S GIO DC V O TO

THANH HO

KHO ST CHT LNG LP 12 NM HC 2015-2016

Mn: HO HC

CHNH THC
( thi gm 04 trang)

Thi gian lm bi: 90 pht, khng k thi gian giao

M : 154

H v tn th sinh:.
S bo danh:
.
Cho: Cl =35,5; Br= 80; F = 19; I = 127; S= 32; O = 16; H=1; N = 14; P=39; C = 12; K= 39; Mn = 55;
Na = 23; Fe = 56; Ba = 137; Pb=207; Cd =112; Cr=52; Mg = 24; Al = 27; Ag = 108; Ca=40; Zn =65; Cu=64,
Ne=20; Ni=59;
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Cu 1. Trong phng th nghim, ngi ta thng iu ch HNO3 t

A. NaNO3 v HCl c.
B. NaNO2 v H2SO4 c.
C. NaNO3 rn v H2SO4 c
D. NH3 v O2.
Cu 2. Cho cc cn bng thun nghch sau:

N2(K) + O2(K)
2NO(K) (1); 2SO2(K) + O2(K) 2SO3(K) (2)
Khi gim p sut th:
A. (1) chuyn dch theo chiu nghch; (2) chuyn dch theo chiu nghch
B. (1) khng chuyn dch; (2) chuyn dch theo chiu nghch
C. (1) chuyn dch theo chiu thun; (2) chuyn dch theo chiu nghch
D. (1) chuyn dch theo chiu thun; (2) chuyn dch theo chiu thun
Cu 3. Pht biu ng l
A. Cc protein u tan trong nc.
B. Enzim amilaza xc tc cho phn ng thu phn xenluloz thnh mantoz
C. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m
D. Khi thu phn n cng cc protein n gin s cho hn hp cc -aminoaxit
Cu 4. Cho cc cht: NaCl, CH3COOH ; ancol etylic; CO2; FeCl2, S cht l cht l cht hu c l
A. 1.
B. 2.
C. 4.
D. 3.
Cu 5. Trong cc cht sau: C2H6 (1), CH2=CH2 (2), NH2-CH2-COOH (3), C6H5CH=CH2 (4), C6H6 (5),
CH2=CH-Cl (6). Cht c th tham gia phn ng trng hp to polime l
A. (4), (5), (6)
B. (3), (4), (5)
C. (1), (2), (3)
D. (2), (4), (6).
Cu 6. Trong cng nghip, kim loi kim v kim loi kim th c iu ch bng phng php
A. thy luyn.
B. in phn nng chy. C. nhit luyn.
D. in phn dung dch.
Cu 7. Mt nonapeptit c cng thc: Arg-Pro-Pro-Gly-Phe-Ser-Pro-Phe-Arg. Khi thu phn khng hon
ton peptit ny, s tripeptit cha phenylalanin (Phe) c th thu c l
A. 6
B. 5
C. 3
D. 4
Cu 8. Chn pht biu ng.
A. Trong mt chu k i t tri sang phi tnh kim loi gim dn, tnh phi kim tng dn.
B. Trong mt chu k i t tri sang phi bn knh nguyn t tng dn.
C. Trong mt chu k i t tri sang phi nng lng ion ha th nht gim dn.
D. Trong mt chu k i t tri sang phi m in gim dn.
Cu 9. Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong dy tc dng vi
lng d dung dch Ba(OH)2 to thnh kt ta l
A. 5.
B. 1.
C. 3.
D. 4.
Cu 10. Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu c
dung dch ch cha mt cht tan v kim loi d. Cht tan l
A. HNO3.
B. Cu(NO3)2.
C. Fe(NO3)2.
D. Fe(NO3)3.
Cu 11. Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH,
CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l
A. 4.
B. 3.
C. 2.
D. 5.
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Cu 12. Trong khng kh m, kim loi ng b bao ph bi lp mng :

A. CuS (mu en).
B. CuO (mu en).
C. Cu(OH)2 (mu xanh).
D. CuCO3.Cu(OH)2 (mu xanh).
Cu 13. Khi cho Cu tc dng vi dung dch cha H2SO4 long v NaNO3, vai tr ca NaNO3 trong phn ng l
A. cht xc tc.
B. cht oxi ha.
C. mi trng.
D. cht kh.
Cu 14. Cho cc phn ng:

