DIAGRAMA DE LA VARIABLE FUNDAMENTAL

SOLUCION 0,01M H3PO4

Log C vs pH
0 [0,01M] H3PO4
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
-1
-2
-3
-4 Log [H3PO4]
-5 Log [H2PO4-]
-6 Log [HPO4-2]
Log C

-7 Log[PO4-3]
-8 log [H+]
Log[OH-]
-9
-10
-11
-12
-13
-14
pH

pH Log [H3PO4] Log [H2PO4-] Log [HPO4-2] Log[PO4-3] log [H+] Log[OH-]
0 -2.00E+00 -3.96E+00 -1.11E+01 -2.34E+01 0 -14
1 -2.05E+00 -3.00E+00 -9.13E+00 -2.04E+01 -1 -13
2 -2.32E+00 -2.28E+00 -7.41E+00 -1.77E+01 -2 -12
3 -3.08E+00 -2.04E+00 -6.16E+00 -1.55E+01 -3 -11
4 -4.05E+00 -2.00E+00 -5.13E+00 -1.34E+01 -4 -10
5 -5.05E+00 -2.00E+00 -4.13E+00 -1.14E+01 -5 -9
6 -6.07E+00 -2.03E+00 -3.16E+00 -9.48E+00 -6 -8
7 -7.28E+00 -2.24E+00 -2.37E+00 -7.69E+00 -7 -7
8 -8.97E+00 -2.93E+00 -2.05E+00 -6.37E+00 -8 -6
9 -1.09E+01 -3.88E+00 -2.01E+00 -5.32E+00 -9 -5
10 -1.29E+01 -4.88E+00 -2.00E+00 -4.32E+00 -10 -4
11 -1.49E+01 -5.90E+00 -2.02E+00 -3.34E+00 -11 -3
12 -1.71E+01 -7.05E+00 -2.17E+00 -2.49E+00 -12 -2
13 -1.97E+01 -8.64E+00 -2.76E+00 -2.08E+00 -13 -1
14 -2.26E+01 -1.06E+01 -3.69E+00 -2.01E+00 -14 0

DIAGRAMA DE LA VARIABLE FUNDAMENTAL

 SOLUCION 0,1 M H3PO4

Log C vs pH
0 [ 0,1M ] H3PO4
-1 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
-2
-3
-4 Log [H3PO4]
-5 Log [H2PO4-]
-6 Log [HPO4-2]
Log C

-7 Log[PO4-3]
-8 log [H+]
-9 Log[OH-]
-10
-11
-12
-13
-14
pH

pH Log [H3PO4] Log [H2PO4-] Log [HPO4-2] Log[PO4-3] log [H+] Log[OH-]
0 -1.00E+00 -2.96E+00 -1.01E+01 -2.24E+01 0 -14
1 -1.05E+00 -2.00E+00 -8.13E+00 -1.94E+01 -1 -13
2 -1.32E+00 -1.28E+00 -6.41E+00 -1.67E+01 -2 -12
3 -2.08E+00 -1.04E+00 -5.16E+00 -1.45E+01 -3 -11
4 -3.05E+00 -1.00E+00 -4.13E+00 -1.24E+01 -4 -10
5 -4.05E+00 -1.00E+00 -3.13E+00 -1.04E+01 -5 -9
6 -5.07E+00 -1.03E+00 -2.16E+00 -8.48E+00 -6 -8
7 -6.28E+00 -1.24E+00 -1.37E+00 -6.69E+00 -7 -7
8 -7.97E+00 -1.93E+00 -1.05E+00 -5.37E+00 -8 -6
9 -9.92E+00 -2.88E+00 -1.01E+00 -4.32E+00 -9 -5
10 -1.19E+01 -3.88E+00 -1.00E+00 -3.32E+00 -10 -4
11 -1.39E+01 -4.90E+00 -1.02E+00 -2.34E+00 -11 -3
12 -1.61E+01 -6.05E+00 -1.17E+00 -1.49E+00 -12 -2
13 -1.87E+01 -7.64E+00 -1.76E+00 -1.08E+00 -13 -1
14 -2.16E+01 -9.57E+00 -2.69E+00 -1.01E+00 -14 0

DIAGRAMA DE LA VARIABLE FUNDAMENTAL

SOLUCION 1 M H3PO4
 Log C vs pH
0
[ 1,0 M ] H3PO4
-1 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
-2
-3
Log [H3PO4]
-4
Log [H2PO4-]
-5
Log [HPO4-2]
-6
Log[PO4-3]
Log C

-7
log [H+]
-8
Log[OH-]
-9
-10
-11
-12
-13
-14
pH

pH Log [H3PO4] Log [H2PO4-] Log [HPO4-2] Log[PO4-3] log [H+] Log[OH-]
0 -4.75E-03 -1.96E+00 -9.09E+00 -2.14E+01 0 -14
1 -4.53E-02 -1.00E+00 -7.13E+00 -1.84E+01 -1 -13
2 -3.22E-01 -2.81E-01 -5.41E+00 -1.57E+01 -2 -12
3 -1.08E+00 -3.78E-02 -4.16E+00 -1.35E+01 -3 -11
4 -2.05E+00 -4.25E-03 -3.13E+00 -1.14E+01 -4 -10
5 -3.05E+00 -3.64E-03 -2.13E+00 -9.45E+00 -5 -9
6 -4.07E+00 -3.14E-02 -1.16E+00 -7.48E+00 -6 -8
7 -5.28E+00 -2.43E-01 -3.68E-01 -5.69E+00 -7 -7
8 -6.97E+00 -9.29E-01 -5.44E-02 -4.37E+00 -8 -6
9 -8.92E+00 -1.88E+00 -5.96E-03 -3.32E+00 -9 -5
10 -1.09E+01 -2.88E+00 -2.66E-03 -2.32E+00 -10 -4
11 -1.29E+01 -3.90E+00 -2.04E-02 -1.34E+00 -11 -3
12 -1.51E+01 -5.05E+00 -1.70E-01 -4.89E-01 -12 -2
13 -1.77E+01 -6.64E+00 -7.63E-01 -8.22E-02 -13 -1
14 -2.06E+01 -8.57E+00 -1.69E+00 -8.95E-03 -14 0
Eh (Volts) Mn - H2O - System at 25.00 C
2.0
MnO4(-a)

1.5

1.0
MnO2

0.5
MnO*OH
0.0
Mn3O4

-0.5
Mn(+2a) Mn(OH)2

-1.0

-1.5
Mn H2 O Limits
-2.0
0 2 4 6 8 10 12 14

C:\HSC6\EpH\MN25.IEP pH

ELEMENTS Molality Pressure

Mn 1.000E-02 1.000E+00