Q 40 m3/h Recuperar 90%

T 20 °C
P 1 atm
G 1664.011182mol/h

ARRIBA ABAJO
L0 G1 1139.85 LN GN+1 1664.01
Ls Gs 1081.61 Ls Gs 1081.61
Lg0 Gg1 58.24 LgN 524.16 GgN+1 582.40
x0 0.02 y1 0.0510948905xN yN+1 0.35
X0 0.020408163Y1 0.0538 XN YN+1 0.5385

YN+1 XNYN+1 0.278 0.5385

X0Y1 0.0204081630.0538

(Ls/Gs)min 1.881330522

Ls min 2034.860767

Lsmin 2034.86
Ls/Lsmin 1.35
Ls 2747.06

ARRIBA ABAJO
L0 2803.12 G1 1139.85 LN 3327.29 GN+1 1664.01
Ls 2747.06 Gs 1081.61 Ls 2747.06 Gs 1081.61
Lg0 56.06 Gg1 58.24 LgN 580.23 GgN+1 582.40
x0 0.02 y1 0.0510948905xN 0.174384064yN+1 0.35
X0 0.020408163Y1 0.0538 XN 0.211216931YN+1 0.5385

XNYN+1 0.2112169310.5385
X0Y1 0.0204081630.0538
 pendiente intercepto
2.5397962040.002013578246

Psat 76 mmHg Q 500000 L/h

P 760 mmHg P 1 atm
K 0.1 T 293.15 K
G 20.80 kmol/h
Recupera 0.95

ARRIBA ABAJO
L0 G1 19.61 LN GN+1 20.80
Ls Gs 19.55 Ls Gs 19.55
Lg0 0 Gg1 0.06 LgN 1.19 GgN+1 1.25
x0 0 y1 0.0031813361xN yN+1 0.06
X0 0 Y1 0.0031914893XN YN+1 0.06382978723

YN+1 0 0.06382978723 X0 Y1 0 0.003191489362

1.6 0.06382978723 XN YN+1 0.845 0.06382978723

Lsmin/Gs 0.07176129926

Ls min 1.40

ARRIBA ABAJO
L0 2.24 G1 19.61 LN 3.43 GN+1 20.80
Ls 2.24 Gs 19.55 Ls 2.24 Gs 19.55
Lg0 0 Gg1 0.06 LgN 1.19 GgN+1 1.25
x0 0 y1 0.0031813361xN 0.345603272yN+1 0.06
X0 0 Y1 0.0031914893XN 0.528125 YN+1 0.06382978723

X0 Y1 0 0.003191489362
XN YN+1 0.528125 0.06382978723
pendiente intercepto
0.1148180780.003191489362

WANKAT
D4. We have a steam stripper operating isothermally at 100°C. The entering liquid stream contains
0.0002 mole frac nitrobenzene in water at 100°C. Flow rate of entering liquid is 1 kmol/min. The
entering steam is pure water at 100°C. We desire an outlet liquid mole frac of 0.00001
nitrobenzene. L/V = 12.0. You can assume that total liquid and gas flow rates are constant. At
100°C equilibrium in terms of nitrobenzene mole frac is y = 28 x. Find the outlet mole fraction of
the nitrobenzene in the vapor stream and the number of stages.

Ls/Gs 12

ARRIBA ABAJO
L0 1 G1 0.0835066685LN 0.999809998GN+1 0.08331666667
Ls 0.9998 Gs 0.0833166666Ls 0.9998 Gs 0.08331666667
Lg0 0.0002 Gg1 0.0001900019LgN 0.000009998GgN+1 0
x0 0.0002 y1 0.0022752901xN 0.00001 yN+1 0
X0 0.000200040Y1 0.0022804788XN 0.000010000YN+1 0

X0Y1 0.00020004000.002280478896
XNYN+1 0.00001000010
 kg NH3/100 pNH3 (mmHgx y
60 945 0.38848921 1.24342105
50 686 0.34615385 0.90263158
1 40 470 0.29752066 0.61842105
30 298 0.24107143 0.39210526
0.9
25 227 0.20930233 0.29868421
0.8 20 166 0.17475728 0.21842105
15 114 0.13705584 0.15
0.7 10 69.6 0.09574468 0.09157895
7.5 50 0.07356948 0.06578947
0.6
5 31.7 0.05027933 0.04171053
0.5 4 24.9 0.04063205 0.03276316
3 18.2 0.03078677 0.02394737
0.4 2 12 0.02073733 0.01578947
0.3

0.2

0.1

0
0 0.05 0.1 0.15 0.2 0.25 0.3

0.7

0.6
X Y
Etapas 0.0204081630.0538
0.063 0.0538 0.5

0.063 0.162020739 1
0.143 0.1620207391 0.4
0.143 0.365204435 1
0.234 0.3652044355 0.3
0.234 0.596325890 1
0.2
Nteorica 3

0.1

0
 0.3

0.2

eficiencia 0.3
0.1
.002013578246 Nreal 10

0
0 0.05 0.1 0.15 0.2

Curva Equilibrio
x y X Y 1

0 0 0 0 0.9
0.1 0.01 0.11111111 0.01010101
0.8
0.2 0.02 0.25 0.02040816
0.7
.06382978723 0.3 0.03 0.42857143 0.03092784
0.4 0.04 0.66666667 0.04166667 0.6
.003191489362 0.5 0.05 1 0.05263158 0.5
.06382978723 0.6 0.06 1.5 0.06382979
0.4
0.62 0.062 1.63157895 0.06609808
0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6
0.07

X Y
0.06

0.05

0.04
 0.07

0.06
Etapas 0 0.003191489362
0.035 0.0032 0.05
0.035 0.007210122 1
.06382978723 0.08 0.0072 0.04
0.08 0.012376935 1
.003191489362 0.142 0.0124 0.03

.06382978723 0.142 0.019495656 1

0.02
0.242 0.0195
.003191489362 0.242 0.030977464 1
0.01
0.435 0.0310
0.435 0.053137353 01
1.02 0.0531 0 0.2 0.4 0.6 0.8 1 1.2 1.4 1
1.02 0.120305929 1

ETAPAS Curva de equilibrio

0.00001
1 x y
0.00020004000.002280478896 0.9
0 0
0.00008128890.002280478896 0.00001 0.00028
0.8
0.00008128890.000875466 1 0.00002 0.00056
0.00003120640.0008754668408 0.7 0.00003 0.00084
0.00003120640.000274477 1 0.6 0.00004 0.00112
0.00000978390.0002744778673 0.5
0.00005 0.0014
0.00000978390.000017406 1 0.00006 0.00168
0.4
.08331666667 0.00007 0.00196
.08331666667 0.3 0.00008 0.00224
0.2 0.00009 0.00252
0.1

0
0 2 4 6 8
 0.1 0.15 0.2 0.25 0.3 0.35

2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

0.8 1 1.2 1.4 1.6 1.8

X Y
0 0
1E-05 0.00028008
2E-05 0.00056031
3.0001E-05 0.00084071
4.0002E-05 0.00112126
5.0003E-05 0.00140196
6.0004E-05 0.00168283
7.0005E-05 0.00196385
8.0006E-05 0.00224503
9.0008E-05 0.00252637

4 6 8 10 12
 CURVA DE EQUILIBRIO
P 760

pCl2 gCl2/kgH2O y

5 0.424 0.006579
10 0.553 0.013158
30 0.873 0.039474
50 1.106 0.065789
100 1.573 0.131579
150 1.966 0.197368
200 2.34 0.263158
250 2.69 0.328947
300 3.03 0.394737

OPERACIÓN 0.9
Q 50 m3/min
0.8
T 30 °C Recupera 75%
P 1 atm 0.7
G 2011.4006mol/min
0.6
ARRIBA ABAJO
0.5
L0 G1 1966.14 LN GN+1 2011.40
Ls Gs 1951.06 Ls Gs 1951.06 0.4
Lg0 0 Gg1 15.09 LgN 45.26 GgN+1 60.34
x0 0 y1 0.007672 xN yN+1 0.03 0.3
X0 0 Y1 0.007731 XN YN+1 0.03092783505
0.2

0.1
YN+1 0 0.03092783505 X0Y1 0 0.007731958763
0.0002 0.03092783505 XNYN+1 0.000192 0.03092783505 0
0 0.00005 0.0001 0.0

(Ls/Gs)mi 120.8118557

Gs 1951.06 mol/min

Lsmin 235711.01mol/min

Lsmin 4242.7981kg/min
 molNH3/mmolNH3/molW

0.015 0.02
0.032 0.04
0.05 0.06
0.072 0.08
0.093 0.1

BC 1 mol Aire
3 mol W/mol Aire

ARRIBA ABAJO 0.1

L0 3.03 G1 LN GN+1 1.086956522 0.09
Ls 3 Gs 1 Ls 3 Gs 1
0.08
Lg0 0.03 Gg1 LgN GgN+1 0.08695652174
0.07
x0 0.009900 y1 0.007401 xN yN+1 0.08
X0 0.01 Y1 0.007456 XN YN+1 0.086956521740.06
0.05

0.04

0.03
YN+1 0 0.08695652174 X0 0.01 0
0.1 0.08695652174 0.01 0.06 0.02
Suponer 0.01
XN YN+1 0.0365 0.08695652174 Y1 0.007456521739
0
X0 Y1 0.01 0.007456521739 y1 0.007512539151 0 0.02 0.04 0.06 0.08

WANKAT
3
D3. A stripper with one equilibrium stage is stripping 1-chloro-naphthalene from water into air. The
liquid feed is xin = 2.0 × 10–6 mole fraction 1-chloro-naphthalene and the total liquid flow rate is
L = 100 kmol/h. The inlet air is pure yin = 0 and total gas flow rate is V = 10.0 kmol/h. The
column operates at T = 25°C, and the Henry’s law constant for 1-chloro-naphthalene is given in
Table 12-2. If an outlet liquid mole fraction of xout = 0.4 × 10–6 is desired, what is the pressure (in
atm) of the stripper, and what is the value of yout?
Assume H does not depend on pressure and that both L and V are constant. Note: there are
multiple approaches to solve this problem. P
1

0.9

0.8
 1 0.265
H 0.9 10.96 atm P
0.8
N 1
0.7
L0 100 kmol/h x0 2.00E-06 Etapas
GN+1 0.6 10 kmol/h yN+1 0 2.00E-06 1.60E-05
0.5 xN 4.00E-07 3.87E-07 1.60E-05
3.87E-07 -1.32E-07
0.4
ARRIBA ABAJO
0.3
L0 100 G1 1.00E+01 LN 1.00E+02 GN+1 10
Ls 1.00E+02
0.2 Gs 10 Ls 1.00E+02 Gs 10
Lg0 2.00E-04
0.1 Gg1 1.60E-04 LgN 4.00E-05 GgN+1 0
x0 2.00E-06 y1 1.60E-05 xN 4.00E-07 yN+1 0
0
X0 2.00E-06
0.5 Y11 1.60E-052 XN 2.5
1.5 4.00E-07
3 YN+1
3.5 0.00E+00

X0Y1 2.00E-06 1.60E-05

XNYN+1 4.00E-07 0.00E+00

9.99998 -0.0000039999936
D7. We wish to absorb ammonia from an air stream using water at 0°C and a total pressure of 1.30 M (kg/kmo
atm. The entering water stream is pure water. The entering vapor is 17.2 wt % ammonia. WNH3 17
desire to recover 98% of the ammonia in the water outlet stream. The total gas flow rate is H2O 18
kg/h. We want to use a solvent rate that is 1.5 times the minimum solvent rate. Assume that
temperature is constant at 0°C, water is nonvolatile, and air does not dissolve in water.
Equilibrium data are available in Table 12-3. Find Lmin, L, and N.

ARRIBA ABAJO
L0 G1 864.47798LN GN+1 1050
Ls Gs 860.69182Ls Gs 860.6918239 0.3
Lg0 0 Gg1 3.7861635LgN 185.52201GgN+1 189.3081761
x0 0 y1 0.004379 xN yN+1 0.180293501 0.25
X0 0 Y1 0.004398 XN YN+1 0.2199488491
0.2

YN+1 0 0.2199488491 X0Y1 0.00E+00 4.40E-03 0.15

0.5 0.2199488491 XNYN+1 0.404 2.20E-01
0.1

Ls min/Gs 0.5335392874 0.05

0
Ls min 459.21 0 0.05 0.1 0.15 0.2 0.25 0.3

Ls 688.8193536

ARRIBA ABAJO ETAPAS

L0 688.81935G1 864.47798LN 874.34136GN+1 1050 0.26933 0.21995
Ls 688.81935Gs 860.69182Ls 688.81935Gs 860.6918239 0.26933 0.103
Lg0 0 Gg1 3.7861635LgN 185.52201GgN+1 189.3081761 0.12320370.103
x0 0 y1 0.004379 xN 0.2121848yN+1 0.180293501 0.12320 0.032
X0 0 Y1 0.004398 XN 0.2693333YN+1 0.2199488491 0.034487 0.032
0.03449 0.0075
YN+1 0 0.2199488491 X0Y1 0.00000 0.00440 0.003874 0.0075
0.5 0.2199488491 XNYN+1 0.26933 0.21995 0.00387 0.002
-0.0029970.002
0.80030890.004398976982

D11.* An absorption column for laboratory use has been carefully constructed so that it hasm 1.402619
equilibrium stages and is being used to measure equilibrium data. Water is used as the solvent to
absorb ammonia from air. The system operates isothermally at 80°F and 1 atm. The inlet waDelta 0.0006
pure distilled water. The ratio of L/V = 1.2, inlet gas concentration is 0.01 mole frac ammonix y
and the measured outlet gas concentration is 0.0027 mole frac ammonia. Assuming that 0 0
equilibrium is of the form y = mx, calculate the value of m for ammonia. Check your result. 0.0006 0.000842
Ls/Gs 1.2 0.0012 0.001683
BC Gs 10 mol/h 0.0018 0.002525
Ls 12 mol/h 0.0024 0.003366
0.003 0.004208
ARRIBA ABAJO 0.0036 0.005049
L0 12 G1 10.027073LN 12.073937GN+1 10.1010101 0.0042 0.005891
Ls 12 Gs 10 Ls 12 Gs 10 0.0048 0.006733
Lg0 0 Gg1 0.027073 LgN 0.073937 GgN+1 0.101010101 0.0054 0.007574
x0 0 y1 0.0027 xN 0.00612 yN+1 0.01 0.006 0.008416
X0 0 Y1 0.002707 XN 0.00616 YN+1 0.0101010101 0.0066 0.009257
0.0072 0.010099
X0Y1 0.00000 0.00271
XNYN+1 0.00616 0.01010

1.2 0.00271
F2.* (Difficult) An absorber with three equilibrium stages is operating at 1 atm. The feed is 10 mol/h
of a 60 mol% ethane, 40 mol% n-pentane mixture and enters at 30°F. The solvent used is pure noctane
at 70°F, solvent flow rate is 20 mol/h. We desire to find all the outlet compositions and
temperatures. The column is insulated. For a first guess assume that all stages are at 70°F. As a
first guess on flow rates, assume:
LN(P)=A-B/(T+C)
Comp A B C N
ETHANE 15.6637 1511.42 -17.16 P 3
N-PENTAN15.8333 2477.07 -39.94 760
N-OCTANE15.9426 3120.29 -63.63

T0 T4 T1 T3
-1.11111121.11111111 -1.11111121.11111111
Comp L0 V4 L3 V1 L1 V3 K1 K3 A1 A3
ETHANE 0 6 22.207 35.730 0.090059 0.055975
N-PENTAN 0 4 0.229 0.583 8.72020183.4318391
N-OCTANE 20 0 0.003 0.015 575.83881136.07685
20 10 20 10 20 10

T0 T4 T1 T3
-1.11111121.11111111 -1.11111121.11111111
Comp L0 V4 L3 V1 L1 V3 K1 K3 A1 A3
ETHANE 0 6 22.207 35.730 0.16694900.081938
N-PENTAN 0 4 0.229 0.583 16.1651285.0235987
N-OCTANE 20 0 0.003 0.015 1067.4647199.19218
20 10 24.28929 5.710712 21.1725378.296535253

T0 T4 T1 T3
-1.11111121.11111111 -1.11111121.11111111
Comp L0 V4 L3 V1 L1 V3 K1 K3 A1 A3
ETHANE 0 6 22.207 35.730 0.17377510.083717
N-PENTAN 0 4 0.229 0.583 16.8260805.1326492
N-OCTANE 20 0 0.003 0.015 1111.1107203.51617
20 10 24.50301 5.496985 21.2134348.191715526
 T0 T4 T1 T3
-1.11111121.11111111 -1.11111121.11111111
Comp L0 V4 L3 V1 L1 V3 K1 K3 A1 A3
ETHANE 0 6 22.207 35.730 0.17426130.083841
N-PENTAN 0 4 0.229 0.583 16.8731605.1402808
N-OCTANE 20 0 0.003 0.015 1114.2196203.81877
20 10 24.51765 5.48235 21.2161548.184439178
 x X Y
0 0
0.000107 0.000107 0.006623
0.00014 0.00014 0.013333
0.000221 0.000221 0.041096
0.00028 0.00028 0.070423
0.000399 0.000399 0.151515
0.000498 0.000498 0.245902
0.000593 0.000593 0.357143
0.000682 0.000682 0.490196
0.000768 0.000768 0.652174

0.00005 0.0001 0.00015 0.0002 0.00025

 molNH3/molW molNH3/ molNH3/molA
0 0
0.02 0.015
0.04 0.032
0.06 0.05
0.08 0.072
0.1 0.093

02 0.04 0.06 0.08 0.1 0.12

 1E-07
x y X Y
0 0 0 0
1E-07 4.14E-06 1E-07 4.14E-06
2E-07 8.27E-06 2E-07 8.27E-06
3E-07 1.24E-05 3E-07 1.24E-05
4E-07 1.65E-05 4E-07 1.65E-05
5E-07 2.07E-05 5E-07 2.07E-05
6E-07 2.48E-05 6E-07 2.48E-05
7E-07 2.9E-05 7E-07 2.9E-05
8E-07 3.31E-05 8E-07 3.31E-05
9E-07 3.72E-05 9E-07 3.72E-05
0.000001 4.14E-05 0.000001 4.14E-05
1.1E-06 4.55E-05 1.1E-06 4.55E-05
1.2E-06 4.96E-05 1.2E-06 4.96E-05

41.36049366

m (kg) n (kmol) x
17.2 1.011765 0.180293501
82.8 4.6
5.611764706

CURVA DE EQUILIBRIO
kgNH3/10pNH3 (mmx y X Y
100 947 0.514286 0.958502 1.058824 23.09756
90 785 0.487952 0.794534 0.952941 3.866995
80 636 0.458599 0.643725 0.847059 1.806818
70 500 0.425676 0.506073 0.741176 1.02459
60 380 0.388489 0.384615 0.635294 0.625
50 275 0.346154 0.27834 0.529412 0.385694
40 190 0.297521 0.192308 0.423529 0.238095
30 119 0.241071 0.120445 0.317647 0.136939
25 89.5 0.209302 0.090587 0.264706 0.09961
20 64 0.174757 0.064777 0.211765 0.069264
05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 15 42.7 0.137056 0.043219 0.158824 0.045171
10 25.1 0.095745 0.025405 0.105882 0.026067
7.5 17.7 0.073569 0.017915 0.079412 0.018242
5 11.2 0.050279 0.011336 0.052941 0.011466
0 0
 0.12

0.1

0.08

0.06

0.04

0.02

0
0 2 4 6 8 10 12 14

ETAPAS

X Y X Y
0 0 0.00000 0.00271
0.0006 0.000842 0.001924 0.00271
0.001201 0.001686 0.001924 0.00502
0.001803 0.002531 0.003566 0.00502
0.002406 0.003378 0.003566 0.00699
0.003009 0.004226 0.004966 0.00699
0.003613 0.005075 0.004966 0.00867
0.004218 0.005926 0.006161 0.00867
0.004823 0.006778 0.006161 0.01010
0.005429 0.007632
0.006036 0.008487
0.006644 0.009344
0.007252 0.010202 0.0000007658058215

0.9
1.40672358
0.8

0.7

0.6

0.5

0.4
 0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0.8 1 1.2 1.4 1.6 1.8 2 2.2

S1 S3 Ae Se fA fS L3 V1 x0 y4
11.10373 17.86486 0.057689 13.98172 0.942321 0.00034 0.346071 5.653929 0 0.6
0.114676 0.291389 5.297255 0.130945 0.005464 0.869311 3.978143 0.021857 0 0.4
0.001737 0.007349 279.669 0.001746 4.56E-08 0.998254 19.96507 0.034926 1 0
24.28929 5.710712

S1 S3 Ae Se fA fS L3 V1 V2
5.989852 12.20426 0.087893 8.407389 0.912161 0.001483 0.527031 5.472969
0.061862 0.19906 8.799501 0.069364 0.001301 0.930657 3.994796 0.005204
0.000937 0.00502 460.8351 0.000941 1.02E-08 0.999059 19.98119 0.018812
24.50301 5.496985 6.883249721

S1 S3 Ae Se fA fS L3 V1 V2
5.754563 11.94496 0.09014 8.145381 0.90992 0.001624 0.54048 5.45952
0.059432 0.194831 9.078362 0.066578 0.001189 0.93344 3.995242 0.004758
0.0009 0.004914 475.2444 0.000904 9.3E-09 0.999096 19.98193 0.018072
24.51765 5.48235 6.710420326
S1 S3 Ae Se fA fS L3 V1 V2
5.738506 11.92723 0.090298 8.127456 0.909762 0.001634 0.541427 5.458573
0.059266 0.194542 9.098076 0.066388 0.001182 0.93363 3.995272 0.004728
0.000897 0.004906 476.263 0.000901 9.24E-09 0.999099 19.98198 0.018022
24.51868 5.481323 6.698504467
x3 y1
D23.* A complete gas treatment plant often consists of both an absorber to remove the solute and a stripper to regenerate the
Some of the treated gas is heated and is used in the stripper. This is called stream B. In a particular application we wish to remo
obnoxious impurity A from the inlet gas. The absorber operates at 1.5 atm and 24°C where equilibrium is given as y = 0.5x
(units are mole fracs). The stripper operates at 1 atm and 92°C where equilibrium is y = 3.0x (units are mole fracs).
The total gas flow rate is 1400 mol/day, and the gas is 15 mol% A. The nonsoluble carrier is air. We desire a treated gas concent
of 0.5 mol% A. The liquid flow rate into the absorber is 800 mol/day and the liquid is 0.5 mol% A.
a. Calculate the number of stages in the absorber and the liquid concentration leaving.
b. If the stripper is an already existing column with four equilibrium stages, calculate the gas flow rate of stream B (concentratio
0.5 mol% A) and the outlet gas concentration from the stripper.
12.D23.
a. Absorber: N = 8 equilibrium stages, Xout = 0.2614 mole ratio
b. Stripper: G (stream B) = 723.7 mol carrier gas/day, Yout ≈ 0.287 mole ratio
0.668907563
ABSORBER
ARRIBA ABAJO
L0 800 G1 1195.97989LN 1004.0201 GN+1 1400
Ls 796 Gs 1190 Ls 796 Gs 1190
Lg0 4 Gg1 5.97989949LgN 208.0201 GgN+1 210
x0 0.005 y1 0.005 xN 0.20718718yN+1 0.15
X0 0.00502512Y1 0.00502512XN 0.26133178YN+1 0.1764705882

ABSORBER X0Y1 0.005025120.005025125628

x y X Y XNYN+1 0.261331780.1764705882
0 0 0 0
0.05 0.025 0.0526316 0.025641 0.668907560.00166378109
0.1 0.05 0.1111111 0.0526316
0.15 0.075 0.1764706 0.0810811
0.2 0.1 0.25 0.1111111
0.25 0.125 0.3333333 0.1428571
1400.026668
1195.979899

DESORBER
ARRIBA ABAJO
L0 1004.0 G1 854.2 LN 800.0 GN+1 650.1
Ls 796.0 Gs 646.9 Ls 796.0 Gs 646.9
Lg0 208.0 Gg1 207.3 LgN 4.0 GgN+1 3.3
x0 0.20718718y1 0.2427 xN 0.0050 yN+1 0.0050
X0 0.261332 Y1 0.3204 XN 0.0050 YN+1 0.0050
ABSORBER
x y X Y X0Y1 0.261332 0.3204
0 0 0 0 XNYN+1 0.0050 0.0050
0.02 0.06 0.0204082 0.0638298
0.04 0.12 0.0416667 0.1363636 1.23049473-0.001158265004
0.06 0.18 0.0638298 0.2195122
0.08 0.24 0.0869565 0.3157895
0.1 0.3 0.1111111 0.4285714
0.12 0.36 0.1363636 0.5625
0.15 0.45 0.1764706 0.8181818

L0

G1
 and a stripper to regenerate the solvent.
ular application we wish to remove
uilibrium is given as y = 0.5x
nits are mole fracs).
We desire a treated gas concentration
ow rate of stream B (concentration is
0.668907563
CUESTIONARIO
1 Entre las dos líneas de operación del problema; cuál es la que facilita la disoluci
2 Dibujar el diagrama de equilibrio para absorción
3 Dibujar el diagrama de equilibrio para desorción
4 Cual es la cantidad de líquido que sale del absorbedor?
5 Cúal es la composición del líquido que sale del absorbedor?
6 Cuantas etapas se necesitan para el absorbedor
7 Cúal es la pendiente de la línea de operación de absorción
8 Cúal es la cantidad de Gas desorbente?
9 Cúal es la pendiente de la línea de operación de desorción?
10
0.1 0.05

ETAPAS 0.1 0.3

0.261331780.1764705882
0.261331780.1157060179
0.170490270.11570601 1
0.170490270.07858762987
0.114999220.07858762 1 1

0.114999220.05428718278 0.9
0.078670660.05428718 1 0.8
0.078670660.03771017404
0.7
0.053888450.03771017 1
0.053888450.02609850823 0.6

0.036529300.02609850 1 0.5
0.036529300.01781837967 0.4
0.024150710.01781837 1
0.3
0.024150710.01184019455
0.015213480.01184019 1 0.2

0.015213480.007485835705 0.1
0.008703820.00748583 1
0
0.008703820.004294089897 0 2 4 6 8 10 12 14 16 18 20
0.003932240.00429408 1

ETAPAS 1
0.0050 0.0050 0.9
0.0050 0.01498955582
0.8
0.013123030.01498955 1
0.013123030.03998287308 0.7

0.033434630.03998287 1 0.6

0.5

0.4

0.3
 0.8

0.7

0.6
0.033434630.1072222567 0.5
0.088078810.10722225 1
0.4
0.088078810.3204109265
0.3
0.261333250.32041092 1
0.2

0.1

0
0 2 4 6 8 10 12 14 16 18 20

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16
Col umn D

0.35

0.3

0.25

0.2

0.15

0.1

0.05

0
0.15

0.1

0.05

0
0 0.02 0.04 0.06 0.08 0.1 0.12 0.14 0.16
 cuál es la que facilita la disolución en la fase lí SOLUCIÖN PASO A PASO

Datos del problema

absorbedor? ABSORBER
ARRIBA ABAJO
L0 800 G1 LN
Ls Gs Ls
e desorción? Lg0 Gg1 LgN
x0 0.005 y1 0.005 xN
X0 Y1 XN

Completar L0
Lg0 800 0.005 4
Ls 800 4 796
X0 0.005 0.005025125628

ARRIBA ABAJO
0.16 L0 800 G1 LN
Ls 796 Gs 1190 Ls
0.14
Lg0 4 Gg1 LgN
0.12 x0 0.005 y1 0.005 xN
X0 0.00502512Y1 XN
0.1

0.08 Completar G1
G1 1190 0.995 1195.979899
0.06 Gg1 1195.979891190 5.979899497
Y1 0.005 0.005025125628
0.04

0.02 ARRIBA ABAJO

L0 800 G1 1195.979899 LN
0
0 12 14 16 18 20 0 Ls
0.05 0.1 7960.15 Gs
0.2 0.25 1190 0.3 0.35 Ls
Lg0 4 Gg1 5.979899497 LgN
x0 0.005 y1 0.005 xN
X0 0.00502512Y1 0.005025125628 XN

Completar LN
LgN 4 210 5.979899497 208.0201005
LN 796 208.0201005 1004.020101
xN 1004.02010208.0201005 0.2071871872
XN 0.2071871872 0.2613317846
 ARRIBA ABAJO
L0 800 G1 1195.979899 LN
Ls 796 Gs 1190 Ls
Lg0 4 Gg1 5.979899497 LgN
x0 0.005 y1 0.005 xN
X0 0.00502512Y1 0.005025125628 XN

4 16 18 20 X0Y1 0.00502512
XNYN+1 0.26133178
Pendiente
0.66890756
Valor máximo de y 0.15
Máximo valor de X 0.2613317846
0.04
x y X Y
0 0 0 0
0.04 0.02 0.0416667 0.0204082
0.08 0.04 0.0869565 0.0416667
0.12 0.06 0.1363636 0.0638298
0.16 0.08 0.1904762 0.0869565
0.2 0.1 0.25 0.1111111
0.24 0.12 0.3157895 0.1363636
0.12 0.14 0.16 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 2 4 6 8 10 12 14 16 18 20

HASTA AQUÍ 10
0.1 0.12 0.14 0.16
 SOLUCIÖN PASO A PASO

Datos del problema

DESORBER
ARRIBA
GN+1 1400 L0 1004.020101
Gs Ls 796
GgN+1 Lg0 208.0201005
yN+1 0.15 x0 0.207187187
YN+1 X0 0.261331784

Completar GN+1 Completar LN

GgN+1 1400 0.15 210 LN 796
Gs 1400 210 1190 LgN 800
YN+1 0.15 0.1764705882
CURVA DE EQUILIBRIO
Valor máximo de y
GN+1 1400 Máximo valor de X
796 Gs 1190 0.04
GgN+1 210 x y
yN+1 0.15 0 0
YN+1 0.1764705882 0.04 0.12
0.08 0.24
0.12 0.36
0.16 0.48
0.2 0.6
0.24 0.72

GN+1 1400
796 Gs 1190
GgN+1 210
yN+1 0.15
YN+1 0.1764705882

208.0201005
1004.020101
0.2071871872 ARRIBA
0.2613317846 L0 1004.020101
Ls 796
 Lg0 208.0201005
1004.02010GN+1 1400 x0 0.207187187
796 Gs 1190 X0 0.261331784
208.020100GgN+1 210
0.6
0.20718718yN+1 0.15
0.26133178YN+1 0.1764705882 0.5

0.005025125628 0.4
0.1764705882
Intercepto 0.3
0.00166378109
0.2
ETAPAS
0.1
0.005025120.005025125628
0.010035550.005025125628 2.77555756156289E-17
0 0.02 0.04 0.06
0.010035550.008376642 1
-0.1
0.016795700.008376642878
0.016795700.012898555 1
0.026001430.01289855554
0.026001430.019056340 1 ARRIBA
0.038694220.01905634011 L0 1004.020101
0.038694220.027546638 1 Ls 796
0.056491320.02754663889 Lg0 208.0201005
0.056491320.039451253 1 x0 0.207187187
0.082024050.03945125373 X0 0.261331784
0.082024050.056530292 1
0.6
0.119834530.05653029202
0.119834530.081822006 1 0.5
0.178380670.08182200609
0.178380670.120983965 1 0.4
0.275049910.1209839658
0.275049910.185646751 1 0.3

9 0.2

16 18 20 0.1

2.77555756156289E-17
0 0.01 0.02 0.03
puntos -0.1
ARRIBA
L0 1004.020101
Ls 796
Lg0 208.0201005
x0 0.207187187
X0 0.261331784
0.6

0.5

0.4

0.3

0.2

0.1

2.77555756156289E-17
0 0.01 0.02 0.03 0.04 0
-0.1

ARRIBA
L0 1004.020101
Ls 796
Lg0 208.0201005
x0 0.207187187
X0 0.261331784
0.6

0.5

0.4

0.3

0.2

0.1

2.77555756156289E-17
0 0.01 0.02 0.03 0.04 0.0
-0.1
2.77555756156289E-17
0 0.01 0.02 0.03 0.04 0.0
-0.1
Se debe desorber el liquido de la primera etapa
El líquido desorbido debe regresar a proceso, su composición es conocida
Cuatro etapas y no se sabe cuanto gas se necesita

ABAJO
G1 LN GN+1
Gs Ls 796 Gs
Gg1 LgN GgN+1
y1 xN 0.005 yN+1 0.005
Y1 XN 0.005025125YN+1 0.005025125628

0.995 800
796 4 3

2.5
0
0.2613317846
2

X Y
1.5
0 0
0.04166667 0.13636364
0.08695652 0.31578947 1

0.13636364 0.5625
0.19047619 0.92307692 0.5

0.25 1.5
0.31578947 2.57142857 0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35

El gas debe entrar con la composición que sale del absorbedor

El líquido debe salir con la composición requerida para el proceso de absorción
Se supondrá una cantidad y se iterará hasta que de 4 etapas

Se supone GN+1
Se calcula Gs, GgN+1
Por balance se calcula G1……

ABAJO Itera
G1 704.02 LN 800 GN+1 500
Gs 497.5 Ls 796 Gs 497.5
 Gg1 206.52 LgN 4 GgN+1 2.5
y1 0.29334404 xN 0.005 yN+1 0.005
Y1 0.4151157799 XN 0.005025125YN+1 0.005025125628

0.6
X0Y1 0.2613317840.4151157799
0.5
XNYN+1 0.0050251250.005025125628
Pendiente Intercepto
0.4 1.6 -0.003015075377

0.3 0.2613317840.4151157799
0.108 0.4151157799
0.2 0.108 0.1697849246
0.05 0.1697849246
0.1 0.05 0.07698492462
0.023 0.07698492462
56289E-17 0.023 0.03378492462
0 0.02 0.04 0.06 0.08 0.1 0.12
0.01 0.03378492462
-0.1
0.01 0.01298492462

ABAJO Itera
G1 1204.02 LN 800 GN+1 1000
Gs 995 Ls 796 Gs 995
Gg1 209.02 LgN 4 GgN+1 5
y1 0.1736018364 xN 0.005 yN+1 0.005
Y1 0.2100704528 XN 0.005025125YN+1 0.005025125628

0.6
X0Y1 0.2613317840.2100704528
0.5 XNYN+1 0.0050251250.005025125628
Pendiente Intercepto
0.4 0.8 0.001005025126

0.3 0.2613317840.2100704528
0.061 0.2100704528
0.2 0.061 0.04980502513
0.015 0.04980502513
0.1
0.015 0.01300502513
0.004 0.01300502513
756156289E-17
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.004 0.004205025126
-0.1
0.0005 0.004205025126
0.0005 0.001405025126
 ABAJO Itera
G1 954.02 LN 800 GN+1 750
Gs 746.25 Ls 796 Gs 746.25
Gg1 207.77 LgN 4 GgN+1 3.75
y1 0.2177837767 xN 0.005 yN+1 0.005
Y1 0.2784188951 XN 0.005025125YN+1 0.005025125628
0.6
X0Y1 0.2613317840.2784188951
0.5 XNYN+1 0.0050251250.005025125628
Pendiente Intercepto
0.4 1.066666667-0.0003350083752

0.3 0.2613317840.2784188951
0.078 0.2784188951
0.2
0.078 0.08286499162
0.0255 0.08286499162
0.1
0.0255 0.02686499162
56289E-17
0.008 0.02686499162
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.008 0.008198324958
-0.1 0.002 0.008198324958
0.002 0.001798324958

ABAJO Itera
G1 854.02 LN 800 GN+1 650
Gs 646.75 Ls 796 Gs 646.75
Gg1 207.27 LgN 4 GgN+1 3.25
y1 0.2426993233 xN 0.005 yN+1 0.005
Y1 0.3204794751 XN 0.005025125YN+1 0.005025125628
0.6
X0Y1 0.2613317840.3204794751
0.5 XNYN+1 0.0050251250.005025125628
Pendiente Intercepto
0.4 1.230769231-0.001159644376

0.3 0.2613317840.3204794751
0.088 0.3204794751
0.2
0.088 0.1071480479
0.0332 0.1071480479
0.1
0.0332 0.03970189409
0.012 0.03970189409
6156289E-17
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.1 0.012 0.01360958639
-0.1 0.004 0.01360958639
6156289E-17
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09 0.1
-0.1
0.004 0.003763432547
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
5 0.3 0.35
0 2 4 6 8 10

0.9

0.8

0.7

0.6

0.5
1
0.4

0.3

0.2

0.1

0
 0.5

0.4

0.3

0.2

0.1

0
0 2 4 6 8 10 12 14 16 18 20

2
3

4
4 6 8 10 12 14 16 18 20

0.9

0.8

0.7

0.6
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 2 4 6 8 10 12 14 16 18 20
D. Problems
*Answers to problems with an asterisk are at the back of the book.
D1. A 5-stage countercurrent absorber is used to absorb acetone from air into water at 3 atm pressure x y X
and 20°C. The total inlet gas flow rate is 100 kmol/h. The inlet gas is 0.004 mole fraction acetone. 0 0 0
The inlet liquid contains 0.0001 mole fraction acetone. Outlet gas is 0.0002 mole fraction acetone. 0.001 0.00039533 0.001001
Assume total liquid and gas flow rates are constant. At 20°C the Henry’s law constant for acetone 0.002 0.00079067 0.00200401
in water is H = 1.186 atm/(mole fraction). Find the liquid flow rate required and the mole fraction 0.003 0.001186 0.00300903
acetone in the outlet liquid. 0.004 0.00158133 0.00401606
H 1.186 atm K 0.3953333333 0.005 0.00197667 0.00502513
P 3 atm N 3 0.006 0.002372 0.00603622
0.394375504
ARRIBA ABAJO N
L0 62 G1 99.61992398LN 62.38007602 GN+1 100 0.0001000100.000200040008
Ls 61.9938 Gs 99.6 Ls 61.9938 Gs 99.6 0.0005070720.000200040008
Lg0 0.0062 Gg1 0.019923984LgN 0.3862760152 GgN+1 0.4 0.0005070720.0004534068403
x0 0.0001 y1 0.0002 xN 0.006192297924yN+1 0.004 0.0011493200.0004534068403
X0 0.000100010Y1 0.000200040XN 0.006230881398YN+1 0.004016064257 0.0011493200.0008531597869
0.0021626350.0008531597869
X0Y1 0.0001000100.000200040008 0.0021626350.001483875405
XNYN+1 0.0062308810.004016064257 0.0037614070.001483875405
0.0037614070.002478995503
0.6224277100.000137791012 0.0062838920.002478995503
0.0062838920.004049059697

D2. We are absorbing hydrogen sulfide at 15°C into water. The entering water is pure. The feed gas
contains 0.0012 mole frac hydrogen sulfide and we want to remove 97% of this in the water. The
total gas flow rate is 10 kmol/h. The total liquid flow rate is 2000 kmol/h. Total pressure is 2.5 atm.
You can assume that total liquid and gas flow rates are constant. Equilibrium data are in Table 12-1.

a. Calculate the outlet gas and liquid mole fracs of hydrogen sulfide.
b. Calculate the number of equilibrium stages required using a McCabe-Thiele diagram.
c. If L/V = M × (L/V)min, find the multiplier M (M > 1).
d. Why is this operation not practical? What would an engineer do to develop a practical process?
H 423 atm
P 2.5 atm
K 169.2
ARRIBA ABAJO
L0 62 G1 99.61992398LN 62.38007602 GN+1 100
Ls 61.9938 Gs 99.6 Ls 61.9938 Gs 99.6
Lg0 0.0062 Gg1 0.019923984LgN 0.3862760152 GgN+1 0.4
x0 0.0001 y1 0.0002 xN 0.006192297924yN+1 0.004
X0 0.000100010Y1 0.000200040XN 0.006230881398YN+1 0.004016064257

X0Y1 0.0001000100.000200040008
XNYN+1 0.0062308810.004016064257

0.6224277100.000137791012

D3. A stripper with one equilibrium stage is stripping 1-chloro-naphthalene from water into air. The
liquid feed is xin = 2.0 × 10–6 mole fraction 1-chloro-naphthalene and the total liquid flow rate is
L = 100 kmol/h. The inlet air is pure yin = 0 and total gas flow rate is V = 10.0 kmol/h. The
column operates at T = 25°C, and the Henry’s law constant for 1-chloro-naphthalene is given in
Table 12-2. If an outlet liquid mole fraction of xout = 0.4 × 10–6 is desired, what is the pressure (in
atm) of the stripper, and what is the value of yout?
Assume H does not depend on pressure and that both L and V are constant. Note: there are
multiple approaches to solve this problem.
D4. We have a steam stripper operating isothermally at 100°C. The entering liquid stream contains
0.0002 mole frac nitrobenzene in water at 100°C. Flow rate of entering liquid is 1 kmol/min. The
entering steam is pure water at 100°C. We desire an outlet liquid mole frac of 0.00001
nitrobenzene. L/V = 12.0. You can assume that total liquid and gas flow rates are constant. At
100°C equilibrium in terms of nitrobenzene mole frac is y = 28 x. Find the outlet mole fraction of
the nitrobenzene in the vapor stream and the number of stages.
D5.* A packed column 0.0762 m in diameter with 3.048 m of Intalox saddle packing is being run in the
laboratory. P is being stripped from nC9 using methane gas. The methane can be assumed to be
insoluble and the nC9 is nonvolatile. Operation is isothermal. The laboratory test results are:

Equilibrium data can be approximated as Y = 1.5X. Find the HETP for the packing.

