PH

Cu 1:

NG PHP PHN TCH TH

PH NG PHP CHU N OXI HO KH

TCH

Cn 1,2540 gam oxalic tinhkhi t (H2C2O4.2H2O) ho tan thnh 250 mL dung d chchu n. 20,00 mL dung d chnydngchu n 22,40 mL dung d ch KMnO4. Tnhn ng ngl ngc a dung d ch KMnO4 vt s T[KMnO4/FeSO4].
Cu2:

Chu n 20,00 mL dung d ch H2C2 O4 h t 22,00 mL dung d chNaOH 0,04500 M. Chu n 25,00 mL dung d ch H2C2 O4trnh t 25,00 mL dung d ch KMnO4 (trong H2SO4 1M). Tnhn ng mol/l c a dung d ch KMnO4.
Cu3:

Ho tan 0,3085 g m tm ux ch a Fe2 O3trongHCl. Kh ion Fe3+thnh Fe2+b ng SnCl2. Chu n honton Fe2+thu c, h t 20,94 mL dung d ch KMnO4 0,01530 M a) Tnhhml ng % Fe theo Fe2 O3 ctrongm ux . b) Tnhs mL dung d ch K2Cr2 O7 0,0250 M c n chu n h tl ngs t(II) nitrn (chu n pH = 0).
Cu4:

Ho tan 1,147 g m tm u vitrongaxit, lmk tt a ion Ca2+d id ng CaC2 O4. Ch hok tt athu cv i 50,00 mL dung d ch KMnO4 0,02562 M trong H2SO4 1 M. L ngd KMnO4 ph n ngh tv i 10,08 mL dung d ch FeSO4 0,0950 M. Tnhhml ng % c aCatheoCaOctrongm u vi.
Cu5:

M tm uqu ngs tcnn ng 1,7950 g cho tan vkh thnhs tnh vpha ng 250,0 mL dung d chphntch. Bi tr ng 20,00 mL dung d chny cchu n b ng 18,65 mL dung d ch KMnO4 c T ! 0,001842 g. Tnh % Fe trongqu ng.
Cu6:

M tl idaoc olmb ngh pkim Fe-Cr. Ho tan 0,1331 g m utrong dung d ch H2SO4longr ichu n b ng KMnO4 h t 20,08 cm3 dung d chny. Bi tr ng chu n 10,00 cm3 H2C2 O4 0,0500 M khicm t H2SO4 ph idngh t 9,75 mL dung d ch KMnO4. 1) Vi tccph ngtrnhph n ng. 2) Tnhn ng mol/l c a dung d ch KMnO4. 3) Tnhhml ngs ttrongdaoc o (Ion Cr3+khngph n ngv i KMnO4 ).
Cu7:

Nungch y 1 gam m uch aMnO, Cr2O3 vt pch ttr v il ngd ch toxihom nh Na2 O2 thu ch nh pch a Na2MnO4 v Na2CrO4. Saukhiph n ngk tthc, ngu ih nh p, ho tan h nh pvon cvlmphnhu h tl ngd Na2 O2.Thmvol ngd dung d ch H2SO4, thu c

 2 dung d chch acc ion MnO4 , Cr2 O7  vk tt a MnO2. L cr ak tt athu

ck tt a MnO2 v dung

d ch B. Thmvo B 50 mL dung d ch FeSO4 0,1 M, l ng FeSO4 cnl itcd ngv a v i 18,4 mL dung d ch KMnO4 0,01 M. Thmvok tt a MnO2 10 mL dung d ch FeSO4 0,1 M (d ) vl ngd dung d ch H2SO4 dnglmmitr ng ho tan hontonk tt a MnO2. L ng FeSO4cnd l iph n ngv ah tv i 8,24 mL dung d ch KMnO4 0,01 M trongmitr ng H2SO4. 1) Vi tph ngtrnhph n ngx yra. 2) Tnh % theokh il ngc aMnOv Cr2 O3trongm u.
Cu8:

unch y 0,935 gam qu ngcromit (ch a Cr2O3 ) v i Na2 O2 oxiho Cr thnh CrO2  . Cho 4 kh ich yvon cv unsi phnhu h t Na2 O2. Axitho dung d ch, thm 50,00 mL dung d ch FeSO4 0,0800 m. Chu n l ng Fe2+d h t 14,85 mL dung d ch KMnO4 4,00.10 3 M. Vi tccph ngtrnhph n ngvtnh % Cr ctrongm uqu ng.
Cu9:

