

,
became C-c
bonel have partial double
bord character due to
Resonance : ④: Q:
-
er
Ge
· C

a
If
X : E tell
II Is
s -
- -

Lix =s
·s
/

:
- I
-
Es
k'
-
oo -

>
- e
·
 4Us & most reachle toward
C--Br
"
Cus SN due to stable

Do Carbocallou forahve

Chlorobenze no Bishar

any
#c ↳ <E)
+ 2Na + U >
-

ethe Lo
-
=
Chlorobere Biphen

2-Bromobutane >
- but-2 ele

C
Bre
I
C-
Us CH-2-Cl
" tal Kol-
B 4
I
A
CHy-CU =
CU-Ch
,
 2 Chy- Cl-CUs A
an
Le
- eth

Choc
-
Cs
+ 2 Nach
CH, -
ch
Cls-ClrBr + AgCN
-
-

a CHy-CH-NC

CUs-CH-Br + KCN >

-
CHs-CK-CN
--
 B PE < Mol Man
. .
B P+ 4 +
.

Branchi

CUs-Cl-C4-CH-Bu CUs
-
C -
Bu
Cha
-

dus
-Butl brovide
being a straight
Chain molecule have stroy
inter molecular forces
Whereas -Butl brovide bein
a branched chain undecule
have low surface area
magnitude of ron der
warl forces is less
hence lower B PL .
 CKs-CY-Br undergo SN2 reach on
# faster became it is a palk
halide have less steric
hindrance
#
and nucleophile
attack easily

Ruf <R-4 [R-BU <R-I

CUs-Cl2-I would underse SN *

reachon faster be came Fod
a better leavin group .
s
&la f
·

ke
Those nucleophile which
have two attacking
Center and can attack
through two distent
sile
CN
C -

eg NC
 CUy-C + AgNOs -
CHy-NO2
Br
Ho
Br
I
Al -

↳ (4 -

AlUs
>
-

due

C2Us-C + Kon I
Cally-OM
cari)
TKL)

e
*
↳ + cco ty)
Als
/
i -- lock
+ H
joch