D6.* We wish to design a stripping column to remove carbon dioxide from water. This is done by ARRIBA
heating the water and passing it countercurrent to a nitrogen stream in a staged stripper. Operation L0 2519.492848
is isothermal and isobaric at 60°C and 1 atm pressure. The water contains 9.2 × 10−6 mole frac Ls 2.52E+03
CO2 and flows at 100,000 lb/h. Nitrogen (N2) enters the column as pure nitrogen and flows at Lg0 2.32E-02
2500 ft3/h. Nitrogen is at 1 atm and 60°C. We desire an outlet water concentration that is 2 × 10−7 x0 9.20E-06
mole frac CO2. Ignore nitrogen solubility in water and ignore the volatility of the water. X0 9.20E-06
Equilibrium data are in Table 12-1. Use a Murphree vapor efficiency of 40%. Find outlet vapor
composition and number of real stages needed.
T 60 °C
P 1 atm
m (lb/h) x M n (lbmol/h)
W 99997.751140.999977511 18 5555.43062 0.9999908 0.0000005
CO2 2.248859004 2.2489E-05 44 0.05111043 0.0000092 0
100000 5555.481729-0.000003894149272
Q 2519.492848kmol/h
N2 2500 p3/h
70.79144839m3/h ABSORBER
M 28 g/mol x y X Y N
G 2.591356285kmol/h 0 0 0 0 9.20E-06 8.75E-03
0.0000005 0.001705 0.0000005 0.00170791 2.54E-06 8.75E-03
0.000001 0.00341 0.000001 0.00342167 2.54E-06 2.28E-03
0.0000015 0.005115 0.0000015 0.0051413 6.81E-07 2.28E-03
0.000002 0.00682 0.000002 0.00686683 6.81E-07 4.68E-04
0.0000025 0.008525 0.0000025 0.0085983 1.60E-07 4.68E-04
0.000003 0.01023 0.000003 0.01033573 1.60E-07 0
0.0000000250
3474.848994-0.00008884369029 0.000000025 0
D7. We wish to absorb ammonia from an air stream using water at 0°C and a total pressure of 1.30
atm. The entering water stream is pure water. The entering vapor is 17.2 wt % ammonia. We
desire to recover 98% of the ammonia in the water outlet stream. The total gas flow rate is 1050
kg/h. We want to use a solvent rate that is 1.5 times the minimum solvent rate. Assume that
temperature is constant at 0°C, water is nonvolatile, and air does not dissolve in water.
Equilibrium data are available in Table 12-3. Find Lmin, L, and N.
D8. HCl is being absorbed from two air streams into water in a countercurrent staged laboratory F1
absorber at 10°C and a pressure of 2.0 atm. Feed rate of gas feed 1 is 1.0 kmol/h of total gas, and Air 0.8
this gas is 20 mol% HCl. Feed rate of gas feed 2 is 0.5 kmol/h of total gas, and this gas is 5 mol% HCl 0.2
HCl. The entering water is pure. The outlet gas should be 0.002 mole fraction HCl. Equilibrium 1
data are given below. Use the optimum feed locations for both gas feeds.
Note: Use ratio units. If careful with units, the liquid units can be in mass and the gas units in
moles, which is effectively the form of the equilibrium data. Derive the operating equation and
external mass balances to determine where to include the molecular weight of HCl (36.46).
Because HCl has a very large heat of absorption in water, the column will have to be well-cooled
to maintain the temperature at 10°C. Commercial units are not isothermal.
a. Find the minimum water flow rate required.
b. If L = 0.4 kg water/h, find the outlet liquid concentration, the number of stages required
(including a fractional number of stages) and the optimum feed location for gas feeds 1 and 2.
Equilibrium data from Perry and Green (1997, p. 2-127):

ARRIBA ABAJO
L0 G1 1.27755511 LN GN+1 1.5
Ls Gs 1.275 Ls Gs 1.275
Lg0 0 Gg1 0.002555110LgN GgN+1 0.225
x0 0 y1 0.002 xN yN+1 0.15
X0 0 Y1 0.002004008XN 0 YN+1 0.1764705882

ABSORBER X0Y1 0 0.002004008016

x y X Y XNYN+1 0 0.1764705882
D9. Problem 12.D2 satisfies the criteria for using the Kremser equation. Repeat Problem 12.D2b, but
use the Kremser equation. Compare your answer with the McCabe-Thiele solution.
D10.* A stripping tower with four equilibrium stages is being used to remove ammonia from
wastewater using air as the stripping agent. Operation is at 80°F and 1 atm. The inlet air is pure
air, and the inlet water contains 0.02 mole frac ammonia. The column operates at L/V = 0.65.
Equilibrium data in mole fracs are given as y = 1.414x. Find the outlet concentrations.
D11.* An absorption column for laboratory use has been carefully constructed so that it has exactly 4
equilibrium stages and is being used to measure equilibrium data. Water is used as the solvent to
absorb ammonia from air. The system operates isothermally at 80°F and 1 atm. The inlet water is
pure distilled water. The ratio of L/V = 1.2, inlet gas concentration is 0.01 mole frac ammonia,
and the measured outlet gas concentration is 0.0027 mole frac ammonia. Assuming that
equilibrium is of the form y = mx, calculate the value of m for ammonia. Check your result.
D12.* Read Section 13.4 on cross flow in Chapter 13 before proceeding. We wish to strip CO2 from a
liquid solvent using air as the carrier gas. Since the air and CO2 mixtures will be vented and since
cross flow has a lower pressure drop, we will use a cross-flow system. The inlet liquid is 20.4
wt % CO2, and the total inlet liquid flow rate is 1000 kg/h. We desire an outlet liquid composition
that is 2.5 wt % (0.025 wt frac) CO2. The gas flow to each stage is 25,190 kg air/h. In the last
stage a special purified air is used that has no CO2. Find the number of equilibrium stages
required. In weight fraction units, equilibrium is y = 0.04x. Use unequal axes for your McCabe-
Thiele diagram. Note: With current environmental concerns, venting the CO2 is not a good idea
even if it is legal.
D13. A water cleanup is stripping vinyl chloride from contaminated ground water at 25°C and 850 mm
Hg using a countercurrent, staged stripper. The feed is 5.0 ppm (molar) vinyl chloride. An outlet
water that contains 0.1 ppm (molar) vinyl chloride is required. The inlet air used for stripping is
pure. For a base liquid flow rate of L = 1.0 kmol/h, determine the following:
a. The minimum gas flow rate Gmin in kmol/h.
b. If G = 2 Gmin, use a McCabe-Thiele diagram to determine the number of equilibrium stages
needed (including a fractional number). Note: Scales on your y and x axes should be different.
Calculate two points to plot the straight lines.
c. If G = 2 Gmin, use one of the forms of the Kremser equation to determine the number of
equilibrium stages needed (including a fractional number).
d. For parts b and c, what is the concentration of vinyl chloride in the outlet gas? What would you
propose doing with this gas (it cannot be vented to the atmosphere)?
e. Are the assumptions required for the solution methods satisfied?
Data are in Table 12-2.
D14. In an ammonia plant we wish to absorb traces of argon and methane from a nitrogen stream using
liquid ammonia. Operation is at 253.2 K and 175 atm pressure. The feed flow rate of gas is 100
kmol/h. The gas contains 0.00024 mole frac argon and 0.00129 mole frac methane. We desire to
remove 95% of the methane. The entering liquid ammonia is pure. Operate with L/V =
1.4(L/V)min. Assume the total gas and liquid rates are constant. The equilibrium data at 253.2 K
are:
Methane: partial pressure methane atm = 3600(methane mole frac in liquid)
Argon: partial pressure argon atm = 7700(argon mole frac in liquid)
Reference: Alesandrini et al., Ind. Eng. Chem. Process Design and Develop., 11, 253 (1972)
a. Find outlet methane mole frac in the gas.
b. Find (L/V)min and actual L/V.
c. Find outlet methane mole frac in the liquid.
d. Find the number of equilibrium stages required.
e. Find the outlet argon mole fracs in the liquid and the gas, and the % recovery of argon in the
liquid.
D15.* We want to remove traces of propane and n-butane from a hydrogen stream by absorbing them
into a heavy oil. The feed is 150 kmol/h of a gas that is 0.0017 mole frac propane and 0.0006
mole frac butane. We desire to recover 98.8% of the butane. Assume that H2 is insoluble. The
heavy oil enters as a pure stream (which is approximately C10 and can be assumed to be
nonvolatile). Liquid flow rate is 300 kmol/h. Operation is at 700 kPa and 20°C. K values can be
obtained from the DePriester charts. Find the equilibrium number of stages required and the
compositions of gas and liquid streams leaving the absorber.
D16. You have a water feed at 25°C and 1 atm. The water has been in contact with air and can be
assumed to be in equilibrium with the normal CO2 content of air (about 0.035 volume %) (Note:
This dissolved CO2 will decrease the pH of the water.) We wish to strip out the CO2. A
countercurrent stripping column will be used operating at 25°C and 50 mm Hg pressure. The
stripping gas used will be nitrogen gas saturated with pure water at 25°C. Assume the nitrogen is
insoluble in water. Assume ideal gas (vol % = mol%). Data: See Table 12-1. We want to remove
95% of the initial CO2 in the water.
a. Calculate the inlet and outlet mole fracs of CO2 in water.
b. Determine (L/G)max. If L = 1 kgmol/h, calculate Gmin (corresponds to (L/G)max).
c. If we operate at G = 1.5 × Gmin find the CO2 mole frac in the outlet nitrogen and the number of
equilibrium stages needed.
D17.* We wish to absorb ammonia from air into water. Equilibrium data are given as yNH3 =
1.414xNH3 in mole fracs. The countercurrent column has three equilibrium stages. The entering air
stream has a total flow rate of 10 kmol/h and is 0.0083 mole frac NH3. The inlet water stream
contains 0.0002 mole frac ammonia. We desire an outlet gas stream with 0.0005 mole frac
ammonia. Find the required liquid flow rate, L.
D18. Dilute amounts of ammonia are to be absorbed from two air streams into water. The absorber
operates at 30°C and 2 atm pressure, and the equilibrium expression is y = 0.596x where y is
mole frac of ammonia in the gas and x is mole frac of ammonia in the liquid. The solvent is pure
water and flows at 100 kmol/h. The main gas stream to be treated has a mole frac ammonia of
yN+1 = 0.0058 (the remainder is air) and flow rate of VN+1 = 100 kmol/h. The second gas stream is
input as a feed in the column with a mole frac ammonia of yF = 0.003 and flow rate of VF = 50
kmol/h. We desire an outlet ammonia mole frac in the gas stream of y1 = 0.0004. Find:
a. The outlet mole frac of ammonia in the liquid, xN.
b. The optimum feed stage for the gas of mole frac yF, and the total number of stages needed.
c. The minimum solvent flow rate, Lmin.
D19.* Use the Kremser equation to check the McCabe-Thiele calculation done in Example 12-1.
D20. We need to remove H2S and CO2 from 1000 kmol/h of a water stream at 0°C and 15.5 atm. The
 Y 1
0 0.8
0.0003954897 0.6
0.0007912923
0.4
0.0011874083
0.2
0.0015838379
0
0.0019805816 0 2 4 6 8 10 12
0.0023776398
0.0000004804573821

.000200040008
.000200040008
.0004534068403
.0004534068403
.0008531597869
.0008531597869
.001483875405
.001483875405
.002478995503
.002478995503
.004049059697
 ABAJO
1
G1 2.61E+00 LN 2.52E+03 GN+1 2.591356285
Gs 2.591356285 Ls 2.52E+03 Gs 2.591356285 0.9
Gg1 2.27E-02 LgN 5.04E-04 GgN+1 0 0.8
y1 8.67E-03 xN 2.00E-07 yN+1 0 0.7
Y1 8.75E-03 XN 2.00E-07 YN+1 0
0.6

X0Y1 9.20E-06 8.75E-03 0.5

XNYN+1 2.00E-07 0 0.4

0.3
972.2590766-0.0001944518542
0.2

0.1

0
0 1 2 3 4 5 6 7 8 9 10

x y* e Nreal
3.59E-06 8.75E-03 9.20E-06
2.54E-06 8.75E-03 0.4 6.16E-03 2.54E-06 6.16E-03 3.59E-06
1 6.81E-07 1.55E-03 3.59E-06
6.81E-07 2.28E-03 0.4 1.55E-03 1.60E-07 2.81E-04 1.39E-06
1 0.00000002556 0 1.39E-06
1.60E-07 4.68E-04 0.4 2.81E-04 5.19E-07
1 2473.813027 -0.0001310869559 5.19E-07
0.00000002556 0 0.4 0 1.78E-07
1 1.78E-07
0.00000005298
0.00000005298
F2 F z1 z2 z
0.475 1.275 0.85
0.025 0.225 0.2 0.05 0.15
0.5 1.5

111
6 7 8 9 10

0.9
8.75E-03
8.75E-03 0.8

3.30E-03 1 0.7
3.30E-03 0.6
1.15E-03 1
0.5
1.15E-03
3.10E-04 1 0.4

3.10E-04 0.3
0 1
0.2

0.1

0
0 1 2 3 4 5 6 7 8 9 10
 0.4

0.3

0.2
0
0.1
0 1
0
0 1 2 3 4 5 6 7 8 9 10
5
Mezcla Benceno Tolueno

Comp A B C Tb
BENZENE 15.9008 2788.51 -52.36 353.3 80.2
TOLUENE 16.0137 3096.52 -53.67 383.8 110.7
1
P 760 0.9

0.8
x1 x2 T Psat1 Psat2 K1 K2 y1
0 1 110.62597469 1784.46236 760 2.34797679 1 0.7 0
0.1 0.9 106.13684401 1589.75991 667.804454 2.09178936 0.87869007 0.20917894
0.6
0.2 0.8 102.1037277 1429.10081 592.724798 1.8803958 0.77990105 0.37607916
0.5
0.3 0.7 98.457948866 1294.88672 530.762835 1.70379831 0.69837215 0.51113949
0.4 0.4
0.6 95.143243304 1181.49595 479.002699 1.55459994 0.63026671 0.62183997
0.5 0.5 92.113369828 1084.71343 435.286569 1.42725451 0.57274549 0.71362726
0.3
0.6 0.4 89.330142799 1001.33687 397.994697 1.31754851 0.52367723 0.79052911
0.2
0.7 0.3 86.761849437 928.902335 365.894552 1.22223991 0.4814402 0.85556794
0.8 0.1
0.2 84.381991118 865.490976 338.036094 1.13880392 0.44478433 0.91104313
0.9 0.1 82.168287 809.591321 313.678125 1.06525174 0.41273438 0.95872656
0
1 0 80.101885236 760 292.235804 1 0.3845208 0 0.1 1 0.2 0.3 0.4 0

SISTEMA NO IDEAL

Agua (1) 1,4-Dioxano ´(2) A B C

W 8.07131 1730.63 233.426
1,4D 7.43155 1554.679 240.337
P A12 A21
760 1.9029739931 1.73204104
x1 x2 T Psat1 Psat2 g1 g2 K1
0 1 101.29539984 796.068444 760 6.70580784 1 7.02405528
0.05 0.95 94.616854772 624.724171 616.705491 5.47728489 1.00518915 4.50235824
0.1 0.9 91.328698511 552.423821 554.704827 4.53320645 1.02071271 3.2950674
0.15 0.85 89.551373207 516.353375 523.368245 3.80029602 1.04673942 2.581968
0.2 0.8 88.56445099 497.191024 506.600972 3.22590286 1.08374745 2.11038151
0.25 0.75 88.020295297 486.883044 497.545266 2.77179716 1.13253278 1.77571189
0.3 0.7 87.729208084 481.442947 492.755601 2.4099407 1.19423246 1.52664336
0.35 0.65 87.580892249 478.690755 490.329674 2.11957319 1.2703634 1.33502643
 0.4 0.6 87.510366355 477.386694 489.179545 1.88518445 1.36287795 1.18416049
0.45 0.55 87.481486127 476.853544 488.709206 1.69508929 1.47423902 1.06356492
0.5 0.5 87.47851926 476.798801 488.660909 1.54041639 1.60751821 0.96640617
0.55 0.45 87.501927572 477.230856 489.042074 1.41438454 1.76652209 0.88814203
0.6 0.4 87.566737615 478.428789 490.098665 1.31178016 1.9559529 0.82578078
0.65 0.35 87.702925298 480.95427 492.324993 1.22857721 2.18161266 0.77748613
0.7 0.3 87.957903516 485.712691 496.515459 1.16165857 2.45066141 0.74241093
0.75 0.25 88.401878835 494.092422 503.881507 1.10861075 2.77194433 0.7207318
0.8 0.2 89.137917273 508.251628 516.289602 1.06757177 3.15640607 0.71394091
0.85 0.15 90.320753553 531.717686 536.751247 1.03711819 3.61761654 0.72559748
0.9 0.1 92.193558309 570.72455 570.497001 1.01618121 4.17243897 0.76310469
0.95 0.05 95.165694473 637.529181 627.582281 1.00398471 4.84188066 0.84219678
1 0 99.996829737 760 730.213579 1 5.65217847 1

0.48 0.52 87.47690069 476.768939 488.634562 1.59850884 1.5513509 1.00278863

0.4813 0.5187 87.476890745 476.768756 488.6344 1.59458653 1.55488218 1.00032768
0.48145 0.51855 87.476890607 476.768753 488.634398 1.5941353 1.55529068 1.0000446
0.4814714739 0.51852853 87.476890604 476.768753 488.634398 1.59407072 1.55534918 1.00000409
0.4814734444 0.51852656 87.476890604 476.768753 488.634398 1.5940648 1.55535455 1.00000038
0.4814736252 0.51852637 87.476890604 476.768753 488.634398 1.59406425 1.55535504 1.00000003

0.48147367 87.476891188
0.4814736699 0.51852633087.47689119 476.7687639488.63440741.5940641181.5553551660.999999972

EFECTO DE LA PRESIÓN EN EL EQUILIBRIO

P 152

x1 x2 T Psat1 Psat2 K1 K2 y1
0 1 62.282589993 424.085268 152 2.79003466 1 0
0.1 0.9 58.014976 364.727041 128.363662 2.39952001 0.84449778 0.239952
0.2 0.8 54.301498517 318.663704 110.334074 2.09647173 0.72588207 0.41929435
0.3 0.7 51.033375576 282.100552 96.2426208 1.85592468 0.63317514 0.5567774
0.4 0.6 48.128136645 252.506292 84.9958053 1.66122561 0.55918293 0.66449024
0.5 0.5 45.522474554 228.144669 75.8553305 1.50095177 0.49904823 0.75047589
0.6 0.4 43.167142162 207.793982 68.3090271 1.36706567 0.44940149 0.8202394
0.7 0.3 41.023320926 190.574507 61.9928169 1.25377965 0.40784748 0.87764576
0.8 0.2 39.06002355 175.83946 56.6421618 1.15683855 0.3726458 0.92547084
0.9 0.1 37.252218816 163.104329 52.0610356 1.0730548 0.34250681 0.96574932
1 0 35.579462452 152 48.1015924 1 0.31645784 1
P 760

x1 x2 T Psat1 Psat2 K1 K2 y1
0 1 110.62597469 1784.46236 760 2.34797679 1 0
0.1 0.9 106.13684401 1589.75991 667.804454 2.09178936 0.87869007 0.20917894
0.2 0.8 102.1037277 1429.10081 592.724798 1.8803958 0.77990105 0.37607916
0.3 0.7 98.457948866 1294.88672 530.762835 1.70379831 0.69837215 0.51113949
0.4 0.6 95.143243304 1181.49595 479.002699 1.55459994 0.63026671 0.62183997
0.5 0.5 92.113369828 1084.71343 435.286569 1.42725451 0.57274549 0.71362726
1
0.6 0.4 89.330142799 1001.33687 397.994697 1.31754851 0.52367723 0.79052911
0.7 0.9
0.3 86.761849437 928.902335 365.894552 1.22223991 0.4814402 0.85556794
0.8 0.2 84.381991118 865.490976 338.036094 1.13880392 0.44478433
0.8 0.91104313
0.9 0.1 82.168287 809.591321 313.678125 1.06525174 0.41273438 0.95872656
0.7
1 0 80.101885236 760 292.235804 1 0.3845208 1
0.6
P 3800
0.5

x1 x2 T Psat1 Psat2 K1 K20.4 y1

0 1 178.99412847 7523.30428 3800 1.97981691 0.3 1 0
0.1 0.9 174.16698467 6908.52994 3454.60778 1.81803419 0.90910731 0.18180342
0.2
0.2 0.8 169.70546658 6373.13272 3156.71682 1.67714019 0.83071495 0.33542804
0.3 0.7 165.57043248 5904.20537 2898.1977 1.55373826 0.7626836
0.1 0.46612148
0.4 0.6 161.72738769 5491.23883 2672.50744 1.44506285 0.70329143 0.57802514
0
0.5 0.5 158.14601697 5125.64429 2474.35571 1.34885376 0.65114624
0 0.10.67442688
0.2 0.3 0.4 0.5
0.6 0.4 154.79970887 4800.37131 2299.44304 1.26325561 0.60511659 0.75795336
Col umn H Col umn A C
0.7 0.3 151.66510279 4509.60448 2144.25621 1.18673802 0.56427795 0.83071661
0.8 0.2 148.7216739 4248.5229 2005.90839 1.11803234 0.52787063 0.89442587
0.9 0.1 145.95136211 4013.10955 1882.01405 1.05608146 0.49526685 0.95047331
1 0 143.33824485 3799.99995 1770.59081 0.99999999 0.46594495 0.99999999

P A12 A21
152 1.9029739931 1.73204104
x1 x2 T Psat1 Psat2 g1 g2 K1
0 1 55.80889426 122.414867 152 6.70580784 1 5.40059591
0.05 0.95 52.016294187 101.937323 129.939421 5.47728489 1.00518915 3.6732879
0.1 0.9 50.077388616 92.6548109 119.739494 4.53320645 1.02071271 2.76331175
0.15 0.85 49.026823031 87.935226 114.498991 3.80029602 1.04673942 2.19855191
0.2 0.8 48.454765105 85.4531849 111.727212 3.22590286 1.08374745 1.8135768
0.25 0.75 48.152590137 84.1665616 110.285951 2.77179716 1.13253278 1.53481997
0.3 0.7 48.003252181 83.5368653 109.579444 2.4099407 1.19423246 1.32446639
 0.35 0.65 47.938214548 83.2638958 109.272945 2.11957319 1.2703634 1.16107843
0.4 0.6 47.917872439 83.1786753 109.177227 1.88518445 1.36287795 1.03162596
0.45 0.55 47.921837919 83.1952822 109.195881 1.69508929 1.47423902 0.92778574
0.5 0.5 47.943967403 83.2880102 109.300027 1.54041639 1.60751821 0.84406721
0.55 0.45 47.99002741 83.4812974 109.517062 1.41438454 1.76652209 0.77680695
0.6 0.4 48.077136483 83.8478973 109.928509 1.31178016 1.9559529 0.72361848
0.65 0.35 48.234774178 84.5148332 110.676385 1.22857721 2.18161266 0.68311183
0.7 0.3 48.507648073 85.6800813 111.981061 1.16165857 2.45066141 0.65480922
0.75 0.25 48.961343777 87.6480255 114.178833 1.10861075 2.77194433 0.63926015
0.8 0.2 49.692836969 90.9026402 117.798414 1.06757177 3.15640607 0.63845456
0.85 0.15 50.850493767 96.265203 123.723019 1.03711819 3.61761654 0.65683153
0.9 0.1 52.67458688 105.264907 133.563611 1.01618121 4.17243897 0.70373829
0.95 0.05 55.587678379 121.130724 150.632685 1.00398471 4.84188066 0.80008813
1 0 60.425748005 152 182.990744 1 5.65217847 1

P A12 A21
760 1.9029739931 1.73204104
x1 x2 T Psat1 Psat2 g1 g2 K1
0 1 101.29539984 796.068444 760 6.70580784 1 7.02405528
0.05 0.95 94.616854772 624.724171 616.705491 5.47728489 1.00518915 4.50235824
0.1 0.9 91.328698511 552.423821 554.704827 4.53320645 1.02071271 3.2950674
0.15 0.85 89.551373207 516.353375 523.368245 3.80029602 1.04673942 2.581968
0.2 0.8 88.56445099 497.191024 506.600972 3.22590286 1.08374745 2.11038151
0.25 0.75 88.020295297 486.883044 497.545266 2.77179716 1.13253278 1.77571189
0.3 0.7 87.729208084 481.442947 492.755601 2.4099407 1.19423246 1.52664336
0.35 0.65 87.580892249 478.690755 490.329674 2.11957319 1.2703634 1.33502643
0.4 0.6 87.510366355 477.386694 489.179545 1.88518445 1.36287795 1.18416049
0.45 0.55 87.481486127 476.853544 488.709206 1.69508929 1.47423902 1.06356492
0.5 0.5 87.47851926 476.798801 488.660909 1.54041639 1.60751821 0.96640617
0.55 0.45 87.501927572 477.230856 489.042074 1.41438454 1.76652209 0.88814203
0.6 0.4 87.566737615 478.428789 490.098665 1.31178016 1.9559529 0.82578078
0.65 0.35 87.702925298 480.95427 492.324993 1.22857721 2.18161266 0.77748613
0.7 0.3 87.957903516 485.712691 496.515459 1.16165857 2.45066141 0.74241093
0.75 0.25 88.401878835 494.092422 503.881507 1.10861075 2.77194433 0.7207318
0.8 0.2 89.137917273 508.251628 516.289602 1.06757177 3.15640607 0.71394091
0.85 0.15 90.320753553 531.717686 536.751247 1.03711819 3.61761654 0.72559748
0.9 0.1 92.193558309 570.72455 570.497001 1.01618121 4.17243897 0.76310469
0.95 0.05 95.165694473 637.529181 627.582281 1.00398471 4.84188066 0.84219678
1 0 99.996829737 760 730.213579 1 5.65217847 1

P A12 A21
 3800 1.9029739931 1.73204104
x1 x2 T Psat1 Psat2 g1 g2 K1
0 1 163.29053986 5115.94318 3799.99995 6.70580784 1 9.02803472
0.05 0.95 151.40498705 3751.39619 2903.4878 5.47728489 1.00518915 5.4072278
0.1 0.9 145.84991117 3223.48589 2545.85434 4.53320645 1.02071271 3.84545448
0.15 0.85 142.88596572 2967.47007 2369.72321 3.80029602 1.04673942 2.96770124
0.2 0.8 141.23071936 2831.83629 2275.61578 3.22590286 1.08374745 2.40400757
0.25 0.75 140.29907012 2757.73772 2223.95637 2.77179716 1.13253278 2.01154988
0.3 0.7 139.7813165 2717.2442 2195.64907 2.4099407 1.19423246 1.72326247
0.35 0.65 139.49957316 2695.41291 2180.36492 2.11957319 1.2703634 1.50345393
0.4 0.6 139.34823875 2683.74553 2172.18993 1.88518445 1.36287795 1.3314093
0.45 0.55 139.26602356 2677.42425 2167.75885 1.69508929 1.47423902 1.19433505
0.5 0.5 139.22178416 2674.02782 2165.37746 1.54041639 1.60751821 1.08397797
0.55 0.45 139.20722872 2672.91111 2164.5944 1.41438454 1.76652209 0.99487478
0.6 0.4 139.23356377 2674.93185 2166.01135 1.31178016 1.9559529 0.92340067
0.65 0.35 139.3308985 2682.41129 2171.25476 1.22857721 2.18161266 0.86724984
0.7 0.3 139.55018545 2699.32414 2183.10436 1.16165857 2.45066141 0.82518237
0.75 0.25 139.96827088 2731.80978 2205.83756 1.10861075 2.77194433 0.79697729
0.8 0.2 140.69769088 2789.24672 2245.94541 1.06757177 3.15640607 0.78361081
0.85 0.15 141.90482179 2886.45242 2313.57953 1.03711819 3.61761654 0.78778745
0.9 0.1 143.84435703 3048.3802 2425.59326 1.01618121 4.17243897 0.81518597
0.95 0.05 146.9289853 3321.01659 2612.46674 1.00398471 4.84188066 0.87743418
1 0 151.88399143 3800 2936.07226 1 5.65217847 1

Una mezcla Benceno Tolueno que tiene 56% de benceno , se somete a flash a 1 atm de presión y se desea que se vaporice el 4
a.- Determinar las composiciones y cantidades de las corrientes de salida
b.- Determinar la temperatura de operación

Mezcla Benceno Tolueno

Comp A B C Tb
BENZENE 15.9008 2788.51 -52.36 353.3 80.2
TOLUENE 16.0137 3096.52 -53.67 383.8 110.7

140
F 200 kmol/h V 80 kmol/h
zi 0.56 L 120 kmol/h
y 0.4 130

0.56 110
T 92.95 0.56 0 120

110
 120

T 0 92.95
110
1 92.95
L/V 1.5
x 0.473 L/V 1.505747126
100
y 0.691

0.473 0 90
0.473 92.95
0.691 92.95
0.691 0 80

70
0.5 0.55 0.6 0

Comp A B C Tb
BENZENE 15.9008 2788.51 -52.36 353.3 80.2
TOLUENE 16.0137 3096.52 -53.67 383.8 110.7

P T Y
760 92.905149214 0.4
Comp zi Ki f x y
Bz 0.56 1.459722351 -0.21745664 0.47301734 0.69047399
Tol 0.44 0.5873552168 0.217456644 0.52698266 0.30952601
0.000015557 1 1

D1.* We are separating a mixture of methanol and water in a flash drum at 1 atm pressure. Equilibrium
data are listed in Table 2-7.
a. Feed is 60 mol% methanol, and 40% of the feed is vaporized. What are the vapor and liquid
mole fractions and flow rates? Feed rate is 100 kmol/h.
b. Repeat part a for a feed rate of 1500 kmol/h.
c. If the feed is 30 mol% methanol and we desire a liquid product that is 20 mol% methanol, what
V/F must be used? For a feed rate of 1000 lbmol/h, find product flow rates and compositions.
d. We are operating the flash drum so that the liquid mole fraction is 45 mol% methanol. L = 1500
kmol/h, and V/F = 0.2. What must the flow rate and composition of the feed be?
e. Find the dimensions of a vertical flash drum for Problem 2.D1c.
Data: ρw = 1.00 g/cm3, ρm,L = 0.7914 g/cm3, MWw = 18.01, MWm = 32.04. Assume vapors are
ideal gas.
f. If z = 0.4, p = 1 atm, and Tdrum = 77°C, find V/F, xm, and ym.
g. If F = 50 mol/h, z = 0.8, p = 1 atm, and ym = 0.892 mole fraction methanol, find V, L, and xm.

Txy
a. Feed is 60 mol% methanol, and 40% of the feed is vaporized. What are the vapor and liquid
mole fractions and flow rates? Feed rate is 100 kmol/h.
F 100 120
z 0.6
Y 0.4
110
V 40
L 60
100
L/V 1.5

90

80

70

60
V 40 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
L 60
1

-L/V -1.5
0.9
x0 0.6
y0 0.6 0.8

x 0 0.7
y 1.5
0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

c. If the feed is 30 mol% methanol and we desire a liquid product that is 20 mol% methanol, what
V/F must be used? For a feed rate of 1000 lbmol/h, find product flow rates and compositions.

F 1000 1
z 0.3
x 0.2 0.9

z 0.3 0 0.8
0.3 0.3
0.7
x 0.2 0
0.2 1
0.6

-L/V 0.3 0.3

0.5
0.2 0.58 y

-2.8 0.4

L/V 2.8
0.3
Y 0.2631578947
0.2
F 1000
V 263.1578947 0.1
L 736.8421053
0
0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95

D2.* Two flash distillation chambers are hooked together as shown in the diagram. Both are at 1 atm
pressure. The feed to the first drum is a binary mixture of methanol and water that is 55 mol%
methanol. Feed flow rate is 10,000 kmol/h. The second flash drum operates with (V/F)2 = 0.7 and
the liquid product composition is 25 mol% methanol. Equilibrium data are given in Table 2-7.
a. What is the fraction vaporized in the first flash drum?
b. What are y1, y2, x1, T1, and T2?

F1 10000 kmol/h
z1 0.55
z1 0.55 0.55 1
0.55 0 0.9

0.8
Y 0.162
F 10000 0.7
V 1620 0.6
L 8380
0.5
-L / V -5.172839506
0.4
x y 0.3
0.55 0.55
0.2
0 3.395061728
0.1
x y 0
0.506 0.7776049383 0.4 0.5 0.6 0.7 0.8 0.9 1

Comp z x y F L V
MetOH 0.55 0.506 0.777604938 5500 4240.28 1259.72
W 0.45 0.494 0.22239506 4500 4139.72 360.28
10000 8380 1620
z1 0.506 0.506 1
0.506 0 0.9

0.8
Y 0.7
F 8380 0.7
V 5866 0.6
L 2514
0.5
-L / V -0.4285714286
0.4
x y 0.3
0.506 0.506
0.2
0 0.7228571429
0.1
x y 0
0.25 0.6157142857 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

D6. A feed that is 45.0 mol% n-butane, 35.0 mol% n-pentane, and 20.0 mol% n-hexane is fed at a rate
of 1.0 kmol/min to a flash drum operating at 50°C and 200 kPa. Find V/F, liquid mole fractions
and vapor mole fractions. Use the DePriester charts.

P (psi) T [R] Y
28.99580558 581.67 0.4
Comp zi Ki f(Y)
nC4 0.45 2.502402429 -0.4222970484
nC5 0.35 0.8375553603 0.06080671378
nC6 0.2 0.3199288111 0.1868400524
1 -0.1746502823

D7. A flash drum is separating methane from propane at 0°C and 2500 kPa. The feed is 30.0 mol%
methane and 70.0 mol% propane. Find V/F, y and x. Use the results of Problem 2.C2. Use the
DePriester chart for K values.
D8.* You want to flash a mixture with a drum pressure of 2 atm and a drum temperature of 25°C. The
feed is 2000 kmol/h. The feed is 5 mol% methane, 10 mol% propane, and the rest n-hexane. Find
the fraction vaporized, vapor mole fractions, liquid mole fractions, and vapor and liquid flow
rates. Use DePriester charts.