Ho tan 0,2486 gam K2Cr2O7tinhkhi tthnh 500 mL dung d chchu n K2Cr2 O7. Ht 25,00 mL dung d chny, thmm tl ngnh t nhHClv KI thchh pr ichu n b ng 25,05 mL dung d ch Nangl ngc a dung d ch Na2 S2O3 v chu nc a dung d ch . 2S2O3. Tnhn ng
Cu10:

M tm uc FeCl3 cnn ng 4,8900 g cho tan thnh 250 mL dung d chphntch. 25,00 mL dung d chny cchu n b ng 32,10 mL dung d ch Na2S2O3 0,0923 N trongmitr ngaxittrungbnhvcd KI. Tnh % FeCl 3trongm u ?
Cu 11:

Ho tan 0,2940 g K2 Cr2O7trongn cvchuy nvobnh nhm c 200,00 mL.Thmn c nv ch.L y 25,00 mL dung d chthu c, axithob ng H2SO4, thm KI d . Chu n I2 gi iphngrah t 10,00 mL dung d chNa2S2O3. Tnhn ng molv chu nc a dung d ch Na2S2 O3.
Cu 12:

Thm 100,00 mL dung d chHClvoh nh pg m KIO3 v KI (d ). Chu n iotgi iphngrah t 10,05 mL dung d ch Na2S2O3 0,01054 M. Tnhn ng dung d chHCl.
Cu 13:

Lmk tt ahontonchtrongm t dung d chmu ichd id ng PbCrO4. Ho tan k tt athu ctrongaxitkhic KI d . Chu n iotgi iphngrah t 23,50 mL dung d ch Na2S2O3 0,1025 M. Tnhs mg c achctrong dung d ch.
Cu 14:

nhl ngchng i ta lmk tt ahontonchd id ng PbCrO4, chok tt athu cph n ngv iHClcm t KI d . Chu n iotgi iphngrah t 28,75 mL dung d ch Na2S2 O3 0,05050 M. Tnhs gam chctrong dung d ch.

Cu 15:

Ho tan 0,4700 gam m th pkim ngtrongaxitr iphalongv in cthnh 200,00 mL.Axitho 30,00 mL dung d chnyb ng H2SO4, thm KI d . Chu n iotgi iphngrah t 7,00 mL dung d ch Na2S2 O3 0,10000 M. Tnhthnhph n % c a Cu trongh pkim.
Cu 16:

Ho tan 0,1475 g K2 Cr2O7trongbnh nhm c 250 mL vphalong nv ch nhm c. Dng pipet l y 50,00 mL dung d chthu c, axithob ng H2SO4 2N, thm KI d , chu n dung d chthu cb ng dung d ch Na2S2O3 cho nmuvngr m, thm 1 mL h tinhb tr ichu n ti pcho nm tmuxanh. Th tch dung d ch Na2S2O3tiuth l 9,54mL.Gi ithchqutrnhchu n .Tnhn ng molc a dung d ch Na2S2O3.
Cu 17:

Ho tan von c 2,000 g m tm u X ch a Na2S.9H2 O v Na2S2O3.5H2 O vt pch ttr , r iphalongthnh 250,00 mL (dung d ch A). Thm 25,00 mL dung d chiot 0,0525 M vo 25,00 mL dung d ch A, axithob ng H2SO4r ichu n iotd h t 12,90 mL dung d ch Na2S2O3 0,1010 M. M tkhccho dung d ch ZnSO4 d vo 50,00 mL dung d ch A. L cb k tt a, chu n dung d chn cl ch t 11,50 mL dung d chiot 0,01010 M. Tnhthnhph n % ccch ttrongh nh p X.
Cu18:

M tm uthpch a Cr cnn ng 1,1584 g cho tan r ioxihothnh Cr6+. Thmvo dung d chny 16,00 mL dung d chmu i Mohr, r ichu n l ngmu i Mohr th ab ng 2,70 mL dung d ch KMnO4. Bi tr ng 1,28 mL dung d ch KMnO4nyt ng ng 1,00 mL dung d chmu i Mohr v T[dung d chmu i Mohr/Cr] = 0,0008638 g. Tnh % Cr trongm uthp ? Cngth cmu i Mohr [(NH4 )2Fe(SO4)2.6H2 O].