Group 2 : To study the thermal decomposition of the nitrates, carbonatea and hydroxides and the solubility of

the sulphates of Group 2 elements

Worksheet
Lesson : Group 2
1. Thermal decomposition

1.1 Which one of the following carbonates will be the first to form a gas that turns
limewater cloudy when heated?
A MgCO3 B CaCO3 C SrCO3 D BaCO3

1.2 Which one of the following sulphates is the least soluble in water?
A BeSO4 B MgSO4 C CaSO4 D BaSO4

1.3 Write equations for the decomposition of:

i. calcium hydroxide
ii. barium nitrate
ii. strontium carbonate
2. Thermal decomposition – Explanation

2.1 Which of the following statements is true?

A The ionic radius of Mg2+ is bigger than that of Ba2+.
B The charge density of Mg2+ is lower than that of Ba2+.
C The thermal stability of MgCO3 is lower than that of BaCO3.
D The polarising power of Mg2+ is less than that of Ba2+.
3. Solubility of sulphates

3.1 Which of the following is/are true about Group 2 sulphates on descending the
group?
1. The solubility decreases.
2. The enthalpy of hydration increases.
3. The lattice energy increases.
A 1 only B 1 and 2 only C 2 and 3 only D 1, 2 and 3

3.2 Explain qualitatively the solubility of the sulphates of Group 2 elements.

3.3 Draw the enthalpy diagram for the dissolution of MgSO4. Use L.E = lattice
energy, _Hhyd = enthalpy of hydration and _Hsoln = enthalpy of solution.