4.36. Bubble point, dew point, and azeotrope of a mixture.

A solution at 107°C contains 50 mol% water (W) and 50 mol%
formic acid (F). Using (2-72) with vapor pressure data and the van
Laar equation with AWF=0.2935 and AFW=0.2757:
(a) Compute the bubble-point pressure. (b) Compute the dew-point
pressure. (c) Determine if the mixture forms an azeotrope. If so, predict
the azeotropic pressure at 107°C and the composition.
Comp A B C Tb
WATER 18.3036 3816.44 -46.13 373.2 100.1
FORMIC ACID 16.9882 3599.58 -26.09 373.8 100.7

T A12 A21
107 0.2935 0.2757
x1 x2 P Psat1/P Psat2/P g1 g2 K1
0 1 917.46833286 1.05780822 1 1.34111318 1 1.41864054
0.1 0.9 950.99502224 1.0205159 0.96474567 1.26452265 1.0030893 1.29046547
0.2 0.8 976.06852061 0.99430063 0.93996304 1.20091212 1.01225585 1.19406767
0.3 0.7 994.21436021 0.97615321 0.92280736 1.14843679 1.02743146 1.12105026
0.4 0.6 1006.4679838 0.96426867 0.9115723 1.10562079 1.04865298 1.06611549
0.5 0.5 1013.4673731 0.95760906 0.90527663 1.07128364 1.0760568 1.02587093
0.6 0.4 1015.5169 0.95567641 0.9034496 1.04448375 1.1098763 0.99818847
0.7 0.3 1012.6291447 0.95840175 0.906026 1.02447473 1.15044211 0.98185837
0.8 0.2 1004.5492568 0.96611046 0.91331344 1.01067167 1.19818463 0.97642047
0.9 0.1 990.76516302 0.97955154 0.92601998 1.00262494 1.25363905 0.9821228
1 0 970.50554171 1 0.94535095 1 1.31745257 1

P
1013.4673731
zi Psat/P g Ki yi
W 0.5 0.9576090632 1.071283643 1.02587093 0.51293546
HF 0.5 0.9052766347 1.076056795 0.97412907 0.48706454
1

P
1017
zi Psat/P g Ki yi
W 0.4 0.9542827352 1.105620792 1.05507483 0.42202993
HF 0.6 0.9021320874 1.048652982 0.9460235 0.5676141
0.9896440352
 1

0.9

0.8
y2 Sy a x y
0.7 1 1 2.34797679 0 0 120
0.6 0.79082106 1 2.38057698 0.1 0.21636574
0.62392084 1 2.41106971 0.2 0.38318719 110
0.5
0.48886051 1 2.43967104 0.3 0.51573343
0.4 0.37816003 1 2.46657473 0.4 0.62358369
100
0.3 0.28637274 1 2.49195245 0.5 0.7130518
0.20947089 1 2.51595531 0.6 0.78846832
0.2 90
0.14443206 1 2.53871595 0.7 0.85290258
0.1 0.08895687 1 2.56035078 0.8 0.90859064
80
0 0.04127344 1 2.580962 0.9 0.95720011
1
0 0.1 0.2 0.3 0.4
0 0.5 0.6 0.7 0.8 0.9
1 2.60063958 1 1 1
0.9 70
11
2.484949574 0.8
60
0.7
0 0.1 0.2 0.3
0.6
1
0.5
0.9
0.4
0.8
0.3
0.7
0.2
0.6
0.1
0.5
0 105
0.4
0 0.1 0.2 0.3
0.3

K2 y1 y2 Sy 0.2

1 0 1 1 100 0.1
0.81566536 0.22511791 0.77488209 1 1
0
0.74499246 0.32950674 0.67049321 0.99999995 0 0.1 0.2
0.72082918 0.3872952 0.6127048 1 0.9

0.72240462 0.4220763 0.5779237 1 95

0.74142937 0.44392797 0.55607203 1 0.8

0.7742957 0.45799301 0.54200699 1

0.81960115 0.46725925 0.53274075 1 0.7
90
0.6

0.5
 95
0.8

0.7

0.87722634 0.4736642 0.5263358 1 90

0.94799234 0.47860421 0.52139579 1 0.6

1.03359383 0.48320308 0.51679692 1

1.1367153 0.48847812 0.51152188 1 0.5

1.26132882 0.49546847 0.50453153 1 85

1.41324005 0.50536598 0.49463402 1 0.4

1.60104115 0.51968765 0.48031235 1

1.83780459 0.54054885 0.45945115 1 0.3

2.14423636 0.57115273 0.42884727 1 80

2.55494762 0.61675786 0.38324214 1 0.2 0 0.1 0.2 0.

3.13205779 0.68679422 0.31320578 1

3.99826119 0.80008694 0.19991306 1 0.1

5.43065457 1 0 1
20.99999995 0
0 0.1 0.2 0.3 0

0.99742588 0.48133854 0.51866146 1 5.329070518E-05

0.99969595 0.48145771 0.51854229 1 0
0.99995859 0.48147147 0.51852853 1 0
0.9999962 0.48147344 0.51852656 1 0
0.99999965 0.48147363 0.51852637 1 -0.0001110223
0.99999997 0.48147364 0.51852636 1 0

1.000000066 0.48147366 0.51852636 1.000000021

y2 Sy
1 1
0.760048 1
0.58070565 1
0.4432226 1
0.33550976 1
0.24952411 1
0.1797606 1
0.12235424 1
0.07452916 1
0.03425068 1
0 1
11
 y2 Sy
1 1
0.79082106 1
0.62392084 1
0.48886051 1
0.37816003 1
0.28637274 1
0.20947089 1
0.14443206 1
0.08895687 1
0.04127344 1
0 1
11 70

60

y2 Sy 50
1 1
0.81819658 1 40
0.66457196 1
30
0.53387852 1
0.42197486 1
20
0.2 0.32557312
0.3 0.4 0.5 0.6 1 0.7 0.8 0.9 1
Col umn H 0.24204664
Col umn A Col umn H 1 Col umn H 10
0.16928339 1
0.10557413 1 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.04952669 1
0 0.99999999
10.99999999

K2 y1 y2 Sy
1 0 1 1
0.85930064 0.1836644 0.8163356 1
0.80407647 0.27633117 0.72366883 1
0.78849084 0.32978279 0.67021721 1
0.7966058 0.36271536 0.63728464 1
0.82172668 0.38370499 0.61629501 1
0.86094296 0.39733992 0.60266007 0.99999999
0.91326546 0.40637745 0.59362255 1
0.97891603 0.41265038 0.58734962 1
1.0590844 0.41750358 0.58249642 1
1.15593279 0.42203361 0.57796639 1
1.27279151 0.42724382 0.57275618 1
1.41457228 0.43417109 0.56582891 1
1.5885066 0.44402269 0.55597731 1
1.80544516 0.45836645 0.54163355 1
2.08221954 0.47944512 0.52055488 1
2.44618177 0.51076365 0.48923635 1
2.94462131 0.5583068 0.4416932 1
3.66635536 0.63336446 0.36663554 1
4.79832554 0.76008372 0.23991628 1
6.8045812 1 0 1
20.99999999

K2 y1 y2 Sy
1 0 1 1
0.81566536 0.22511791 0.77488209 1
0.74499246 0.32950674 0.67049321 0.99999995
0.72082918 0.3872952 0.6127048 1
0.72240462 0.4220763 0.5779237 1
0.74142937 0.44392797 0.55607203 1
0.7742957 0.45799301 0.54200699 1
0.81960115 0.46725925 0.53274075 1
0.87722634 0.4736642 0.5263358 1
0.94799234 0.47860421 0.52139579 1
1.03359383 0.48320308 0.51679692 1
1.1367153 0.48847812 0.51152188 1
1.26132882 0.49546847 0.50453153 1
1.41324005 0.50536598 0.49463402 1
1.60104115 0.51968765 0.48031235 1
1.83780459 0.54054885 0.45945115 1
2.14423636 0.57115273 0.42884727 1
2.55494762 0.61675786 0.38324214 1
3.13205779 0.68679422 0.31320578 1 1

3.99826119 0.80008694 0.19991306 1

5.43065457 1 0 1 0.9
20.99999995 70

0.8

0.7 60

0.6
 0.9
70

0.8

0.7 60
K2 y1 y2 Sy
0.99999999 0 0.99999999 0.99999999
0.6
0.76804064 0.27036139 0.72963861 1 50
0.68383839 0.38454545 0.61545455 1
0.5
0.65275861 0.44515519 0.55484481 1
0.64899811 0.48080151 0.51919849 1
40
0.66281671 0.50288747 0.49711253 1 0.4
0.69003037 0.51697874 0.48302126 1
0.72890942 0.52620888 0.47379112 1 0.3
30
0.77906046 0.53256372 0.46743628 1
0.8409986 0.53745077 0.46254923 1 0.2
0.91602203 0.54198899 0.45801101 1
1.00626416 0.54718113 0.45281887 1 20
0.1
1.114899 0.5540404 0.4459596 1
1.24653602 0.56371239 0.43628761 1
0 10
1.4079078 0.57762766 0.42237234 1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
1.60906813 0.59773297 0.40226703 1
1.86555678 0.62688864 0.37311136 1
2.20253779 0.66961933 0.33038067 1 0
2.66332628 0.73366737 0.26633263 1 0 0.1 0.2 0.3 0.4

3.32875057 0.83356247 0.16643753 1

4.36715906 1 0 1
20.99999999

e desea que se vaporice el 40% de la alimentación

120

110
140

130 100

120
90

110
80
120
90

110
80

100

70

90

60
80 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

70
0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1

T x y 105
100 0 0
100
96.4 0.02 0.134
1
93.5 0.04 0.23 95
91.2 0.06 0.304 0.9
90
89.3 0.08 0.365 0.8
87.7 0.1 0.418 85
0.7
84.4 0.15 0.517 80
81.7 0.2 0.579 0.6
75
78 0.3 0.665 0.5
75.3 0.4 0.729 0.4 70
73.1 0.5 0.779
0.3 65
71.2 0.6 0.825
69.3 0.7 0.87 0.2 60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
67.6 0.8 0.915 0.1
66 0.9 0.958 0
65 0.95 0.979 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
64.5 1 1
 z 0.6 0
0.6 100

T 0 73.37
1 73.37

x 0.486 0
0.486 73.37
y 0.774 73.37
0.774 0

0.174
0.114

1.526315789

0.9 1

z 0.6 0
0.6 0.6

-L/V 0.6 0.6

0 1.5

x 0.486 0
y 0.486 0.773
0 0.773

0.9 1
 0.9 1

0.8 0.85 0.9 0.95 1 0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2
 0.4

0.3

0.2

0.1

0
0.5 0.55 0.6 0.65

aT1 aT2 aT6 aP1 aP2

C1 -292860 0 8.2445 -0.8951 59.8465
C2= -600076.88 0 7.90595 -0.84677 42.94594
C2 -687248.25 0 7.90694 -0.886 49.02654
C3= -923484.69 0 7.71725 -0.87871 47.67624
C3 -970688.56 0 7.156059 -0.76984 0
iC4 -1166846 0 7.72668 -0.92213 0
nC4 -1280557 0 7.94986 -0.96455 0
iC5 -1481583 0 7.58071 -0.93159 0
nC5 -1524891 0 7.33129 -0.89143 0
nC6 -1778901 0 6.96783 -0.84634 0
nC7 -2013803 0 6.52914 -0.79543 0
nC8 0 -7646.81641 12.48457 -0.73152 0
nC9 -2551040 0 5.69313 -0.67818 0
nC10 0 -9760.45703 13.80354 -0.7147 0
K2 y1 y2 1040 Sy
1 0 1020 1 1
0.96772606 0.12904655 0.87095345 1
1000
0.95148308 0.23881353 0.76118647 1
0.94812132 0.33631508 0.66368492
980 1
0.95592301 0.4264462 1018
0.5735538 1
960
0.97412907 0.51293546 0.48706454
1016 1
1.0027173 0.59891308 940
0.40108692 1
1014
1.04233046 0.68730086 0.31269914
920 1
1.09431812 0.78113638 0.21886362
1012 1
900
1.1608948 0.88391052 0.11608948 1
1010
1.24545503 1 880 0 1
1008 11
860
1006 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

1004 1

1002 0.9

1000 0.8
0.4 0.42 0.44 0.46 0.48 0.5 0.52 0.54 0.56 0.58 0.6
0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 120

110

100

90

80
1

0.9 70

0.8
60
0.7
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.6
1
0.5
0.9
0.4
0.8
0.3
0.7
0.2
0.6
0.1
0.5
0 105
0.4
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.3

0.2
100 0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

95

90
 95

90

85

80
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Col umn C Col umn J

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.5 0.6 0.7 0.8 0.9 1

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1
 0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.7 0.8 0.9 1

0.4 0.5 0.6 0.7 0.8 0.9 1

0.7 0.8 0.9 1

 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2
0.4

0.3

0.2

0.1

0
0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1

aP3
0
0
0
0
6.90224
0
0
0
0
0
0
0
0
0
0.7 0.8 0.9 1
7 0.8 0.9 1
Curvas de ELV del sistema Benceno-Tolueno

Comp A B C Tb (K)
BENZENE 15.9008 2788.51 -52.36 353.3 80.2
TOLUENE 16.0137 3096.52 -53.67 383.8 110.7
P
1
760
x1 x2 T Psat1 Psat2 K1 K2 0.9 y1
0 1 110.625975 1784.46236 760 2.34797679 1 0
0.1 0.9 106.136844 1589.75991 667.804454 2.09178936 0.87869007 0.20917894
0.8
0.2 0.8 102.103728 1429.10081 592.724798 1.8803958 0.77990105 0.37607916
0.7
0.3 0.7 98.4579489 1294.88672 530.762835 1.70379831 0.69837215 0.51113949
0.4 0.6 95.1432433 1181.49595 479.002699 1.55459994 0.63026671
0.6 0.62183997
0.5 0.5 92.1133698 1084.71343 435.286569 1.42725451 0.57274549 0.71362726
0.6 0.4 89.3301428 1001.33687 397.994697 1.31754851 0.52367723
0.5 0.79052911
0.7 0.3 86.7618494 928.902335 365.894552 1.22223991 0.4814402 0.85556794
0.4
0.8 0.2 84.3819911 865.490976 338.036094 1.13880392 0.44478433 0.91104313
0.9 0.1 82.1682869 809.59132 313.678124 1.06525174 0.41273437
0.3 0.95872656
1 0 80.1018852 760 292.235804 1 0.3845208 1
0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0

SISTEMA NO IDEAL
Agua (1) 1,4-Dioxano ´(2) A B C
W 8.07131 1730.63 233.426
1,4D 7.43155 1554.679 240.337
P A12 A21
760 1.90297399 1.73204104

x1 x2 T Psat1 Psat2 g1 g2 K1
0 1 101.2954 796.068444 760 6.70580784 1 7.02405528
0.05 0.95 94.6168548 624.724171 616.705491 5.47728489 1.00518915
1 4.50235824
0.1 0.9 91.3286999 552.423851 554.704853 4.53320645 1.02071271 3.29506758
0.9
0.15 0.85 89.5513732 516.353375 523.368245 3.80029602 1.04673942 2.581968
0.2 0.8 88.564451 497.191024 506.600972 3.22590286 1.08374745
0.8 2.11038151
0.25 0.75 88.0202953 486.883044 497.545266 2.77179716 1.13253278 1.77571189
0.3 0.7 87.7292081 481.442947 492.755601 2.4099407 0.7
1.19423246 1.52664336
0.35 0.65 87.5808922 478.690755 490.329674 2.11957319 1.2703634 1.33502643
0.6
0.4 0.6 87.510367 477.386706 489.179556 1.88518445 1.36287795 1.18416052
0.45 0.55 87.4814861 476.853544 488.709206 1.69508929 1.47423902
0.5 1.06356492
0.5 0.5 87.4785193 476.798801 488.660909 1.54041639 1.60751821 0.96640617
0.55 0.45 87.5019276 477.230856 489.042074 1.41438454 0.4
1.76652209 0.88814203
0.6 0.4 87.5667376 478.428789 490.098665 1.31178016 1.9559529 0.82578078
0.3
0.65 0.35 87.7029253 480.95427 492.324993 1.22857721 2.18161266 0.77748613
0.7 0.3 87.9579035 485.712691 496.515459 1.16165857 2.45066141
0.2 0.74241093
0.75 0.25 88.4018788 494.092422 503.881507 1.10861075 2.77194433 0.7207318
0.1
0.8 0.2 89.1379173 508.251628 516.289602 1.06757177 3.15640607 0.71394091
0.85 0.15 90.3207536 531.717686 536.751247 1.03711819 3.61761654
0
0.72559748
0.9 0.1 92.1935583 570.72455 570.497001 1.01618121 4.17243897
0 0.76310469
0.1 0.2 0.3 0.4 0.5
0.95 0.05 95.1656945 637.529181 627.582281 1.00398471 4.84188066 0.84219678
1 0 99.9968297 760 730.213579 1 5.65217847 1

0.5 0.5 87.4785193 476.798801 488.660909 1.54041639 1.60751821 0.96640617

0.48320308 0.51679692 87.4769045 476.76901 488.634625 1.58888216 1.56008111 0.99674971
0.48163253 0.51836747 87.4768907 476.768755 488.6344 1.59358657 1.55578808 0.99970038
0.48148823 0.51851177 87.4768906 476.768753 488.634398 1.59402035 1.55539482 0.99997249
0.48147498 0.51852502 87.4768906 476.768753 488.634398 1.59406017 1.55535874 0.99999748
0.48147377 0.51852623 87.4768906 476.768753 488.634398 1.59406383 1.55535543 0.99999977 1
0.9

0.8
D3. We are separating a mixture of methanol and water in a flash drum at 1.0 atm pressure. Use the
equilibrium data listed in Table 2-7. Feed rate is 10.0 kmol/h. 0.7

a. The feed is 40 mol% methanol and 60% of the feed is vaporized. Find mole fractions and flow 0.6

0.5

0.4

0.3
 0.8

0.7

0.6
rates of vapor and liquid products. Estimate the temperatures by linear interpolation for both 0.5
vapor and liquid products.
0.4
b. The feed is 40 mol% methanol, the product temperatures are both 78.0°C. Find the mole
fractions of liquid and vapor products and V/F. 0.3

c. We desire a vapor product that is 80 mol% methanol and want to operate at V/F = 0.3. What 0.2
must the feed composition be? 0.1

0
F 10 kmol/h T 0 0.1 0.2
z 0.4
Y 0.6

z 0.4 0 105
0.4 100
100

T 82.9 95

90
T 0 82.9
85
1 82.9
80
x 0.173 0 75
0.173 82.9
70

y 0.551 82.9 65
0.551 0
60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
F L V
10 4 6

L/V 0.666666666L/V 0.6651982379

b. The feed is 40 mol% methanol, the product temperatures are both 78.0°C. Find the mole
fractions of liquid and vapor products and V/F.

F 10 kmol/h 105
z 0.4
100
T 78
95

z 0.4 0 90
0.4 100
85

T 78 80

75
T 0 78
70

65

60
 80

75

70
1 78
65
x 0.3 0
60
0.3 78 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

y 0.665 78
0.665 0

F L V Y
10 7.2602739732.739726027 0.2739726027

L/V 2.65

c. We desire a vapor product that is 80 mol% methanol and want to operate at V/F = 0.3. What
must the feed composition be?

Y F L V
0.3 10 7 3

L/V 2.333333333
1
y 0.8
0.9
y 0 0.8
0.8
x 0.55 0.8
0.55 0 0.7

0.6
x0 y0
0.625 0.625 0.5
0.55 0.8
0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

D2.* Two flash distillation chambers are hooked together as shown in the diagram. Both are at 1 atm
pressure. The feed to the first drum is a binary mixture of methanol and water that is 55 mol%
methanol. Feed flow rate is 10,000 kmol/h. The second flash drum operates with (V/F)2 = 0.7 and
the liquid product composition is 25 mol% methanol. Equilibrium data are given in Table 2-7.
a. What is the fraction vaporized in the first flash drum?
b. What are y1, y2, x1, T1, and T2?

SEPARADOR 1 1
F1 10000
0.9
z1 0.55
0.8

Y1 0.458 0.7

V 4580 0.6
L 5420 0.5

0.4
-L1/V1 -1.183406114
0.3

z1 0.55 0.55 0.2

0.55 0 0.1

0
x 0.4 0.727510917 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.55 0.55

Comp F1 L1 V1 z1 x1 y1
MetOH 5500 2168 3332 0.55 0.4 0.727510917
W 4500 3252 1248 0.45 0.6 0.27248908
10000 5420 4580

Y2 0.7 1

0.9
F2 5420
0.8
L2 1626
0.7
V2 3794
0.6
-L2/V2 -1.5 0.5

0.4
z2 0.4 0.4
0.3
0.4 0
0.2

x 0.25 0.625 0.1

0.4 0.4 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.25
Comp F2 L2 V2 z2 x2 y2
MetOH 2168 406.5 2371.25 0.4 0.25 0.625
W 3252 1219.5 1422.75 0.6 0.75 0.375
5420 1626 3794
 y2 Sy a x y
1 1 2.34797679 0 0
0.79082106 1 2.38057698 0.1 0.21636574
0.62392084 1 2.41106971 0.2 0.38318719
0.48886051 1 2.43967104 0.3 0.51573343
0.37816003 1 2.46657473 0.4 0.62358369
0.28637274 1 2.49195245 0.5 0.7130518
0.20947089 1 2.51595531 0.6 0.78846832
0.14443206 1 2.53871595 0.7 0.85290258
0.08895687 1 2.56035078 0.8 0.90859064
0.04127344 1 2.580962 0.9 0.95720011
0 1 2.60063958 1 1
11
2.484949574

1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

 K2 y1 y2 Sy
1 0 1 1
0.81566536 0.22511791 0.77488209 1
0.74499249 0.32950676 0.67049324 1
0.72082918 0.3872952 0.6127048 1 105
0.72240462 0.4220763 0.5779237 1
0.74142937 0.44392797 0.55607203 1
100
0.7742957 0.45799301 0.54200699 1
0.81960115 0.46725925 0.53274075 1
0.87722636 0.47366421 0.52633581 1.00000002 95
0.94799234 0.47860421 0.52139579 1
1.03359383 0.48320308 0.51679692 1
90
1.1367153 0.48847812 0.51152188 1
1.26132882 0.49546847 0.50453153 1
1.41324005 0.50536598 0.49463402 1 85
1.60104115 0.51968765 0.48031235 1
1.83780459 0.54054885 0.45945115 1
80
2.14423636 0.57115273 0.42884727 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
2.55494762 0.61675786 0.38324214 1
0.1 0.2 3.13205779
0.3 0.4 0.68679422
0.5 0.6 0.31320578
0.7 0.8 0.9 11
3.99826119 0.80008694 0.19991306 1
5.43065457 1 0 1

21.00000002

1.03359383 0.48320308 0.51679692 1 -8.9706E-05

1.00303901 0.48163253 0.51836747 1 -6.6613E-06
1.00027839 0.48148823 0.51851177 1 0
1.00002554 0.48147498 0.51852502 1 0
1.00000234 0.48147377 0.51852623 1 -0.0002636
1.00000022
1 0.48147365 0.51852635 1 0
0.9 105

0.8 100
0.7
95
0.6
90
0.5
85
0.4
80
0.3
 0.8 100
0.7
95
0.6
90
0.5
85
0.4
80
0.3
75
0.2

0.1 70

0 65
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

0.4 0.5 0.6 0.7 0.8 0.9 1

 0.4 0.5 0.6 0.7 0.8 0.9 1

0.8 0.9 1
 105

100

95

90

85
T
75.1 80

75
0 75.1
70
0.4 75.1
65
0.8 0.9 1
60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

105

100

95

90
T2
85
79.6
80
0 79.6 75
0.25 79.6
70

.6 0.7 0.8 0.9 1 65

60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

120 0.2

0.1
110
0
0 0.1 0.2 0.3 0.4 0.5
100

90

80

70

60
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.6 0.7 0.8 0.9 1
0.5 0.6 0.7 0.8 0.9 1
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3
0.7 0.8 0.9 1
0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.8 0.9 1
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Para la ecuación de Antoine en la forma
, con Psat en mm Hg y T en °C, las constantes de n-pentano son: A = 6.853, B = 1064.8, C = 233.01. y para el n-hexano son: A = 6.876, B = 1171.17, C = 224.41 (Dean
a. Predecir la presión de vapor a 0 ºC para n-pentano puro
b. Predecir el punto de ebullición de n-pentano puro a 3 atmósferas de presión.
c. Predecir la presión de ebullición si n-pentano puro hierve a 0°C.
d. A una presión de 500 mm Hg y temperatura de 30°C, predecir los valores de K para n-pentano y n-hexano mediante ley Raoult.
e. Para una mezcla binaria con dos fases en equilibrio, F = C-P+2 = 2–2+2=2 grados de libertad. Si T=30°C y P = 500 mm de Hg, determinar las fracciones molares en
f. Un mol de una mezcla que es 75 mol % n-pentano se coloca en una cámara cerrada. La presión se ajusta al 500 mm Hg y la temperatura a 30°C. El vapor y la fracci
g. Si 1 mol/min de una mezcla que contiene 75% de n-pentano se alimenta continuamente a un Flash, que trabaja a 30°C y 500 mmHg¿Cuáles son los flujos de vapor

a. Predecir la presión de vapor a 0 ºC para n-pentano puro

P T 191.972511 a
191.972511 0 71.64812607b
A B C Psat/P 45.3 c
Pentano 6.853 1064.8 233.01 1 1.2750133440.374589232d
Hexano 6.876 1171.17 224.41 0.2365243611 0.694573545 0.88559054 e
0.305426454 0.11440946
b. Predecir el punto de ebullición de n-pentano puro a 3 atmósferas de presión. 0.2901650460.709834953f
P T 0.694573545 0.88559054 g
2280 71.6481261 0.305426454 0.11440946
Psat/P
1
4.333934788

c. Predecir la presión de ebullición si n-hexano puro hierve a 0°C.

P T 0.3015681544
45.3 0
Psat/P
4.237803775
1.00234383

d. A una presión de 500 mm Hg y temperatura de 30°C, predecir los valores de K para n-pentano y n-hexano mediante ley Raoult.
 P T
500 30
Psat/P
1.275013344
0.3745892325

e. Para una mezcla binaria con dos fases en equilibrio, F = C-P+2 = 2–2+2=2 grados de libertad. Si T=30°C y P = 500 mm de Hg, determinar
las fracciones molares en las fases líquido y vapor de una mezcla de equilibrio de n-pentano y n-hexano.
P T
500 30
Psat/P x y
1.2750133440.694573545 0.88559054
0.3745892320.305426454 0.11440946
1

f. Un mol de una mezcla que es 75 mol % n-pentano se coloca en una cámara cerrada. La presión se ajusta al 500 mm Hg y la temperatura a 30°C.
El vapor y la fracción molar de líquido fueron encontrados en la parte (e). ¿Cuantos moles de vapor y líquido hay en el equilibrio?
P T Y V L
500 30 0.29016505 0.2901650460.7098349539
z Psat/P f
0.75 1.275013344-0.19101699 0.69457355 0.88559054
0.25 0.3745892320.191016993 0.30542645 0.11440946
0.000000009 1 1

g. Si 1 mol/min de una mezcla que contiene 75% de n-pentano se alimenta continuamente a un Flash, que trabaja a 30°C y 500 mmHg¿Cuáles son los flujos de vapor
76, B = 1171.17, C = 224.41 (Dean, 1985)

erminar las fracciones molares en las fases líquido y vapor de una mezcla de equilibrio de n-pentano y n-hexano.
eratura a 30°C. El vapor y la fracción molar de líquido fueron encontrados en la parte (e). ¿Cuantos moles de vapor y líquido hay en el equilibrio?
Hg¿Cuáles son los flujos de vapor y líquido?

2
3
3
3
3

3
3

20
eratura a 30°C.

Hg¿Cuáles son los flujos de vapor y líquido?

atmosphere pressure. The column has a total condenser and a partial reboiler. The distillate is 90
mol% acetone, and the bottoms is 10 mol% acetone. The reflux is returned as a saturated liquid.
Use a boilup ratio of Vm/B = 2.0. Two feeds are fed to the column. The first feed has a flow rate of
75 kmol/h, it is a saturated liquid, and it is 60 mol% acetone. The second feed has a flow rate of
100 kmol/h, it is a two-phase mixture that is 60% vapor, and it is 40 mol% acetone. Use the
optimum feed location for each feed. Assume CMO. Equilibrium data are in Problem 4.D7.
a. Find the distillate and bottoms flow rates, D and B.
b. Plot the two feed lines and the three operating lines.
c. Step off stages and find the optimum feed location for each feed stream and the total number of
equilibrium stages required.

Comp F1 F2 D B z1 z2 xD xB
Ac 45 40 75.9375 9.0625 0.6 0.4 0.9 0.1
EtOH 30 60 8.4375 81.5625 0.4 0.6 0.1 0.9
75 100 84.375 90.625
1
xD 0.9 0.9
0.9
0.9 0
0.8
z1 0.6 0.6
0.6 0 0.7

0.6
z2 0.4 0.4
0.4 0 0.5

0.4
xB 0.1 0.1
0.1 0 0.3

Vm/B 2 0.2

q1 1
0.1
q2 0.4
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
BALANCES INTERNOS

F1 F2 D B q1 q2 Vm/B
75 100 84.375 90.625 1 0.4 2

Vm Lm Vi Li Vn Ln R
181.25 271.875 241.25 231.875 241.25 156.875 1.859259259

1
LOR 0.9 0.9 mLOR bLOR
0.6 0.7049222798 0.6502590670.3147668394 0.9

LOF1 0.6 0.6 mLOF1 bLOF1 0.8

0.6 0.7049222798 #DIV/0! #DIV/0!
0.7

LOI 0.6 0.7049222798 mLOI bLOI 0.6

0.3307692300.4461538462 0.9611398960.128238342
0.5

LOF2 0.4 0.4 mLOF2 bLOF2 0.4

0.3307692300.4461538462 -0.66666666 0.6666666667
0.3

LOS 0.1 0.1 mLOS bLOS

0.2
0.3307692300.4461538462 1.5 -0.05
0.1

0
ETAPAS N 0 0.1 0.2 0.3 0.4 0.5 0.6
0.9 0.9 1
0.856 0.9
0.856 0.871388601 1 0.9
0.81 0.871388601
0.81 0.841476683 1 0.8
0.762 0.8414766839
0.7

0.6
 0.9

0.8

0.762 0.810264248 1 0.7

0.712 0.8102642487
0.712 0.777751295 1 0.6
0.665 0.7777512953
0.665 0.747189119 1 0.5
0.614 0.7471891192
0.614 0.714025906 1
0.4
0.57 0.7140259067
0.57 0.676088082 1
0.3
0.504 0.6760880829
0.504 0.612652849 1
0.2
0.412 0.6126528497
0.412 0.524227979 1
0.1
0.302 0.5242279793
0.302 0.403 1
0
0.19 0.403
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.19 0.235 1
0.09 0.235
0.09 0.085 1

1
0.6 0.7 0.8 0.9 1
 0.6 0.7 0.8 0.9 1

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9 1
D1. A continuous, steady-state distillation column with a total condenser and a partial reboiler is
separating methanol from water at one atmosphere (see Table 2-7 for data). The feed rate is 100
kmol/h. The feed is 55 mol% methanol and 45 mol% water. We desire a distillate product that is
90 mol% methanol and a bottoms product that is 5 mol% methanol. Assume CMO.
a. If the external reflux ratio L/D = 1.25 plot the top operating line.
b. If the boilup ratio Vm/B = 2.0 plot the bottom operating line.
c. Step off stages starting at the bottom with the partial reboiler. Use the optimum feed stage.
Report the optimum feed stage and the total number of stages.
d. Plot the feed line. Calculate its slope. Calculate q. What type of feed is this?

DIAGRAMA xy

0 0 0 0
1
2 13.4 0.02 0.134
4 23 0.04 0.23
0.9
6 30.4 0.06 0.304
8 36.5 0.08 0.365 0.8
10 41.8 0.1 0.418
15 51.7 0.15 0.517 0.7
20 57.9 0.2 0.579
0.6
30 66.5 0.3 0.665
40 72.9 0.4 0.729
0.5
50 77.9 0.5 0.779
60 82.5 0.6 0.825 0.4
70 87 0.7 0.87
80 91.5 0.8 0.915 0.3

90 95.8 0.9 0.958

0.2
95 97.9 0.95 0.979
100 100 1 1 0.1

0
0 0.1 0.2 0.3 0.4

BALANCES EXTERNOS

Comp F D B z xD xB
MetOH 55 52.94 2.06 0.55 0.9 0.05
W 45 5.88 39.12 0.45 0.1 0.95
100 58.82 41.18

z, xD, xB

xD 0.9 0
0.9 0.9

z 0.55 0
0.55 0.55
xB 0.05 0
0.05 0.05

LOR
D R xD
58.82 1.25 0.9

mLOR bLOR
0.5555555550.4

LOR 0.9 0.9

0 0.4

LOS

B Vm/B Vm Lm xB
41.18 2 82.35 123.53 0.05

mLOS bLOS
1.5 -0.025
1
LOS 0.05 0.05
0.45 0.65 0.9

0.8
N, Nf
0.05 0.05 0.7
0.05 0.27
0.6
0.1966666660.27 1
0.196666666 0.576 0.5
0.4006666660.576 1
0.4
0.400666666 0.73
0.594 0.73 1 0.3
0.594 0.822
0.2
0.7596 0.822 1
0.7596 0.896 0.1
0.8928 0.896 1
0
0.8928 0.955
0.5 0.55 0.6 0.65 0.7 0.75 0.8
0.999 0.955 1

LOF 0.55 0.55

0.45 0.65
mLOF bLOF q
 -1 1.1 0.5

D6. We are separating a mixture of acetone and ethanol in a distillation column operating at one
atmosphere pressure. The column has a total condenser and a partial reboiler. The distillate is 90
mol% acetone, and the bottoms is 10 mol% acetone. The reflux is returned as a saturated liquid.
Use a boilup ratio of Vm/B = 2.0. Two feeds are fed to the column. The first feed has a flow rate of
75 kmol/h, it is a saturated liquid, and it is 60 mol% acetone. The second feed has a flow rate of
100 kmol/h, it is a two-phase mixture that is 60% vapor, and it is 40 mol% acetone. Use the
optimum feed location for each feed. Assume CMO. Equilibrium data are in Problem 4.D7.
a. Find the distillate and bottoms flow rates, D and B.
b. Plot the two feed lines and the three operating lines.
c. Step off stages and find the optimum feed location for each feed stream and the total number of
equilibrium stages required.

Comp F1 F2 D B z1 z2 xD
Ac 45 40 75.9375 9.0625 0.6 0.4 0.9
EtOH 30 60 8.4375 81.5625 0.4 0.6 0.1
75 100 84.375 90.625
1
xD 0.9 0.9 0.9
0.9 0
0.8

z1 0.6 0.6 0.7

0.6 0 0.6

0.5
z2 0.4 0.4
0.4
0.4 0
0.3

xB 0.1 0.1 0.2

0.1 0 0.1

0
Vm/B 2 0 0.1 0.2 0.3
q1 1
q2 0.4

BALANCES INTERNOS

F1 F2 D B q1 q2 Vm/B
75 100 84.375 90.625 1 0.4 2

Vm Lm Vi Li Vn Ln R
181.25 271.875 241.25 231.875 241.25 156.875 1.859259259

LINEAS DE OPERACIÓN
LOR LOS LOI
mLOR bLOR mLOS bLOS mLOI
 0.6502590670.3147668394 1.5 -0.05 0.961139896

LOF1 LOF2
mLOF1 bLOF1 mLOF2 bLOF2
#DIV/0! #DIV/0! -0.66666666 0.6666666667

LOR 0.9 0.9

0.6 0.7049222798

LOF1 0.6 0.6

0.6 0.7049222798

LOI 0.6 0.7049222798

0.3307692300.4461538462

LOF2 0.4 0.4

0.3307692300.4461538462

LOS 0.1 0.1

0.3307692300.4461538462
1

ETAPAS
N 0.9
0.9 0.9
0.857 0.9
0.857 0.872038860 1 0.8

0.813 0.8720388601
0.813 0.843427461 1
0.7
0.766 0.8434274611
0.766 0.812865285 1
0.715 0.812865285 0.6
0.715 0.779702072 1
0.665 0.7797020725
0.665 0.747189119 1 0.5

0.615 0.7471891192
0.615 0.714676165 1
0.4
0.565 0.7146761658
0.565 0.671282383 1
0.498 0.6712823834 0.3
0.498 0.606886010 1
0.405 0.6068860104
0.405 0.5175 1 0.2

0.295 0.5175
0.295 0.3925 1
0.1
0.182 0.3925

0
0 0.1 0.2 0.3 0.4 0.5
 0.1

0.182 0.223 1
0.084 0.223 0
0.084 0.076 1 0 0.1 0.2 0.3 0.4 0.5

12

D10.* A distillation column is separating phenol from p-cresol at 1 atm pressure. The distillate
composition desired is 0.96 mole fraction phenol. An external reflux ratio of L/D = 4 is used, and
the reflux is returned to the column as a saturated liquid. The equilibrium data can be represented
by a constant relative volatility, αphenol−cresol = 1.76 (Perry et al., 1963, pp. 13–3). CMO can be
assumed.
a. What is the vapor composition leaving the third equilibrium stage below the total condenser?
Solve this by an analytical stage-by-stage calculation alternating between the operating equation
and the equilibrium equation.
b. What is the liquid composition leaving the sixth equilibrium stage below the total condenser?
Solve this problem graphically using a McCabe-Thiele diagram plotted for αp−c = 1.76.

R xD a
4 0.96 1.76

x y mLOR bLOR N
0 0 0.8 0.192 0.96 0.96
0.1 0.16356877 0.9316770180.96
0.2 0.30555556 LOR 0.9316770180.937341614
0.3 0.42996743 0.96 0.96 0.8947340460.9373416149
0.4 0.5398773 0 0.192 0.8947340460.907787236
0.5 0.63768116 0.8483345120.9077872369
0.6 0.72527473 0.8483345120.870667609
0.7 0.80417755 0.7927464830.8706676098
0.8 0.87562189 0.7927464830.826197186
0.9 0.94061758 0.7297980600.8261971869
1 1 0.7297980600.775838448
0.6629042390.7758384483
0.6629042390.722323391

D17. A mixture of acetone and ethanol (acetone is more volatile) is fed to an enriching column that has
a liquid side stream withdrawn. The feed flow rate is 100.0 mol/min. Feed is 60.0 mol% acetone
and is a saturated vapor. The liquid side product is withdrawn from the second stage below the
total condenser at a flow rate of S = 15.0 mol/min. The reflux is returned as a saturated liquid.
The distillate should be 90.0 mol% acetone. The external reflux ratio is L/D = 7/2. Column
pressure is 1.0 atm. Column is adiabatic and CMO is valid. Equilibrium data are in Problem
4.D7. Note: Trial and error is not required.
Find the mole fraction of acetone in the sidestream xS, the mole fraction of acetone in the bottoms
xB, and the number of equilibrium stages required.

