1/Ngi ta lp mt pin theo s :

(-)Ag|Ag+||Fe2+, Fe3+ |Pt(+)

vi nng [Fe2+]=[Fe3+]=0,1 M
a)Khi nng Ag+ bng bao nhiu th sc in ng ca pin bng 0?
b)Tnh hng s cn bng ca phn ng:
Fe2+ + Ag+ Fe3+ + Ag 298K.
Cho bit:

Fe3+ + e Fe2+ ;

E10 = 0,771V

E 02 = 0,799V
Ag+ + e Ag ;
Bi 9: Mui natri ca axit hipphotphor trong mi trng baz l 1 cht kh tt trong cng ngh m kim
loi
H2PO2- + 3OH- HPO32- + 2H2O + 2e ; Eo = 1,6V
a, N c th kh c dd mui km 1M thnh Zn kim loi trong mi trng baz khng?
b, Cu hi tng t i vi mui crm(III) 1M? Cho bit:
[Zn(OH)4]2- + 2e Zn(r) + 4OH- ; Eo = -1,22V
Cr(OH)3 + 3e Cr(r ) + 3OH- ; Eo = -1,3V
Bi 7:
a, Th chun ca cp Cu2+/Cu bng 0,34V. Mt dy Cu nhng vo dung dch CuSO4
102-M. Tnh th in cc.
b, Ha tan 0,1mol NH3 vo 100ml dung dch trn (b qua s thay i v th tch) v
chp nhn rng ch xy ra phn ng: Cu2+ + 4NH3 Cu(NH3)42+
Th in cc o c gim i 0,40V. Xc nh hng s bn ng (II) tetramin.
Bi 6: Cho cc in cc sau:
Cu| Cu2+ (1 M); Pt| Fe2+ (0,4M), Fe3+ (0,6 M); Ag, AgCl| Cl- (0,1 M);
Pt, H2 (p = 0,5 atm)| H+(0,1 M); Pt, Cl2 (p = 2 atm)| Cl- (0,5 M).
a, Tnh th in cc ca cc in cc 25oC. ( Eo(AgCl/Ag, Cl-) = + 0,224 V).
b, Vi cc in cc cho, c th lp c nhng pin no? (Vit s pin theo qui c ca IUPAC).
Tnh sc in ng ca pin. Vit cc phn ng in cc v phn ng xy ra khi pin hot ng.
Bi 5: (HSG QG 2004-2005)
pH = 0 v 25oC th in cc tiu chun Eo ca mt s cp oxi ho - kh c
cho nh sau:

2IO4 / I2 (r) 1,31 V ; 2IO 3 / I2 (r) 1,19 V ; 2HIO/ I 2 (r) 1,45 V ; I 2 (r)/ 2I
0,54 V.
1. Vit phng trnh na phn ng oxi ho - kh ca cc cp cho.

2. Tnh Eo ca cc cp IO4 / IO3 v IO3 / HIO

3. V phng din nhit ng hc th cc dng oxi ho - kh no l bn, cc
dng no l khng bn? Ti sao?
4. Thm 0,40 mol KI vo 1 lt dung dch KMnO4 0,24 M pH = 0
a) Tnh thnh phn ca hn hp sau phn ng.
b) Tnh th ca in cc platin nhng trong hn hp thu c so vi in cc
calomen bo ho.

5. Tnh Eo ca cp IO
3 / I2(H2O). I2(H2O) ch it tan trong nc.
Cho bit:MnO
Eo 4 /
= 1,51 V ; E ca in cc calomen bo ho bng
Mn2+
0,244 V ;
RT

