Worksheet 46 GrouplT (2) Lesson : Group 17 (I) 44 12 24 Reaction of halide ions Potassium chloride end potassium iodide react with concentrated sulphurie acid in different ways. b. Write equations for these reactions. Sate the observation obtained for each of the halide salts above. Explain why these two halides do not reactin the same way with concentrated cuiphuric acid, Wil potassium bromide react in the same way as potassium chloride or potassium iodide? Explain your answer. Whats the observation when each of the following hydrogen halides is passed into an aqueous solution of silver nitrate followed by the addition of aqueous ammonia? a b. HCI HI Write balanced equations for the reactions involved. Reaction of chlorine with NaQH(aq) Chlorine gas is bubbled through cold aqueous sodium hydroxide. a ». ‘ Write a balanced equation for the reaction. Identify the type of roastion that occurs. State the changes in the oxidation states of chore in the reacton. Write the balanced equation for the reaction of chlorine with hot aqueous sodium hydroxide. Explain why the producis formed are different from that of the cold aqueous sodium hydroxide.3 Uses 3.1 State one important use of eech of the following halogen compounds. a ASBr b.—Naoci c. Tincture of le Hu a Oro cl ColWorksheet Answers 1 12 48 Group I7 (2) Reaction of hie ions KCL HsS0.——> KHSO. + HC! KI + H,SO, ———+ KHSO, + HI SHI + H2SO, ———> 4l + HS + 4H, b. KCI: White fumes of HCI evolved, KI: Vioet vapour of |p evolved, GF Snot axigised by concentrated HyS0,. I is oxidised by concentrated eS. to le d. As potassium iodide. [Br produced will also be oxicised to Br Anite precipitate is formed which dissolves in aqueous ammonia Ag + Cr ——» Agcl AgCl + 2NH, ——> [Ag(NHe}* + Cr b. _Ayellow precpitate is formed which is insoluble in aqueous ammonia, Agi + —— agi Reaction of chlorine with NaOH(aq) @— Cle+ 2NaQH_ ——» NaCl + NaOc +H.0 b. _Disproportionation cc. From Oto +1 inNaOcl From Oto ~1 in NaCl d. S0k-+ 6NzOH —— SNaCI+ NaCI, +3H.O ‘thigh temperature, OOF dispreportionate to CI and CIOs a. Black andwhite photography b. —Blesching agent c. Antiseptic 6. InsecticideLesson Plan yg Lesson: Group. . Aim: To study the reactions of halides and the uses of halogens. Learning Outcomes : Aithe end of the lesson, students wil be able to = explain the reastion of concentrated H,SO,with solid halides ‘+ exolain the reaction of aqueous AgNOs with aqueous halides ‘+ explain the reaction of chlorine with cold and hot alkalis ‘+ slate the uses of halogens and thelr compounds. ‘Assumed prior knowledge : ‘Students should already be familar with 1. oxidation states 2. the concept of dsproportionation. Underlying Principles 1. Making the invisible, visible. 2. Enabling students to know wnatto look fr. Differentiation ‘Questions inthe student notes are designed to enable al students to complete the actuty ‘The pop-up answers are provided forthe studens to vew wren they have consdered their responses. Worksheet questiors include questions that require recal, understancing ard application of he new concepts leamed.Development of Lesson : No, | Steps Strategy Resources| T_| Selinducion “Teacher to gat students fo calculate the (Ascertaining prior | oxidation states of some elements in knowledge and different compounds. Teacher to get introducing lesson | students to recall the definition of topic for the day). isproporionation, ‘+ Teacher fo point out the lasson obectives of te day, D_ | Suaent Ay Teachar & go through Aciiviies 1 - Swit ‘he students Activity 1: Reaction of halide ions Students getto view the reactions of the halides wih concentrated sulphuric acid and then with aqueous siver nitrata. Activity 2: Reaction of chlorinewith NaOHiaa) Students getto view the reaction of Chlorine with botn not and cold aqueous NaOH, They are get to learn that these reactions are cispropertionation reactions. Activity 3: Uses Students getto view some ofthe uses of the halogens and their compounds. > Courseware S| evaluaion + STUOenTS fo answer questions in re > worksnest student worksheet on their own. [Extension aciviy [+ Students fo ead up referenos matariis |» References on their own,