F z q S xD R
 100 0.6 0 15 0.9 3.5

xD 0.9 0.9 LOR LOF

0.9 0 mLOR bLOR mLOF
0.7777777770.2 0
z 0.6 0.6
0.6 0 0.9 0.9 0.6
0 0.2 0

N
0.9 0.9
0.85 0.9
0.85 0.861111111 1
0.795 0.8611111111
0.795 0.818333333 1

BALANCES
F Vp Vn R D Ln S
100 100 100 3.5 22.22 77.78 15

F D S Lp z xD xS
Acetona 60 19.998 11.925 28.077 0.6 0.9 0.795
EtOH 40 2.222 3.075 34.703 0.4 0.1 0.205
100 22.22 15 62.78

mLOP bLOP mLOF

1 bLOF
0.6277777770.31925 0 0.6
0.9

0.795 0.8183333333 0.8

0.4472123890.6 0.7

0.6
N
0.5
0.795 0.8183333333
0.727 0.8183333333 0.4

0.727 0.7756444444 0.3

0.66 0.7756444444 0.2
0.66 0.7335833333
0.1
0.59 0.7335833333
0.59 0.6896388889 0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
0.522 0.6896388889
0.522 0.64695
0.46 0.64695
0.46 0.6080277778
 0.4 0.6080277778
0.4 0.5703611111

D18. We have a stripping column with two feeds separating acetone and ethanol at 1 atm. Feed F1 is a
saturated liquid and is fed into the top of column (no condenser). Flow rate of F1 is 100 kgmol/h,
and this feed is 60 mol% acetone. Feed F2 is 40 mol% acetone, it is a two-phase feed that is 80%
vapor, and flow rate is 80 kmol/h. We desire a bottoms mole fraction that is 0.04 mole fraction
acetone. The column has a partial reboiler. Equilibrium data are in Problem 4.D7.
a. Calculate (Vm /B)min.
b. If (Vm/B) = 1.5, find D and yD, the optimum feed stage for feed F2, and the total number of stages.
Please step off stages from the bottom upwards.

DATOS
F1 100 F2 80 xB 0.04
z1 0.6 z2 0.4
q1 1 q2 0.2 Vm/B 1.5

Alimentaciones 1

z1 0.6 0.6 0.9

0.6 0
0.8

z2 0.4 0.4 0.7

0.4 0
0.6

0.5

0.4

Cálculo de (Vm/B)min 0.3

0.2
LOF1 0.6 0.6
0.6 1 0.1

0
LOF2 0.4 0.4 mLOF2 bLOF2 0 0.1 0.2 0.3 0
0 0.5 -0.25 0.5

Se supones datos de (x,y) hasta casi punto pinch

(LOS)max 0.04 0.04 mLOSmax bLOSmax

1 2.1 2.145833333-0.04583333333

B/Vm 1.145833333

(Vm/B)min 0.8727272727

CALCULO DE ETAPAS
BALANCES INTERNOS

F1 q1 F2 q2 Vm/B Lm/Vm
100 1 80 0.2 1.5 1.666666667

Lp Vp Lm Vm B
100 133.60 116 69.60 46.40

BALANCES EXTERNOS
datos Balance
F1 F2 V1 B z1 z2 y1
Ac 60 32 90.144 1.856 0.6 0.4 0.674730538
EtOH 40 48 43.456 44.544 0.4 0.6 0.325269461
100 80 133.6 46.40

La salida de cabeza tiene una composición de 0.6747

1

Entonces; punto de línea de operación (z1,y1) z1

0.6
0.9

LOS 0.04 0.04 mLOS bLOS

0.2747826080.4313043478 1.666666667-0.02666666667
0.8

LOP 0.2747826080.4313043478 mLOP bLOP

0.6 0.6747 0.7485029940.2256287425
0.7

0.6
ETAPAS N
0.6 0.6747
0.501 0.6747
0.5
0.501 0.600628742 1
0.394 0.6006287425
0.394 0.520538922 1 0.4
0.2955 0.5205389222
0.2955 0.446811377 1
0.223 0.4468113772 0.3
0.223 0.345 1
0.149 0.345
0.149 0.221666666 1 0.2

0.0835 0.2216666667
0.0835 0.1125 1
0.1
0.0425 0.1125
0.0425 0.044166666 1
0.016 0.04416666667 0
0.016 0 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.
D13. A distillation column is separating a 30% methanol–70% water feed. The feed rate is 237 kmol/h
and is a saturated liquid. The column has a partial reboiler and a partial condenser. We desire a
distillate mole fraction of yD,M = 0.95 and a bottoms mole fraction of xB,M = 0.025. Assume CMO
is valid. Data are in Table 2-7 and Problem 3.E1.
a. Find Nmin.
b. Find (L/V)min and (L/D)min.
c. If L/D = 2.0 (L/D)min, find the optimum feed plate location and the total number of equilibrium
stages required.
d. Determine the boilup ratio used.

BALANCE EXTERNO
F D B z xD xB
MetOH 71.1 66.94 4.16 0.3 0.95 0.025
W 165.9 3.52 162.38 0.7 0.05 0.975
237 70.46 166.54
1
xD 0.95 0.95
0.95 0 0.9

0.8
z 0.3 0.3
0.3 0 0.7

xB 0.025 0.025 0.6

0.025 0
0.5

NUMERO MINIMO DE ETAPAS 0.4

Nmin
0.95 0.95 0.3

0.8850221910.95
0.2
0.8850221910.885022191 1
0.7322573360.885022191 0.1
0.7322573360.732257336 1
0.4096989740.7322573363 0
0.5 0.55 0.6 0.65 0.7 0.75
0.4096989740.409698974 1
0.0939290800.4096989747
0.0939290800.093929080 1
0.0082648400.09392908078
0.0082648400.008264840 1

Nmin 5

REFLUJO MÍNIMO 1

LOF 0.3 0.3 0.9

0.8

0.7
 1

0.9

0.3 1 Rmin 0.82

0.8

LORmin 0.95 0.95 mLORmin bLORmin 0.7

0 0.521978022 0.4505494500.521978022
0.6

CONDICIONES DE OPERACIÓN
0.5

Rmin R/Rmin R q 0.4

0.82 2 1.64 1
0.3

F D B
0.2
237.00 70.46 166.54
0.1
Ln Vn Lm Vm
115.5535135186.01 352.5535135186.01 0
0 0.1 0.2 0.3

LOR 0.95 0.95 mLOR bLOR

0.3 0.5462121212 0.6212121210.3598484848 1

LOS 0.3 0.5462121212 mLOS bLOS 0.9

0.025 0.025 1.895316804-0.02238292011

0.8

LOF 0.3 0.3 mLOF bLOF 0.7

0.3 0.5462121212 -0.02289538 0
0.6

N
0.5
0.95 0.95
0.8850221910.95 0.4
0.8850221910.909634997 1
0.7902301480.9096349974 0.3

0.7902301480.850749031 1
0.2
0.6529370200.8507490319
0.6529370200.765460876 1 0.1
0.4715659990.7654608766
0.4715659990.652790999 1 0
0 0.1 0.2 0.3
0.2854120690.6527909994
0.2854120690.518563371 1
0.1504206280.518563371
0.1504206280.262711823 1
0.0512553400.2627118239
0.0512553400.074762187 1
0.012 0.07476218757
0.012 0.012 1
E1. A system known as a pump-around is shown below. Saturated liquid is withdrawn from stage 2
above the partial reboiler, and the liquid is returned to stage 3 (assume it is still a saturated
liquid). Pump-around rate is P = 40.0 kmol/h. The column is separating methanol and water at
101.3 kPa. The feed flow rate is 100.0 kmol/h. The feed is 60.0 mol% methanol and 40.0 mol%
water. The feed is saturated liquid. We desire a bottoms product that is 2.5 mol% methanol. The
distillate product should be 95.0 mol% methanol. The column has a total condenser and the reflux
is a saturated liquid. Assume CMO. Use (L/D) = 2.0 x (L/D)min. Data are given in Table 2-7. Find
xp, the optimum feed stage and total number of equilibrium stages required.

F D B z xD xB
MetOH 60.00 59.05 0.95 0.6 0.95 0.025
W 40.00 3.11 36.89 0.4 0.05 0.975
100 62.16 37.84

xD 0.95 0.95
0.95 0

z 0.6 0.6
0.6 0

xB 0.025 0.025
0.025 0

CÁLCULO DE Rmin y R

q F
1

LOF 0.6 0.6

0.6 1

Rmin 0.56

LORmin 0.95 0.95 mLORmin bLORmin

0 0.608974359 0.3589743590.608974359

R 1.12

BALANCES INTERNOS
F D B q1 R
100 62.16 37.84 1 1.12

Ln Vn q1 Li Vi F2 q2
69.62 131.78 1 169.62 131.78 40 1

Lp Vp S Lm Vm B
209.62 131.78 40 169.62 131.78 37.84

LINEAS DE OPERACIÓN

LOS 0.025 0.025 mLOS bLOS

1 1.279942576 1.287120591-0.007178014766

N
0.025 0.025
0.025 0.1471723862 xp
0.1199191450.147172386Rehervidor 0.3693562667
0.1199191450.4682280414
0.3693562660.468228041 1
0.3693562660.7042303906
0.5527130950.704230390 2

ALIMENTACIÓN P=F2

LOF2 0.3693562660.3693562667
0.369356266 1

LOR 0.95 0.95 mLOR bLOR

0.5341017900.7302801912 0.5283018860.4481132075

LOP 0.6 0.8351010511 mLOP bLOP

0 -0.1192877922 1.590648072-0.1192877922

N
0.3693562660.7042303906
0.5177249430.7042303906
0.5177249430.7920872382
0.6510937000.7920872382
0.6510937000.8517377723
0.7640036400.8517377723
0.7640036400.8946270042
0.8451868290.8946270042
0.8451868290.932401337
0.9166882450.932401337
0.9166882450.9709362956
 0.9896294160.9709362956
0.9896294160.9998943823

7-24 A saturated-liquid mixture of 69.4 mol% benzene (B) in

toluene (T) is to be contilluously distilled at atmospheric pressure
to a distillate containing 90 mol% benzene, with a yield
of 25 moles of distillate per 100 moles of feed. The feed is sent to , steamheated still (reboiler), where residue is to be with
continu~~~Tlhye. vapors from the still pass directly to a partial
condenser. From a liquid separator following the condenser, reflux
is returned to the still. Vapors from the separator, which are in equilibrium
with the liquid reflux, are sent to a total condenser and are
continu~~w~ilthyd rawn as distillate. At equilibrium the mole ratio
ofB to T in the vapor may be taken as 2.5 times the mole ratio of B
to T in the liquid. Calculate analytically and graphically the total
moles of vapor generated in the still per 100 mol of feed.
to T in the liquid. Calculate analytically and graphically the total

7.29. Distillation of an azeotrope-forming mixture.

A continuous distillation unit, consisting of a perforated-tray column
with a partial reboiler and a total condenser, is to be designed
to separate ethanol and water at 1 atm. The bubble-point feed contains
20 mol% alcohol. The distillate is to contain 85 mol% alcohol,
and the recovery is to be 97%. (a) What is the molar concentration
of the bottoms? (b) What is the minimum value of the reflux ratio
L=V, the reflux ratio L=D, and the boilup ratio V=B? (c) What is the
minimum number of theoretical stages and the number of actual
plates, if the overall plate efficiency is 55%? (d) If the L=V is 0.80,
how many actual plates will be required?
Vapor–liquid equilibrium for ethanol–water at 1 atm in terms of
mole fractions of ethanol are [Ind. Eng. Chem., 24, 881 (1932)]:

0.97
F D B z xD xB
20 19.4 0.6 0.2 0.85 0.007774390244
80 3.423529412 76.5764706 0.8 0.15 0.99222561
100 22.82352941 77.1764706
1

0.9

0.8

0.7
 1

0.9

xD 0.85 0.85 0.8

0.85 0
0.7

z 0.2 0.2
0.6
0.2 0
0.5
xB 0.0077743900.007774390244
0.007774390 0 0.4

LOF 0.2 0.2 0.3

0.2 1
0.2
Rmin 1.8
0.1

LORmin 0.85 0.85

0
0 0.3035714286 (Ln/Vn)min 0.6428571429 0 0.1

(Lm/B)min 1.9

Lm B Vm Lm/Vm 2.111111111 -0.00863821 0.007774390

146.635294177.1764705969.45882353 1

(Vm/B)min 0.9

Nmin 1

0.85 0.85 0.9

0.84 0.85
0.8
0.84 0.84 1
0.825 0.84 0.7
0.825 0.825 1
0.805 0.825 0.6

0.805 0.805 1
0.5
0.778 0.805
0.778 0.778 1 0.4
0.742 0.778
0.742 0.742 1 0.3
0.682 0.742
0.2
0.682 0.682 1
0.573 0.682 0.1
0.573 0.573 1
0.305 0.573 0
0.305 0.305 1 0 0.1 0.2

0.05 0.305
0.05 0.05 19
0.005 0.05
0.005 0.005 Rehervidor

1
Ln/Vn R
0.8 4

LOR 0.85 0.85 mLOR bLOR 0.9

0.2 0.33 0.8 0.17

LOS 0.2 0.33 mLOS bLOS 0.8

0.0077743900.007774390244 1.67628866 -0.005257731959

0.85 0.85
0.7
0.84 0.85
0.84 0.842 1
0.828 0.842
0.828 0.8324 1 0.6
0.817 0.8324
0.817 0.8236 1
0.804 0.8236
0.5
0.804 0.8132 1
0.791 0.8132
0.791 0.8028 1
0.777 0.8028 0.4
0.777 0.7916 1
0.761 0.7916
0.761 0.7788 1
0.3
0.7435 0.7788
0.7435 0.7648 1
0.723 0.7648
0.723 0.7484 1 0.2
0.694 0.7484
0.694 0.7252 1
0.652 0.7252 0.1
0.652 0.6916 1
0.588 0.6916
0.588 0.6404 1
0.467 0.6404 0
0
0.467 0.5436 1
0.231 0.5436
0.231 0.3548 1
0.062 0.3548
0.062 0.098672164 1
 0.01 0.09867216495
0.01 0.011505154 1 16
0.002 0.01150515464
0.002 -0.00190515 1 1 30.90909091

A Una columna de destilación que tiene ocho etapas teóricas (siete etapas + rehervidor parcial + condensador total) se
que contiene 50% mol A en un producto de 94% en moles A. La relación molar de líquido a vapor en la etapa superior es 0
entra en la etapa 4 desde la parte superior. La volatilidad es constante e igual a 2.36. Determinar:
(a) la composición de fondos
(b) la relación Lm/Vm en la sección de agotamiento
(c) los moles de fondos por hora
(d) Calcular Nmin
(e) Calcular R/Rmin
(f) Dibujar el diagrama de McCabe
(g) Cual es la composición del líquido que sale de la tercera etapa
Desconocido por los operadores, los tornillos que sostienen las etapas 5, 6 y 7 se oxidan y los platos caen en el rehervidor
Un problema desconocido por los operadores, los tornillos que sostienen las etapas 5, 6 y 7 se oxidan y los platos caen en
(h) Dibujar el diagrama McCabe en esta situación
(i) Cuál es la nueva composición de fondos?
(j) Cual es el valor de Lm/Vm en esta situación?
x 0 0.1 0.2 0.3 0.4 0.5 0.6
y 0 0.19 0.37 0.5 0.62 0.71 0.78
1.9 1.85 1.6666666667 1.55 1.42 1.3
0.9 0.7875 0.7142857143 0.6333333333 0.58 0.55

2.11111111 2.34920635 2.33333333 2.447368421 2.44827586 2.36363636

0 0.20758835 0.37084493 0.50260067 0.611170614 0.70218002 0.77957059

F D B z xD xB
A 150 142.29 7.71 0.5 0.9 0.05433404
B 150 15.81 134.19 0.5 0.1 0.94566596
300 158.1

xD 0.9 0.9
0.9 0

z 0.5 0.5
0.5 0
R Rmin
xB 0.0543340380.05433403805 3
0.054334038 0
LOR 0.9 0.9 mLOR bLOR R
0.5 0.6 0.75 0.225 3

LOF 0.5 0.5

0.5 0.6

LOS 0.0543340380.05433403805 mLOS bLOS

0.5 0.6 -0.01219165085
 D6. We are separating a mixture of acetone and ethanol
atmosphere pressure. The column has a total condenser
mol% acetone, and the bottoms is 10 mol% acetone. The
Use a boilup ratio of Vm/B = 2.0. Two feeds are fed to the
75 kmol/h, it is a saturated liquid, and it is 60 mol% aceto
100 kmol/h, it is a two-phase mixture that is 60% vapor, a
optimum feed location for each feed. Assume CMO. Equi
a. Find the distillate and bottoms flow rates, D and B.
b. Plot the two feed lines and the three operating lines.
c. Step off stages and find the optimum feed location for
equilibrium stages required.

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.65 0.7 0.75 0.8 0.85 0.9 0.95 1

0.9

0.8

0.7
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

xB
0.1
0.9

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

bLOI
 0.128238342

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

3 0.4 0.5 0.6 0.7 0.8 0.9 1

3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8
1
0.7
.9373416149
1 0.6
.9077872369
0.5
1
.8706676098 0.4

1 0.3
.8261971869
0.2
1
.7758384483 0.1
1
0
0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1

0.9

0.8

0.7

0.6

0.5
 1

0.9

0.8

0.7

0.6

bLOF 0.5

0.6 0.4

0.3
0.6
0.2
0.6
0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Lp
62.78

xp
0.4472123894
0.5527876106

0.4 0.5 0.6 0.7 0.8 0.9 1

 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 xB
0.04
0.96

y1
0.6747

0.4 0.5 0.6 0.7 0.8 0.9 1

 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3
q
1 0.2

0.1

0
0 0.1 0.2 0.3 0.4

0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1

0.9

0.8

0.7
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

0.9

0.8

0.7 0.84

0.6
0.835

0.5
0.83
0.4

0.825
0.3

0.2 0.82

0.1
0.815

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 0.81

0.805

0.8
0.56

0.9
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0.5 0.55 0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1

0.9

0.8

0.7

0.6

0.5

0.3693562660.4682280414 0.4
0 -0.1192877922
0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6
 7.15. Loss of trays in a distillation column.
A continuous distillation with a reflux ratio (L=D) of 3.5 yi
distillate containing 97 wt% B (benzene) and a bottoms o
where residue is to be withdrawn (toluene). Due to weld failures, the 10 stripping plates in
section of the column are ruined, but the 14 upper rectif
are intact. It is suggested that the column still be used, w
(F) as saturated vapor at the dew point, with F ¼ 13,600 k
40 wt% B and 60 wt% T. Assuming that the plate efficienc
remains unchanged at 50%: (a) Can this column still yield
containing 97 wt% B? (b) How much distillate is there?
(c) What is the residue composition in mole %?
For vapor–liquid equilibrium data, see Exercise 7.13.

x y T, [°C] x 0 0.019 0.0721 0.0966

0 0 100 y 0 0.17 0.3891 0.4375
0.019 0.17 95.5
0.0721 0.3891 89
0.0966 0.4375 86.7
0.1238 0.4704 85.3
0.1661 0.5089 84.1
0.2337 0.5445 82.7
0.2608 0.558 82.3
0.3273 0.5826 81.5
0.3965 0.6122 80.7
0.5079 0.6564 79.8
0.5198 0.6599 79.7
0.5732 0.6841 79.3
0.6763 0.7385 78.74
0.7472 0.7815 78.41
0.8943 0.8943 78.15
1 1
1

1 0.9

0.9
0.8
7.29 (a) 0.777 mol% ethanol in
0.8
0.7

0.7
0.6
 1 0.9

0.9
0.8

0.8 bottoms
0.7
(b) (1) Min L/V = 0.65
0.7
0.6 (2) Min R = 1.86
(3) Min boilup ratio = 0.846
0.6
0.5 (c) 9 + reboiler theoretical stag
0.5
18.2 minimum plates
0.4
(d) 26 plates + reboiler
0.4
0.3

0.3
0.2

0.2
0.1

0.1
0
0 0.1 0.2 0.3 0.4 0.5 0
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.007774390244
2.1024729

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
rcial + condensador total) separa 100 kmol / h de una alimentación líquida saturada
por en la etapa superior es 0,75. La alimentación de líquido saturado

Lm/Vm B Nmin
platos caen en el rehervidor. 1.224383302141.9 5.892455945
oxidan y los platos caen en el rehervidor.

0.7 0.8 0.9 1

0.84 0.9 0.96 1
1.2 1.125 1.0666666667
0.5333333333 0.5 0.4

2.25 2.25 2.66666667 2.357733123

0.84618644 0.90413129 0.95499469 1
1

N
0.9 0.9 0.9
0.7924116460.9
0.7924116460.819308734 1
0.8
0.6579046470.8193087346
0.6579046470.718428485 1
0.5197345150.7184284858 0.7
0.5197345150.614800886 1
0.4036781720.6148008865 0.6
0.4036781720.482065163 1
0.2830320990.4820651632
0.5
0.2830320990.3343481253
0.1756235210.3343481253
0.4

0.3
 0.5

0.1756235210.2028388558 0.4
0.0974094650.2028388558
0.0974094650.1070748721
0.3
0.0483986150.1070748721
0.0483986150.04706680601
0.2

0.1

0
0 2 4 6 8 10
xture of acetone and ethanol in a distillation column operating at one
olumn has a total condenser and a partial reboiler. The distillate is 90
oms is 10 mol% acetone. The reflux is returned as a saturated liquid.
= 2.0. Two feeds are fed to the column. The first feed has a flow rate of
iquid, and it is 60 mol% acetone. The second feed has a flow rate of
e mixture that is 60% vapor, and it is 40 mol% acetone. Use the
each feed. Assume CMO. Equilibrium data are in Problem 4.D7.
ttoms flow rates, D and B.
nd the three operating lines.
he optimum feed location for each feed stream and the total number of
 0 0
0.1 0.262
0.15 0.348
0.2 0.417
0.25 0.478
0.3 0.524
0.35 0.566
0.4 0.605
0.5 0.674
0.6 0.739
0.7 0.802
0.8 0.865
0.9 0.929
1 1
 1

0.9

0.8

0.7

0.6

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
 1

0.9
 1

0.9

0.8
1
0.7
0.9
0.6
0.8
0.5
0.7
0.4
0.6
0.3
0.5
0.2
0.4
0.1
0.3
0.6 0.7 0.8 0.9 1 0
0.2 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.84

0.835

0.83

0.825

0.82

0.815

0.81

0.805

0.8
0.56 0.58 0.6 0.62 0.64
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 ation column.
h a reflux ratio (L=D) of 3.5 yields a
B (benzene) and a bottoms of 98 wt% T
res, the 10 stripping plates in the bottom
uined, but the 14 upper rectifying plates
at the column still be used, with the feed
e dew point, with F ¼ 13,600 kg/h containing
uming that the plate efficiency
(a) Can this column still yield a distillate
ow much distillate is there?
position in mole %?
m data, see Exercise 7.13.

0.1238 0.1661 0.2337 0.2608 0.3273 0.3965 0.5079 0.5198

0.4704 0.5089 0.5445 0.558 0.5826 0.6122 0.6564 0.6599

0.95

0.9

.29 (a) 0.777 mol% ethanol in 0.85

0.8
 0.85

b) (1) Min L/V = 0.65

2) Min R = 1.86
0.8
3) Min boilup ratio = 0.846
c) 9 + reboiler theoretical stages
8.2 minimum plates
d) 26 plates + reboiler 0.75

0.7
0.7 0.8 0.9 1

0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

8 0.9 1
R/Rmin x3 xB
3 0.5197345150.2830320992

Rmin
1

0.45

0.9 0.9
0 0.45
6 8 10 12 14 16 18
0.4 0.5 0.6 0.7 0.8 0.9 1
0.5732 0.6763 0.7472 0.8943 1
0.6841 0.7385 0.7815 0.8943 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1
 0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

1
N 1
0.9 0.9
0.7924116460.9
0.9
0.7924116460.8193087346
0.6579046470.8193087346
0.6579046470.7184284858 0.8
0.5197345150.7184284858
0.5197345150.6148008865
0.7
0.4036781720.6148008865
0.4036781720.5277586296
0.3215731070.5277586296 0.6
0.3215731070.3815370925
0.2073900750.3815370925 0.5
0.2073900750.2417332943
0.1191083790.2417332943
0.4

0.3
 0.5

0.4
0.1191083790.1336426605
0.0614087030.1336426605
0.0614087030.06299614084 0.3

0.2

0.1

0
0 2 4 6 8
0.9 1
6 8 10 12 14 16 18
A batch still is loaded with 100 kmol of a binary mixture of 50 mol%
benzene in toluene. As a function of time, make plots of: (a) still
temperature, (b) instantaneous vapor composition, (c) still-pot composition, alfa
and (d) average total-distillate composition. Assume a constant
boilup rate, and, therefore, constant D of 10 kmol/h, and a
constant a of 2.41 at a pressure of 101.3 kPa (1 atm).

x y
0 0
0.1 0.21121823
0.2 0.37597504
0.3 0.50808152
0.4 0.61636829
0.5 0.70674487
0.6 0.78331528
0.7 0.84901862
0.8 0.90601504
0.9 0.95592772
1 1

W0 100 V 10
xW0 0.5

xW0 0.5 0.5 0.45 0.45 0.4 0.4 0.35

0.5 0 0.45 0 0.4 0 0.35

xW 0.45 0.45 0.4 0.4 0.35 0.35 0.3

0.45 0.6635056590.4 0.6163682860.35 0.5647807160.3
yD 0.6635056590.6635056590.6163682860.6163682860.5647807160.5647807160.5080815179

yD

xW yD f I W D
100
0.45 0.663505659 4.6837166 -0.2326367 79.24 20.76
0.4 0.616368286 4.62174941 -0.2319415 62.84 16.40
0.35 0.564780716 4.65591147 -0.236543 49.60 13.24
0.3 0.508081517 4.80580885 -0.2480412 38.71 10.90
0.25 0.445471349 5.11583924 -0.2699616 29.55 9.16
0.2 0.375975039 5.68262411 -0.3105401 21.66 7.89
0.15 0.298390425 6.73897928 -0.3932578 14.62 7.04
0.1 0.211218229 8.99133176 -0.6243727 7.83 6.79
0.05 0.112564222 15.983576

92.17
A three-stage batch rectifier (first stage is the still-pot) is charged with
100 kmol of a 20 mol% n-hexane in n-octane mixture. At a constant-
reflux ratio of Ln/Vn=0.5. How many moles of charge must be
distilled for an average product composition of 70 mol% nC6?
The phase-equilibrium curve at column pressure is given in
Figure 13.5. If the boilup rate is 10 kmol/h, calculate distillation time.

P (psi)
7
x1 x2 T K1 K2 y1 y2 Sy
0 1 691.325268 4.94728034 1 0 1 1
0.1 0.9 668.570195 3.82347772 0.68628025 0.38234777 0.61765223 1
0.2 0.8 649.789016 3.02762106 0.49309424 0.60552421 0.39447539 0.999999604
0.3 0.7 634.531887 2.4663355 0.3715705 0.73990065 0.26009935 1
0.4 0.6 622.060888 2.06226904 0.29182064 0.82490762 0.17509238 1
0.5 0.5 611.715177 1.76295802 0.23704198 0.88147901 0.11852099 1
0.6 0.4 602.988412 1.53479138 0.19781293 0.92087483 0.07912517 1
0.7 0.3 595.510011 1.35627537 0.1686908 0.94939276 0.05060724 1
0.8 0.2 589.010357 1.21339896 0.14640416 0.97071917 0.02928083 1
0.9 0.1 583.291405 1.09678823 0.1289059 0.98710941 0.01289059 1
1 0 578.205451 1 0.11486618 1 0 1

10.9999996
W0 100
xW0 0.2
Ln/Vn 0.5
xDprom 0.7
V¬ 10

R R R R
1 1 1 1
xD xD xD xD
0.92 0.88 0.84 0.8
mLOR bLOR mLOR bLOR mLOR bLOR mLOR
0.5 0.46 0.5 0.44 0.5 0.42 0.5

0.92 0.92 0.88 0.88 0.84 0.84 0.8

0 0.46 0 0.44 0 0.42 0

0.92 0.92 0.88 0.88 0.84 0.84 0.8

0.6152678760.92 0.5048982340.88 0.4219902510.84 0.357428618
0.6152678760.7676339380.5048982340.6924491170.4219902510.6309951250.357428618
0.3147861190.7676339380.2384416100.6924491170.1921114690.6309951250.1603886909
0.3147861190.6173930590.2384416100.5592208050.1921114690.5160557340.1603886909
0.1832713710.6173930590.1499700130.5592208050.1291391640.5160557340.1138402901
 0.1832713710.5516356850.1499700130.5149850060.1291391640.4845695820.1138402901

0.2 0.2 0.1832713710.1832713710.1499700130.1499700130.1291391644

0.2 0 0.183271371 0 0.149970013 0 0.1291391644

xW yD f I W D
100
0.1832713710.92 1.35735189 -0.045409 95.56 4.44
0.1499700130.88 1.36980675 -0.028919 92.84 2.72
0.1291391640.84 1.4067451 -0.021909 90.82 2.01
0.1138402900.8 1.45738665 -0.0182388 89.18 1.64
0.1015837840.76 1.51879613 -0.0160752 87.76 1.42
0.0912434840.72 1.59044077 -0.0147102 86.48 1.28
0.0822279760.68 1.67287856 -0.0138231 85.29 1.19
0.0741918930.64 1.76738366 -0.0132527 84.17 1.12
0.0669167210.6 1.87587951 -0.0063581 83.64 0.53
0.0635165690.6 1.86399047 -0.006177 83.12 0.52
0.0602552380.58 1.92402132 -0.0061318 82.61 0.51
0.0571208360.56 1.98854928 0.0063832 83.14 -0.53
0.0602552380.54 2.08444173

16.86

REFLUJO VARIABLE

R R R R
0.4 0.8 1.2 1.6

xD xD xD xD
0.7 0.7 0.7 0.7
mLOR bLOR mLOR bLOR mLOR bLOR mLOR
0.2857142850.5 0.4444444440.3888888880.5454545450.3181818180.6153846154

LOR 0.7 0.7 0.7 0.7 0.7 0.7 0.7

0 0.5 0 0.388888888 0 0.318181818 0

xW 0.2 0.2 0.1425235540.1425235540.0994863530.0994863530.0767901492

0.2 0 0.142523554 0 0.099486353 0 0.0767901492
N 0.7 0.7 0.7 0.7 0.7 0.7 0.7
0.2449853500.7 0.2449853500.7 0.2449853500.7 0.2449853501
0.2449853500.5699958140.2449853500.4977712660.2449853500.4518101910.2449853501
0.1556440430.5699958140.1211322410.4977712660.1028274340.4518101910.0914841167
0.1556440430.5444697260.1211322410.4427254400.1028274340.3742695090.0914841167
0.1425235540.5444697260.0994863530.4427254400.0767901490.3742695090.0628957964
0.1425235540.5407210150.0994863530.4331050450.0767901490.3600673540.0628957964

R (R+1) xW yD f I W D
100
0.4 1.4 0.1425235540.7 1.79379776 -0.0744337 92.83 7.17
0.8 1.8 0.0994863530.7 1.66524109 -0.0371064 89.45 3.38
1.2 2.2 0.0767901490.7 1.60459595 -0.0220517 87.49 1.95
1.6 2.6 0.0628957960.7 1.56960195 -0.0145725 86.23 1.27
2 3 0.0535439830.7 1.54689565 -0.0124629 85.16 1.07
2.5 3.5 0.0454370370.7 1.52773691 -0.008735 84.42 0.74
3 4 0.0396944760.7 1.51445045 -0.006459 83.88 0.54
3.5 4.5 0.0354158030.7 1.50470024 -0.0147615 82.65 1.23
5.5 6.5 0.0255331310.7 1.48265252 -0.0057823 82.17 0.48
7 8 0.0216218980.7 1.47410419 -0.0048149 81.78 0.39
9 10 0.0183476820.7 1.46702355 -0.0017076 81.64 0.14
10 11 0.0171827250.7 1.46452065
0.0171827250.7 1.46452065

18.36

EXAMEN DE DESTILACIÓN BATCH

Se tiene una mezcla de A en B, siendo esta mezcla ideal y su volatilidad puede considerarse igual a 3, si se carga a un destila
de esta mezcla que contiene 30% molar de A, y, en una primera destilación se obtiene que el líquido que sale de la segund
tercera etapa es de 0.34794; a partir de estos datos. Calcular:
1. Dibujar el diagrama xy (2 pts)
2.- Cúal es el valor de R
3. El valor de Nmin (3 pts) Rmin
2. El valor de Rmin (3 pts) 1.3
4. Cuál es el valor de xD, de esta primera fracción (3 pts) Rmin
5. Cuál es el valor de xW, en esta primera fracción (3 pts) 0.9
6. Cuál es el valor de R/Rmin (3 pts) 0
7. ¿Cuál es el número de etapas teóricas necesarias? (3 pts)
alfa
 3 xWO
0.3 0
x y 0.3 1
0 0
0.1 0.25 xD
0.2 0.42857143 0.9
0.3 0.5625 0.54255
0.4 0.66666667 R
0.5 0.75 3.9 0.34794
0.6 0.81818182
0.7 0.875 LOR
0.8 0.92307692
0.9 0.96428571 0.9 0.9 0.7959183670.1836734694
1 1 0 0.1836734694
 2.41

0.35 0.3 0.3 0.25 0.25 0.2 0.2

0 0.3 0 0.25 0 0.2 0

18
0.3 0.25 0.25 0.2 0.2 0.15 0.15
0.50808151790.25 0.44547134940.2 0.375975039 0.15 16 0.2983904251
0.50808151790.44547134940.44547134940.375975039 0.375975039 0.29839042510.2983904251
14

12

10
xD d t
8

0.6399 13.28 2.075585454 6

0.5906 9.69 1.640413287 4

0.5364 7.10 1.323712717
2
0.4768 5.20 1.08963754
0.4107 3.76 0.915761884 0
0.3372 2.66 0.788804874 0 1 2 3 4 5

0.2548 1.79 0.704291973

0.1619 1.10 0.678860267

0.4836764269 44.58 9.22

4.947280337 0
5.571306631 0.4441372
6.140045451 0.642571382
6.637597719 0.75501465
7.066905981 0.827408571
7.437323892 0.877915466
7.758802003 0.915157665
8.040008123 0.943754204
8.288008944 0.966402572
8.508440974 0.984783796
8.705782689 1

7.191045704

R R R
1 1 1
xD xD
0.76 0.72 0.68
bLOR mLOR bLOR mLOR bLOR mLOR bLOR
0.4 0.5 0.38 0.5 0.36 0.5 0.34

0.8 0.76 0.76 0.72 0.72 0.68 0.68

0.4 0 0.38 0 0.36 0 0.34

0.8 0.76 0.76 0.72 0.72 0.68 0.68

0.8 0.30573031510.76 0.26339926730.72 0.22810107070.68
0.578714309 0.30573031510.53286515750.26339926730.49169963370.22810107070.4540505354
0.578714309 0.13691106870.53286515750.11857010130.49169963370.10366455110.4540505354
0.48019434550.13691106870.44845553440.11857010130.41928505070.10366455110.3918322755
0.48019434550.10158378480.44845553440.09124348420.41928505070.08222797660.3918322755
0.456920145 0.10158378480.43079189240.09124348420.40562174210.08222797660.3811139883

0.12913916440.11384029010.11384029010.10158378480.10158378480.09124348420.0912434842
0 0.1138402901 0 0.1015837848 0 0.0912434842 0

xD d t

0.9000 4.00 0.88786964

0.8600 2.34 0.544787738
0.8200 1.65 0.402367998
0.7800 1.28 0.3283043
0.7400 1.05 0.284436125
0.7000 0.90 0.256307782
0.6600 0.78 0.237438744
0.6200 0.70 0.22457933
0.6000 0.32 0.106691518
0.5900 0.30 0.103005204
0.5700 0.29 0.101624201
0.5500 -0.29 -0.10580424

0.7901236896 13.32 3.37

R R R
2 2.5 3

xD xD xD
0.7 0.7 0.7
bLOR mLOR bLOR mLOR bLOR mLOR bLOR
0.26923076920.66666666670.23333333330.71428571430.2 0.75 0.175

0.7 0.7 0.7 0.7 0.7 0.7 0.7

0.2692307692 0 0.2333333333 0 0.2 0 0.175

0.07679014920.06289579640.06289579640.05354398380.05354398380.04543703770.0454370377
0 0.0628957964 0 0.0535439838 0 0.0454370377 0
 0.7 0.7 0.7 0.7 0.7 0.7 0.7
0.7 0.24498535010.7 0.24498535010.7 0.24498535010.7
0.41999098470.24498535010.39665690010.24498535010.37498953580.24498535010.3587390126
0.41999098470.08376551230.39665690010.07700831150.37498953580.07217978290.3587390126
0.32552868720.08376551230.28917700820.07700831150.25500593680.07217978290.2291348372
0.32552868720.05354398380.28917700820.04543703770.25500593680.03969447670.2291348372
0.30793587480.05354398380.26902932250.04543703770.232455027 0.03969447670.2047708576

xD d R+1 t

0.7000 5.02 1.6 1.147695368

0.7000 2.37 2 0.676270669
0.7000 1.37 2.4 0.468201326
0.7000 0.89 2.8 0.354414851
0.7000 0.75 3.25 0.347099077
0.7000 0.52 3.75 0.277739682
0.7000 0.38 4.25 0.230992549
0.7000 0.86 5.5 0.67598016
0.7000 0.33 7.25 0.345472317
0.7000 0.28 9 0.355228951
0.7000 0.10 10.5 0.146495306

