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  • Ácido Monoprótico Fraco: Log (H+) Log (OH-) Log (HA) Log (A-)

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    Lu Machado
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    1. The document contains data on the equilibrium constants of various acids at different pH values. It includes graphs of fractional acid concentration (α) versus pH for weak monoprotic, strong monoprotic, and weak diprotic acids. 2. For weak monoprotic acids, as pH increases the fractional concentration of the conjugate base increases and approaches 1, following the expected sigmoidal curve. For strong monoprotic acids α approaches 1 more sharply. 3. For weak diprotic acids like H2CO3, there are two α values graphed versus pH, one for each proton dissociation, both again following sigmoidal curves but with different pKa values.

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    1. The document contains data on the equilibrium constants of various acids at different pH values. It includes graphs of fractional acid concentration (α) versus pH for weak monoprotic, strong monoprotic, and weak diprotic acids. 2. For weak monoprotic acids, as pH increases the fractional concentration of the conjugate base increases and approaches 1, following the expected sigmoidal curve. For strong monoprotic acids α approaches 1 more sharply. 3. For weak diprotic acids like H2CO3, there are two α values graphed versus pH, one for each proton dissociation, both again following sigmoidal curves but with different pKa values.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLS, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    12 views6 pages

    Ácido Monoprótico Fraco: Log (H+) Log (OH-) Log (HA) Log (A-)

    Uploaded by

    Lu Machado
    1. The document contains data on the equilibrium constants of various acids at different pH values. It includes graphs of fractional acid concentration (α) versus pH for weak monoprotic, strong monoprotic, and weak diprotic acids. 2. For weak monoprotic acids, as pH increases the fractional concentration of the conjugate base increases and approaches 1, following the expected sigmoidal curve. For strong monoprotic acids α approaches 1 more sharply. 3. For weak diprotic acids like H2CO3, there are two α values graphed versus pH, one for each proton dissociation, both again following sigmoidal curves but with different pKa values.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as XLS, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 6

    pH

    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14

    Monoprtico fraco (cido benzico)


    log[H+]
    log[OH-] log [HA]
    log[A-]
    [H]
    [A]
    -1
    -13 -1.000217
    -4.301247089
    0.099950025
    -2
    -12 -1.002166
    -3.303196057
    0.099502488
    -3
    -11 -1.021189
    -2.322219295
    0.095238095
    -4
    -10 -1.176091
    -1.477121255
    0.066666667
    -5
    -9 -1.778151
    -1.079181246
    0.016666667
    -6
    -8
    -2.70757
    -1.008600172
    0.001960784
    -7
    -7 -3.699838
    -1.000867722
    0.000199601
    -8
    -6 -4.699057
    -1.00008685
    0.000019996
    -9
    -5 -5.698979
    -1.000008686
    0.000001999
    -10
    -4 -6.698971
    -1.000000869
    0.000000199
    -11
    -3
    -7.69897
    -1.000000087
    0.00000002
    -12
    -2
    -8.69897
    -1.000000009
    0.000000002
    -13
    -1
    -9.69897
    -1.000000001 2^-10
    -14
    0 -10.69897
    -1 2^-11

    Cha
    0.00004998 pka
    0.00049762 ka
    0.00476211
    0.03333496
    0.08334892
    0.09817479
    0.09981596
    0.09998
    0.09999799
    0.099999799
    0.099999979
    0.099999997
    0.09999999
    0.1

    log C

    cido monoprtico fraco

    0
    -2
    -4
    -6
    -8
    -10
    -12
    -14
    -16

    10 11 12 13 14
    log[H+]
    log[OH-]
    log [HA]
    log[A-]

    pH

    Monoprtico fraco
    1
    pH 0
    1
    0.99950025
    0.0004998
    2 0.995024876
    0.0049762
    3 0.952380952
    0.0476211
    4 0.666666667
    0.3333496
    5 0.166666667
    0.8334892
    6 0.019607843
    0.9817479
    7 0.001996008
    0.9981596
    8
    0.00019996
    0.9998
    9
    0.00001999
    0.9999799
    10
    0.00000199
    0.99999799
    11
    0.0000002
    0.99999979
    12
    0.00000002
    0.99999997
    13
    0.00000002
    0.9999999
    14
    #VALUE!
    1