(1) Fe3O4 + HNO3

(2) Fe3O4 + HCl
o
(4) Cl2 + H2O
(5) C2H5Cl + NaOH t
o

(3) Fe2O3 + HNO3

(6) PCl3 + H2O
o

t , Ni
(7) MnO2 + HCl t
(8) C2H5OH + CuO t
(9) C2H4 + H
2
Cc phn ng oxi ho-kh gm:
A. (1), (4), (7), (8), (9).
B. (1), (4), (5), (6), (7).
C. (2), (3), (5), (6), (7).
D. (1), (3), (4), (8), (9).
Cu 15. Cho cc cht sau:
CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3), CH2=CH-CH2-OH (4).
Nhng cht phn ng hon ton vi lng d H2 (Ni, to) cng to ra mt sn phm l:
A. (2), (3), (4).
B. (1), (3), (4).
C. (1), (2), (4).
D. (1), (2), (3).
Cu 16. Trong cc cht Xiclopropan, xiclohexan, benzen, stiren, s cht c lin kt i l
A. 2
B. 1
C. 3
D. khng
Cu 17. Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu. Trong phn ng ny xy ra
A. s kh Fe2+ v s kh Cu2+.
B. s kh Fe2+ v s oxi ha Cu.
C. s oxi ha Fe v s oxi ha Cu.
D. s oxi ha Fe v s kh Cu2+.
Cu 18. C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3
cht
lng trn l :
A. giy qu tm.
B. nc brom.
C. dung dch phenolphtalein.
D. dung dch NaOH.
Cu 19. Khi nu canh cua th thy cc mng "riu cua" ni ln l do :
A. S ng t ca protein do nhit .
B. S ng t ca lipit.
C. Phn ng thy phn ca protein.
D. Phn ng mu ca protein.
Cu 20. nhn bit 4 cc nc: cc 1 cha nc ct, cc 2 cha nc cng tm thi, cc 3 cha nc
cng vnh cu, cc 4 cha nc cng ton phn. C th lm bng cch l:
A. ch dng dung dch HCl
B. un si nc, dng dung dch Na2CO3
C. ch dng Na2CO3
D. un si nc, dng dung dch NaCl
Cu 21. Hp cht X l 1 amin n chc bc 1 cha 31,11% nit. Cng thc phn t ca X l:
A. C4H7NH2
B. CH3NH2
C. C3H5NH2
D. C2H5NH2
Cu 22. Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca
A. ankan.
B. ankaien.
C. anken.
D. ankin.
Cu 23. C th phn bit 3 dung dch : KOH, HCl, H2SO4 (long) bng mt thuc th l
A. Al
B. Zn
C. BaCO3
D. giy qu tm
Cu 24. Cho cc cht sau: axit axetic (X); axit fomic (Y); glucoz (Z); etylfomat (T); axit glutamic (M).
Nhng cht tc dng c vi dung dch AgNO3/NH3 l:
A. Y, Z, T
B. X, Y, Z
C. T, X, Y
D. Z, T, X

Cu 25. Hn hp X gm axit axetic, axit fomic v axit salixylic (axit o-hiroxibenzoic). Bit a gam X tc
dng va vi 400ml dung dch NaOH 1M. Nu t chy hon ton a gam X cn 16,24 lt O2(ktc) thu
c 35,2 gam CO2 v m gam H2O. Gi tr ca m l:
A. 14,4 gam
B. 10,8 gam.
C. 18 gam.
D. 9,0 gam
Cu 26. t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri
hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v dung
dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no?
A. Tng 7,92 gam.
B. Tng 2,70 gam.
C. Gim 7,38 gam.
D. Gim 7,74 gam.
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Cu 27. em nung nng mt lng qung hemantit (cha Fe2O3, c ln tp cht tr) v cho lung kh CO i

