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John Campbell’s “Casting Rules” making a process with a poor reputa- ing reliability. These researchers have
were developed over a lifetime of work tion for reliability even worse, and most shown demonstrably and quantitatively
in the foundry industry and later research foundrymen did not even realize it. In the importance of running system design
at the University of Birmingham. Much the intervening years this message has and control of oxides to the integrity of
of the research work focused on the started to get out into the industry and aluminum castings.
effect of melt handling at the various a band of industrialists and academics
LIQUID METAL QUALITY
transfer stages on the number of defects has been persuading manufacturers of
created and the effect on the reliability the truth of John Campbell’s arguments. “Immediately prior to casting the melt
of the castings subsequently made. This This article is a brief synopsis of the should be prepared and treated using
article provides the author’s analysis of major reasons castings fail, supported the best current practice.”
Campbell’s ten rules for metal casting. by the underlying science. It follows
from the conference held in his honor Before making a casting, the liquid
INTRODUCTION
at the 2005 TMS Annual Meeting in metal that is used should be cleaned to
The author first met John Campbell San Francisco. Campbell is now retired the highest level possible. There is no
in a pub in the outskirts of Birming- from the University of Birmingham but point in developing filling and feeding
ham, United Kingdom, some 20 years still works there most days. systems to ensure good quality in the
ago. Intrigued initially by the fact that John Campbell’s “Casting Rules”1
Campbell wore a bow tie, eventually he were developed over a lifetime of work
began to hear the truth about castings in the foundry industry, and later research
and the dreadful news that they were work at the University of Birmingham. 9
8 ■
■
all full of defects. And what’s more, the Much of the research has investigated
Bending Stress (MPa)
7
way most foundries made castings was the effect of melt handling at the various 6 ■
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transfer stages on the number of defects 5 ■
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4 ■
created and the effect on the reliability ■
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3
of the castings subsequently made. 2 ■
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Runyoro2 showed the effect of in-gate 1 ■ ■■ ■ ■■ ■ ■■ ■
■ ■■■■■■ ■■ ■ ■ ■ ■
0 ■■■
velocity on the amount of turbulence cre- 0.0 0.5 1.0 1.5 2.0 2.5
ated. His video recordings of liquid alu- a Gate Entry Velocity (m/s)
minum jetting up are graphic examples
of what foundry workers do not usually 6
Crack Length/Unit Width
ently related to detectable cracks within Figure 2. The drop off in properties for
the castings. Nyahumwa3 then went on to aluminum in bend tests when plotted
show that a number of different types of against gate entry velocity and the
lack of relationship with detected crack
Figure 1. A video capture of in-gate oxide existed and that each type had an length. (a) Bend strength against gate
jetting in aluminum for velocities of 3.00 individual effect on the fatigue life, which entry velocity for aluminum. (b) Detected
ms–1, 0.75 ms–1, 0.50 ms–1, and 0.21 ms–1 could best be shown by using Weibull crack lengths against gate entry velocity
from left to right. The metal is traveling for aluminum.3
up the page.2 statistical plots (Figure 3). Filtering the
metal during casting and post-casting
hot isostatic pressing improved the cast-
2.0 the reactive aluminum surface. This is both hydrogen and nitrogen by inert gas
shown in the following equation: flushing. Steel is similarly affected by
1.5 hydrogen and nitrogen.
2Al + 3H2O = Al2O3 + 6H (1) In ferrous alloys, the other source of
poor quality is inclusions. These can be
1.0
The hydrogen is then dissolved as nascent endogenous in nature, such as oxides,
hydrogen in the molten alloy. sulfides, or even nitrides, or complex
0.5 Figure 4 shows the relative solubility compounds of all three. They are nearly
of hydrogen in liquid and solid alumi- always detrimental to mechanical proper-
0 num and demonstrates why dissolved ties. Exogenous inclusions usually are a
400 500 600 700 800 900 hydrogen is a problem. Figure 5 shows result of the breakdown of containment
Temperature (°C) the effect of high hydrogen levels on or mold refractory materials. Exogenous
Figure 4. The solubility of hydrogen in casting after heat treatment. The rec- inclusions are generally larger, and as it
aluminum with temperature.
ommended level of hydrogen for good is now common practice to filter most
aluminum casting is less than 0.1 cm3 castings, it is rare to find such inclusions
casting if the original material is flawed. per 100 g (0.09 ppm by mass), although in a well-run foundry. Endogenous inclu-
High quality means that there should in aerospace casting it is recommended sions are usually controlled chemically.
