%(P/V) m ρs(g/ml) ρ0(g/ml) φ(ml/mo

2 0.3430 1.0101 1.0108 0.9976 21.6968

4 0.6861 1.0264 1.0243 1.0236 1.0221 0.9976 15.9430
8 1.3722 1.0514 1.0515 1.0511 1.0510 0.9976 18.2042
12 2.0582 1.0736 1.0719 1.0758 1.0754 0.9976 19.9599
16 2.7443 1.1012 1.1003 0.9976 18.7077

m φ(ml/mol)
Volumen molar aparente vs. molalidad
0.34304 21.6967696

Volumen molar aparente

0.34304 19.6581119 23
0.68608 15.9429749
0.68608 18.9711029
0.68608 19.98324 22
0.68608 22.1567736
1.37216 18.2041927
21
1.37216 18.1329863
1.37216 18.4178932
1.37216 18.4891539 20
2.058241 19.9598585 f(x) = − 0.543426389614112 ln(x) + 19.3445706785038
R² = 0.062413773233165
2.058241 20.7639138
2.058241 18.9230887 19
2.058241 19.1112768
2.744321 18.7077411
2.744321 19.0218154 18

17

16

15
0 0.5 1 1.5 2
molalidad (moles soluto/kg solvente)
 φ(ml/mol)
19.6581
18.9711 19.9832 22.1568
18.1330 18.4179 18.4892
20.7639 18.9231 19.1113
19.0218

1.0105 20.6771
ente vs. molalidad
1.0241 19.2601
1.0513 18.3110
1.0742 19.6885
1.1008 18.8647

Chart Title
Axis Title
.3445706785038 21.0000
20.5000
20.0000 f(x) = − 0.688857706474054 ln(x) + 19.443
19.5000 R² = 0.423556416549436

19.0000
18.5000
18.0000
17.5000
17.0000
0.0000 0.5000 1.0000 1.5000 2.0000
Axis Title

1.5 2 2.5 3
s soluto/kg solvente)
rt Title

88857706474054 ln(x) + 19.443104364505

56416549436

.0000 1.5000 2.0000 2.5000 3.0000

Axis Title
%(P/V) m φc(ml/mol) Ū°1(ml/mol) Δφ/Δm Ū1(ml/mol) Ū2(ml/mol) VTG(ml)
2 0.3430 19.9260 18.0592 -1.5829 18.0625 19.3830 1006.8349
4 0.6861 19.5496 18.0592 -0.7915 18.0659 19.0066 1013.4117
6 1.0291 19.3294 18.0592 -0.5276 18.0693 18.7864 1019.8909
8 1.3722 19.1732 18.0592 -0.3957 18.0726 18.6302 1026.3069
12 2.0582 18.9530 18.0592 -0.2638 18.0793 18.4100 1039.0072
16 2.7443 18.7968 18.0592 -0.1979 18.0860 18.2538 1051.5809

Vol. Total (calculado)

m Δφ/Δm y = -0,543ln(x) + 19,345
x y'= -0,543/x φc(ml/mol)
0.34304 -1.58290578 19.9259602 Vol. total calc. vs
0.68608 -0.79145289 19.5495812
1050
1.02912 -0.52763526 19.3294137
1.37216 -0.39572645 19.1732023 1040 f(x) = 15.3274301641757 x +
R² = 0.996549369978435
2.058241 -0.2638175 18.9530345 1030
2.744321 -0.19786315 18.7968232
1020

1010

1000

990
0.0000 0.5000 1.0000 1.50
mola
 %(P/V) m ρs(g/ml) ρs Promedio
2 0.3430 1.0101 1.0108 1.0105
4 0.6861 1.0264 1.0243 1.0236 1.0221 1.0241
6 1.0291 - - - - -
8 1.3722 1.0514 1.0515 1.0511 1.0510 1.0513
12 2.0582 1.0736 1.0719 1.0758 1.0754 1.0742
16 2.7443 1.1012 1.1003 1.1008

Vol. Total (gráfico)

Vol. total gráfico. vs. molalida
Vol. total calc. vs. molalidad
1060.0
1050.0
f(x) = 18.6154384141889 x + 1000.6287004358
f(x) = 15.3274301641757 x + 1002.49068872115 R² = 0.999939671309027
R² = 0.996549369978435 1040.0
1030.0
1020.0
1010.0
1000.0
990.0
980.0
0.5000 1.0000 1.5000 2.0000 2.5000 3.0000 0.0000 0.5000 1.0000 1.5000 2.0000
molalidad molalidad
 VTC(ml) VTG(ml)
1008.14087 1006.8349
1012.94003 1013.4117
1018.274 1019.8909
1022.31037 1026.3069
1035.26495 1039.0072
1044.20406 1051.5809

fico. vs. molalidad

141889 x + 1000.6287004358
309027

0 1.5000 2.0000 2.5000 3.0000

molalidad