qua, thu c 300,8 gam hn hp cc cht rn, ng thi c hn hp kh thot ra. Cho hp th hn hp kh
ny vo bnh ng lng d dung dch xt th thy khi lng bnh tng thm 52,8 gam. Nu ha tan ht hn
hp cht rn trong lng d dung dch HNO3 long th thu c 387,2 gam mt mui nitrat. Hm lng
Fe2O3 (% khi lng) trong loi qung hematite ny l:
A. 80%
B. 20%
C. 40%
D. 60%
Cu 28. oxi ha hon ton 0,02 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt KOH th lng ti thiu Cl2
v KOH tng ng l
A. 0,03 mol v 0,16 mol
B. 0,06 mol v 0,16 mol
C. 0,03 mol v 0,08 mol
D. 0,06 mol v 0,08 mol
Cu 29. Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21:2:4. Hp cht X
c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng
vi cng thc phn t ca X l
A. 4.
B. 5.
C. 6.
D. 3.
Cu 30. Hn hp X gm 3 axit n chc mch h trong c hai axit no l ng ng k tip v m t axit
khng no c m t lin kt i. Cho m gam X tc dng vi dung dch cha 0,7 mol NaOH. trung ha lng
NaOH d cn 200ml dung dch HCl 1M v thu c dung dch D. C cn cn thn D thu c 52,58 gam
cht rn khan E. t chy hon ton E ri hp th ton b sn phm kh v hi vo bnh ng dung dch
NaOH d thy khi lng bnh tng 44,14 gam. Thnh phn % khi lng axit khng no l:
A. 44,89
B. 48,19
C. 40,57
D. 36,28
Cu 31. Ly 18,20 gam C3H9O2N (X) tc dng vi dung dch NaOH d, un nng, c 4,48 lt (o ktc) kh
Y thot ra lm xanh giy qu tm m. t chy ht 6,72 lt (o ktc) kh Y thu c 13,2 gam CO2. Cng
thc cu to ca X v Y l:
A. CH2=CHCOONH4; NH3.
B. CH3COONH3CH3; CH3NH2.
C. HCOONH3C2H3 ; C2H3NH2.
D. HCOONH3C2H5 ; C2H5NH2.
Cu 32. Hn hp X gm Cu, Ag, Fe2O3 c t l s mol tng ng l 1:2:1. Cho 44 gam hn hp X tc dng
vi dung dch HCl d thu c cht rn Y v dung dch Z. Cho dung dch Z tc dng vi dung dch NaOH d
(khng c khng kh) n khi phn ng xy ra hon ton thu c m gam kt ta. Gi tr ca m l:
A. 27,8 gam
B. 24,1 gam
C. 21,4 gam
D. 28,7 gam
Cu 33. Hn hp X gm Fe, FeO v Fe2O3. Cho mt lung CO i qua ng s ng m gam hn hp X nung
nng. Sau khi kt thc th nghim thu c 64 gam cht rn A trong ng s v 11,2 lt kh B (ktc) c t khi
so vi H2 l 20,4. Tnh gi tr m.
A. 35,2 gam.
B. 105,6 gam.
C. 70,4 gam.
D. 140,8 gam.
Cu 34. Cho 19,2 gam Cu vo 500 ml dung dch NaNO3 1M, sau thm 500 ml dung dch HCl 2M n
phn ng hon ton th thu c kh NO v dung dch X. Phi thm bao nhiu lt dung dch NaOH 0,2M
kt ta ht in Cu2+ trong dung dch X?
A. 4 lt.
B. 1,5 lt.
C. 2 lt.
D. 2,5 lt.
Cu 35. Cho hn hp gm Na v Al c t l s mol tng ng l 1:2 vo nc d. Sau khi cc phn ng xy
ra hon ton, thu c 8,96 lt kh H2 ( iu kin tiu chun) v m gam cht rn khng tan. Gi tr ca m l:
A. 43,20
B. 10,80
C. 5,40
D. 7,80
Cu 36. Cho a mol Mg v b mol Zn dng bt vo dung dch cha c mol Cu(NO3)2 v d mol AgNO3 thu c
dung dch cha 3 mui. (Bit a < c +0,5d). Quan h gia a, b, c, d l :
A. b > c - a +d
B. a > c + d - b/2
C. b < c - a + 0,5d
D. b < c + 0,5d
Cu 37. Kh SO2 do cc nh my sinh ra l nguyn nhn quan trng nht gy nhim mi trng. Tiu
chun quc t quy nh nu lng SO2 vt qu 30.10-6 mol/m3 khng kh th coi l khng kh b nhim.
Nu ngi ta ly 50 lt khng kh mt thnh ph v phn tch c 0,0012 mg SO2 th:
A. khng kh b nhim
B. th khng kh c b nhim qu 25% so vi quy nh
C. th khng kh c b nhim gp 2 ln cho php.
D. th khng kh cha b nhim

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Cu 38. Ha tan hon ton m gam hn hp A gm kim loi kim v kim th vo 400 ml dung dch HCl