0.7 12.85 52.30 5.03

ual a 3, si se carga a un destilador batch, que tiene un condensador total, 10 kmol

íquido que sale de la segunda etapa es de fracción 0.54255 y el que sale de la

0.9
0.3913043478 Nmin
0.9 0.9
0.75 0.9
 0.75 0.75
Etapas 0.5 0.75
0.9 0.9 0.5 0.5
0.75 0.9 0.25 0.5
0.75 0.7806122449 0.25 0.25
0.54255319150.7806122449
0.54255319150.6155015198
0.34793814430.6155015198
0.34793814430.4606038292
0.22157279490.4606038292
0.22157279490.3600273266
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2
0.15 0.15 0.1 0.1
0.1
0.15 0 0.1 0
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.1 0.1 0.05 0.05

0.1 0.21121822960.05 0.1125642223
0.21121822960.21121822960.11256422230.1125642223

1 2 3 4 5 6 7 8 9 10
 aT1 aT2 aT6 aP1 aP2 aP3
C1 -292860 0 8.2445 -0.8951 59.8465 0
C2= -600076.875 0 7.90595 -0.84677 42.94594 0
C2 -687248.25 0 7.90694 -0.886 49.02654 0
C3= -923484.688 0 7.71725 -0.87871 47.67624 0
C3 -970688.563 0 7.156059 -0.76984 0 6.90224
iC4 -1166846 0 7.72668 -0.92213 0 0
nC4 -1280557 0 7.94986 -0.96455 0 0
iC5 -1481583 0 7.58071 -0.93159 0 0
nC5 -1524891 0 7.33129 -0.89143 0 0
nC6 -1778901 0 6.96783 -0.84634 0 0
nC7 -2013803 0 6.52914 -0.79543 0 0
nC8 0 -7646.81641 12.48457 -0.73152 0 0
nC9 -2551040 0 5.69313 -0.67818 0 0
nC10 0 -9760.45703 13.80354 -0.7147 0 0

R R R R
1 1 1 1

0.64 0.6 0.58 0.56

mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR
0.5 0.32 0.5 0.3 0.5 0.29 0.5 0.28

0.64 0.64 0.6 0.6 0.58 0.58 0.56 0.56

0 0.32 0 0.3 0 0.29 0 0.28

0.64 0.64 0.6 0.6 0.58 0.58 0.56 0.56

0.198217501 0.64 0.17259142930.6 0.1611004070.58 0.1503735120.56
0.198217501 0.41910875050.17259142930.38629571460.1611004070.3705502030.1503735120.355186756
0.09118345990.41910875050.08048713950.38629571460.0756695520.3705502030.0711502200.355186756
0.09118345990.36559173 0.08048713950.34024356980.0756695520.3278347760.0711502200.315575110
0.07419189380.36559173 0.06691672100.34024356980.0635165690.3278347760.0602552380.315575110
0.07419189380.35709594690.06691672100.33345836050.0635165690.3217582840.0602552380.310127619

0.08222797660.08222797660.07419189380.07419189380.0669167210.0669167210.0635165690.063516569
0.0822279766 0 0.0741918938 0 0.066916721 0 0.063516569 0

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

R R R R
3.5 5.5 7 9

xD xD xD xD
0.7 0.7 0.7 0.7
mLOR bLOR mLOR bLOR mLOR bLOR mLOR bLOR
0.77777777780.15555555560.84615384620.10769230770.875 0.0875 0.9 0.07

0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7

0 0.1555555556 0 0.1076923077 0 0.0875 0 0.07

0.03969447670.03969447670.03541580360.03541580360.0255331310.0255331310.0216218980.021621898
0.0396944767 0 0.0354158036 0 0.025533131 0 0.021621898 0
0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7
0.24498535010.7 0.24498535010.7 0.2449853500.7 0.2449853500.7
0.24498535010.34609971680.24498535010.314987604 0.2449853500.3018621810.2449853500.290486815
0.06855731570.34609971680.06010132160.314987604 0.0567175230.3018621810.0538673880.290486815
0.06855731570.20887791230.06010132160.15854727210.0567175230.1371278330.0538673880.118480649
0.03541580360.20887791230.02553313140.15854727210.0216218980.1371278330.0183476820.118480649
0.03541580360.18310118060.02553313140.129297265 0.0216218980.1064191610.0183476820.086512914

0.9

0.8

0.7
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 1

R 0.9
1
xD 0.8

0.54
0.7
mLOR bLOR
0.5 0.27 0.6

0.54 0.54 0.5

0 0.27
0.4

0.54 0.54
0.3 1
0.1403369790.54
0.1403369790.3401684897 0.9
0.2
0.0668958390.3401684897 0.8
0.0668958390.3034479197 0.1
0.0571208360.3034479197 0.7
0
0.60 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.5
 0.2
0.8
0.1
0.7
0
0.0571208360.2985604183 0.60 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.0602552380.06025523881 0.5

0.060255238 0 0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

0.9

0.8

0.7

0.6

R 0.5

10 0.4

xD 0.3
0.7
0.2
mLOR bLOR
0.9090909090.06363636364 0.1

0
0.7 0.7 1 0 0.1 0.2
0 0.06363636364

0.0183476820.01834768276 0.9
0.018347682 0

0.8
 0.9

0.7 0.7 0.8

0.2449853500.7
0.2449853500.2863503183
0.0528493440.2863503183
0.7
0.0528493440.1116812227
0.0171827250.1116812227
0.0171827250.0792570231
0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5
0.8 0.9 1
 0.8 0.9 1

6 0.7 0.8 0.9 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Section 8.3
8.11. Extraction of acetone by trichloroethane. Extract
One thousand kg/h of a 45 wt% acetone-in-water solution is to C
be extracted at 25_x0003_C in a continuous, countercurrent system with Ac
pure 1,1,2-trichloroethane to obtain a raffinate containing 10 wt% 0.6
acetone. Using the following equilibrium data, determine with an 0.5
equilateral-triangle diagram: (a) the minimum flow rate of solvent; 0.4
(b) the number of stages required for a solvent rate equal to 1.5 0.3
times minimum; (c) the flow rate and composition of each stream 0.2
leaving each stage. 0.1

Solvente TCE B Extract

Portador W A A
Soluto Ac C W
0.13
0.04
0.03
0.02
0.015
0.01
D18. We contact 100 kg/h of a feed mixture that is 50 wt % methylcyclohexane and 50 wt % n-heptane
with a solvent stream (15 wt % methylcyclohexane and 85 wt % aniline) in a mixer-settler that
acts as a single equilibrium stage. We obtain an extract phase which is 10 wt %
methylcyclohexane and a raffinate phase which is 61 wt % methylcyclohexane. Equilibrium data
are in Table 13-6. What flow rate of the solvent stream was used?

A B C A B C
nC7 ANILINA MCH nC7 ANILINA MCH
0.926 0.074 0 0.062 0.938 0
0.831 0.077 0.092 0.06 0.932 0.008
0.734 0.08 0.186 0.053 0.92 0.027
0.698 0.0815 0.22 0.051 0.919 0.03
0.576 0.086 0.338 0.045 0.909 0.046
0.504 0.087 0.409 0.04 0.9 0.06
0.45 0.09 0.46 0.036 0.89 0.074
0.307 0.103 0.59 0.028 0.88 0.092
0.228 0.1 0.672 0.021 0.866 0.113
0.182 0.102 0.716 0.016 0.857 0.127
0.16 0.104 0.736 0.014 0.855 0.131
0.054 0.113 0.833 0.006 0.838 0.156
0 0.119 0.881 0 0.831 0.169

D18. We contact 100 kg/h of a feed mixture that is 50 wt % methylcyclohexane and 50 wt % n-heptane
with a solvent stream (15 wt % methylcyclohexane and 85 wt % aniline) in a mixer-settler that
acts as a single equilibrium stage. We obtain an extract phase which is 10 wt %
methylcyclohexane and a raffinate phase which is 61 wt % methylcyclohexane. Equilibrium data
are in Table 13-6. What flow rate of the solvent stream was used?
 F S M R E
nC7 50 0 50
Anilina 0 449.778028 449.778028
MCH 50 79.3725932 129.372593
100 529.150622 629.1506217 xF
yS
xF yS xM x y
nC7 0.5 0 0.07947223075 xM
Anilina 0 0.85 0.7148972070.102 0.875
MCH 0.5 0.15 0.205630561 0.61 0.1 x
y
0.07947222538 -0.00005369174855
0.7148972169
0.2056305578

F Smin M R E
CHCl3 700 0 700
H2O 0 61 61
H Ac 300 0 300
1000 61 1061 xF
yS
xF yS xM x y
CHCl3 0.7 0 0.6597549482 xM min
H2O 0 1 0.0574929312
H Ac 0.3 0 0.2827521206 xM max

F Smax M R E
CHCl3 700 0 700
H2O 0 60000 60000
H Ac 300 0 300
1000 60000 61000

xF yS xM x y
CHCl3 0.7 0 0.01147540984
H2O 0 1 0.9836065574
H Ac 0.3 0 0.004918032787

Concentración máxima

yS 1 0
Emax 0 0.97

0.809278350 0.185
 F S1 M1 R1 E1 xF
A 70 0 70 60.09 10.53 0.7
B 0 50 50 3.96 45.41 0
C 30 0 30 7.92 22.08 0.3
100 50 150 71.97 78.03

R1 S2 M2 R2 E2 x1
A 60.09 0 60.09 53.62 6.36 0.835
B 3.96 50 53.96 2.92 51.15 0.055
C 7.92 0 7.92 1.81 6.11 0.11
71.97 50 121.97 58.35 63.62

R2 S3 M3 R3 E3 x2
A 53.62 0 53.62 52.77 5.18 0.919
B 2.92 50 52.92 2.80 45.79 0.05
C 1.81 0 1.81 0.45 1.36 0.031
58.35 50 108.35 56.02 52.33

E1 E2 E3 E
10.53 6.36 5.18 22.08
45.41 51.15 45.79 142.35
22.08 6.11 1.36 29.55
193.98
xN 0.03

F S1 M1 R1 E1 xF
CCl3 65 0.00 65.00 61.19 3.63 0.65
H2O 0 33.33 33.33 1.46 32.06 0
H Ac 35 0.00 35.00 10.20 24.80 0.35
100 33.33 133.33 72.84 60.49

R1 S2 M2 R2 E2 x1
CCl3 61.19 0.00 61.19 61.74 0.25 0.84
H2O 1.46 33.33 34.79 0.78 33.20 0.02
H Ac 10.20 0.00 10.20 2.61 7.59 0.14
72.84 33.33 106.17 65.13 41.04

R2 S3 M3 R3 E3 x2
CCl3 61.74 0.00 61.74 65.79 0.15 0.948
H2O 0.78 33.33 34.11 0.61 29.31 0.012
H Ac 2.61 0.00 2.61 1.22 1.39 0.04
65.13 33.33 98.46 67.62 30.85

E1 E2 E3
3.63 0.25 0.15
32.06 33.20 29.31
24.80 7.59 1.39
Se desea extraer el ácido acético de una mezcla que tiene 35% de éste ácido en cloroformo; el refinado debe contener
como máximo 3% de ácido. Si la cantidad de agua pura a emplear es de 100 kg/h, ¿Cuántas etapas en contracorriente se n

F S M Rn E1 xF
CCl3 65 0.00 65.00 63.51 1.60 0.65
H2O 0 100.00 100.00 0.86 99.03 0
H Ac 35 0.00 35.00 1.99 33.01 0.35
100 100.00 200.00 66.36 133.64

Si en lugar de emplear 100 kg/h de agua, se emplean 50 kg/h, calcular el número de etpas teóricas que se requieren

F S M Rn E1 xF
CCl3 65 0.00 65.00 61.32 4.47 0.65
H2O 0 50.00 50.00 0.83 48.37 0
H Ac 35 0.00 35.00 1.92 33.08 0.35
100 50.00 150.00 64.08 85.92
 Raffinate
A B C A B 0.044 0.44
W TCE Ac W TCE 0.345 0.56
0.13 0.27 0.55 0.35 0.1
0.04 0.46 0.5 0.43 0.07 0.018 0.29
0.03 0.57 0.4 0.57 0.03 0.565 0.4
0.02 0.68 0.3 0.68 0.02
0.015 0.785 0.2 0.79 0.01 0.01 0.12
0.01 0.89 0.1 0.895 0.005 0.8 0.18

Raffinate
B C A B C
TCE Ac W TCE Ac
0.27 0.6 0.35 0.1 0.55 0.7
0.46 0.5 0.43 0.07 0.5
0.57 0.4 0.57 0.03 0.4 0.6
0.68 0.3 0.68 0.02 0.3
0.785 0.2 0.79 0.01 0.2 0.5
0.89 0.1 0.895 0.005 0.1
0.4

0.3

0.2

0.1

0
0.2 0.3 0.4 0.5 0.6
 0.074 0
0.938 0
1
0.077 0.092 0 1
0.932 0.008 1 0
0.9

0.08 0.186
0.92 0.027 0.8

0.0815 0.22 0.7

0.919 0.03

0.6
0.086 0.338
0.909 0.046
0.5
0.087 0.409
0.9 0.06
0.4

0.09 0.46
0.89 0.074 0.3

0.103 0.59 0.2

0.88 0.092

0.1
0.1 0.672
0.857 0.127
0
0.102 0.716 0 0.1 0.2 0.3 0.4 0.5 0.6 0

0.857 0.127

0.104 0.736
0.855 0.131

0.113 0.833
0.838 0.156
1
0.119 0.881
0.9

0.8
 1

0.831 0.169 0.9

0.8
LECTURA GRAFICO
x y
0 0.5 0.7
0.85 0.15 -0.41176470 0.5

0.6
0.7148972070.2056305615

0.102 0.61 0.5

0.875 0.1 -0.65976714 0.6772962484

0.4

0.3

0.2

0.1

0
0 0.1 0.2

A
CHCl3
0.9901
0.9185
1 0.8
0.7013
0.9 0.6715
0.5999
0.8 0.5581

0.7

0.6

0.5
LECTURA GRAFICO
x y 0.4

0 0.3
0.3
1 0 -0.3 0.3

0.2
0.0574929310.2827521206
0.1

0
0 1 2 3 4
 0.3

0.2

0.1
0.9836065570.004918032787
#DIV/0! #DIV/0! 0
0 1 2 3 4

Col umn J

0.4

0.35

0.3

0.25

-0.97 0.97
0.2

0.15

0.1

0.05

0
0 0.02 0.04 0.06 0.08 0.1

Col umn R

A B C A B
0.95 0.05 0 0.1 0.9
0.925 0.05 0.025 0.101 0.82
0.899 0.051 0.05 0.108 0.742
0.873 0.052 0.075 0.115 0.675
0.846 0.054 0.1 0.127 0.611
0.819 0.056 0.125 0.142 0.558
 0.791 0.059 0.15 0.159 0.503
0.763 0.062 0.175 0.178 0.457
0.734 0.066 0.2 0.196 0.414
0.675 0.075 0.25 0.246 0.329
0.611 0.089 0.3 0.28 0.275
0.544 0.106 0.35 0.333 0.217
0.466 0.134 0.4 0.405 0.165
0.434 0.15 0.416 0.434 0.15

B C
F 0 0.3
yS1 xM1 x1 y1 S1 1 0
0 0.466666666 0.835 0.135
1 0.3333333330.055 0.582 M1 0.3333333330.2
0 0.2 0.11 0.283
R1 0.055 0.11
E1 0.582 0.283

R1 0.055 0.11
yS2 xM2 x2 y2 S2 1 0
0 0.492689573 0.919 0.1
1 0.4424052130.05 0.804 M2 0.4424052130.06490521327
0 0.0649052130.031 0.096
R2 0.05 0.031
E2 0.804 0.096

R2 0.05 0.031
yS3 xM3 x3 y3 S3 1 0
0 0.494895473 0.942 0.099
1 0.4884105550.05 0.875 M3 0.4884105550.01669397135
0 0.0166939710.008 0.026
R3 0.05 0.008
E3 0.875 0.026

y
0.1138097442
0.7338491844
0.1523410715
 B C
yS1 xM1 x1 y1 xF 0 0.35
0 0.4875 0.84 0.06 yS1 1 0
1 0.25 0.02 0.53
0 0.2625 0.14 0.41 xM1 0.25 0.2625

x1 0.02 0.14
y1 0.53 0.41

yS2 xM2 x2 y2 x1 0.02 0.14

0 0.576279069 0.948 0.006 yS2 1 0
1 0.3276744180.012 0.809
0 0.0960465110.04 0.185 xM2 0.3276744180.09604651163

x2 0.012 0.04
y2 0.809 0.185

yS3 xM3 x3 y3 x2 0.012 0.04

0 0.627081712 0.973 0.005 yS3 1 0
1 0.3464591440.009 0.95
0 0.0264591430.018 0.045 xM3 0.3464591440.02645914397

x3 0.009 0.018
y3 0.95 0.045
E y
4.03 0.03044291993
94.57 0.7143657412
33.78 0.2551913388
132.38
 l refinado debe contener
tapas en contracorriente se necesitan?

B C
yS xM xn y1 xF 0 0.35
0 0.325 0.957 0.012 yS 1 0
1 0.5 0.013 0.741
0 0.175 0.03 0.247 xM1 0.5 0.175

xn 0.013 0.03
y1 0.741 0.247

y1 0.741 0.247
x1 0.014 0.064
D 2.942786192-0.05905125203

y2 0.967 0.024
x2 0.012 0.017

óricas que se requieren

B C
yS xM xn y1 xF 0 0.35
0 0.433333333 0.957 0.052 yS 1 0
1 0.3333333330.013 0.563
0 0.2333333330.03 0.385 xM1 0.3333333330.2333333333

xn 0.013 0.03
y1 0.563 0.385

F 0 0.35
E1 0.563 0.385
D -3.45286964 0.1353455818
R 0.013 0.03
S 1 0

y1 0.563 0.385
x1 0.025 0.15

D -3.45286964 0.1353455818
x1 0.025 0.15
y2 0.84 0.1534340996
x2 0.015 0.03
 0.3986710960.4224584718 0.044 0.44 0.345 0.44
0.345 0.44 0.565 0.29
0.345 0.56 0.8 0.12
0.2010968920.2863802559
0.018 0.29
0.565 0.29 0.05
0.0759493670.1192405063 0.565 0.4
0.0890123160.534024
0.01 0.12 0.2 0.613
0.8 0.12
0.8 0.18 0.0693759790.5020375
0.25 0.6057234375

0.0539368440.469594
0.3 0.5903195

0.0420493010.4366935
0.35 0.5676698125

0.0330866380.403336
0.4 0.538656

0.0264507170.3695215
0.45 0.5041596875

0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

0.0215823830.33525
0.5 0.4650625

0.0179726180.3005215
0.55 0.4222460625

0.0151744750.265336
0.6 0.376592

0.0128158030.2296935
0.65 0.3289819375

0.0106128090.193594
0.7 0.2802975

0.0083844570.1570375
0.75 0.2314203125

0.0060677580.120024
 0.8 0.183232

.4 0.5 0.6 0.7 0.8 0.9 1

0.9

0.8
 1

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

B C A B C
H2O H Ac CHCl3 H2O H Ac 0.0099
0.0099 0 0.0084 0.9916 0 0.9916
0.0138 0.0677 0.0121 0.7369 0.251
0.0228 0.1772 0.073 0.4858 0.4412 0.0138
0.0412 0.2575 0.1511 0.3471 0.5018 0.7369
0.052 0.2765 0.1833 0.3111 0.5056
0.0793 0.3208 0.252 0.2539 0.4941 0.0228
0.0953 0.3466 0.2885 0.2328 0.4787 0.4858

0.0412
0.3471

0.052
0.3111

0.0793
0.2539

0.0953

2 3 4 5 6 7
 0.2328

2 3 4 5 6 7

Col umn J

0.08 0.1 0.12

B C
C x 0.05 0
0 y 0.9 0
0.079
0.15 0.05 0.025
0.21 0.82 0.079
0.262
0.3 0.051 0.05
 0.338 0.742 0.15
0.365
0.39 0.052 0.075
0.425 0.675 0.21
0.445
0.45 0.054 0.1
0.43 0.611 0.262
0.416 0.3
0.056 0.125
0.558 0.3

0.059 0.15
0.503 0.338
0.25

0.062 0.175
0.457 0.365

0.066 0.2
0.2 0.414 0.39

0.075 0.25
.06490521327 0.329 0.425

0.089 0.3
0.15
0.275 0.445

0.106 0.35
0.217 0.45

.01669397135 0.1 0.134 0.4

0.165 0.43

0.15 0.416
0.15 0.416

0.05

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

0.45
Col umn P

0.4
 0.45

0.4

0.35

0.3

0.25

0.2

0.15

0.1

.09604651163
0.05

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Col umn P

.02645914397
 0.3

F 0 0.35
0.25
E1 0.741 0.247 -0.13900134 0.35
D 2.942786192-0.05905125203
R 0.013 0.03
S 1 0 -0.03039513 0.03039513678
0.05905125203
0.2

0.15

0.1

0.05

0
-0.3

0.4

0.4

0.35

0.35

0.3
 0.4

0.35
.2333333333
0.35

0.3

0.3

0.0621669620.35
0.25
.1353455818
0.25
-0.03039513 0.03039513678
0.2

0.2

0.15
.1353455818
0.15
0.0042136190.1498946595
.1534340996
0.1

0.1

0.05

0.05

0
-0.2 -1.66533453693773E-16 0.2
0
-0.5 -0.45 -0.4 -0.35 -0.3 -0.25 -0.2 -0.15 -0.1 -0.05 0 0.05 0.1 0.15 0.2 0.25 0.
.6057234375

.5676698125

.5041596875

.4222460625

.3289819375

.2314203125
 0.4

0.35
0
0 0.3

0.25
0.0677
0.2
0.251
0.15
0.1772
0.1
0.4412
0.05

0.2575 0
0.5018 0 0.02 0.04 0.06 0.08 0.1 0.12
Col umn R
0.2765
0.5056

0.3208
0.4941

0.3466
0.4787
0.6 0.7 0.8 0.9 1

0.45
 0.45

0.4

0.35

0.3

0.25

0.2

0.15

0.1

0.8 0.9 1

0.05

0
0 0.1 0.2 0.3
 0.3

0.25

0.2

0.15

0.1

0.05

0
0.2 0.7 1.2

Col umn P
693773E-16 0.2 0.4 0.6 0.8

0 Col umn
0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0.5 0.55 0.6 0.65 0.7 0.75R 0.8 0.85 0.9 0.95 1 1.05 1.1 1.15 1.2

Col umn R
0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

Col umn P
1.2
0.8 1 1.2
DATA
NUMBER COMPONENT MOLE WT FREEZE BOILING CRITICAL CRITICAL CRITICAL
POINT POINT TEMP PRESSURE VOLUME
K K K ATM CC/G-MOL
(TFP) (TB) (TC) (PC) (VC)
0 1 2 3 4 5 6 7