    0.1
    4.301029996
    0.00005

    Diagrama de distribuio cido fraco


    (alfa x pH)
    1.2
    1

    alfa

    0.8
    0.6
    0.4
    0.2
    0
    1

    8
    pH

    10 11 12 13 14

    Monoprtico forte HCl


    pH log[H+]
    log[OH-] log [HA]
    log[A-]
    [H]
    [A-]
    1
    -1
    -13
    -1
    -6.3 0.099999499
    5.01185E-07
    2
    -2
    -12 -1.00002 -5.30002 0.099994988
    5.01162E-06
    3
    -3
    -11 -1.00022 -4.30022 0.099949906
    5.00936E-05
    4
    -4
    -10 -1.00217 -3.30217 0.099501312
    0.000498688
    5
    -5
    -9 -1.02124 -2.32124 0.095227328
    0.004772672
    6
    -6
    -8 -1.17643 -1.47643 0.066613942
    0.033386058
    7
    -7
    -7 -1.77901 -1.07901 0.016633753
    0.083366247
    8
    -8
    -6 -2.70858 -1.00858
    0.00195623
    0.09804377
    9
    -9
    -5 -3.70087 -1.00087 0.000199129
    0.099800871
    10
    -10
    -4 -4.70009 -1.00009 1.99486E-05
    0.099980051
    11
    -11
    -3 -5.70001 -1.00001 1.99522E-06
    0.099998005
    12
    -12
    -2
    -6.7
    -1 1.99526E-07
    0.0999998
    13
    -13
    -1
    -7.7
    -1 1.99526E-08
    0.09999998
    14
    -14
    0
    -8.7
    -1 1.99526E-09
    0.099999998

    cido monoprtico forte


    0

    -2
    0

    -4

    loc C

    -6
    -8

    -10
    -12
    -14
    -16
    pH

    10

    11

    Cha
    pka
    ka

    0.1
    -6.3
    5.01187E-07

    pH
    1
    2
    3
    4
    5
    6
    7
    8
    9
    10
    11
    12
    13
    14

    Monoprtico fraco
    1
    0
    0.999994988 5.01185E-06
    0.999949884 5.01162E-05
    0.999499064 0.000500936
    0.995013121 0.004986879
    0.952273279 0.047726721
    0.666139425 0.333860575
    0.166337531 0.833662469
    0.019562304 0.980437696
    0.001991289 0.998008711
    0.000199486 0.999800514
    1.99522E-05 0.999980048
    1.99526E-06 0.999998005
    1.99526E-07
    0.9999998
    1.99526E-08
    0.99999998

    co forte

    Diagrama de distribuio alfa x pH cido forte


    1.2
    12

    13

    14

    1
    0.8

    log[H+]
    log[OH-]
    log [HA]
    log[A-]

    alfa

    11

    0.6
    0.4
    0.2
    0
    1

    8
    pH

    10 11

    cido Fraco Poliprtico H2CO3


    pH [H+]
    log[H+] alfa0
    1
    0.1
    -1
    0.99999875
    2
    0.01
    -2
    0.9999875
    3
    0.001
    -3
    0.999875016
    4
    0.0001
    -4
    0.998751561
    5
    0.00001
    -5
    0.98765432
    6
    0.000001
    -6
    0.888888781
    7
    0.0000001
    -7
    0.444441753
    8 0.00000001
    -8
    0.074066599
    9 0.000000001
    -9
    0.007927935
    10
    1E-10
    -10
    0.000790748
    11
    1E-11
    -11
    7.21319E-05
    12
    1E-12
    -12
    7.33934E-06
    13
    1E-13
    -13
    6.72269E-08
    14
    1E-14
    -14
    7.27273E-10

    lfa x pH cido forte

    Diagrama de distribuio alfa x pH do H2S (fraco)


    1.2
    1

    0
    1

    alfa

    0.8
    0.6
    0.4
    0.2
    0
    1

    8
    pH

    11 12 13 14

    10 11 12

    iprtico H2CO3
    alfa1
    1.25E-06
    1.24998E-05
    0.000124984
    0.001248439
    0.012345679
    0.111111098
    0.555552191
    0.925832485
    0.990991884
    0.988435307
    0.901648213
    0.478467068
    0.084033608
    0.009090909

    alfa2
    1.3625E-17
    1.36248E-15
    1.36233E-13
    1.3608E-11
    1.34568E-09
    1.21111E-07
    6.05552E-06
    0.000100916
    0.001080181
    0.010773945
    0.098279655
    0.521529104
    0.915966325
    0.99090909

    fa x pH do H2S (fraco)

    alfa0
    alfa1
    alfa2

    11 12 13 14

    Cha
    pka1
    pka2
    k1
    k2

    0.1
    6.9
    11.96
    0.000000125
    1.09E-12

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