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    Methane conversion and products selectivity affected by catalysts. Catalyst run empty zeolite reduced selectivity by 5%. Catalysts with higher selectivity also reduced selectivity.

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    Methane conversion and products selectivity affected by catalysts. Catalyst run empty zeolite reduced selectivity by 5%. Catalysts with higher selectivity also reduced selectivity.

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    17 views2 pages

    Table

    Uploaded by

    api-3728640
    Methane conversion and products selectivity affected by catalysts. Catalyst run empty zeolite reduced selectivity by 5%. Catalysts with higher selectivity also reduced selectivity.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOC, PDF, TXT or read online from Scribd
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    of 2

    Table 1.

    Effects of catalysts on methane conversion and products selectivity

    1 CH4 conv. selectivity (%)


    catalyst run
    (%) H2 C2H2 C2H6 C3H8 C4
    empty 1 7.51 34.52 5.13 35.73 11.73 4.81
    2 18.05 23.99 7.73 33.83 17.59 9.73
    3 21.11 34.63 6.93 35.37 19.59 0.00
    Al2O3 1 8.69 39.69 7.62 26.31 15.85 5.74
    2 14.23 27.19 9.82 38.64 15.78 0.00
    3 20.16 41.51 6.80 40.06 18.05 0.00
    3% Fe/ Al2O3 1 5.93 24.74 0.00 58.70 10.26 0.00
    2 12.11 34.39 11.40 44.79 16.53 0.00
    3 25.10 34.13 9.77 41.33 19.74 11.85
    3% Cu/ Al2O3 1 6.79 25.63 5.98 27.46 13.65 1.25
    2 19.09 21.52 6.26 29.32 11.58 0.00
    3 24.92 28.93 6.50 28.00 12.10 0.00
    1% Pt/ Al2O3 1 9.91 35.79 4.83 47.80 20.34 0.00
    2 13.57 41.05 3.15 50.68 20.38 0.00
    3 21.06 38.67 4.95 42.96 17.50 4.53
    3% Pt/ Al2O3 1 8.25 33.53 2.14 45.68 10.65 0.00
    2 17.56 35.12 1.58 48.95 14.65 2.63
    3 27.01 32.92 0.00 44.87 16.36 5.51
    3% Ni/ Al2O3 1 8.45 37.14 6.12 38.56 10.46 4.32
    2 15.64 30.49 5.46 32.87 13.65 0.00
    3 20.98 38.89 5.23 27.97 14.02 5.31
    5% Mn/ Al2O3 1 10.36 29.94 12.42 39.54 0.00 0.00
    2 15.24 30.26 10.26 36.45 5.62 4.16
    3 35.63 39.16 7.36 32.24 8.70 8.70
    3% Ru/ Al2O3 1 9.54 34.34 14.89 30.35 18.28 0.00
    2 15.63 30.25 8.63 29.63 11.25 2.36
    3 38.20 40.70 6.06 31.31 14.09 8.21
    zeolite 1 7.56 29.85 10.56 38.96 8.97 0.00
    2 13.29 30.88 10.03 36.37 7.67 0.00
    3 18.54 42.90 10.73 40.57 9.83 5.74
    3% Fe/ zeolite 1 8.52 30.25 2.39 60.35 9.57 1.23
    2 15.20 38.87 6.26 53.25 19.53 11.11
    3 22.01 34.32 10.23 58.43 7.70 0.00
    3% Cu/ zeolite 1 8.89 47.10 9.57 37.89 4.97 0.00
    2 15.67 30.03 13.83 36.59 1.37 1.94
    3 20.93 35.74 8.04 34.60 6.64 0.00
    3% Pt/ zeolite 1 7.65 38.10 4.91 50.52 10.56 0.00
    2 11.67 33.22 1.20 45.58 6.52 0.00
    3 20.16 31.04 5.44 46.05 4.23 0.00
    3% Ni/ zeolite 1 6.56 49.33 6.28 39.47 5.12 0.00
    2 16.28 46.45 13.23 36.92 4.63 0.00
    3 21.84 11.84 15.50 38.71 3.65 0.00
    3% Ru/ zeolite 1 6.22 35.57 8.04 35.94 2.15 0.00
    2 14.33 40.50 8.09 31.61 5.63 0.00
    3 22.89 38.95 12.92 42.10 3.11 0.00
    Note: 1Run 1 is flow rate: 30 ml/min, power: 35 W; run 2 is flow rate: 30 ml/min, power: 50 W; run 3 is
    flow rate: 15 ml/min, power 50 W.

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