1 1,1,1-TRIFLOUROETHANE 84.041 161.9 225.5 346.2 37.1 221.0

2 1,1,2,2-TETRACHLORO-1,2-DIFLUOROETHANE 203.831 298.0 364.7 551.0 0.0 0.0
3 1,1,2-TRICHLOROETHANE 133.405 236.5 386.9 602.0 41.0 294.0
4 1,1,2-TRIMETHYLCLOPENTANE 112.216 0.0 386.9 579.5 29.0 0.0
5 1,1,3-TRIMETHYLCLOPENTANE 112.216 0.0 378.0 569.5 27.9 0.0
6 1,1-DICHLORO-1,2,2,2-TETRAFLUOROETHANE 170.922 179.0 277.0 418.6 32.6 294.0
7 1,1-DICHLOROETHANE 98.960 176.2 330.4 523.0 50.0 240.0
8 1,1-DIFLOUROETHANE 66.051 156.2 248.4 386.6 44.4 181.0
9 1,1-DIFLUOROETHYLENE 64.035 0.0 0.0 302.8 44.0 154.0
10 1,1-DIMETHYLCYCLOHEXANE 112.216 239.7 392.7 591.0 29.3 416.0
11 1,1-DIMETHYLCYCLOPENTANE 98.189 203.4 361.0 547.0 34.0 360.0
12 1,2,2-TRICHLORO-1,1,2TRIFLUOROETHANE 187.380 238.2 320.7 487.2 33.7 304.0
13 1,2,3,4-TETRAHYDRONAPHTHALENE 132.206 242.0 480.7 719.0 34.7 0.0
14 1,2,3-TRICHLOROPROPANE 147.432 258.5 429.0 651.0 39.0 348.0
15 1,2,3-TRIMETHYLBENZENE 120.195 247.7 449.2 664.5 34.1 430.0
16 1,2,4,5-TETRAMETHYLBEENZENE 134.222 352.0 470.0 675.0 29.0 480.0
17 1,2,4-TRIMETHYLBENZENE 120.195 227.0 442.5 649.1 31.9 430.0
18 1,2-BUTADIENE 54.092 137.0 284.0 443.7 44.4 219.0
19 1,2-DICHLORO-1,1,2,2-TETRAFLUOROETHANE 170.922 179.3 276.9 418.9 32.2 293.0
20 1,2-DICHLOROETHANE 98.960 237.5 356.6 561.0 53.0 220.0
21 1,2-DICHLOROPROPANE 112.987 172.7 369.5 577.0 44.0 226.0
22 1,2-DIMETHOXYETHANE 90.123 202.0 358.6 536.0 38.2 271.0
23 1,2-PENTADIENE 68.119 135.9 318.0 503.0 40.2 276.0
24 1,2-PROPANEDIOL 76.096 213.0 460.5 625.0 60.0 237.0
25 1,3,5-TRIMETHYLBENZENE 120.195 228.4 437.9 637.3 30.9 433.0
26 1,3-BUTADIENE 54.092 164.3 268.7 425.0 42.7 221.0
27 1,3-PROPANEDIOL 76.096 246.4 487.6 658.0 59.0 241.0
28 1,4 DIOXANE 88.107 285.0 374.5 587.0 51.4 238.0
29 1,4-DIETHYLBENZENE 134.222 231.0 456.9 657.9 27.7 480.0
30 1,4-PENTADIENE 68.119 124.9 299.1 478.0 37.4 276.0
31 1,5 HEXADIENE 82.146 132.0 332.6 507.0 34.0 328.0
32 1-BUTENE 56.108 87.8 266.9 419.6 39.7 240.0
33 1-BUTYNE 54.092 147.4 281.2 463.7 46.5 220.0
34 1-CHLORO-1,1-DIFLUOROETHANE 100.496 142.0 263.4 410.2 40.7 231.0
35 1-CHLOROBUTANE 92.569 150.1 351.6 542.0 36.4 312.0
36 1-DECANOL 158.285 280.1 503.4 700.0 22.0 600.0
37 1-DECENE 140.270 206.9 443.7 615.0 21.8 650.0
38 1-DODECENE 168.324 238.0 486.5 657.0 18.3 0.0
39 1-EICOSANOL 298.555 339.0 629.0 770.0 12.0 0.0
40 1-HEPTANOL 116.204 239.2 449.5 633.0 30.0 435.0
41 1-HEPTENE 98.189 154.3 366.8 537.2 28.0 440.0
42 1-HEXADECENE 224.432 277.3 558.0 717.0 13.2 0.0
43 1-HEXANOL 102.177 229.2 430.2 610.0 40.0 381.0
44 1-HEXENE 84.162 133.3 336.6 504.0 31.3 350.0
45 1-METHYL-1-ETHYLCYCLOPENTANE 112.216 0.0 394.7 592.0 29.5 0.0
46 1-METHYL-2-ETHYLBENZENE 120.195 192.3 438.3 651.0 30.0 460.0
47 1-METHYL-2-ISOPROPYLBENZENE 134.222 0.0 451.5 670.0 28.6 0.0
48 1-METHYL-2-ISOPROPYLBENZENE 134.222 0.0 448.3 666.0 29.0 0.0
49 1-METHYL-3-ETHYLBENZENE 120.195 177.6 434.5 637.0 28.0 490.0
50 1-METHYL-4-ETHYLBENZENE 120.195 210.8 435.2 640.0 29.0 470.0
51 1-METHYL-4-ISOPROPYLBENZENE 134.222 200.0 450.3 653.0 27.9 0.0
52 1-METHYLNAPHTHALENE 142.201 242.7 517.8 772.0 35.2 445.0
53 1-NONENE 126.243 191.8 420.0 592.0 23.1 580.0
54 1-OCTADECANOL 270.501 331.0 608.0 747.0 14.0 0.0
55 1-OCTADECENE 252.486 290.8 588.0 739.0 11.2 0.0
56 1-OCTANOL 130.231 257.7 468.4 58.0 34.0 490.0
57 1-OCTENE 112.216 171.4 394.4 566.6 25.9 464.0
58 1-PENTADECENE 210.405 269.4 541.5 704.0 14.4 0.0
59 1-PENTANOL 88.150 195.0 411.0 586.0 38.0 326.0
60 1-PENTENE 70.135 107.9 303.1 464.7 40.0 300.0
61 1-PENTYNE 68.119 167.5 313.3 493.4 40.0 278.0
62 1-PROPANOL 60.096 146.9 370.4 536.7 51.0 218.5
63 1-TERADECENE 196.378 260.3 524.3 689.0 15.4 0.0
64 1-TRANS-3-PENTADIENE 68.119 185.7 315.2 496.0 39.4 275.0
65 1-TRIDECENE 182.351 250.1 505.9 674.0 16.8 0.0
66 1-UNDECENE 154.297 224.0 465.8 637.0 19.7 0.0
67 2,2 DIMETHYL BUTANE 86.178 173.3 322.9 488.7 30.4 359.0
68 2,2,3 TRIMETHYLPETANE 114.232 160.9 383.0 563.4 26.9 436.0
69 2,2,3,3-TETRAMETHYLHEPTANE 142.286 0.0 433.5 623.1 24.8 0.0
70 2,2,3,3-TETRAMETHYLPENTANE 128.259 0.0 413.4 607.6 27.0 0.0
71 2,2,3,4-TETRAMETHYLPENTANE 128.259 0.0 406.2 592.7 25.7 0.0
72 2,2,3-TRIMETHYLBUTANE 100.205 248.3 354.0 531.1 29.2 398.0
73 2,2,3-TRIMETHYLHEXANE 128.259 0.0 406.8 588.0 24.6 0.0
74 2,2,4 TRIMETHYLPENTANE 114.232 165.8 372.4 543.9 25.3 468.0
75 2,2,4,4-TETRAMETHYLPENTANE 128.259 206.0 395.4 574.7 24.5 0.0
76 2,2,4-TRIMETHYLHEXANE 128.259 153.0 399.7 573.7 23.4 0.0
77 2,2,5,5-TETRAMETHYLHEPTANE 142.286 0.0 410.6 581.5 21.6 0.0
 78 2,2,5-TRIMETHYLHEXANE 128.259 167.4 397.3 568.0 23.0 519.0
79 2,2-DIMETHYL PROPANE 72.151 256.6 282.6 433.8 31.6 303.0
80 2,2-DIMETHYL-1-PROPANOL 88.150 327.0 386.3 549.0 39.0 319.0
81 2,2-DIMETHYLHEXANE 114.232 152.0 382.0 549.8 25.0 478.0
82 2,2-DIMETHYLPENTANE 100.205 149.4 352.4 520.4 27.4 416.0
83 2,3 DIMETHYL BUTANE 86.178 144.6 331.2 499.9 30.9 358.0
84 2,3,3 TRIMETHYLPENTANE 114.232 172.5 387.9 573.5 27.8 455.0
85 2,3,3,4-TETRAMETHYLPENTANE 128.259 0.0 414.7 607.6 26.8 0.0
86 2,3,3-TRIMETHYL-1-BUTENE 98.189 163.3 351.0 533.0 28.6 400.0
87 2,3,4 TRIMETHYLPENTANE 114.232 163.9 386.6 56.3 26.9 461.0
88 2,3-DIMETHYL-1-BUTENE 84.162 115.9 328.8 501.0 32.0 343.0
89 2,3-DIMETHYL-2-BUTENE 84.162 198.9 346.4 524.0 33.2 351.0
90 2,3-DIMETHYLHEXANE 114.232 0.0 388.8 563.4 25.9 468.0
91 2,3-DIMETHYLPENTANE 100.205 0.0 362.9 537.3 28.7 393.0
92 2,3-DIMETHYLPYRIDINE 107.156 0.0 434.0 655.4 0.0 0.0
93 2,3-XYLENOL 122.167 348.0 490.1 722.8 0.0 0.0
94 2,4-DIMETHYLHEXANE 114.232 0.0 382.6 553.5 25.2 472.0
95 2,4-DIMETHYLPENTANE 100.205 154.0 353.7 519.7 27.0 418.0
96 2,4-XYLENOL 122.167 298.0 484.0 707.6 0.0 0.0
97 2,5-DIMETHYLHEXANE 114.232 181.9 382.3 550.0 24.5 42.0
98 2,5-DIMETHYLPYRIDINE 107.156 0.0 430.2 644.2 0.0 0.0
99 2,5-XYLENOL 122.167 348.0 484.3 723.0 0.0 0.0
100 2,6-XYLENOL 122.167 322.0 474.1 701.0 0.0 0.0
101 2-BUTANOL 74.123 158.5 372.7 536.0 41.4 268.0
102 2-BUTYNE 54.092 240.9 300.2 488.6 50.2 221.0
103 2-CHLOROBUTANE 92.569 141.8 341.4 520.6 39.0 305.0
104 2-ETHYLHEXANOL 130.231 203.2 457.8 613.0 27.2 494.0
105 2-METHYL BUTANE 72.151 113.3 301.0 460.4 33.4 306.0
106 2-METHYL PENTANE 86.178 119.5 333.4 497.5 29.7 367.0
107 2-METHYL-1,3-BUTADIENE 68.119 127.2 307.2 484.0 38.0 276.0
108 2-METHYL-1-BUTANOL 88.150 203.0 409.1 571.0 38.0 322.0
109 2-METHYL-1-BUTENE 70.135 135.6 304.3 465.0 34.0 294.0
110 2-METHYL-2-BUTENE 70.135 139.4 311.7 470.0 34.0 318.0
111 2-METHYL-2-PENTENE 84.162 138.1 340.5 518.0 32.4 351.0
112 2-METHYL-3-ETHYLPENTANE 114.232 158.2 388.8 567.0 26.7 443.0
113 2-METHYLHEPTANE 114.232 164.0 390.8 559.6 24.5 488.0
114 2-METHYLHEXANE 100.205 154.9 363.2 530.3 27.0 421.0
115 2-METHYLNAPHTHALENE 142.201 307.7 514.2 761.0 34.6 462.0
116 2-OCTANOL 130.231 241.2 452.9 637.0 27.0 494.0
117 3,3,5-TRIMETHYLHEPTANE 142.286 0.0 428.8 609.6 22.9 0.0
118 3,3-DIETHYLPENTANE 128.259 0.0 419.3 610.0 26.4 0.0
119 3,3-DIMETHYL-1-BUTENE 84.162 158.0 314.4 490.0 32.1 340.0
120 3,3-DIMETHYLHEXANE 114.232 147.0 385.1 562.0 26.2 443.0
121 3,3-DIMETHYLPENTANE 100.205 138.7 359.2 536.3 29.1 414.0
122 3,4 DIMETHYLHEXANE 114.232 0.0 390.9 568.8 26.6 466.0
123 3,4-DIMETHYLPYRIDINE 107.156 0.0 452.3 683.8 0.0 0.0
124 3,4-XYLENOL 122.167 328.0 500.0 729.8 0.0 0.0
125 3,5-DIMETHYLPYRIDINE 107.156 0.0 445.1 667.2 0.0 0.0
126 3,5-XYLENOL 122.167 337.0 494.8 715.6 0.0 0.0
127 3-ETHYLHEXANE 114.232 0.0 391.7 565.4 25.7 455.0
128 3-ETHYLPENTANE 100.205 154.6 366.6 540.6 28.5 416.0
129 3-METHYL PENTANE 86.178 155.0 336.4 504.4 30.8 367.0
130 3-METHYL-1,2-BUTADIENE 68.119 159.5 314.0 496.0 40.6 267.0
131 3-METHYL-1-BUTANOL 88.150 156.0 404.4 579.5 38.0 329.0
132 3-METHYL-1-BUTENE 70.135 104.7 293.3 450.0 34.7 300.0
133 3-METHYL-2-BUTANOL 88.150 264.4 375.2 545.0 39.0 319.0
134 3-METHYL-3-ETHYLPENTANE 114.232 182.3 391.4 576.6 27.7 455.0
135 3-METHYL-CIS-2-PENTENE 84.162 138.3 340.9 518.0 32.4 351.0
136 3-METHYLHEPTANE 114.232 152.7 392.1 563.6 25.1 464.0
137 3-METHYLHEXANE 100.205 100.0 365.0 535.2 27.8 404.0
138 3-METHYL-TRANS-2-PENTENE 84.162 134.7 343.6 521.0 32.5 350.0
139 4- METHYL PYRIDINE 93.129 276.9 418.5 646.0 44.0 311.0
140 4-METHYL-CIS-2-PENTENE 84.162 139.0 329.6 490.0 30.0 360.0
141 4-METHYLHEPTANE 114.232 152.2 390.9 561.7 25.1 476.0
142 4-METHYL-TRANS-2-PENTENE 84.162 132.0 331.7 493.0 30.0 360.0
143 ACETALDEHYDE 44.054 150.2 293.6 461.0 55.0 154.0
144 ACETIC ACID 60.052 289.8 391.1 594.4 57.1 171.0
145 ACETIC ANHYDRIDE 102.089 199.0 412.0 569.0 46.2 290.0
146 ACETONE 58.080 178.2 329.4 508.1 46.4 209.0
147 ACETONITRILE 41.053 229.3 354.8 548.0 47.7 173.0
148 ACETYL CHLORIDE 78.498 160.2 323.9 508.0 58.0 204.0
149 ACETYLENE 26.038 192.4 189.2 308.3 60.6 113.0
150 ACROLEIN 56.064 186.0 326.0 506.0 51.0 0.0
151 ACRYLIC ACID 72.064 285.0 414.0 615.0 56.0 210.0
152 ACRYLONITRILE 53.064 189.5 350.5 536.0 45.0 210.0
153 ALLYL ALCOHOL 58.080 144.0 370.0 545.0 56.4 203.0
154 ALLYL CHLORIDE 76.526 138.7 318.3 514.0 47.0 234.0
155 ALLYL CYANIDE 67.091 186.7 392.0 585.0 39.0 265.0
156 ALPHA-METHYL STYRENE 118.179 0.0 438.5 654.0 33.6 397.0
157 AMMONIA 17.031 195.4 239.7 405.6 111.3 72.5
158 ANILINE 93.129 267.0 457.5 699.0 52.4 270.0
159 ANTHRACENE 178.234 489.7 614.4 883.0 0.0 0.0
160 ARGON 39.948 83.8 87.3 150.8 48.1 74.9
161 BENZALDEHYDE 106.124 216.0 452.0 695.0 46.0 0.0
162 BENZENE 78.114 278.7 353.3 562.1 48.3 259.0
163 BENZOIC ACID 122.124 395.6 523.0 752.0 45.0 341.0
164 BENZONITRILE 103.124 260.0 464.0 699.4 41.6 0.0
165 BENZYL ALCOHOL 108.140 257.8 478.6 677.0 46.0 334.0
166 BORON TRICHLORIDE 117.169 165.9 285.7 452.0 38.2 0.0
167 BORON TRIFLUORIDE 67.805 146.5 173.3 260.8 49.2 0.0
168 BROMINE 159.808 266.0 331.9 584.0 102.0 127.0
169 BROMOBENZENE 157.010 242.3 429.3 670.0 44.6 324.0
170 BUTYL BENZOATE 178.232 251.0 523.0 723.0 26.0 561.0
171 BUTYL ETHER 130.231 175.3 415.6 580.0 25.0 500.0
172 BUTYRONITRILE 69.107 161.0 391.0 582.2 37.4 285.0
173 C,C,T-1,2,4-TRIMETHYLCYCLOPENTANE 112.216 0.0 391.0 579.0 284.0 0.0
174 C,T,C-1,2,4-TRIMETHYLCYCLOPENTANE 112.216 0.0 382.4 571.0 27.7 0.0
175 CAPRYLONITRILE 153.269 255.3 516.0 622.0 32.1 0.0
176 CARBON DIOXIDE 44.010 216.6 194.7 304.2 72.8 94.0
177 CARBON DISULFIDE 76.131 161.3 319.4 552.0 78.0 170.0
178 CARBON MONOXIDE 28.018 68.1 81.7 32.9 34.5 93.1
179 CARBON TETRACHLORIDE 153.823 250.0 349.7 556.4 45.0 276.0
180 CARBON TETRAFLUORIDE 88.005 86.4 145.2 227.6 36.9 140.0
181 CARBONYL SULFIDE 60.070 134.3 222.9 375.0 58.0 140.0
182 CHLORINE 70.906 172.2 238.7 417.0 76.0 124.0
183 CHLOROBENZENE 112.559 227.6 404.9 632.4 44.6 308.0
184 CHLORODIFLUOROMETHANE 86.469 113.0 232.4 369.2 49.1 165.0
185 CHLOROFORM 119.378 209.6 334.3 536.4 54.0 239.0
186 CHLOROPENTAFLUOROETHANE 154.467 167.0 234.0 353.2 31.2 252.0
187 CHLOROTRIFLUOROMETHANE 104.459 92.0 191.7 302.0 38.7 180.0
188 CIS-1,2-DIMETHYLCYCLOHEXANE 112.216 223.1 402.9 606.0 29.3 0.0
189 CIS-1,2-DIMETHYLCYCLOPENTANE 98.189 219.3 372.7 564.8 34.0 368.0
190 CIS-1,3-DIMETHYLCYCLOHEXANE 112.216 197.6 393.3 591.0 29.3 0.0
191 CIS-1,4-DIMETHYLCYCLOHEXANE 112.216 185.7 397.5 598.0 29.3 0.0
192 CIS-2-BUTENE 56.108 134.3 276.9 435.6 41.5 234.0
193 CIS-2-HEXENE 84.162 132.0 342.0 518.0 32.4 351.0
194 CIS-2-PENTENE 70.135 121.8 310.1 476.0 36.0 300.0
195 CIS-3-HEXENE 84.162 135.3 339.6 517.0 32.4 350.0
196 CIS-DECALIN 138.254 230.0 468.9 702.2 31.0 0.0
197 CYANOGEN 52.035 245.3 252.5 400.0 59.0 0.0
198 CYCLOBUTANE 56.108 182.4 285.7 459.9 49.2 210.0
199 CYCLOHEPTANE 98.189 265.0 391.9 589.0 36.7 390.0
200 CYCLOHEXANE 84.162 279.7 353.9 553.4 40.2 308.0
201 CYCLOHEXANOL 100.161 298.0 434.3 625.0 37.0 327.0
202 CYCLOHEXANONE 95.145 242.0 428.8 629.0 38.0 312.0
203 CYCLOHEXENE 82.146 169.7 356.1 560.4 42.9 292.0
204 CYCLOPENTANE 70.135 179.3 322.4 511.6 44.5 260.0
205 CYCLOPENTANONE 84.118 222.5 403.9 626.0 53.0 268.0
206 CYCLOPENTENE 68.119 138.1 317.4 506.0 0.0 0.0
207 CYCLOPROPANE 42.081 145.7 240.4 397.8 54.2 170.0
208 DEUTERIUM 4.032 18.7 23.7 38.4 16.4 60.3
209 DEUTERIUM OXIDE 20.031 277.0 374.6 644.0 213.8 55.6
210 DIBROMOMETHANE 173.835 220.6 370.0 583.0 71.0 0.0
211 DIBUTYLAMINE 129.247 211.0 432.8 596.0 25.0 517.0
212 DIBUTYL-O-PHTHALATE 278.350 238.0 608.0 0.0 0.0 0.0
213 DICHLORODIFLUOROMETHANE 120.914 115.4 243.4 385.0 40.7 217.0
214 DICHLOROMETHANE 84.933 178.1 313.0 510.0 60.0 193.0
215 DICHLOROMONOFLUOROMETHANE 102.923 138.0 282.0 451.6 51.0 197.0
216 DIETHYL AMINE 45.085 181.0 280.0 437.6 52.4 187.0
217 DIETHYL AMINE 73.139 223.4 328.6 496.6 36.6 301.0
218 DIETHYL DISULFIDE 122.244 171.7 427.2 642.0 0.0 0.0
219 DIETHYL KETONE 86.134 234.2 375.1 561.0 36.9 336.0
220 DIETHYL SULFIDE 90.180 169.2 365.3 557.0 39.1 318.0
221 DIETHYLENE GLYCOL 106.122 265.0 519.0 681.0 6.0 316.0
222 DIHEXYL ETHER 186.339 230.0 499.6 657.0 18.0 720.0
223 DIISOPROPYL ETHER 102.177 187.7 341.5 500.0 28.4 386.0
224 DIMETHYL ETHER 46.069 131.7 248.3 400.0 53.0 178.0
225 DIMETHYL OXALATE 118.090 327.0 436.6 628.0 39.3 0.0
226 DIMETHYL SULFIDE 62.130 174.9 310.5 503.0 54.6 201.0
227 DIPHENYL 154.212 342.4 528.4 789.0 38.0 502.0
228 DIPHENYL ETHER 170.211 300.0 531.2 766.0 31.0 0.0
229 DIPHENYLMETHANE 168.239 30537.5 767.0 29.4 0.0 0.0
230 DIPROPYLAMINE 101.193 210.0 382.4 550.0 31.0 407.0
231 DODECANOL 186.339 297.1 533.1 679.0 19.0 718.0
232 ETHANE 30.070 89.9 184.5 305.4 48.2 148.0
233 ETHANOL 46.069 159.1 351.5 516.2 63.0 167.0
234 ETHYL ACETATE 88.107 189.6 350.3 523.2 37.8 286.0
235 ETHYL ACRYLATE 100.118 201.0 373.0 552.0 37.0 320.0
236 ETHYL AMINE 45.085 192.0 289.7 456.0 55.5 178.0
237 ETHYL BENZOATE 150.178 238.3 485.9 697.0 32.0 451.0
238 ETHYL BROMIDE 108.966 154.6 311.5 503.8 61.5 215.0
239 ETHYL BUTYL ETHER 102.177 170.0 365.4 531.0 30.0 390.0
240 ETHYL BUTYRATE 116.160 180.0 394.0 566.0 31.0 395.0
241 ETHYL CHLORIDE 64.515 136.8 285.4 460.4 52.0 199.0
242 ETHYL ETHER 74.123 156.9 307.7 466.7 35.9 280.0
243 ETHYL FLUORIDE 48.060 129.9 235.4 375.3 49.6 169.0
244 ETHYL FORMATE 74.080 193.8 327.4 508.4 46.8 229.0
245 ETHYL ISOBUTYRATE 116.160 185.0 384.2 553.0 30.0 410.0
246 ETHYL MERCAPTAN 62.134 125.3 308.2 499.0 54.2 207.0
247 ETHYL PROPIONATE 102.134 199.3 273.0 546.0 33.2 345.0
248 ETHYL PROPYL ETHER 88.150 146.4 336.8 500.6 32.1 0.0
249 ETHYLBENZENE 106.168 178.2 409.3 617.1 35.6 374.0
250 ETHYLCYCLOHEXANE 112.216 161.8 404.9 609.0 29.9 450.0
251 ETHYLCYCLOPENTANE 98.189 134.7 376.6 569.5 33.5 375.0
252 ETHYLENE 28.054 104.0 169.4 282.4 49.7 129.0
253 ETHYLENE GLYCOL 62.069 260.2 470.4 645.0 76.0 186.0
254 ETHYLENE IMINE 43.069 195.0 329.8 0.0 0.0 0.0
255 ETHYLENE OXIDE 44.054 161.0 283.5 469.0 71.0 140.0
256 ETHYLENEDIAMINE 60.099 284.0 390.4 593.0 62.0 206.0
257 FLUORINE 37.997 53.5 85.0 144.3 51.5 66.2
258 FLUOROBENZENE 96.104 234.0 358.5 560.1 44.9 271.0
259 FORMALDEHYDE 30.026 156.0 254.0 408.0 65.0 0.0
260 FORMIC ACID 46.025 281.5 373.8 580.0 0.0 0.0
261 FURAN 68.075 187.5 304.5 490.2 54.3 218.0
262 GLYCEROL 92.095 291.0 563.0 726.0 66.0 255.0
263 HELIUM-4 4.003 0.0 4.2 5.2 2.2 57.3
264 HEPTADECANOL 256.474 327.0 597.0 736.0 14.0 0.0
265 HYDRAZINE 32.045 274.7 386.7 653.0 145.0 96.1
266 HYDROGEN 2.016 14.0 20.4 33.2 12.8 65.0
267 HYDROGEN BROMIDE 80.912 187.1 206.1 363.2 84.4 100.0
268 HYDROGEN CHLORIDE 36.461 159.0 188.1 324.6 82.0 81.0
269 HYDROGEN CYANIDE 27.026 259.9 298.9 456.8 53.2 139.0
270 HYDROGEN FLUORIDE 20.006 190.0 292.7 461.0 64.0 69.0
271 HYDROGEN IODIDE 127.912 222.4 237.6 424.0 82.0 131.0
272 HYDROGEN SULFIDE 34.080 187.6 212.8 373.2 88.2 98.5
273 IODINE 253.808 386.8 457.5 819.0 115.0 155.0
274 IODOBENZENE 204.011 241.8 461.4 721.0 44.6 351.0
275 ISOBUTANE 58.124 113.6 261.3 408.1 36.0 263.0
276 ISOBUTANOL 74.123 165.2 381.0 547.7 42.4 273.0
277 ISOBUTYL ACETATE 116.160 174.3 390.0 561.0 30.0 414.0
278 ISOBUTYL AMINE 73.139 188.0 340.6 516.0 42.0 284.0
279 ISOBUTYL FORMATE 102.134 178.0 371.6 551.0 38.3 350.0
280 ISOBUTYLBENZENE 134.222 221.7 445.9 650.0 31.0 480.0
281 ISOBUTYLCYCLOHEXANE 140.270 0.0 444.5 659.0 30.8 0.0
282 ISOBUTYLENE 56.108 132.8 266.3 417.9 39.5 239.0
283 ISOBUTYRALDEHYDE 72.107 208.2 337.0 513.0 41.0 274.0
284 ISOBUTYRIC ACID 88.107 227.2 427.9 609.0 40.0 292.0
285 ISOPROPYL ALCOHOL 60.096 184.7 355.4 508.3 47.0 220.0
286 ISOPROPYL AMINE 59.112 177.9 305.6 476.0 50.0 229.0
287 ISOPROPYL CHLORIDE 78.542 156.0 308.9 485.0 46.6 230.0
288 ISOPROPYLBENZENE 120.195 177.1 425.6 631.0 31.7 428.0
289 ISOPROPYLCYCLOHEXANE 126.243 183.4 427.7 640.0 28.0 0.0
290 ISOPROPYLCYCLOPENTANE 112.216 160.5 399.6 601.0 29.0 0.0
291 KETENE 42.038 138.0 232.0 380.0 64.0 145.0
292 KRYPTON 83.800 115.8 119.8 209.4 54.3 91.2
293 MALEIC ANHYDRIDE 98.058 326.0 472.8 0.0 0.0 0.0
294 M-CRESOL 108.140 285.4 475.4 705.8 45.0 310.0
295 M-DICHLOROBENZENE 147.004 248.4 446.0 684.0 38.0 359.0
296 METHANE 16.043 90.7 111.7 190.6 45.4 99.0
297 METHANOL 32.042 175.5 337.8 512.6 79.9 118.0
298 METHYCYCLOPENTANE 84.162 130.7 345.0 532.7 37.4 319.0
299 METHYL ACETATE 74.080 175.0 330.1 506.8 46.3 228.0
300 METHYL ACETYLENE 40.065 170.5 250.0 402.4 55.5 164.0
301 METHYL ACRYLATE 86.091 196.7 353.5 536.0 42.0 265.0
302 METHYL AMINE 31.058 179.7 266.8 430.0 73.6 140.0
303 METHYL BENZOATE 136.151 260.8 472.2 692.0 36.0 396.0
304 METHYL BROMIDE 94.939 179.5 276.7 464.0 85.0 0.0
305 METHYL BUTYRATE 102.134 188.4 275.8 554.4 34.3 340.0
306 METHYL CHLORIDE 50.488 175.4 248.9 416.3 65.9 139.0
307 METHYL ETHYL ETHER 60.096 134.0 280.5 437.8 43.4 221.0
308 METHYL ETHYL KETONE 72.107 186.5 352.8 535.6 41.0 267.0
309 METHYL ETHYL SULFIDE 76.157 167.2 339.8 533.0 42.0 0.0
310 METHYL FLUORIDE 34.033 131.4 194.8 317.8 58.0 124.0
311 METHYL FORMATE 60.052 174.2 304.9 487.2 59.2 172.0
312 METHYL HYDRAZINE 46.072 0.0 364.0 567.0 79.3 271.0
313 METHYL IODIDE 141.939 206.7 315.6 528.0 65.0 190.0
314 METHYL ISOBUTYL KETONE 100.161 189.0 389.6 571.0 32.3 371.0
315 METHYL ISOBUTYRATE 102.134 185.4 365.4 540.8 33.9 339.0
316 METHYL ISOCYANATE 57.052 0.0 312.0 491.0 55.0 0.0
317 METHYL ISOPROPYL KETONE 86.134 181.0 367.4 553.4 38.0 310.0
318 METHYL MERCAPTAN 48.107 150.0 279.1 470.0 71.4 145.0
319 METHYL N-PROPYL KETONE 86.134 196.0 375.5 564.0 38.4 301.0
320 METHYL PHENYL ETHER 108.140 235.7 426.8 641.0 41.2 0.0
321 METHYL PHENYL KETONE 120.151 292.8 474.9 701.0 38.0 376.0
322 METHYL PROPIONATE 88.107 185.7 353.0 530.6 39.5 282.0
323 METHYLAL 76.096 168.0 315.0 497.0 0.0 0.0
324 METHYLCYCLOHEXANE 98.189 146.6 374.1 572.1 34.3 368.0
325 M-ETHYLPHENOL 122.167 269.0 491.6 716.4 0.0 0.0
326 METHYLPHENYLAMINE 107.156 216.0 469.1 701.0 51.3 0.0
327 MONOETHANOLAMINE 61.084 283.5 443.5 614.0 44.0 196.0
328 MORPHOLINE 87.122 268.4 401.4 618.0 54.0 253.0
329 M-TERPHENYL 230.310 360.0 638.0 924.8 34.6 784.0
330 M-TOLUIDINE 107.156 242.8 476.5 709.0 41.0 343.0
331 M-XYLENE 106.168 225.3 412.3 617.0 35.0 376.0
332 N,N-DIMETHYLANILINE 121.183 275.6 466.7 687.0 35.8 0.0
333 NAPHTHALENE 128.174 353.5 491.1 748.4 40.0 410.0
334 N-BUTANE 58.124 134.8 272.7 425.2 37.5 255.0
335 N-BUTANOL 74.123 183.9 390.9 562.9 43.6 274.0
336 N-BUTYL AMINE 73.139 224.1 350.6 524.0 41.0 288.0
337 N-BUTYL-ACETATE 116.161 189.0 389.6 571.0 32.3 371.0
338 N-BUTYLANILINE 149.236 259.0 513.9 721.0 28.0 518.0
339 N-BUTYLBENZENE 134.222 185.2 456.4 660.5 28.5 497.0
340 N-BUTYLCYCLOHEXANE 140.270 198.4 454.1 667.0 31.1 0.0
341 N-BUTYRALDEHYDE 72.107 176.8 348.0 524.0 40.0 278.0
342 N-BUTYRIC ACID 88.107 267.9 436.4 628.0 52.0 292.0
343 N-DECANE 142.286 243.5 447.3 617.6 20.8 603.0
344 N-DECYCLCYCLOPENTANE 210.405 0.0 552.5 723.8 15.0 0.0
345 N-DECYCYCLOHEXANE 224.432 0.0 570.8 750.0 13.4 0.0
346 N-DODECENE 170.340 263.6 489.5 658.3 18.0 713.0
347 N-DODECYCLOPENTANE 238.459 0.0 584.1 750.0 12.8 0.0
348 N-EICOSANE 282.556 310.0 617.0 767.0 11.0 0.0
349 NEON 20.183 24.5 27.0 44.4 27.2 41.7
350 N-HEPTADECANE 240.475 295.0 575.2 733.0 13.0 1000.0
351 N-HEPTANE 100.205 182.6 371.6 540.2 27.0 432.0
352 N-HEPTYLCYCLOPENTANE 168.324 0.0 497.3 679.0 19.2 0.0
353 N-HEXADECANE 226.448 291.0 560.0 717.0 14.0 0.0
354 N-HEXADECYLCYCLOPENTANE 294.567 0.0 637.0 791.0 9.6 0.0
355 N-HEXANE 86.178 177.8 341.9 507.4 29.3 370.0
356 N-HEXYLCYCLOPENTANE 154.297 0.0 476.3 660.1 21.1 0.0
357 NITRIC OXIDE 30.006 109.5 121.4 180.0 64.0 58.0
358 NITROGEN 28.013 63.3 77.4 126.2 33.5 89.5
359 NITROGEN DIOXIDE 46.006 261.9 294.3 431.4 100.0 170.0
360 NITROGEN TRIFLUORIDE 71.002 66.4 144.1 234.0 44.7 0.0
361 NITROMETHANE 61.041 244.6 374.4 588.0 62.3 173.0
362 NITROSYL CHLORIDE 65.459 213.5 2667.7 440.0 90.0 139.0
363 NITROUS OXIDE 44.013 182.3 184.7 309.6 71.5 97.4
364 N-NONADECANE 268.529 305.0 603.1 756.0 11.0 0.0
365 N-NONANE 128.259 219.7 424.0 594.6 22.8 548.0
366 N-NONYCLYCLOPENTANE 196.378 0.0 535.3 710.5 16.3 0.0
367 N-OCTADECANE 254.502 301.3 589.5 745.0 11.9 0.0
368 N-OCTANE 114.232 216.4 398.8 568.8 24.5 492.0
369 N-OCTYLCYCLOPENTANE 182.351 0.0 516.9 694.0 17.7 0.0
370 N-PENTADECANE 212.421 283.0 543.8 707.0 15.0 880.0
371 N-PENTADECYLCYCLOPENTANE 280.540 0.0 625.0 780.0 10.1 0.0
372 N-PENTANE 72.151 143.4 309.2 469.6 33.3 304.0
373 N-PROPYL ACETATE 102.134 178.0 374.8 549.4 32.9 345.0
374 N-PROPYL AMINE 59.112 190.0 321.8 497.0 46.8 233.0
375 N-PROPYL FORMATE 88.107 180.3 353.7 538.0 40.1 285.0
376 N-PROPYL PROPIONATE 116.161 197.3 395.7 578.0 0.0 0.0
377 N-PROPYLBENZENE 120.195 173.7 432.4 638.3 31.6 440.0
378 N-PROPYLCYCLOHEXANE 126.243 178.7 429.9 639.0 27.7 0.0
379 N-PROPYLCYCLOPENTANE 112.216 155.8 404.1 603.0 29.6 425.0
380 N-TETRADECANE 198.394 279.0 526.7 694.0 16.0 830.0
381 N-TETRADECYCLOPENT 266.513 0.0 599.0 772.0 11.1 0.0
382 N-TRIDECANE 184.367 267.8 508.6 675.8 17.0 780.0
383 N-TRIDECYLCYCLOPENTANE 252.486 0.0 598.6 761.0 11.9 0.0
384 N-UNDECENE 156.313 247.6 469.1 638.8 19.4 660.0
385 N-VALERIC ACID 102.134 239.0 458.7 651.0 38.0 340.0
386 O-CRESOL 108.140 304.1 464.2 697.6 49.4 282.0
387 O-DICHLOROBENZENE 147.004 256.1 453.6 697.3 40.5 360.0
388 O-ETHYLPHENOL 122.167 269.8 477.7 703.0 0.0 0.0
389 O-TERPHENYL 230.310 330.0 605.0 891.0 38.5 769.0
390 O-TOLUIDINE 107.156 258.4 473.3 694.0 37.0 343.0
391 OXYGEN 31.999 54.4 90.2 154.6 49.8 73.4
392 O-XYLENE 106.168 248.0 417.6 630.2 36.8 369.0
393 OZONE 47.998 80.5 161.3 261.0 55.0 88.9
394 P-CRESOL 108.140 307.9 475.1 704.6 50.8 0.0
395 P-DICLOROBENZENE 147.004 326.3 447.3 685.0 39.0 372.0
396 PERFLUOROBENZENE 186.056 0.0 353.4 516.7 32.6 0.0
397 PERFLUOROCYCLOHEXANE 300.047 0.0 325.7 457.2 24.0 0.0
398 PERFLUOROETHANE 100.016 130.7 197.5 306.4 38.9 175.0
399 PERFLUOROETHANE 138.012 172.4 194.9 292.8 0.0 224.0
400 PERFLUOROMETHYLCYCLOHEXANE 350.055 0.0 349.5 486.8 23.0 0.0
401 PERFLUORO-N-HEPTANE 388.051 195.0 355.7 474.8 16.0 664.0
402 PERFLUORO-N-HEXANE 338.044 186.0 330.3 451.7 18.8 442.0
403 P-ETHYLPHENOL 122.167 318.0 491.0 716.4 0.0 0.0
404 PHENANTHRENE 178.234 373.7 612.6 878.0 0.0 0.0
405 PHENETOLE 122.167 243.0 443.0 647.0 33.8 0.0
406 PHENOL 94.113 314.0 455.0 694.2 60.5 229.0
407 PHOSGENE 98.916 145.0 280.8 455.0 56.0 190.0
408 PHOSPHORUS TRICHLORIDE 137.333 161.0 349.0 563.0 0.0 260.0
409 PHTHALIC ANHYDRIDE 148.118 404.0 560.0 810.0 47.0 368.0
410 PIPERIDINE 85.150 262.7 379.7 594.0 47.0 289.0
411 PROPADIENE 40.065 136.9 238.7 393.0 54.0 162.0
412 PROPANE 44.097 85.5 231.1 369.8 41.9 203.0
413 PROPIONALDEHYDE 58.080 193.0 321.0 496.0 47.0 223.0
414 PROPIONIC ACID 74.080 252.5 414.0 612.0 53.0 230.0
415 PROPIONITRILE 55.080 180.3 370.5 564.4 41.3 230.0
416 PROPYL CHLORIDE 78.542 150.4 319.6 503.0 45.2 254.0
417 PROPYLENE 42.081 87.9 225.4 365.0 45.6 181.0
418 PROPYLENE OXIDE 58.080 161.0 307.5 482.2 48.6 186.0
419 P-TERPHENYL 230.310 485.0 649.0 926.0 32.8 779.0
420 P-TOLUIDINE 107.156 316.9 473.8 667.0 0.0 0.0
421 P-XYLENE 106.168 286.4 411.5 616.2 34.7 379.0
422 PYRIDINE 79.102 231.5 388.5 620.0 55.6 254.0
423 PYRROLE 67.091 0.0 403.0 640.0 0.0 0.0
424 PYRROLIDINE 71.123 0.0 359.7 568.6 55.4 249.0
425 SEC-BUTYLBENZENE 134.222 197.7 446.5 664.0 29.1 0.0
426 SEC-BUTYLCYCLOHEXANE 140.270 0.0 452.5 669.0 26.4 0.0
427 SILICON TETRACHLORIDE 169.898 204.3 330.4 507.0 37.0 326.0
428 SILICON TETRAFLUORIDE 104.080 183.0 187.0 259.0 36.7 0.0
429 STYRENE 104.152 242.5 418.3 647.0 39.4 0.0
430 SUCCINIC ACID 118.090 456.0 508.0 0.0 0.0 0.0
431 SULFUR DIOXIDE 64.063 197.7 263.0 430.8 77.8 122.0
432 SULFUR HEXAFLUORIDE 146.050 222.5 209.3 318.7 37.1 198.0
433 SULFUR TRIOXIDE 80.058 290.0 318.0 491.0 81.0 130.0
434 TERT-BUTANOL 74.123 298.8 355.6 506.2 39.2 275.0
435 TERT-BUTYL CHLORIDE 92.569 247.8 324.0 507.0 39.0 295.0
436 TERT-BUTYLBENZENE 134.222 215.3 442.3 660.0 29.3 0.0
437 TERT-BUTYLCYCLOHEXANE 140.270 232.0 444.7 659.0 26.3 0.0
438 TETRACHLOROETHYLENE 165.834 251.0 394.3 620.0 44.0 290.0
439 TETRAHYDROFURAN 72.107 164.7 339.1 540.2 51.2 224.0
440 THIOPHENE 84.136 234.9 357.3 579.4 56.2 219.0
441 TOLUENE 92.141 178.0 383.8 591.7 40.6 316.0
442 TRANS-1,2-DIMETHYLCYCLOHEXANE 112.216 185.0 396.6 596.0 29.3 0.0
443 TRANS-1,2-DIMETHYLCYCLOPENTANE 98.189 155.6 365.0 553.2 34.0 362.0
444 TRANS-1,3-DIMETHYLCYCLOHEXANE 112.216 183.0 397.6 598.0 29.3 0.0
445 TRANS-1,4-DIMETHYLCYCLOHEXANE 112.216 236.2 392.5 590.0 29.3 0.0
446 TRANS-2-BUTENE 56.108 167.6 274.0 428.6 40.5 238.0
447 TRANS-2-HEXENE 84.162 140.0 341.0 516.0 32.3 351.0
448 TRANS-2-OCTENE 112.216 185.4 398.1 580.0 27.3 0.0
449 TRANS-2-PENTENE 70.135 132.9 309.5 475.0 36.1 300.0
450 TRANS-3-HEXENE 84.162 159.7 340.3 519.9 32.1 350.0
451 TRANS-DECALIN 138.254 242.8 460.4 690.0 31.0 0.0
452 TRIBUTYLAMINE 185.355 0.0 486.6 643.0 18.0 0.0
453 TRICHLOROETHYLENE 131.389 186.8 360.4 571.0 48.5 256.0
454 TRICHLOROFLUOROMETHANE 37.368 162.0 297.0 471.2 43.5 248.0
455 TRIETHYLAMINE 101.193 158.4 362.7 535.0 30.0 390.0
456 TRIFLUOROACETIC ACID 114.024 257.9 345.6 491.3 32.2 0.0
457 TRIFLUOROBROMOMETHANE 148.910 0.0 214.0 340.2 39.2 200.0
458 TRIMETHYL AMINE 59.112 156.0 276.1 433.2 40.2 254.0
459 VALERALDEHYDE 86.134 182.0 376.0 554.0 35.0 333.0
460 VINYL ACETATE 86.091 173.0 346.0 525.0 43.0 265.0
461 VINYL CHLORIDE 62.499 119.4 259.8 429.7 55.3 169.0
462 VINYL ETHYL ETHER 72.107 157.9 308.8 475.0 40.2 260.0
463 VINYL FLUORIDE 46.044 130.0 235.5 327.8 51.7 144.0
464 VINYL FORMATE 72.064 215.5 319.6 475.0 57.0 210.0
465 VINYL METHYL ETHER 58.080 151.5 278.0 436.0 47.0 205.0
466 VINYLACETYLENE 52.076 227.6 278.1 455.0 49.0 202.0
467 WATER 18.015 273.2 373.2 647.3 217.6 56.0
468 XENON 131.300 161.3 165.0 289.7 57.6 118.0

Component-1 Component-2 Binary Mixtur A12 A21

1-Propanol Water 1-Propanol + 906.5256 1396.6398
Acetone Chloroform Acetone + Chl 116.1171 -506.8519
Acetone Methanol Acetone + Me -114.4047 545.2942
Acetone Water Acetone + Wat 344.3346 1482.2133
Acetone Toluene Acetone + Tol 809.1 -345.07
Acetone IsopropylalcohAcetone + Iso 548.028 113.562
Acetone n-Hexane Acetone + n-H 956.23 374.78
Acetonitrile Water Acetonitrile + 328.86 1689.3
Benzene Toluene Benzene + Tol 794.407 -550.89
CCL4 Benzene CCL4 + Benze 7.0459 59.6233
Chloroform Methanol Chloroform + -361.7944 1694.0241
Dichloromethane Methanol Dichlorometh -243.987 1902.66
Dichloromethane Ethylacetate Dichlorometha -174.549 -212.107
Ethanol Benzene Ethanol + Ben 1264.4318 266.6118
Ethanol Water Ethanol + Wat 325.0757 953.2792
Ethylacetate Ethanol Ethylacetate + 58.8869 570.0349
Ethylacetate Water Ethylacetate 1147.4 2084
Ethylacetate Aceticacid Ethylacetate + -997.893 2738.13
Methanol Benzene Methanol + B 1666.441 227.2126
Methanol Ethylacetate Methanol + Et 982.2689 -172.9317
Methanol Water Methanol + W 82.9876 520.6458
Methanol IsopropylalcohMethanol + Is -38.4124 176.318
Methanol Acetonitrile Methanol + Ace 667.303 42.5767
Methanol Toluene Methanol + To 1753.94 307.37
Methylacetate Methanol Methylacetate -93.89 847.4348
Methylacetate Ethylacetate Methylacetate 37.5877 -40.9238
Methylacetate Acetic acid Methylacetate -208.93 269.707
Methylacetate Water Methylacetate 887.37 1966.7
N-Hexane Ethanol N-Hexane + Et 320.3611 2189.2896
THF Water THF + Water 1475.2583 1844.7926
Water Aceticacid Water + Acetic 813.1 -180.84
Water N-Butanol Water + N-But 1549.66 2050.2569
Water Formic Acid Water + Formi -310.106 1180.804
Water Toluene Water + Tolue 13433 3708.3
Water Morpholine Water + Morp 1713.5 -1341.7
Water Pyridine Water + Pyrid 951.702 1143.85
Water MIBK Water + MIBK 2561.13 1874.96
 CRITICAL ACENTRIC LIQ DEN REF T FOR DIPOLE VAPOR HEAT CAPACITY LIQUID VISCOSITY
COMPRESS FACTOR @TDEN LIQDEN MOMENT CP=A+(B*T)+(C*T^2)+(D*T^3) LOG(V)=B*(1/T-1/C)
G/CC K DEBYES CAL/G-MOLE-K T AS K AND V AS CP
(ZC) (OMEGA) (LIQDEN) (TDEN) (DIPM) (A) (B) (C) (D) B C
8 9 10 11 12 13 14 15 16 17 18