be no, or a low level of, inclusions, and that levels be lower than 0.05 cm3 per Oxides can be reduced by deoxidizing
similarly a level of dissolved gas that 100 g (0.045 ppm by mass). with aluminum or silicon; sulfides are
will not give problems on solidification. In aluminum alloys, both metal quality controlled by the refining process. It is
The starting point for clean metal is the and hydrogen levels can be measured also usual to ensure that there is enough
ingot from which it is manufactured or using a number of different techniques, manganese present to form MnS inclu-
the cleanliness of the scrap. as listed in Tables I and II. Molten alu- sions, which melt at a lower temperature
In aluminum foundries, the furnace minum quality can be measured directly than FeS. Complex silicates also form
charge could be made up from a mixture or destructively from the solidified as slag on the surface of the melt.
of primary ingot, secondary (recycled) component. Direct measurement tends With ductile iron, the use of magne-
ingot, bought-in scrap, and in-house to be more expensive, but it is funda- sium to produce the nodularity of the
returns from the runners and feeders that mentally more accurate. Unfortunately, graphite phase creates problems via the
have been cut off in the fettling process. not all foundries use measurement formation of complex stable magnesium
It is unusual to start with only ingot but techniques. oxides and silicates. These problems are
that may be necessary to ensure certain Hydrogen and nitrogen can also cause exacerbated by turbulent filling.
alloy compositions (e.g., for aerospace problems with porosity in cast irons. In copper-based alloys, the main qual-
castings). Recycled aluminum alloy Cupola-melted iron is usually saturated ity problem is caused by oxygen, which
tends to have a higher iron content, with nitrogen. As the carbon content forms a eutectic with copper with a com-
which in turn results in higher levels of increases, the solubility levels decrease position of 0.39 wt.% oxygen. The Cu2O
detrimental iron-containing intermetal- (Table III). Silicon further decreases the will produce internal, endogenous oxide
lics. The two major defects that arise at solubility of nitrogen. Unlike hydrogen inclusions. This can be controlled with
this stage in the liquid metal are oxides in aluminum, the solubility of nitrogen the addition of elements that combine
and dissolved hydrogen. increases on solidification. The amount to form oxides more easily than copper
The level of oxide in the ingot will by which it increases depends on the does, such as lithium, boron, magnesium,
depend on the manufacturing route and carbon content of the first solidifying and phosphorus. Some copper alloys
supplier. Material that is supplied from phase. For hydrogen, the solubility in are also prone to dross formation; an
continuously cast billet tends to have a austenite is about the same as for the example of this is aluminum bronze,
lower oxide inclusion level than tradi- eutectic composition of liquid. In this where precautions similar to those for
➞
the velocity is less than the critical value,
Surface turbulence during
mould filling results in then metal entering through an orifice
film-to-film contact fills a cavity quiescently without surface
Liquid Metal breaking. This should not be confused
with bulk turbulence, because in the
➞
majority of casting regimes the Reyn-
olds number is far greater than 2,000,
even when there is no surface-breaking
turbulence.
In many cases, the films do not wet each More recent work from the research
other or bond and remain as crack-like defects The invisible defects lead to
in the liquid metal and in the solid casting premature failure in service group in Birmingham7 has indicated
that the Weber number is more relevant
➞
Figure 6. A schematic of the mechanism of surface film damage from turbulence.
to whether surface turbulence is going
Original image by R.A. Harding. to occur. Bulk turbulence is important
once the bubbles have been generated,
as the swirling and eddying in the liquid
aluminum alloys must be taken in run- velocity. The velocity, v, of a falling metal can fold up the oxide films into
ning and gating. stream can be calculated by concentrated regions of defect. These
will then act as nuclei for shrinkage
SURFACE TURBULENCE
v = 2gH (3) and dissolved gas evolution during the
(MENISCUS DAMAGE)
subsequent solidification processes.