25oC,
ln = 0,0592 lg ; tan ca it trong nc bng 5,0.10 4 M.
F
Cau 8:
a. Them t t NaOH vao 1 lt dung dch cha 0,2 mol Fe2+ va 0,2 mol Fe3+
co pH =1 cho ti khi pH = 5 th the ien cc cua dung dch o c la
0,152 Volt. Hoi chat nao ket tua trc va co khoi lng la bao

nhieu. Tnh tch so tan cua Fe(OH)3 (bo qua s thay oi the tch dung
dch). Cho E0Fe+/Fe+ = 0.77V. Fe = 56.
Cau 4. (3 iem)
Cho 4 gam PbSO4 tinh khiet vao 150 ml nc va khuay cho en khi can
bang dung dch tren phan ran c thiet lap. Sau o nhung mot
ien cc ch va mot ien cc oi chieu (E0 = 0,237V) vao dung dch.
Ngi ta o c 298K mot hieu ien the E = 0,478V; E 0Pb2+/Pb =
-0,126V.
1. Hay cho biet
ien cc nao trong hai ien cc tren co the thap hn. ien cc nao
la catot, ien cc nao la anot. Tnh tch so tan cua PbSO4. Cho biet mau
PbSO4 se khong cho vao nc ma cho vao 150 ml dung dch H 2SO4 co pH
= 3. Hay giai thiet rang axit sunfuric a b proton hoa hoan toan.
2. Hieu ien the nao co the co gia ien cc ch va ien cc oi
chieu. Tai mot nhiet o nhat nh th tch so tan cua PbSO 4 la T =
1,1.10-8. Cho 3 hang so can bang di ay:

PbI2 (r ) + SO42- , K1 = 4,6.10-1

PbSO4 (r ) + 2I-

PbCrO + 2I- , K = 4,3.10-12

PbI + CrO 2-
2

PbCrO4 + S2- , K3 = 7,5.10-8

PbS + CrO42-
3. Hay tnh tch so tan cua PbS.
Mt axit hai cha H2A tham gia vo cc phn ng phn li sau:
H2A HA- + H+ K1 = 4,50.10-7
HA- A2- + H+ K2 = 4,70.10-11.
Mt mu 20,00mL dung dch cha hn hp Na2A v NaHA c chun vi axit clohydric 0,300M. Qu
trnh chun c thc hin vi mt pH - k in cc thy tinh. Hai im tng ng trn ng cong
chun nh sau: S mL HCl thm vo pH
1,00
10,33
v
10,00
8,34
1) Khi thm 1,00mL HCl, tiu phn no phn ng trc ht v to sn phm g?
2) Lng sn phm to thnh (mmol) cu 1 l bao nhiu?
3) Vit cn bng chnh ca sn phm cu 1 tc dng vi dung mi
4) Lng (mmol) Na2A v NaHA c mt lc u?
5) Tnh tng th tch ca HCl cn thit t n im tng ung th hai.
1/ Dung dch A c to thnh bi CoCl2 0,0100M; NH 3 0,3600M v H 2 O2 3, 00.103 M .
a, Tnh pH v nng ion Co 2+ trong dung dch A.
b, Vit s pin v sc in ng E ca pin c to thnh bi in cc Pt nhng trong dung dch A vi
in cc Ag nhng trong dich dch AgNO3 8, 0.103 M
0
0
0
+
Cho: pK a ca NH 4 l 9,24; ECo3+ / Co2 + :1,84V ; EH 2O2 /2OH : 0,94V ; E Ag + / Ag : 0, 799V ;

RT
ln = 0, 0592 lg
F

Cho hng s bn ca phc : Co3+ + 6NH3 Co(NH3)63+ ; lg 1 = 35,16

Co2+ + 6NH3 Co(NH3)62+ ; lg 2 = 4,39
Bi 3: Cho cc cp oxi ha kh: E0Cu2+/Cu+ = E01 = 0,15V; E0I2/2I- = E02 = 0,62V
a, Vit cc phng trnh phn ng oxi ha kh v phng trnh Nernst tng ng. iu kin chun
c th xy ra s oxi ha I- bng Cu2+?
b, Khi dung dch KI vo dung dch Cu2+ thy c phn ng:
Cu2+ + 2I- CuI + 1/2I2
Hy xc nh hng s cn bng ca phn ng trn. Bit tch s tan T ca CuI l 10-12.