0.289 0.257 0.000 0.0 2.3 1.3720 7.502E-02 -6.203E-05 2.010E-08 0.00 0.00
0.000 0.000 1.645 298.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.240 0.220 1.441 293.0 1.7 1.5100 8.194E-02 -7.064E-05 2.339E-08 346.72 304.43
0.000 0.252 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.211 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.279 0.000 1.455 298.0 0.0 9.6620 7.830E-02 6.572E-05 1.868E-08 0.00 0.00
0.280 0.248 1.168 298.0 2.0 2.9790 6.439E-02 -4.896E-05 1.505E-08 412.27 239.10
0.253 0.266 0.000 0.0 2.3 2.0720 5.722E-02 -3.480E-05 8.107E-09 319.27 186.56
0.273 0.000 0.000 0.0 1.4 0.7340 5.839E-02 -5.014E-05 1.677E-08 0.00 0.00
0.250 0.238 0.785 289.0 0.0 -17.1220 2.149E-01 -1.199E-04 2.461E-08 0.00 0.00
0.270 0.273 0.759 289.0 0.0 -13.8270 1.832E-01 -1.075E-04 2.413E-08 0.00 0.00
0.256 0.252 1.580 289.0 0.0 14.6030 6.865E-02 -5.780E-05 1.649E-08 0.00 0.00
0.000 0.303 0.973 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.250 0.310 1.389 293.0 0.0 6.4210 8.651E-02 -6.656E-05 2.099E-08 818.63 342.88
0.270 0.390 0.894 293.0 0.6 -1.6580 1.513E-01 -7.945E-05 1.579E-08 0.00 0.00
0.250 0.426 0.838 354.0 0.0 3.9460 1.557E-01 -6.876E-05 7.779E-09 0.00 0.00
0.258 0.390 0.880 289.0 0.3 -1.1150 1.490E-01 -7.793E-05 1.523E-08 872.74 297.75
0.267 0.255 0.652 293.0 0.4 2.6750 6.505E-02 -3.507E-05 7.378E-09 0.00 0.00
0.275 0.255 1.480 277.0 0.5 9.2620 8.216E-02 7.047E-05 2.032E-08 0.00 0.00
0.250 0.286 1.250 289.0 1.8 4.8930 5.518E-02 -3.435E-05 8.094E-09 473.95 277.98
0.210 0.240 1.150 293.0 1.9 2.4960 8.729E-02 -6.219E-05 1.849E-08 514.36 281.03
0.235 0.371 0.867 293.0 0.0 7.6990 8.520E-02 -3.190E-05 6.000E-12 0.00 0.00
0.269 0.173 0.693 293.0 0.0 2.1080 9.267E-02 -5.446E-05 1.253E-08 0.00 0.00
0.280 0.000 1.036 293.0 3.6 0.1510 1.006E-01 -7.121E-05 2.138E-08 1404.20 426.74
0.260 0.398 0.865 293.0 0.1 -4.6790 1.606E-01 -8.819E-05 1.839E-08 437.52 268.27
0.270 0.195 0.621 293.0 0.0 -0.4030 8.165E-02 -5.589E-05 1.513E-08 300.59 163.12
0.260 0.000 1.053 293.0 3.7 1.9750 8.779E-02 -5.163E-05 1.207E-08 1813.00 406.96
0.254 0.288 1.033 293.0 0.4 -12.7960 1.430E-01 -9.757E-05 2.537E-08 660.36 308.77
0.250 0.403 0.862 293.0 0.1 -8.9370 2.071E-01 -1.328E-04 3.370E-08 0.00 0.00
0.263 0.104 0.661 293.0 0.4 1.6710 9.438E-02 -5.670E-05 1.337E-08 0.00 0.00
0.260 0.160 0.692 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.277 0.187 0.595 293.0 0.3 -0.7150 8.436E-02 -4.754E-05 1.066E-08 256.30 151.86
0.270 0.050 0.650 289.0 0.8 2.9970 6.553E-02 -3.690E-05 8.240E-09 0.00 0.00
0.279 0.000 1.100 303.0 2.1 4.0170 6.584E-02 -4.758E-05 1.267E-08 0.00 0.00
0.255 0.218 0.886 293.0 2.0 -0.6240 1.074E-01 -7.014E-05 1.930E-08 783.72 260.03
0.230 0.000 0.830 293.0 1.8 3.4800 2.137E-01 -9.365E-05 8.242E-09 1481.80 380.00
0.280 0.491 0.741 293.0 0.0 -1.1140 2.168E-01 -1.208E-04 2.616E-08 518.37 277.80
0.000 0.558 0.758 293.0 0.0 -1.5630 2.622E-01 -1.470E-04 3.203E-08 615.67 310.07
0.000 0.000 0.000 0.0 0.0 -3.0050 4.657E-01 -2.671E-04 6.009E-08 0.00 0.00
0.250 0.560 0.822 293.0 1.7 1.1720 1.619E-01 -8.232E-05 1.444E-08 1287.00 361.83
0.280 0.358 0.697 293.0 0.3 -0.7890 1.504E-01 -8.388E-05 1.817E-08 368.69 214.32
0.000 0.721 0.788 283.0 0.0 -2.3180 3.523E+00 -1.000E+00 -1.982E+00 -4.00 4.32
0.300 0.560 0.819 293.0 1.8 1.1490 1.407E-01 -7.189E-05 1.296E-08 1179.40 354.94
0.260 0.285 0.673 293.0 0.4 0.4170 1.268E-01 -6.933E-05 1.446E-08 357.43 197.74
0.000 0.250 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.260 0.294 0.881 293.0 0.0 -3.9280 1.671E-01 -9.841E-05 2.228E-08 0.00 0.00
0.000 0.277 0.876 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.279 0.861 293.0 0.0 -11.6460 2.165E-01 -1.446E-04 3.887E-08 0.00 0.00
0.260 0.360 0.865 293.0 0.0 -6.9260 1.742E-01 -1.042E-04 2.388E+00 8.00 0.00
0.260 0.322 0.861 293.0 0.0 -6.5230 1.714E-01 -1.009E-04 2.279E-08 463.17 266.08
0.000 0.371 0.857 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.250 0.334 1.020 293.0 0.5 -15.4820 2.242E-01 -1.658E-04 4.814E-08 862.89 361.76
0.280 0.430 0.745 273.0 0.0 0.8880 1.940E-01 -1.077E-04 2.318E-08 471.00 258.92
0.000 0.000 0.812 332.0 1.7 -2.0790 4.174E-01 -2.360E-04 5.153E-08 0.00 0.00
0.000 0.807 0.789 293.0 0.0 -2.7060 3.975E-01 -2.239E-04 4.893E-08 816.19 376.93
0.310 0.530 0.826 293.0 2.0 1.4740 1.817E-01 -9.069E-05 1.496E-08 1312.10 369.97
0.260 0.386 0.715 293.0 0.3 -0.9790 1.729E-01 -9.641E-05 2.072E-08 418.82 237.63
0.000 0.682 0.791 273.0 0.0 -2.1980 3.302E+00 -1.000E+00 -1.859E+00 -4.00 4.07
0.260 0.580 0.815 293.0 1.7 0.9240 1.205E-01 -6.304E-05 1.223E-08 1151.10 349.62
0.310 0.245 0.640 293.0 0.4 -0.0320 1.034E-01 -5.534E-05 1.118E-08 305.25 174.70
0.275 0.164 0.690 293.0 0.9 4.3150 8.386E-02 -4.570E-05 9.787E-09 0.00 0.00
0.253 0.624 0.804 293.0 1.7 0.5900 7.942E-02 -4.431E-05 1.026E-08 951.04 327.83
0.000 0.644 0.786 273.0 0.0 -1.9030 3.071E+00 -1.000E+00 -1.722E+00 -4.00 3.75
0.266 0.175 0.676 293.0 0.7 7.3300 6.714E-02 -1.603E-05 -5.617E-09 0.00 0.00
0.000 0.598 0.766 293.0 0.0 -1.7000 2.845E+00 -1.000E+00 -1.594E+00 -4.00 3.47
0.000 0.518 0.751 293.0 0.0 -1.3340 2.395E-01 -1.338E-04 2.905E-08 566.26 294.89
0.272 0.231 0.649 293.0 0.0 -3.9730 1.503E-01 -8.314E-05 1.636E-08 438.44 226.67
0.254 0.297 0.716 293.0 0.0 2.2010 1.877E-01 -1.051E-04 2.316E-08 474.57 257.61
0.000 0.360 0.000 0.0 0.0 -14.0520 2.941E-01 -2.110E-04 6.174E-08 0.00 0.00
0.000 0.279 0.000 0.0 0.0 -13.0370 2.601E-01 -1.808E-04 5.116E-08 0.00 0.00
0.000 0.311 0.000 0.0 0.0 -13.0370 2.601E-01 -1.808E-04 5.166E-08 0.00 0.00
0.267 0.251 0.690 293.0 0.0 -5.4800 1.796E-01 -1.056E-04 2.400E-08 0.00 0.00
0.000 0.332 0.000 0.0 0.0 -10.8990 2.521E-01 -1.713E-04 4.745E-08 0.00 0.00
0.266 0.303 0.692 293.0 0.0 -1.7820 1.858E-01 -1.024E-04 2.191E-08 467.04 246.43
0.000 0.315 0.719 293.0 0.0 -16.0990 2.790E-01 -2.057E-04 6.147E-08 0.00 0.00
0.000 0.321 0.720 289.0 0.0 -14.4050 2.638E-01 -1.842E-04 5.225E-08 0.00 0.00
0.000 0.374 0.000 0.0 0.0 -14.8900 2.973E-01 -2.139E-04 6.253E-08 0.00 0.00
0.260 0.357 0.717 289.0 0.0 -12.9230 2.615E-01 -1.850E-04 5.385E-08 0.00 0.00
0.269 0.197 0.591 293.0 0.0 -3.9630 1.326E-01 -7.897E-05 1.823E-08 355.54 196.35
0.280 0.000 0.783 327.0 0.0 2.9030 1.289E-01 -7.547E-05 1.701E-08 0.00 0.00
0.264 0.338 0.695 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.267 0.289 0.674 293.0 0.0 -11.9660 2.139E-01 -1.519E-04 4.146E-08 417.37 226.19
0.270 0.247 0.662 293.0 0.0 -3.4890 1.469E-01 -8.063E-05 1.629E-08 444.19 228.86
0.269 0.290 0.726 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.000 0.299 0.000 0.0 0.0 -13.1170 2.606E-01 -1.816E-04 5.154E-08 0.00 0.00
0.260 0.192 0.705 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.267 0.317 0.719 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.270 0.221 0.678 293.0 0.0 1.6780 1.334E-01 -8.828E-05 2.539E-08 0.00 0.00
0.270 0.239 0.708 293.0 0.0 0.5480 1.153E-01 -5.252E-05 7.265E-09 0.00 0.00
0.262 0.346 0.712 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.256 0.299 0.695 293.0 0.0 -1.6830 1.633E-01 -8.919E-05 1.871E-08 0.00 0.00
0.000 0.000 0.942 298.0 2.2 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.262 0.343 0.700 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.265 0.306 0.673 293.0 0.0 -1.6830 1.633E-01 -8.919E-05 1.871E-08 0.00 0.00
0.000 0.000 0.000 0.0 2.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.262 0.352 0.693 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.000 0.000 0.938 273.0 2.2 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.000 0.0 1.5 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.252 0.576 0.807 293.0 1.7 1.3740 1.014E-01 -5.561E-05 1.140E-08 1441.70 331.50
0.277 0.124 0.691 293.0 0.8 3.8040 5.688E-02 -2.555E-05 4.188E-09 0.00 0.00
0.280 0.300 0.873 293.0 2.1 -0.8200 1.089E-01 -7.119E-05 1.972E-08 480.77 237.30
0.267 0.000 0.833 293.0 1.8 -3.5810 2.067E-01 -1.261E-04 3.068E-08 1798.00 351.17
0.271 0.227 0.620 293.0 0.1 -2.2750 1.210E-01 -6.519E-05 1.367E-08 367.32 191.58
0.267 0.279 0.653 293.0 0.0 -2.5240 1.477E-01 -8.533E-05 1.931E-08 384.13 208.27
0.264 0.164 0.681 293.0 0.3 -0.8150 1.095E-01 -7.971E-05 2.389E-08 328.49 182.48
0.260 0.700 0.819 293.0 0.0 -2.2665 1.356E-01 -8.315E-05 2.063E-08 1259.40 349.85
0.262 0.232 0.650 293.0 0.5 2.5250 9.547E-02 -4.648E-05 7.915E-09 369.27 193.39
0.280 0.285 0.662 293.0 0.0 2.8190 8.381E-02 -2.667E-05 -1.387E-09 322.47 180.43
0.270 0.229 0.691 289.0 0.0 -3.5230 1.354E-01 -7.979E-05 1.902E-08 0.00 0.00
0.254 0.330 0.719 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.260 0.378 0.702 289.0 0.0 -21.4350 2.967E-01 -2.808E-04 1.103E-07 643.61 259.51
0.261 0.330 0.679 293.0 0.0 -9.4080 2.064E-01 -1.502E-04 4.386E-08 417.46 225.13
0.260 0.382 0.990 313.0 0.4 -13.4990 2.149E-01 -1.545E-04 4.395E-08 695.42 351.79
0.260 0.520 0.821 293.0 1.6 6.1810 1.825E-01 -1.009E-04 2.165E-08 0.00 0.00
0.000 0.388 0.000 0.0 0.0 -16.8080 2.943E-01 -2.065E-04 5.864E-08 0.00 0.00
0.000 0.338 0.752 293.0 0.0 -16.0670 2.690E-01 -1.908E-04 5.508E-08 0.00 0.00
0.270 0.121 0.653 293.0 0.0 -2.9990 1.310E-01 -6.963E-05 1.244E-08 0.00 0.00
0.252 0.321 0.710 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 446.20 244.67
0.274 0.270 0.693 293.0 0.0 -1.6830 1.633E-01 -8.919E-05 1.871E-08 0.00 0.00
0.265 0.338 0.719 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.000 0.000 0.954 298.0 1.9 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.000 0.0 1.7 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.939 298.0 2.6 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.000 0.0 1.8 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.252 0.361 0.718 289.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 437.60 238.33
0.267 0.310 0.698 0.3 0.0 -1.6830 1.633E-01 -8.919E-05 1.871E-08 0.00 0.00
0.273 0.275 0.664 293.0 0.0 -0.5700 1.359E-01 -6.854E-05 1.202E-08 372.11 207.55
0.266 0.160 0.686 293.0 0.0 3.5080 8.593E-02 -4.719E-05 1.018E-08 0.00 0.00
0.260 0.580 0.810 293.0 1.8 -2.2790 1.357E-01 -8.323E-05 2.066E-08 1148.80 349.51
0.282 0.209 0.627 293.0 0.0 5.1930 9.290E-02 -4.794E-05 9.579E-09 0.00 0.00
0.280 0.500 0.809 293.0 1.9 -2.8870 1.456E-01 -1.004E-04 2.934E-08 1502.00 336.75
0.267 0.304 0.727 293.0 0.0 -2.2010 1.877E-01 -1.501E-04 2.316E-08 0.00 0.00
0.270 0.269 0.694 293.0 0.0 -3.5230 1.354E-01 -7.979E-05 1.902E-08 0.00 0.00
0.252 0.369 0.706 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.256 0.324 0.687 293.0 0.0 -1.6830 1.633E-01 -8.919E-05 1.871E-08 0.00 0.00
0.270 0.207 0.698 293.0 0.0 -3.5230 1.354E-01 -7.979E-05 1.902E-08 0.00 0.00
0.260 0.270 0.955 293.0 0.0 -4.1630 1.166E-01 -6.683E-05 1.302E-08 500.97 285.50
0.270 0.290 0.669 293.0 0.0 -0.4000 1.284E-01 -7.271E-05 1.613E-08 0.00 0.00
0.259 0.369 0.705 293.0 0.0 -2.2010 1.877E-01 -1.051E-04 2.316E-08 0.00 0.00
0.270 0.290 0.669 293.0 0.0 3.0160 1.231E-01 -7.182E-05 1.750E-08 0.00 0.00
0.220 0.303 0.778 293.0 2.5 1.8430 4.353E-02 -2.404E-05 5.685E-09 368.70 192.82
0.200 0.454 1.049 293.0 1.3 1.1560 6.087E-02 -4.187E-05 1.182E-08 600.94 306.21
0.287 0.000 1.087 293.0 3.0 -5.5240 1.215E-01 -8.551E-05 2.349E-08 502.33 286.04
0.232 0.309 0.790 293.0 2.9 1.5050 6.224E-02 -2.992E-05 4.867E-09 367.25 209.68
0.184 0.321 0.782 293.0 3.5 4.8920 2.857E-02 -1.073E-05 7.650E-10 334.91 210.05
0.280 0.344 1.104 293.0 2.4 5.9760 4.086E-02 -2.354E-05 5.300E-09 0.00 0.00
0.271 0.184 0.615 189.0 0.0 6.4060 1.810E-02 -1.196E-05 3.373E-09 0.00 0.00
0.000 0.330 0.839 293.0 2.9 2.8590 5.029E-02 -2.557E-05 4.552E-09 388.17 217.14
0.230 0.560 1.051 293.0 0.0 0.4160 7.621E-02 -5.618E-05 1.666E-08 733.02 307.15
0.210 0.350 0.806 293.0 3.5 2.5540 5.273E-02 -3.739E-05 1.099E-08 343.31 210.42
0.256 0.630 0.855 288.0 0.0 -0.2640 7.515E-02 -4.853E-05 1.271E-08 793.52 307.26
0.260 0.130 0.937 293.0 2.0 0.6040 7.277E-02 -5.442E-05 1.742E-08 368.27 210.61
0.220 0.390 0.835 293.0 3.4 5.1830 6.142E-02 -2.847E-05 2.936E-09 521.30 252.03
0.250 0.000 0.911 293.0 0.0 -5.8110 1.656E-01 -1.082E-04 2.802E-08 354.34 270.80
0.242 0.250 0.639 273.2 1.5 6.5240 5.692E-03 4.078E-06 -2.830E-09 349.04 169.63
0.247 0.382 1.022 293.0 1.6 9.6770 1.525E-01 -1.226E-04 3.901E-08 1074.60 337.21
0.000 0.000 0.000 0.0 0.0 -14.0870 2.402E+00 -1.000E+00 -1.575E+00 -4.00 3.84
0.291 -0.004 1.373 90.0 0.0 4.9690 -7.670E-06 1.234E-08 0.000E+00 107.57 58.76
0.000 0.320 1.045 293.0 2.8 -2.9000 1.185E-01 -6.794E-05 1.234E-08 686.84 314.66
0.271 0.212 0.885 289.0 0.0 8.1010 1.133E-01 -7.206E-05 1.703E-08 545.64 265.34
0.250 0.620 1.075 403.0 1.7 -12.2510 1.503E-01 -1.012E-04 2.537E-08 2617.60 407.88
0.000 0.360 1.010 288.0 3.5 -6.2210 1.369E-01 -1.058E-04 3.222E-08 0.00 0.00
0.280 0.710 1.041 298.0 1.7 -1.7670 1.309E-01 -8.019E-05 1.856E-08 1088.00 367.21
0.000 0.150 1.350 284.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.420 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.270 0.132 3.119 293.0 0.2 8.0870 2.688E-03 -2.846E-06 1.083E-09 387.82 292.79
0.263 0.249 1.495 293.0 1.5 -6.8800 1.278E-01 -9.746E-05 2.894E-08 508.18 302.42
0.250 0.580 1.006 293.0 0.0 -4.1480 2.072E-01 -1.101E-04 1.728E-08 882.36 350.34
0.260 0.500 0.768 293.0 1.2 1.4460 1.846E-01 -9.758E-05 1.931E-08 473.50 266.56
0.223 0.371 0.792 293.0 3.8 3.6330 7.657E-02 -3.912E-05 7.123E-09 438.04 256.84
0.000 0.277 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.246 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.820 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.274 0.225 0.777 293.0 0.0 4.7280 1.754E-02 -1.338E-05 4.097E-09 578.08 185.24
0.293 0.115 1.293 273.0 0.0 6.5550 1.941E-02 -1.831E-05 6.384E-09 274.08 200.22
0.295 0.049 0.803 81.0 0.1 7.3730 -3.070E-03 6.662E-06 -3.037E-09 94.06 48.90
0.272 0.194 1.584 298.0 0.0 9.7250 4.893E-02 -5.421E-05 2.112E-08 2540.15 290.84
0.277 0.191 0.000 0.0 0.0 3.3390 4.838E-02 -3.882E-05 1.078E-08 0.00 0.00
0.260 0.099 1.274 173.7 0.7 5.6290 1.907E-02 -1.676E-05 5.860E-09 0.00 0.00
0.275 0.073 1.563 239.1 0.2 6.4320 8.082E-03 -9.241E-06 3.695E-09 191.96 172.55
0.265 0.249 1.106 293.0 1.6 -8.0940 1.345E-01 -1.080E-04 3.407E-08 477.76 276.22
0.267 0.215 1.230 289.0 0.0 4.1320 3.865E-02 -2.794E-05 7.305E-09 0.00 0.00
0.293 0.216 1.489 293.0 1.1 5.7330 4.522E-02 -4.397E-05 1.590E-09 394.81 246.50
0.271 0.253 0.000 0.0 0.3 6.6480 8.340E-02 -6.904E-05 1.944E-08 0.00 0.00
0.282 0.180 0.000 0.0 0.5 5.4490 4.565E-02 -3.765E-05 1.065E-08 0.00 0.00
0.000 0.236 0.796 293.0 0.0 -17.2220 2.149E-01 -1.199E-04 2.461E-08 0.00 0.00
0.270 0.269 0.777 289.0 0.0 -13.2900 1.819E-01 -1.071E-04 2.422E-08 0.00 0.00
0.000 0.224 0.766 293.0 0.0 -15.5640 2.111E-01 -1.178E-04 2.436E-08 0.00 0.00
0.000 0.234 0.783 293.0 0.0 -15.3230 2.108E-01 -1.198E-04 2.552E-08 0.00 0.00
0.272 0.202 0.621 293.0 0.3 0.1050 7.054E-02 -2.431E-05 -1.470E-10 268.94 155.34
0.270 0.256 0.687 293.0 0.0 2.3430 1.268E-01 -6.490E-05 1.153E-08 344.33 197.95
0.280 0.240 0.656 293.0 0.0 -3.4140 1.099E-01 -6.068E-05 1.303E-08 305.31 175.72
0.270 0.225 0.680 293.0 0.3 5.1900 1.388E-01 -8.028E-05 1.781E-08 344.33 197.95
0.000 0.230 0.897 293.0 0.0 -26.8600 2.671E-01 -1.578E-04 3.432E-08 0.00 0.00
0.000 0.240 0.000 0.0 0.2 8.5830 2.210E-02 -1.946E-05 7.045E-09 0.00 0.00
0.274 0.209 0.694 293.0 0.0 -12.0030 1.200E-01 -8.498E-05 2.501E-08 0.00 0.00
0.300 0.336 0.810 293.0 0.0 -18.1970 1.879E-01 -1.004E-04 1.806E-08 0.00 0.00
0.273 0.213 0.779 293.0 0.3 -13.0270 1.460E-01 -6.027E-05 3.156E-09 653.62 290.84
0.240 0.550 0.942 303.0 1.7 -13.2640 1.723E-01 -9.760E-05 1.967E-08 0.00 0.00
0.230 0.443 0.951 288.0 3.1 -9.0300 1.323E-01 -4.665E-05 -3.664E-09 787.38 336.47
0.270 0.210 0.816 289.0 0.6 -16.3970 1.732E-01 -1.293E-04 3.927E-08 506.92 264.54
0.276 0.192 0.745 293.0 0.0 -12.8080 1.296E-01 -7.239E-05 1.549E-08 406.69 231.67
0.280 0.350 0.950 293.0 3.0 -9.7070 1.248E-01 -7.462E-05 1.703E-08 574.71 303.44
0.000 0.000 0.772 293.0 0.9 -9.9150 1.106E-01 -6.160E-05 1.298E-08 396.83 218.66
0.282 0.264 0.563 288.0 0.0 -8.4170 9.108E-02 -6.882E-05 2.158E-08 0.00 0.00
0.314 -0.130 0.165 22.7 0.0 7.2250 -1.580E-03 2.794E-06 -8.800E-10 19.67 8.38
0.225 0.000 1.105 293.0 1.9 0.0000 0.000E+00 0.000E+00 0.000E+00 757.92 304.58
0.000 0.000 2.500 293.0 1.9 0.0000 0.000E+00 0.000E+00 0.000E+00 428.91 294.57
0.260 0.590 0.767 293.0 1.1 2.3320 1.930E-01 -1.049E-04 2.209E-08 581.42 286.54
0.000 0.000 1.047 293.0 0.0 0.4490 2.995E+00 -1.000E+00 -1.462E+00 -4.00 1.67
0.280 0.176 1.750 158.0 0.5 7.5470 4.257E-02 -3.603E-05 1.037E-08 215.09 2165.55
0.277 0.193 1.317 298.0 1.8 3.0940 3.877E-02 -3.110E-05 1.005E-09 359.55 225.13
0.272 0.202 1.380 282.0 1.3 5.6520 3.770E-02 -2.866E-05 7.795E-09 0.00 0.00
0.272 0.288 0.656 293.0 0.0 -0.0410 6.438E-02 -3.175E-05 5.587E-09 0.00 0.00
0.270 0.299 0.707 293.0 1.1 0.4870 1.058E-01 -5.214E-05 8.725E-09 473.89 229.29
0.000 0.000 0.998 293.0 2.0 6.4240 1.099E-01 -6.472E-05 1.426E-08 0.00 0.00
0.269 0.347 0.814 293.0 2.7 7.1680 9.409E-02 -4.554E-05 8.115E-09 409.17 236.65
0.272 0.300 0.837 293.0 1.6 3.2470 9.457E-02 -4.251E-05 6.327E-09 407.59 233.32
0.260 0.000 1.116 293.0 0.0 17.4500 8.266E-02 -3.506E-05 4.410E-09 1943.00 385.24
0.240 0.700 0.794 293.0 0.0 8.0100 2.564E-01 -1.322E-04 4.007E-08 723.43 323.35
0.267 0.340 0.724 293.0 1.2 1.7920 1.397E-01 -7.229E-05 1.396E-08 410.58 219.67
0.287 0.192 0.667 293.0 1.3 4.0640 4.277E-02 -1.250E-05 -4.580E-10 0.00 0.00
0.000 0.000 1.150 288.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.266 0.190 0.848 293.0 1.5 5.8050 4.478E-02 -1.642E-05 9.790E-10 267.34 184.24
0.295 0.364 0.990 347.0 0.0 -23.1840 2.641E-01 -2.115E-04 6.664E-08 733.87 369.58
0.000 0.440 1.066 303.0 1.1 -14.5050 2.217E-01 -1.402E-04 3.245E-08 1146.00 379.29
0.000 0.471 1.006 293.0 0.4 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.280 0.455 0.738 293.0 1.0 1.5430 1.503E-01 -8.098E-05 1.689E-08 561.11 257.39
0.240 0.000 0.835 293.0 1.6 2.2030 2.635E+00 -1.000E+00 -1.275E+00 -4.00 1.86
0.285 0.098 0.548 183.0 0.0 1.2920 4.254E-02 -1.657E-05 2.081E-09 156.60 95.57
0.248 0.635 0.789 293.0 1.7 2.1530 5.113E-02 -2.004E-05 3.280E-10 686.64 300.88
0.252 0.363 0.901 293.0 1.9 1.7280 9.725E-02 -4.996E-05 6.818E-09 427.38 235.94
0.261 0.400 0.921 293.0 0.0 4.0150 8.813E-01 -3.300E-05 -1.369E-09 438.04 256.84
0.264 0.284 0.683 293.0 1.3 0.8820 6.572E-02 -3.781E-05 9.096E-09 340.54 192.44
0.250 0.480 1.046 293.0 1.9 4.9370 1.645E-01 -8.618E-05 1.209E-08 746.50 338.47
0.320 0.254 1.451 298.0 2.0 1.5900 5.608E-02 -3.517E-05 9.086E-09 369.80 220.68
0.270 0.400 0.749 293.0 1.2 5.6430 1.282E-01 -6.039E-05 9.928E-09 443.32 234.68
0.260 0.470 0.879 293.0 1.8 5.1370 1.177E-01 -4.629E-05 8.500E-10 489.95 264.22
0.274 0.190 0.896 293.0 2.0 -0.1320 6.225E-02 -4.394E-05 1.325E-08 320.94 190.83
0.262 0.281 0.713 293.0 1.3 5.1170 8.022E-02 -2.473E-05 -2.235E-09 353.14 190.58
0.272 0.238 0.000 0.0 2.0 1.0380 5.207E-02 -2.784E-05 5.757E-09 0.00 0.00
0.257 0.283 0.927 289.0 2.0 5.8930 5.532E-02 -5.063E-06 -1.280E-08 400.91 226.23
0.270 0.427 0.869 293.0 2.1 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.274 0.190 0.839 293.0 1.5 3.5640 5.615E-02 -3.239E-05 7.552E-09 419.60 206.21
0.256 0.395 0.895 289.0 1.8 4.7420 9.636E-02 -3.432E-05 -1.768E-09 463.31 248.72
0.000 0.331 0.733 293.0 1.2 0.0000 0.000E+00 0.000E+00 0.000E+00 399.87 213.39
0.263 0.301 0.867 293.0 0.4 -10.2940 1.689E-01 -1.149E-04 3.107E-08 472.82 264.22
0.270 0.243 0.788 293.0 0.0 -15.2600 2.124E-01 -1.220E-04 2.634E-08 506.43 280.76
0.269 0.283 0.771 289.0 0.0 -13.2110 1.794E-01 -1.050E-04 2.398E-08 433.81 249.72
0.276 0.085 0.577 163.0 0.0 0.9090 3.740E-02 -1.994E-05 4.192E-09 168.98 93.94
0.270 0.000 1.114 293.0 2.2 8.5260 5.931E-02 -3.576E-05 7.190E-09 1365.00 402.41
0.000 0.000 0.833 298.0 1.9 -4.9610 7.219E-02 -4.927E-05 1.349E-08 0.00 0.00
0.258 0.200 0.899 273.0 1.9 -1.7960 5.308E-02 -3.001E-05 6.190E-09 341.88 194.22
0.260 0.510 0.896 293.0 1.9 9.1470 5.749E-02 -1.036E-05 -9.430E-09 839.76 316.41
0.288 0.048 1.510 85.0 0.0 5.5450 8.734E-03 -8.269E-06 2.876E-09 84.20 52.52
0.265 0.245 1.024 293.0 1.4 -9.2500 1.354E-01 -1.059E-04 3.237E-08 452.06 252.89
0.000 0.253 0.815 253.0 2.3 5.6070 7.540E-03 7.130E-06 -5.494E-09 319.83 171.35
0.000 0.000 1.226 288.0 1.5 2.7980 3.243E-02 -2.009E-05 4.817E-09 729.35 325.72
0.294 0.204 0.938 293.0 0.7 -8.4860 1.032E-01 -8.251E-05 2.566E-08 389.40 222.70
0.280 0.000 1.261 293.0 3.0 2.0120 1.061E-01 -7.545E-05 2.240E-08 3337.10 406.00
0.301 -0.387 0.123 4.3 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.848 327.0 0.0 -1.8610 3.948E-01 -2.232E-04 4.881E-08 0.00 0.00
0.260 0.328 1.008 293.0 3.0 2.3330 4.525E-02 -3.958E-05 1.439E-08 524.98 290.88
0.305 -0.220 0.071 20.0 0.0 6.4830 2.215E-03 -3.298E-06 1.826E-09 13.82 5.39
0.283 0.063 2.160 216.0 0.8 7.3200 -2.260E-03 4.114E-06 -1.490E-09 88.08 166.32
0.249 0.120 1.193 188.1 1.1 7.2350 -1.720E-03 2.976E-06 -9.310E-10 372.78 277.74
0.197 0.407 0.688 293.0 3.0 5.2220 1.448E-02 -1.185E-05 4.336E-09 194.70 145.31
0.120 0.372 0.967 293.0 0.0 6.9410 1.579E-04 -4.854E-07 5.980E-10 438.74 199.62
0.309 0.050 2.803 237.0 0.5 7.4420 -3.410E-03 7.099E-06 -3.232E-09 155.15 285.43
0.284 0.100 0.993 213.6 0.9 7.6290 3.431E-04 5.809E-06 -2.810E-09 342.79 165.54
0.265 0.299 3.740 453.2 1.3 8.5010 1.556E-03 -1.669E-06 6.770E-10 559.62 520.55
0.265 0.246 1.855 277.0 1.4 -6.9920 1.329E-01 -1.077E-04 3.447E-08 565.72 331.21
0.283 0.176 0.557 293.0 0.1 -0.3320 9.189E-02 -4.409E-05 6.915E-09 302.51 170.20
0.257 0.588 0.802 293.0 1.7 -1.8410 1.120E-01 -6.888E-05 1.727E-08 1199.10 343.85
0.270 0.479 0.875 293.0 1.9 1.7460 1.371E-01 -6.152E-05 2.630E-09 533.99 270.49
0.280 0.000 0.000 0.0 1.2 2.2670 1.038E-01 -5.039E-05 5.572E-09 0.00 0.00
0.296 0.390 0.885 293.0 1.9 4.7410 9.634E-02 -3.431E-05 -1.768E-09 0.00 0.00
0.280 0.378 0.853 293.0 0.3 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.319 0.795 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.275 0.190 0.594 293.0 0.5 3.8340 6.698E-02 -2.607E-05 2.173E-09 0.00 0.00
0.270 0.350 0.789 293.0 0.0 5.8430 8.015E-02 -4.913E-05 1.521E-08 464.06 253.64
0.230 0.610 0.968 293.0 1.3 2.3440 1.115E-01 -8.884E-05 3.225E-08 583.65 311.24
0.248 0.000 0.786 293.0 1.7 7.7450 4.502E-02 1.530E-05 -2.212E-08 1139.70 323.44
0.290 0.297 0.688 293.0 0.0 -1.7880 9.973E-02 -6.749E-05 1.994E-08 433.64 228.46
0.269 0.232 0.862 293.0 2.1 0.4400 8.330E-02 -5.359E-05 1.400E-08 306.25 212.24
0.260 0.335 0.862 293.0 0.4 -9.0420 1.873E-01 -1.215E-04 3.084E-08 517.17 276.22
0.000 0.237 0.802 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.240 0.776 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.300 0.207 0.000 0.0 1.4 1.5250 3.913E-02 -2.590E-05 6.455E-09 0.00 0.00
0.288 -0.002 2.420 120.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 1.310 333.0 4.0 -3.1230 8.323E-02 -5.217E-05 1.156E-08 952.48 365.81
0.241 0.464 1.034 293.0 1.8 -10.7500 1.735E-01 -1.440E-04 4.962E-08 1785.60 370.75
0.240 0.260 1.288 293.0 1.4 -3.2460 1.312E-01 -1.076E-04 3.408E-08 402.20 300.89
0.288 0.008 0.425 111.7 0.0 4.5980 1.245E-02 2.860E-06 -2.703E-09 114.14 57.60
0.224 0.559 0.791 293.0 1.7 5.0520 1.694E-02 6.179E-06 -6.811E-09 555.30 260.64
0.273 0.239 0.754 289.0 0.0 11.9680 1.524E-01 -8.699E-05 1.914E-08 440.52 243.24
0.254 0.324 0.934 293.0 1.7 3.9530 5.363E-02 -1.037E-05 6.961E-09 408.62 224.03
0.276 0.218 0.706 223.0 0.7 3.5130 4.453E-02 -2.803E-05 7.701E-09 0.00 0.00
0.250 0.350 0.956 293.0 0.0 3.6220 6.678E-02 -2.103E-05 -3.966E-09 451.02 245.30
0.292 0.275 0.703 259.6 1.3 2.7410 3.409E-02 -1.274E-05 1.135E-09 311.80 176.30
0.250 0.430 1.086 293.0 1.9 -5.0660 1.314E-01 -4.298E-05 1.057E-08 768.94 332.33
0.000 0.273 1.737 268.0 1.8 3.4460 2.606E-02 -1.290E-05 2.389E-09 298.15 211.15
0.257 0.382 0.898 293.0 1.7 0.0000 0.000E+00 0.000E+00 0.000E+00 479.35 254.66
0.268 0.156 0.915 293.0 1.9 3.3140 2.422E-02 -9.288E-06 6.130E-10 426.45 193.56
0.267 0.236 0.700 293.0 1.2 4.4590 6.414E-02 -2.447E-05 2.138E-09 303.82 171.66
0.249 0.329 0.805 293.0 3.3 2.6140 8.501E-02 -4.538E-05 9.362E-09 423.84 231.67
0.000 0.000 0.837 293.0 0.0 4.6640 6.904E-02 -2.888E-05 3.073E-09 0.00 0.00
0.275 0.190 0.843 213.0 1.8 3.3020 2.058E-02 -4.946E-06 -4.740E-10 0.00 0.00
0.255 0.252 0.974 293.0 1.8 0.3420 6.449E-02 -4.656E-05 1.362E-08 363.19 212.70
0.462 0.000 0.000 0.0 1.7 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.285 0.172 2.279 293.0 1.6 2.5810 3.318E-02 -2.487E-05 8.325E-09 336.19 229.95
0.260 0.400 0.801 293.0 2.8 0.9300 1.351E-01 -7.925E-05 1.966E-08 473.65 259.03
0.259 0.367 0.891 293.0 2.0 0.0000 0.000E+00 0.000E+00 0.000E+00 451.21 246.09
0.000 0.278 0.958 293.0 0.0 8.0000 5.420E+02 2.483E-02 -1.390E-06 0.00 616.78
0.259 0.349 0.803 293.0 2.8 -0.6960 1.192E-01 -7.009E-05 1.592E-08 0.00 0.00
0.268 0.155 0.866 293.0 1.3 3.1690 3.479E-02 -2.041E-05 4.956E-09 0.00 0.00
0.250 0.348 0.806 293.0 2.5 0.2740 1.147E-01 -6.731E-05 1.591E-08 437.94 243.03
0.000 0.000 0.996 293.0 1.2 0.0000 0.000E+00 0.000E+00 0.000E+00 388.84 325.85
0.250 0.420 1.032 288.0 3.0 -7.0650 1.531E-01 -9.724E-05 2.322E-08 1316.40 310.82
0.256 0.352 0.915 293.0 1.7 4.3480 7.499E-02 -2.234E-05 -4.365E-09 442.88 238.39
0.000 0.000 0.888 291.0 1.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.269 0.233 0.774 289.0 0.0 -14.7890 1.873E-01 -1.060E-04 2.237E-08 528.41 271.58
0.000 0.000 1.025 273.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.989 293.0 1.7 0.0000 0.000E+00 0.000E+00 0.000E+00 915.12 332.74
0.170 0.000 1.016 293.0 2.6 2.2240 7.188E-02 -4.342E-05 1.112E-08 1984.10 367.03
0.270 0.370 1.000 293.0 1.5 -10.2230 1.287E-01 -6.368E-05 1.003E-08 914.14 332.75
0.358 0.000 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 940.58 460.94
0.240 0.406 0.989 293.0 1.5 -3.8190 1.357E-01 -7.244E-05 1.109E-08 928.12 354.07
0.260 0.331 0.864 293.0 0.3 -6.9660 1.504E-01 -8.950E-05 2.025E-08 453.42 257.18
0.000 0.000 0.956 293.0 1.6 0.0000 0.000E+00 0.000E+00 0.000E+00 553.02 320.03
0.267 0.302 0.971 363.0 0.0 -16.4330 2.030E-01 -1.554E-04 4.731E-08 873.32 352.57
0.274 0.193 0.579 293.0 0.0 2.2660 7.913E-02 -2.647E-05 -6.740E-10 265.84 160.20
0.259 0.590 0.810 293.0 1.8 0.7800 9.984E-02 -5.354E-05 1.119E-08 984.54 341.12
0.270 0.396 0.739 293.0 1.3 1.2130 1.069E-01 -5.749E-05 1.815E-08 472.06 246.98
0.260 0.400 0.801 293.0 2.8 3.2530 1.311E-01 -5.442E-05 -1.890E-10 537.58 272.30
0.250 0.000 0.932 293.0 0.0 -8.1370 2.184E-01 -1.328E-04 3.075E-08 1111.10 341.28
0.261 0.392 0.860 293.0 0.4 -5.4910 1.895E-01 -1.050E-04 2.047E-08 563.84 296.01
0.000 0.362 0.799 293.0 0.0 -15.0370 2.582E-01 -1.506E-04 3.344E-08 598.30 311.39
0.260 0.352 0.802 293.0 2.6 3.3630 8.257E-02 -4.115E-05 6.896E-09 472.31 233.42
0.295 0.670 0.958 293.0 1.5 2.8040 9.881E-02 -5.804E-05 1.321E-08 640.42 321.13
0.247 0.490 0.730 293.0 0.0 -1.8900 2.295E-01 -1.263E-04 2.701E-08 558.61 288.37
0.000 0.654 0.000 0.0 0.0 -14.7900 3.601E+00 -1.000E+00 -2.082E+00 -4.00 4.68
0.000 0.583 0.000 0.0 0.0 -16.4840 3.951E+00 -1.000E+00 -2.296E+00 -4.00 5.12
0.240 0.562 0.748 293.0 0.0 -2.2280 2.744E-01 -1.516E-04 3.246E-08 631.63 318.78
0.000 0.719 0.000 0.0 0.0 -15.1100 4.049E-01 -2.333E-04 5.220E-08 853.90 385.53
0.000 0.907 0.775 313.0 0.0 -5.3460 4.632E-01 -2.667E-04 6.039E-08 811.29 401.67
0.311 0.000 1.204 27.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.220 0.770 0.778 293.0 0.0 -3.3360 3.879E-01 -2.169E-04 4.710E-08 757.88 375.90
0.263 0.351 0.684 293.0 0.0 -1.2290 1.615E-01 -8.720E-05 1.829E-08 436.73 232.53
0.000 0.515 0.000 0.0 0.0 14.1550 2.922E-01 -1.692E-04 3.813E-08 654.77 333.12
0.000 0.742 0.773 293.0 0.0 -3.1090 3.652E-01 -2.039E-04 4.418E-08 738.30 366.11
0.000 0.861 0.000 0.0 0.0 -15.9270 4.954E-01 -2.851E-04 6.373E-08 977.42 412.29
0.260 0.296 0.659 293.0 0.0 -1.0540 1.390E-01 -7.449E-05 1.551E-08 362.79 207.09
0.000 0.476 0.000 0.0 0.0 13.9300 2.694E-01 -1.561E-04 3.518E-08 617.57 318.65
0.250 0.607 1.280 121.0 0.2 7.0090 -2.240E-04 2.328E-06 -1.000E-09 0.00 0.00
0.290 0.040 0.804 78.1 0.0 7.4400 -3.240E-03 6.400E-06 -2.790E-09 90.30 46.41
0.480 0.860 1.447 292.9 0.4 5.7880 1.155E-02 -4.970E-06 7.000E-11 406.20 230.21
0.000 0.132 1.537 144.0 0.2 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.224 0.346 1.138 293.0 3.1 1.7730 4.724E-02 -2.583E-05 4.980E-09 452.50 261.21
0.350 0.318 1.420 261.0 1.8 8.1440 1.068E-02 -7.977E-06 2.424E-09 0.00 0.00
0.274 0.160 1.226 183.6 0.2 5.1640 1.739E-02 -1.380E-05 4.371E-09 0.00 0.00
0.000 0.827 0.789 305.0 0.0 -3.7000 4.329E-01 -2.424E-04 5.267E-08 793.62 393.54
0.260 0.444 0.718 293.0 0.0 0.7510 1.618E-01 -4.606E-05 -7.121E-09 525.56 272.12
0.000 0.610 0.000 0.0 0.0 -14.5240 3.372E+00 -1.000E+00 -1.948E+00 -4.00 4.37
0.000 0.790 0.777 301.0 0.0 -3.4560 4.101E-01 -2.291E-04 4.964E-08 777.40 385.00
0.259 0.394 0.703 293.0 0.0 -1.4560 1.842E-01 -1.002E-04 2.115E-08 473.70 251.71
0.000 0.564 0.000 0.0 0.0 -14.3190 3.145E+00 -1.000E+00 -1.818E+00 -4.00 4.08
0.230 0.706 0.769 293.0 0.0 -2.8460 3.422E+00 -1.000E+00 -1.904E+00 -4.00 4.11
0.000 0.833 0.000 0.0 0.0 -15.7860 4.730E-01 -2.724E-04 6.090E-08 950.57 406.33
0.262 0.251 0.626 293.0 0.0 -0.8660 1.164E-01 -6.163E-05 1.267E-08 313.66 182.45
0.252 0.392 0.887 293.0 1.8 3.6830 1.075E-01 -4.027E-05 -3.437E-09 489.53 255.83
0.267 0.229 0.717 293.0 1.3 1.5980 8.356E-02 -4.352E-05 8.566E-09 0.00 0.00
0.259 0.315 0.911 289.0 1.9 0.0000 0.000E+00 0.000E+00 0.000E+00 452.97 246.09
0.000 0.000 0.881 293.0 1.8 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.265 0.344 0.862 293.0 0.4 -7.4730 1.788E-01 -1.099E-04 2.582E-08 527.45 282.65
0.000 0.258 0.793 293.0 0.0 -14.9320 2.362E-01 -1.384E-04 3.084E-08 549.08 293.93
0.250 0.335 0.781 289.0 0.0 -13.3690 2.018E-01 -1.176E-04 2.669E-08 454.23 264.22
0.230 0.679 0.763 293.0 0.0 -2.6230 3.195E+00 -1.000E+00 -1.773E+00 -4.00 3.82
0.000 0.789 0.000 0.0 0.0 -15.5080 4.501E-01 -2.592E-04 5.794E-08 924.60 399.62
0.240 0.623 0.756 293.0 0.0 -2.4990 2.974E+00 -1.000E+00 -1.651E+00 -4.00 3.56
0.000 0.755 0.000 0.0 0.0 -15.3360 4.276E-01 -2.465E-04 5.516E-08 891.80 392.78
0.240 0.535 0.740 293.0 0.0 -2.0050 2.517E-01 -1.385E-04 2.954E-08 605.50 305.01
0.240 0.616 0.939 293.0 0.0 3.1980 1.202E-01 -7.001E-05 1.581E-08 729.09 341.13
0.240 0.443 1.028 313.0 1.6 -7.7090 1.673E-01 -1.415E-04 5.073E-08 1533.40 365.61
0.225 0.272 1.306 293.0 2.3 -3.4160 1.315E-01 -1.078E-04 3.414E-08 554.35 319.07
0.000 0.000 1.037 273.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.405 0.000 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 1094.10 461.27
0.260 0.435 0.998 293.0 1.6 0.0000 0.000E+00 0.000E+00 0.000E+00 1085.10 356.46
0.288 0.021 1.149 90.0 0.0 6.7130 -8.790E-07 4.170E-06 -2.544E-09 85.68 51.50
0.263 0.314 0.880 293.0 0.5 -3.7860 1.424E-01 -8.224E-05 1.798E-08 513.54 277.98
0.288 0.215 1.356 161.3 0.6 4.9070 1.913E-02 -1.491E-05 4.054E-09 313.79 120.34
0.000 0.515 1.019 313.0 1.6 -9.7050 1.685E-01 -1.375E-04 4.699E-08 1826.90 372.68
0.260 0.270 1.248 328.0 0.0 -3.4260 1.322E-01 -1.089E-04 3.458E-08 483.82 312.03
0.000 0.400 0.000 0.0 0.0 8.6600 1.258E-01 -1.086E-04 3.477E-08 0.00 0.00
0.000 0.000 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.271 0.226 1.519 197.0 0.0 6.9290 5.439E-02 -4.863E-05 1.619E-08 0.00 0.00
0.000 0.000 1.590 195.0 0.0 6.4050 8.259E-02 -6.853E-05 1.943E-08 0.00 0.00
0.000 0.482 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.273 0.560 1.733 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.224 0.730 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.000 0.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 0.000 0.0 0.0 -14.0870 2.402E+00 -1.000E+00 -1.575E+00 -4.00 3.84
0.000 0.000 0.979 277.0 1.2 0.0000 0.000E+00 0.000E+00 0.000E+00 646.88 305.91
0.240 0.440 1.059 313.0 1.6 8.5610 1.429E-01 -1.153E-04 3.647E-08 1405.50 370.07
0.280 0.204 1.381 293.0 1.1 6.7090 3.250E-02 -3.281E-05 1.211E-08 0.00 0.00
0.000 0.000 1.574 294.0 0.9 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.260 0.000 0.000 0.0 5.3 -1.0640 1.562E-01 -1.023E-04 2.411E-08 0.00 0.00
0.280 0.250 0.862 293.0 1.2 -12.6750 1.502E-01 -8.020E-05 1.535E-08 772.79 313.49
0.271 0.313 0.658 238.0 0.2 2.3660 4.723E-02 -2.822E-05 6.645E-09 0.00 0.00
0.281 0.152 0.582 231.0 0.0 -1.0090 7.315E-02 -3.789E-05 7.678E-09 222.67 133.41
0.260 0.313 0.797 293.0 2.7 2.8000 6.244E-02 -3.105E-05 5.078E-09 343.44 219.33
0.242 0.536 0.993 293.0 1.5 1.3540 8.811E-02 -6.842E-05 2.359E-08 535.04 299.32
0.205 0.318 0.782 293.0 3.7 3.6790 5.363E-02 -2.628E-05 4.667E-09 366.77 225.86
0.278 0.230 0.891 293.0 2.0 -0.7990 8.660E-02 -5.991E-05 1.779E-08 374.77 215.00
0.275 0.148 0.612 223.0 0.4 0.8860 5.602E-02 -2.771E-05 5.266E-09 273.84 131.63
0.228 0.269 0.829 293.0 2.0 -2.0200 7.779E-02 -4.750E-05 1.152E-08 377.43 213.36
0.336 0.000 0.000 0.0 0.7 0.0000 0.000E+00 0.000E+00 0.000E+00 911.01 461.10
0.000 0.000 0.964 323.0 1.6 0.0000 0.000E+00 0.000E+00 0.000E+00 738.90 356.02
0.260 0.324 0.861 293.0 0.1 -5.9930 1.443E-01 -8.058E-05 1.629E-08 475.16 261.40
0.277 0.240 0.983 293.0 2.3 9.5040 1.177E-01 -8.498E-05 2.399E-08 618.50 291.58
0.000 0.000 0.967 294.0 1.8 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.296 0.000 0.852 295.0 1.6 -12.3080 1.275E-01 -7.738E-05 1.798E-08 0.00 0.00
0.000 0.274 0.862 293.0 0.4 -15.5600 2.363E-01 -1.723E-04 5.140E-08 582.66 295.82
0.000 0.264 0.813 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.290 0.264 1.480 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.000 1.660 178.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.000 0.257 0.906 293.0 0.1 -6.7470 1.471E-01 -9.609E-05 2.373E-08 528.64 276.71
0.000 0.000 0.000 0.0 2.2 3.6000 1.120E-02 -7.508E-05 1.896E-08 0.00 0.00
0.268 0.251 1.455 263.0 1.6 5.6970 1.600E-02 -1.185E-05 3.172E-09 397.85 208.42
0.281 0.286 1.830 223.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 251.29 180.75
0.260 0.410 1.780 318.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 1372.80 315.99
0.259 0.618 0.787 293.0 1.7 -11.6110 1.713E-01 -1.692E-04 6.974E-08 972.10 363.38
0.280 0.190 0.842 293.0 2.1 -0.9390 1.111E-01 -6.893E-05 1.880E-08 543.41 253.35
0.000 0.265 0.867 293.0 0.5 -20.5410 2.632E-01 -2.089E-04 6.751E-08 0.00 0.00
0.000 0.252 0.813 293.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.250 0.000 1.620 293.0 0.0 10.9800 5.387E-02 -5.478E-05 2.002E-08 392.58 281.82
0.259 0.000 0.889 293.0 1.7 -4.5630 1.233E-01 -9.868E-05 3.473E-08 419.79 244.46
0.259 0.200 1.071 289.0 0.5 -7.3100 1.070E-01 -9.009E-05 2.992E-08 498.60 264.90
0.264 0.257 0.867 293.0 0.4 -5.8170 1.224E-01 -6.605E-05 1.173E-08 467.33 255.24
0.000 0.242 0.776 293.0 0.0 -16.3560 2.179E-01 -1.279E-04 2.821E-08 0.00 0.00
0.270 0.269 0.756 289.0 0.0 -13.0220 1.813E-01 -1.070E-04 2.429E-08 0.00 0.00
0.000 0.189 0.785 293.0 0.0 -15.3230 2.108E-01 -1.198E-04 2.552E-08 0.00 0.00
0.000 0.242 0.763 293.0 0.0 -16.8060 2.181E-01 -1.268E-04 2.758E-08 0.00 0.00
0.274 0.214 0.604 293.0 0.0 4.3750 6.123E-02 -1.675E-05 -2.147E-09 259.01 153.30
0.270 0.242 0.678 293.0 0.0 -7.8640 1.655E-01 -1.342E-04 4.788E-08 344.33 197.95
0.000 0.350 0.720 293.0 0.0 -3.0620 1.799E-01 -1.061E-04 2.509E-08 427.64 240.32
0.280 0.237 0.649 293.0 0.0 0.4650 9.988E-02 -5.201E-05 1.052E-08 349.33 176.62
0.260 0.227 0.677 293.0 0.0 -1.0360 1.316E-01 -7.840E-05 1.922E-08 344.33 197.95
0.000 0.270 0.870 293.0 0.0 -23.3280 2.495E-01 -1.308E-04 2.145E-08 702.27 339.66
0.000 0.000 0.779 293.0 0.8 1.9090 2.861E+00 -1.000E+00 -1.601E+00 -4.00 3.46
0.265 0.213 1.462 293.0 0.9 7.2070 5.462E-05 -5.324E-05 1.696E-08 145.60 196.60
0.279 0.188 0.000 0.0 0.5 9.7890 3.893E-02 -3.383E-05 9.903E-09 0.00 0.00
0.270 0.329 0.728 293.0 0.9 -4.4020 1.709E-01 -1.049E-04 2.609E-08 355.52 214.48
0.000 0.000 1.535 273.0 2.3 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.280 0.000 0.000 0.0 0.7 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.287 0.195 0.633 293.0 0.6 -1.9600 9.486E-02 -5.299E-05 1.104E-08 0.00 0.00
0.260 0.400 0.810 293.0 2.6 3.4010 1.034E-01 -5.033E-05 7.553E-09 521.30 252.03
0.260 0.340 0.932 293.0 1.7 3.6210 6.676E-02 -2.103E-05 -3.965E-09 457.89 235.35
0.265 0.122 0.969 259.0 1.5 1.4210 4.823E-02 -3.669E-05 1.140E-08 276.90 167.04
0.270 0.000 0.793 293.0 1.3 4.1270 7.729E-02 -3.514E-05 5.134E-09 349.95 189.02
0.277 0.000 0.000 0.0 1.4 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
0.310 0.550 0.963 293.0 0.0 6.6430 4.392E-02 -8.502E-06 -5.577E-08 428.40 224.83
0.270 0.340 0.750 293.0 0.0 3.7330 5.592E-02 -2.316E-05 2.537E-09 318.41 180.98
0.260 0.092 0.710 273.0 0.0 1.6140 6.785E-02 -5.410E-05 1.782E-08 0.00 0.00
0.229 0.344 0.998 293.0 1.8 7.7010 4.595E-04 2.521E-06 -8.590E-10 658.25 283.16
0.286 0.002 3.060 165.0 0.0 0.0000 0.000E+00 0.000E+00 0.000E+00 0.00 0.00
 STD HEAT STD ENERGY
ANTOINE VAPOR PRESSURE EQN VAP PRESS VAP PRESS HARLACHER VAPOR PRESSURE EQN
FORM FORM LN(P)=A-B/(T+C) MAX TEMP MIN TEMP LN(PVP)=A+B/T+C*LN(T)+(D*PVP/(T^2))
KCAL/G-MOLE KCAL/G-MOLE P AS mmHg AND T AS K K K PVP AS mmHg AND T AS K
DELHG DELGF A B C TMX TMN A B C D
19 20 21 22 23 24 25 26 27 28 30