0,25M thu c 400 ml dung dch B trong sut c pH = 13. C cn dung dch B thu c 10,07 gam cht
rn. Gi tr ca m l
A. 6,16.
B. 5,84.
C. 4,30.
D. 6,45.
Cu 39. Nung 6,58 gam Cu(NO3)2 trong bnh kn, sau mt thi gian thu c 4,96 gam cht rn v hn hp
kh X. Hp th hon ton hn hp X vo nc, c 300 ml dung dch Y. Dung dch Y c pH l:
A. 2
B. 1
C. 4
D. 3
Cu 40. Cho Fe tc dng vi dung dch H2SO4 long to thnh kh X; nhit phn tinh th KNO3 to thnh kh
Y; cho tinh th KMnO4 tc dng vi dung dch HCl c to thnh kh Z. Cc kh X, Y v Z ln lt l
A. H2, O2 v Cl2.
B. SO2, O2 v Cl2.
C. Cl2, O2 v H2S
D. H2, NO2 v Cl2.
Cu 41. Khi t chy cc ng ng ca metyamin, a l t s mol kh CO2 so vi s mol nc bin i trong
khong:
A. 0,4 < a < 1,2
B. 0,8 < a < 2,5
C. 0,75 < a < 1
D. 0,4 < a < 1
Cu 42. Ha tan ht 30,4 gam hn hp gm CuO v FeO bng dung dch HCl d, thu c dung dch X.
Chia dung dch X thnh 2 phn bng nhau. Phn 1 cho tc dng vi dung dch NH3 d, sau lc ly kt ta,
nung trong khng kh n khi lng khng khng i thu c 16gam cht rn. C cn phn 2 thu c cht
rn khan Z. un nng ton b cht rn Z vi lng d H2SO4 c ri dn kh v hi i qua bnh ng lng
d P2O5, th th tch kh (ktc) cn li i qua bnh ng P2O5 l
A. 8,96 lt.
B. 9,408 lt.
C. 11,648 lt.
D. 11,2 lt.
Cu 43. un 132,8 gam hn hp 3 ancol no, n chc vi H2SO4 c 140oC thu c hn hp cc ete c
s mol bng nhau v c khi lng l 111,2 gam. S mol ca mi ete trong hn hp l bao nhiu?
A. 0,4 mol.
B. 0,15 mol.
C. 0,1 mol.
D. 0,2 mol.
Cu 44. Hn hp A gm CH3OH v 1 ancol X c t l mol l 2: 1. Chia hn hp A thnh 2 phn bng nhau.
Phn 1. Cho tc dng ht vi Na thu c 336 ml H2 (ktc). Phn 2. Cho bay hi v trn vi lng d O2 th
thu c 5,824 lt kh 136,50C, 0,75 atm. Sau khi bt tia la in t chy th thu c 5,376 lt kh
136,50C, 1atm. Bit cc phn ng xy ra hon ton, Vy X l:
A. C2H5OH
B. C4H9OH
C. C3H7OH
D. C5H11OH
Cu 45. Khuy 7,85 g hn hp bt kim loi Zn v Al vo 100 ml dd gm FeCl2 1M v CuCl2 0,75M th thy
phn ng va vi nhau . V vy % khi lng ca Al trong hn hp l:
A. 17,2%.
B. 12,7%.
C. 27,1%.
D. 21,7%
Cu 46. C bn thanh st c t tip xc vi nhng kim loi khc nhau v nhng trong cc dung dch HCl nh
hnh v di y.

Thanh st b ha tan chm nht s l thanh c t tip xc vi :

A. Sn
B. Zn
C. Cu
D. Ni
Cu 47. C x mol hn hp 2 kim loi kim thuc 2 chu k lin tip (hn hp X). X tc dng va vi dung
dch HCl thu c a gam hn hp mui clorua khan, cn nu cho X tc dng va vi dung dch H2SO4 th
thu c b gam hn hp mui sunfat khan. Gi tr ca x l:
A. (a+b)/12,5
B. (2a+b)/25
C. (b-a)/12,5
D. (2a-b)/25
Cu 48. Nitro ha benzen thu c 14,1g hn hp gm 2 cht nitro c khi lng phn t hn km nhau 45
(u). t chy hon ton hn hp 2 cht nitro ny c 0,07mol N2. Hai cht nitro l:
A. C6H4(NO2)2 v C6H3(OH)3
B. C6H2(NO2)4 vC6H(NO2)5
C. C6H5NO2 v C6H4(NO2)2
D. C6H3(NO2)3 v C6H2(NO2)4
Cu 49. un si 15,7 gam C3H7Cl vi hn hp KOH/C2H5OH d, sau khi loi tp cht v dn kh sinh ra qua
dung dch brom d thy c x gam Br2 tham gia phn ng. Tnh x nu hiu sut phn ng ban u l 80%.
A. 16,0 gam
B. 25,6 gam
C. 32,0 gam
D. 12,8 gam
Cu 50. X l hp cht hu c cha C, H, O. Bit X c phn ng trng bc v phn ng vi NaOH. Nu t
chy hon ton a mol X thi sinh ra 3a mol hn hp CO2 v H2O. X l:
A. OCHCH2COOH.
B. HCOOCH3.
C. HCOOH.
D. OCHCOOH.
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