“The liquid metal front should not go If we assume that the critical velocity If the critical velocity is exceeded
too fast. Critical meniscus velocity for is 0.5 ms–1 and the acceleration due to this can lead to folding in of the surface,
most liquid engineering alloys is in the gravity is 9.81 ms–2, then the distance, H, one of the most detrimental effects that
range 0.4 to 0.6 ms–2.” in millimeters that the metal has to fall to occur during casting. If the liquid surface
reach the critical velocity is given by: is covered by a solid oxide film, as is
Latest research has demonstrated that the case for a large number of casting
v2 0.52
for every liquid metal there is a critical H= = = 12.7 alloys, then the surface film is folded
velocity above which the surface will 2g 2 × 9.81 into the bulk of the metal, forming what
fold over and entrain itself in the bulk of This is stating that if the metal falls is essentially a crack in the liquid metal.
the metal. It has been postulated that the a distance greater than 12.7 mm, then The mechanism for the formation of
critical velocity, vcrit, can be given by there will be surface turbulence and the these double oxide films is described in
probability of oxide generation, which the series of schematics in Figure 6. If
γg γ
v crit ≈ 2 4 ≈ 3.54 4 (2)
ρ ρ Table I. Summary of Metal Quality Tests for Aluminum Alloys
Solid Samples Liquid Samples
where g is the acceleration due to gravity Name Technique Name Technique
in ms–2, γ is the surface tension in Nm,
Acoustic “Wheel tapping” RFDA PoDFA Filtration (pressure)
and ρ is the liquid density in kg/m–3.
Metallographic Small laboratory samples Prefil footprint Filtration (pressure)
For the metallic elements in the peri- Extraction Chemical/electrolytic LAIS/VFT Filtration (vacuum)
odic table, vcrit falls between 0.25 ms–1 Fast Neutron Oxygen determination Density separation Molten metal centrifuge
(Se) and 0.60 ms–1 (Be); for the most Fracture Bar Mechanical test LiMCA Coulter method Electrical
common engineering materials (i.e., Tool Wear Historical Ultrasonic Reflection of ultrasound
steel, Al, Cu, Mg, Zn, and Ni alloys) it
falls between 0.37 ms–1 (Zn) and 0.50 Table II. Summary of Hydrogen Measurement Tests for Aluminum4
ms–1 (Ti, Al). Essentially, the critical Reduced Pressure Tests Fundamental Tests
velocity is directly proportional to the
Name Technique Name Technique
fourth power of the ratio of surface
tension to density, so that there is little Straube-Pfeiffer Fixed pressure Ransley Probe Recirculating carrier gas
First Bubble Variable pressure Telegas Development of above
change throughout the periodic table.
Vibrated Vacuum Encourage gas bubbles AlSCAN Similar to above
In the majority of casting processes, Constant Volume Minimize shrinkage effects CHAPEL Direct partial pressure
the metal falls at some stage, either Density Index Magnify porosity NOTORP Solid-state galvanic cell
during transfer of liquid metal from one Hyscan QRP Hydrogen from sample Vacuum solid extraction Pressure rise
furnace to another or during the pouring Nitrogen carrier fusion Similar to Telegas
LECO Remelting test for chilled
of the casting itself. The metal does not
samples
have to fall very far to achieve the critical
100 µm
Figure 7. An SEM picture of aluminum oxide
film draped over dendrite tips in an A319 ▲
alloy (micrograph by G.E. Byczynski).
▲
▲
Figure 11. Bubble trail generation, movement, and trail collapse mechanisms in liquid
Figure 8. The meandering flow occurring
metals.11
in a horizontal plate casting.
c d
Figure 12. An SEM picture of bubbles
and their trails in a die-cast zinc alloy— Figure 13. (a) A schematic of core blow from a raised core13 (b) a
the largest bubble is about 0.5 mm macrograph of a core blow in a squeeze casting, and (c) and (d) a
diameter.11 macrograph and micrograph showing the bubble trail arising from
the core blow with the associated oxide film.
0.95
solidifies directionally toward the feeder.
0.90 To calculate the size of feeder required it
is therefore necessary to know how long
Figure 14. The density changes the casting is going to take to solidify,
0.85
in metals as they are heated as a
function of their room temperature
so that the feeder solidification time is
0.80 (RT) value. longer. M.C. Flemings15 proposed that
0 500 1,000 1,500 2,000 the solution of the partial differential
Temperature (ºC)
equations for the time of solidification
a c d
b Figure 20. An example of shrinkage
Figure 17. The effect of feeder geometry on the volume of metal available for feeding (a) created by convection in an aluminum
un-insulated cylinder, (b) hemisphere, (c) truncated cone, and (d) insulated cylinder.14 casting marked up by a foundry quality
inspector.