-178.2 -162.23 15.8965 1814.91 -29.92 300 270 50.589 -3540.17 -5.223 1.790
0 0 0.0000 0.00 0.00 0 0 75.315 -7113.72 -8.344 4.950
-33.1 -18.52 16.0381 3110.79 -56.16 428 302 0.000 0.00 0.000 0.000
0 0 15.7084 3015.51 -54.59 414 279 0.000 0.00 0.000 0.000
0 0 15.6794 2938.09 -53.25 404 273 0.000 0.00 0.000 0.000
0 0 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
-31.05 -17.47 16.0842 2697.29 -45.03 352 242 56.233 -5422.68 -5.726 3.170
-118 -104.26 16.1871 2095.35 -29.16 273 238 48.591 -3837.61 -4.811 1.870
-82.5 -76.84 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
-43.26 8.42 16.9647 4276.08 -52.80 480 345 0.000 0.00 0.000 0.000
-33.05 9.33 15.6973 2807.94 -51.20 390 260 0.000 0.00 0.000 0.000
-178.1 0 15.8424 2523.61 -45.67 360 250 57.097 -5249.75 -5.913 3.910
6.6 39.9 16.2805 4009.49 -64.89 500 365 0.000 0.00 0.000 0.000
-44.4 -23.37 16.1246 3417.27 -69.15 470 315 0.000 0.00 0.000 0.000
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-88.74 0 16.1611 2603.30 -54.15 360 240 60.604 -5724.26 -6.305 3.070
0 0 0.0000 0.00 0.00 0 0 74.336 -7477.19 -8.108 5.660
 -11.02 -1.12 16.0077 2497.23 -41.77 330 224 51.954 -4900.34 -5.139 2.550
-112.3 -77.32 16.1620 2935.11 -64.17 396 276 67.631 -6869.83 -7.193 4.980
0 0 15.4539 2423.41 -62.28 360 246 58.911 -5663.85 -6.100 4.330
7.12 31.21 16.0195 3279.47 -59.95 450 300 58.100 -6792.54 -5.802 5.750
-41.05 9.38 15.8125 3183.25 -58.15 433 293 0.000 0.00 0.000 0.000
-30.37 10.65 15.8581 2990.13 -52.47 402 270 0.000 0.00 0.000 0.000
12.5 16.28 15.5368 1347.01 -18.15 182 120 38.961 -2282.37 -3.678 0.881
-9.3 -72.77 20.2501 6022.18 -28.25 494 364 0.000 0.00 0.000 0.000
29.5 42.54 16.4227 2610.44 -63.15 359 248 0.000 0.00 0.000 0.000
-12.58 -3.13 16.7400 2567.61 -29.01 310 200 0.000 0.00 0.000 0.000
0 0 16.4082 3108.49 -72.15 425 292 0.000 0.00 0.000 0.000
0 0 15.6700 714.10 -6.00 91 59 30.772 -1040.27 -2.683 0.210
-27.86 -16.5 16.5487 3181.78 -37.59 370 250 55.141 -5819.21 -5.489 3.880
-27.7 -26.27 16.4775 2204.13 -30.15 271 185 45.118 -3873.26 -4.200 3.410
90.49 -83.89 16.9882 3599.58 -26.09 409 271 0.000 0.00 0.000 0.000
-8.29 0.21 16.0612 2442.70 -45.41 363 238 0.000 0.00 0.000 0.000
-139.8 0 17.2392 4487.04 -140.20 600 440 0.000 0.00 0.000 0.000
0 0 12.2514 33.73 1.79 4.3 3.7 8.622 -12.23 0.433 0.007
-130.47 -10.67 15.6161 3672.62 -188.10 656 464 0.000 0.00 0.000 0.000
22.75 37.89 17.9899 3877.65 -45.15 343 288 56.096 -6951.84 -5.286 1.630
0 0 13.6333 164.90 3.19 25 14 12.050 -114.95 0.048 0.048
-8.66 -12.73 14.4687 1242.53 -47.86 221 184 28.102 -2394.35 -1.843 0.871
-22.06 -22.77 16.5040 1714.25 -14.45 200 137 38.614 -2626.67 -3.443 0.717
31.2 28.71 16.5138 2585.80 -37.15 330 234 37.742 -4183.37 3.004 2.180
-64.8 -65.3 17.6958 3404.49 15.06 313 206 26.160 -3496.52 -1.338 1.840
6.3 0.38 12.9149 957.96 -85.06 256 215 33.884 -3013.08 -2.673 1.230
-4.82 -7.9 16.1040 1768.69 -26.06 230 190 42.687 -3132.31 -3.985 0.871
0 0 16.1597 3709.23 -68.16 487 383 0.000 0.00 0.000 0.000
38.85 44.88 16.1454 3776.53 -64.38 470 290 57.691 -7589.50 -5.646 6.460
-32.15 -4.99 15.5381 2032.73 -33.15 280 187 46.141 -3771.21 -4.509 2.570
-67.69 -39.99 16.8712 2874.73 -100.30 388 293 0.000 0.00 0.000 0.000
-118.34 0 16.1714 3092.83 -66.15 427 289 0.000 0.00 0.000 0.000
0 0 16.1419 2704.16 -56.15 373 251 0.000 0.00 0.000 0.000
0 0 16.2292 2980.47 -64.15 409 278 58.420 -6314.51 -5.879 4.410
-5.15 0 15.9524 3512.47 -69.03 476 326 0.000 0.00 0.000 0.000
0 0 15.8141 3437.99 -69.99 455 355 0.000 0.00 0.000 0.000
-4.04 13.88 15.7528 2125.75 -33.15 290 190 50.832 -4104.56 -5.157 2.460
-51.56 -29 15.9888 2676.98 -51.15 370 247 0.000 0.00 0.000 0.000
-115.66 0 16.7792 3385.49 -94.15 465 330 82.657 -9222.72 -8.986 5.150
-65.11 -41.44 18.6929 3640.20 -53.54 374 273 0.000 0.00 0.000 0.000
-20.02 0 16.3637 2582.35 -40.15 337 239 0.000 0.00 0.000 0.000
-35 -14.94 16.0384 2490.48 -43.15 340 225 0.000 0.00 0.000 0.000
 0.94 32.74 15.9722 3363.60 -63.37 454 311 46.941 -6285.25 -4.227 6.860
0 0 15.8260 3346.12 -63.71 440 330 0.000 0.00 0.000 0.000
0 0 15.8561 3176.22 -55.18 427 289 0.000 0.00 0.000 0.000
-14.6 -14.41 16.0197 1849.21 -35.15 255 170 0.000 0.00 0.000 0.000
0 0 15.2677 958.75 -8.71 129 113 30.717 -1408.77 -2.579 0.448
0 0 16.2747 3765.65 -82.15 516 352 0.000 0.00 0.000 0.000
-31.63 -9.69 17.2878 4274.42 -74.09 480 370 79.796 -9855.80 -8.509 6.140
6.32 18.78 16.8173 4104.13 -43.15 475 326 0.000 0.00 0.000 0.000
-17.89 -12.15 15.2243 897.84 -7.16 120 93 30.175 -1300.61 -2.641 0.442
-48.08 -38.84 18.5875 3626.55 -34.29 364 257 72.268 -7064.20 -7.680 1.860
-25.5 8.55 15.8023 2731.00 -47.11 375 250 0.000 0.00 0.000 0.000
-97.86 0 16.1295 2601.92 -56.15 360 245 61.268 -5840.56 -6.374 3.080
44.32 46.47 15.6227 1850.66 -44.07 267 183 0.000 0.00 0.000 0.000
0 0 16.1088 2788.43 -59.15 390 260 0.000 0.00 0.000 0.000
-5.5 7.71 17.2622 2484.83 -32.92 311 212 62.306 -4954.32 -6.642 1.400
-60.68 0 16.2272 3751.83 -81.51 516 350 0.000 0.00 0.000 0.000
-9 -6.73 16.0252 2271.71 -34.83 326 215 55.295 -4467.46 -5.788 2.350
0 0 0.0000 0.00 0.00 0 0 65.898 -6819.11 -6.941 4.980
-20.63 -15.03 16.1052 2077.97 -29.55 266 180 43.660 -3642.21 -4.064 1.460
-51.73 -28.12 13.5435 1161.63 -112.40 310 205 74.838 -5631.77 -8.549 2.450
-56.97 -34.91 16.5986 3150.42 -36.65 376 257 47.683 -5328.22 -4.426 3.880
-14.25 2.73 15.9765 2722.95 -48.37 360 250 0.000 0.00 0.000 0.000
-55.9 -50.19 16.3428 1704.41 -19.27 209 141 43.063 -2890.54 -4.102 0.906
-83.6 -71.03 16.5104 2590.87 -42.60 324 225 57.840 -5258.90 -5.939 2.230
20.4 42.51 15.1424 2319.84 -91.70 400 270 0.000 0.00 0.000 0.000
3.34 3.74 16.0905 2639.55 -36.50 325 260 47.781 -4686.90 -4.577 2.840
-67.84 0 15.7165 2893.66 -70.75 425 285 0.000 0.00 0.000 0.000
0 0 0.0000 0.00 0.00 0 0 66.160 -6637.51 -7.016 4.790
-21.5 0 16.3258 2480.37 -56.31 340 230 0.000 0.00 0.000 0.000
0 0 14.1779 1993.12 -103.20 406 271 0.000 0.00 0.000 0.000
-5.49 -2.37 16.1909 2338.38 -34.44 300 200 46.610 -4233.88 -4.408 1.710
-61.82 -32.76 16.0031 2934.87 -62.25 410 275 0.000 0.00 0.000 0.000
0 0 16.2394 3430.82 -69.58 440 370 0.000 0.00 0.000 0.000
-20.76 0.44 16.2384 3781.07 -81.15 520 350 0.000 0.00 0.000 0.000
0 0 16.1693 2804.06 -58.92 385 260 65.367 -6419.79 -6.915 3.980
0 0 15.8237 2415.92 -52.58 315 270 0.000 0.00 0.000 0.000
-36.99 6.52 15.7105 2926.04 -51.75 400 270 52.902 -5797.19 -5.199 5.230
-35.01 0 17.1955 4272.77 -86.08 500 370 0.000 0.00 0.000 0.000
20.4 47.61 16.3066 3756.28 -80.71 480 320 0.000 0.00 0.000 0.000
-48.18 0 17.8174 3988.33 -86.93 477 344 0.000 0.00 0.000 0.000
0 0 16.2364 3171.35 -71.15 440 300 0.000 0.00 0.000 0.000
0 0 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
 0 0 16.7498 4080.32 -73.15 500 355 0.000 0.00 0.000 0.000
4.12 28.41 16.1390 3366.99 -58.04 440 300 55.493 -6666.23 -5.436 6.080
20.1 55.26 16.9647 4276.08 -52.80 480 345 0.000 0.00 0.000 0.000
36.08 53.44 16.1426 3992.01 -71.29 525 360 0.000 0.00 0.000 0.000
-30.15 -4.1 15.6782 2154.90 -34.42 290 195 48.334 -4065.57 -4.781 2.680
-65.65 -36.04 17.2160 3137.02 -94.43 404 288 0.000 0.00 0.000 0.000
-22 11.76 16.6085 3012.70 -48.96 373 259 0.000 0.00 0.000 0.000
-116.26 0 16.1836 3151.09 -69.15 435 295 0.000 0.00 0.000 0.000
0 0 16.3994 4079.72 -96.15 560 385 0.000 0.00 0.000 0.000
-3.3 34.58 16.0793 3633.40 -71.77 486 335 0.000 0.00 0.000 0.000
-50.95 13.49 15.9116 3542.57 -72.32 485 332 0.000 0.00 0.000 0.000
-49 -27.43 16.1668 2839.09 -50.15 380 255 0.000 0.00 0.000 0.000
-113.73 0 17.9240 4130.93 -70.55 470 335 73.806 -9015.33 -7.651 4.220
-59.67 7.94 16.0114 3456.80 -78.67 476 330 75.475 -8563.64 -8.149 10.200
-8 771.74 368.3000 -69.78 26.73 16.1261 4203.94 -109.700 586.00 413.000 0.000
-8 925.84 378.6900 0.00 0.00 16.1627 4373.37 -111.800 573.00 463.000 0.000
-69.52 11.96 16.1134 3774.56 -91.31 520 364 84.248 -10012.50 -9.236 13.370
-80.28 30.1 16.1915 4395.87 -124.20 619 441 0.000 0.00 0.000 0.000
-108.93 28.04 16.4685 4680.46 -141.10 652 471 0.000 0.00 0.000 0.000
0 0 14.0099 180.47 -2.61 29 24 26.181 -295.44 -2.645 0.041
-94.15 22.01 16.1510 4294.55 -124.00 610 434 0.000 0.00 0.000 0.000
-44.88 1.91 15.8737 2911.32 -56.51 400 270 61.276 -6303.87 -6.373 6.000
-55 20.7 16.0589 3850.38 -88.75 529 368 0.000 0.00 0.000 0.000
-89.23 20 16.1841 4214.91 -118.70 594 423 95.680 -12411.30 -10.580 20.270
-99.33 38.79 16.3553 4715.69 -152.10 674 488 0.000 0.00 0.000 0.000
-39.96 -0.06 15.8366 2697.55 -48.78 370 245 57.279 -5587.42 -5.885 4.778
-50.07 18.69 16.0140 3702.56 -81.55 507 351 0.000 0.00 0.000 0.000
21.6 20.72 20.1314 1572.52 -4.88 140 95 61.514 -2465.78 -7.211 0.279
0 0 14.9342 588.72 -6.60 90 54 31.927 -924.86 -3.075 0.264
8.09 12.42 20.5324 4141.29 3.65 320 230 61.862 -6073.34 -6.094 1.040
-29.78 -30.38 15.6107 1155.69 -15.37 155 103 39.219 -1971.37 -3.810 0.679
-17.86 -1.66 16.2193 2972.64 -64.15 409 278 50.133 -5996.30 -4.641 3.080
12.57 16 166.9505 2520.70 -23.46 285 210 36.380 -3748.59 -2.819 1.200
19.49 24.77 16.1271 1506.49 -25.99 200 144 46.444 -2867.98 -4.655 0.743
-104 26.03 16.1533 4450.44 -135.60 639 456 0.000 0.00 0.000 0.000
-54.74 5.93 15.9671 3291.45 -71.33 452 312 73.133 -7969.42 7.890 8.690
-8 735.19 357.7400 -64.85 24.72 16.1089 4096.3 -103.000 569.00 400.000 0.000
-99.08 24.02 16.1232 4361.79 -129.90 625 445 0.000 0.00 0.000 0.000
-49.82 3.92 15.9426 3120.29 -63.63 425 292 66.639 -7100.69 -7.053 7.310
-8 695.83 346.1900 -59.92 22.72 16.0941 3983.01 -95.850 549.00 385.000 0.000
-8 718.51 355.9200 -84.31 17.98 16.1724 4121.51 -111.800 577.00 408.000 95.000
-94.41 36.78 16.3092 4642.01 -145.10 661 476 0.000 0.00 0.000 0.000
 -35 -2 15.8333 2477.07 -39.94 330 220 56.682 -4827.08 -5.313 3.680
-111.31 0 16.2291 2980.47 -64.15 410 280 69.656 -7028.88 -7.475 5.100
-17.3 9.51 15.9957 2551.72 -49.15 350 235 0.000 0.00 0.000 0.000
0 0 15.7671 2593.95 -69.69 360 280 63.318 -6292.56 -6.635 4.010
0 0 16.8641 3558.18 -47.86 420 292 0.000 0.00 0.000 0.000
1.87 32.8 16.0062 3433.84 -66.01 461 316 0.000 0.00 0.000 0.000
-46.2 11.31 15.8567 3363.62 -65.21 459 313 0.000 0.00 0.000 0.000
-35.39 12.57 15.8969 3187.67 -59.99 431 294 0.000 0.00 0.000 0.000
-8 689.85 344.2100 -79.38 15.97 16.148 4008.52 -105.400 560.00 394.000 91.172
-89.48 34.77 16.2632 4439.38 -138.10 648 465 0.000 0.00 0.000 0.000
-8 664.1 332.1000 -74.45 13.97 16.1355 3892.91 -98.930 540.00 380.000 0.000
-84.55 32.74 16.2270 4483.13 -131.30 634 453 0.000 0.00 0.000 0.000
-64.6 9.94 16.0541 3614.07 -85.45 498 348 80.121 -9305.80 -8.729 11.750
-117.2 -85.37 17.6306 4092.15 -86.55 495 350 0.000 0.00 0.000 0.000
-30.74 -8.86 15.9148 3305.37 -108.00 480 370 75.616 -9341.59 -7.959 5.470
7.16 19.76 16.2799 3798.23 -59.84 483 331 0.000 0.00 0.000 0.000
-34.82 0 17.9610 4928.36 -45.75 500 350 0.000 0.00 0.000 0.000
0 0 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
0 0 16.7834 4072.58 -72.15 500 375 0.000 0.00 0.000 0.000
0 0 15.4075 734.55 -6.45 100 63 31.041 -1082.52 -2.761 0.265
4.54 29.18 16.1156 3395.57 -59.46 445 305 61.763 -7149.21 -6.302 6.110
34.1 38.91 15.7427 1272.18 -22.16 174 109 0.000 0.00 0.000 0.000
-29.97 -7.38 16.1989 3479.39 -111.30 480 370 64.083 -8825.19 -6.316 5.420
5.5 18.44 16.1135 3626.83 -64.64 477 326 0.000 0.00 0.000 0.000
-228.64 -210.18 16.1940 2827.53 -57.66 390 270 74.686 -6815.04 -8.318 5.310
0 0 13.9087 1374.07 -136.80 400 280 119.200 -8611.09 -14.890 6.040
-157.4 -149.07 15.8800 1574.60 -27.22 210 140 51.903 -3165.74 -5.537 1.340
-321 -300.52 15.6422 1512.94 -26.94 200 170 48.373 -2969.90 -5.032 1.530
-692.2 0 15.7130 2610.57 -61.93 385 290 51.689 -5514.04 -5.004 5.470
-808.9 -737.87 15.9747 2719.68 -64.50 390 270 83.896 -7348.95 -9.644 7.820
0 0 15.8307 2488.59 -59.73 330 270 90.505 -7074.74 -10.780 7.330
-34.55 0 19.0905 5579.62 -44.15 500 370 0.000 0.00 0.000 0.000
-8 0 0.0000 48.40 0.00 16.7187 5477.94 -69.390 655.00 450.000 0.000
0 0 16.1673 3473.20 -78.66 460 385 0.000 0.00 0.000 0.000
-23.03 7.86 16.4270 3490.89 -98.59 481 345 72.558 -9072.60 7.516 4.420
-52.8 -49.42 15.7565 2167.31 -43.15 341 213 0.000 0.00 0.000 0.000
0 0 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
-88.8 0 15.9984 4467.01 -83.15 615 409 0.000 0.00 0.000 0.000
11.71 0 16.1004 3015.46 -61.15 416 280 0.000 0.00 0.000 0.000
45.92 48.37 13.1563 1054.72 -77.08 257 174 0.000 0.00 0.000 0.000
-24.82 -5.61 15.7260 1872.46 -25.16 249 164 43.492 -3266.92 -4.179 1.810
-45.9 -31.18 16.2315 2659.02 -44.15 350 235 0.000 0.00 0.000 0.000
-108.78 -88.27 17.3789 3723.42 -67.48 450 315 76.490 -8619.48 -8.139 3.930
12.1 22.98 15.9571 2940.86 -55.15 405 270 53.398 -5937.37 -5.200 4.280
-31.1 -12.11 15.9594 2581.48 -42.95 350 230 0.000 0.00 0.000 0.000
4.88 14.99 15.7027 1807.53 -26.15 240 160 44.794 -3260.31 -4.379 1.630
-22.17 -6.16 15.3227 2107.58 -64.87 340 225 0.000 0.00 0.000 0.000
0 0 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
0 0 16.6968 4041.04 -72.15 500 350 0.000 0.00 0.000 0.000
4.29 28.95 16.0963 3346.65 -57.84 440 300 56.175 -6673.70 -5.543 6.190
33.5 45.46 16.0910 3095.13 -61.15 425 285 0.000 0.00 0.000 0.000
25.88 0 16.7966 3457.47 -62.73 440 330 0.000 0.00 0.000 0.000
-0.86 27.41 15.9444 2717.03 -67.90 400 300 0.000 0.00 0.000 0.000
-4.17 0 15.9999 3544.19 -68.10 476 325 0.000 0.00 0.000 0.000
0 0 15.8670 3524.57 -70.78 470 360 0.000 0.00 0.000 0.000
0 0 15.8019 2634.16 -43.15 364 238 0.000 0.00 0.000 0.000
0 0 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
35.22 51.1 16.0193 3328.57 -63.72 460 305 0.000 0.00 0.000 0.000
0 0 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
-70.95 -71.74 16.7680 2302.35 -35.97 280 195 55.502 -4552.50 -5.666 1.320
-291.8 -267 19.3785 2524.78 -11.16 220 159 0.000 0.00 0.000 0.000
-94.47 -88.52 20.8403 3995.70 -36.66 332 290 139.560 -10420.10 -17.380 1.600
-74.67 -42.46 16.8548 2658.29 -95.50 376 293 0.000 0.00 0.000 0.000
-43.8 -15.32 15.8121 2567.15 -44.15 360 235 0.000 0.00 0.000 0.000
-5.42 0 15.9300 3462.28 -69.87 472 323 0.000 0.00 0.000 0.000
0 0 15.7884 3457.85 -67.04 450 357 0.000 0.00 0.000 0.000
-2.9 5.4 16.1642 3259.29 -52.15 460 307 0.000 0.00 0.000 0.000
-44.03 0 16.1069 2768.38 -46.90 370 270 0.000 0.00 0.000 0.000
27.66 30.3 16.0243 2869.07 -51.80 380 260 0.000 0.00 0.000 0.000
11.95 29.16 16.0137 3096.52 -53.67 410 280 56.785 -6283.50 -5.681 4.840
-43.02 8.24 15.7337 3117.43 -54.02 424 286 53.523 -6162.66 -5.245 6.380
-32.67 9.17 15.7594 2861.53 -51.46 390 260 0.000 0.00 0.000 0.000
-42.2 8.68 15.7371 3093.95 -57.76 425 288 56.097 -6271.67 -5.615 6.290
-44.12 7.58 15.6984 3063.44 -54.57 420 283 52.909 -6071.72 -5.163 6.200
-2.67 15.05 15.8177 2212.32 -33.15 300 200 50.137 -4174.56 -5.041 2.660
-12.88 18.27 15.8727 2701.72 -48.62 365 245 60.438 -5734.51 -6.348 4.730
-22.59 22.15 15.8554 3134.97 -58.00 425 289 0.000 0.00 0.000 0.000
-7.59 16.71 15.9011 2495.97 -40.18 330 220 56.420 -5028.79 -5.853 3.620
-13.01 18.55 15.9288 2718.68 -47.77 365 245 0.000 0.00 0.000 0.000
-43.57 17.55 15.7989 3610.66 -66.49 470 363 0.000 0.00 0.000 0.000
-8 889.06 312.4800 0.00 0.00 16.2878 3865.58 -86.150 531.00 362.000 0.000
-1.4 4.75 16.1827 3028.13 -43.15 400 260 53.482 -5776.65 -5.295 3.700
-68 -58.64 15.8516 2401.61 -36.30 300 240 48.709 -4464.14 -4.753 2.850
-23.8 26.36 15.8853 2882.38 -51.15 400 260 0.000 0.00 0.000 0.000
 0 0 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
-155.1 -148.8 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
-5.7 23.64 16.0499 2230.51 -39.15 305 215 50.869 -4261.51 -5.127 2.590
-54.45 -25.88 16.1623 3030.20 -58.15 412 277 0.000 0.00 0.000 0.000
-75.5 0 16.1003 2744.68 -56.15 379 255 0.000 0.00 0.000 0.000
8.4 12.31 14.9601 1803.84 -43.15 290 185 48.672 -3955.89 -4.823 1.850
-33.5 0 15.8911 2449.26 -44.15 340 225 0.000 0.00 0.000 0.000
0 0 0.0000 0.00 0.00 0 0 0.000 0.00 0.000 0.000
0 0 16.6531 2569.68 -63.15 350 240 0.000 0.00 0.000 0.000
0 0 14.4602 1950.22 -25.15 315 190 0.000 0.00 0.000 0.000
72.8 73.13 16.0100 2203.57 -43.15 305 200 0.000 0.00 0.000 0.000
-57.8 -54.64 18.3036 3816.44 -46.13 441 284 55.336 -6869.50 -5.115 1.050
0 0 15.2958 1303.92 -14.50 178 158 31.429 -1951.76 -2.544 0.804
HEAT VAPOR
NORMAL BP
CAL/G-MOLE
HV
31

4580
0
7960
7790
7570
0
6860
5100
0
0
7240
6570
9490
9180
9570
10880
9380
5800
5560
7650
7500
7510
6590
12940
9330
5370
13500
8690
9410
6010
6561
5238
5970
0
7170
 12000
9240
10270
15600
11500
7430
-13117
11600
6760
8040
9290
0
9110
7.2
9180
0
11000
8680
0
12970
12100
8070
-12205.3
10600
6022
0
9980
-11329.2
6460
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