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To fully oxidize one mole of CH4, two moles of O2 is needed. Oxidation products are CO2 and
H2O. The stoichometry
It is of course also possible to calculate the chemical oxygen demand of other compounds. Take
for instance the VFAs:
Chemical oxygen demand can be measured experimentally by oxidizing a sample. Small kits are
available, where the sample is just dropped into a small vial containing strong oxidizing agent
and heated for a long period of time. Afterwards the vial is evaluated photometrically. The
change in color reflects how much could be oxidized in the sample.
Usually, chemical oxygen demand is measured in gCOD or in kgCOD. In the example above,
two moles of oxygen is needed to oxidize one mole of CH4. Therefore, the COD of 1 mole of
CH4 is the weight of two moles of oxygen. That is 64 g.
COD in the different boxes: composite material, carbohydrates, proteins, lipids, monosaccarides,
aminoacids, LCFA (long chained fatty acids), the volatile fatty acids (VFAs): valerate, butyrate,
propionate and acetate, and finally hydrogen and methane.
In the ADM1, all the COD in e.g. LCFA is converted into digestion products from the anaerobic
digestion of LCFA, and bacterial biomass. No COD is lost in such systems (mass balance)
except loss due to bacteria, substrates and products being washed out of the system.