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Jianxin Wang
P & Sc Group PRRC, New Mexico Tech Oct. 18, 2000
Outline
What is asphaltene? Why to study asphaltene? How to characterize asphaltene stability in crude oil?
Asphaltenes are the most heavy and polar components in crude oil
Crude oil
Saturates
Aromatics
Resins
Asphaltenes (0-20%)
S
nonpolar
Asph. (wt%)
30
20
10
10
12
Asph. (wt%)
6 5 4 3 2 1 0 2 5 10 20 50
Mars-pink
100 200 500
Mars-pink/nC7=1/10
Asph. (wt%)
Molecular weight
n-C5 asph.
polarity = N, S, O aromaticity =
OH N S S N N S S S O
Speight, J.G.: "A Chemical and Physical Explanation of Incompatibility during Refining Operations," Proc. 4th Intl. Conf. on the Stability and Handling of Liquid Fuels, US Dept. Energy, 169 (1992).
Buckley, J.S.: "Asphaltenes: Separating Fact from Fiction," SPE Distinguished Lecture Slides (1998-99).
Outline
What is asphaltene? Why to study asphaltene? How to characterize asphaltene stability in crude oil?
plugging reservoir
Asphaltene Flocculation
poisoning refinary catalysts altering wettability
Asphaltene stability
Temperature Pressure
High asphaltene content is not necessary to associate with high risk of trouble
troublesome
100
troublefree
asphaltenes resins
80
Weight %
60
40
aromatics saturates
20
10 11 12 13 14 15 16 17 18 19
troublefree
1.50
PRI
RI
1.45
Low RI
1.40 1 2 3 4 5 6 7 8
High RI
9 10 11 12 13 14 15 16 17 18 19
Oil #
Buckley, J.S.: "Asphaltenes: Separating Fact from Fiction," SPE Distinguished Lecture Slides (1998-99).
Outline
What is asphaltene? Why to study asphaltene? How to characterize asphaltene stability in crude oil?
crude oil
PRI
redissolved
maltene
alkane
flocculated
Volume fraction
Buckley, J.S.: "Asphaltenes: Separating Fact from Fiction," SPE Distinguished Lecture Slides (1998-99).
Low RI
Buckley, J.S.: "Asphaltenes: Separating Fact from Fiction," SPE Distinguished Lecture Slides (1998-99).
RI measurement
sample
GPR-11-37
refractometer
RI accuracy = 0.0001 T: 10 ~ 70 C
n=
1 sin()
3 2
n-C15
PRI 1.47
1.46 1.45 1.44
n-C9
n-C5
Time (day)
3
A-93 A-95 Lagrave Lost Hills Mars-pink Tensleep
10
12
14
16
Chain-length of n-alkane
PRI
10
12
14
16
Chain-length of n-alkane
PRI
11
12
13
14
15
16
17
vp
Conclusions
Asphaltene molecules are polyaromatics with side chains. They exist in crude oils as monomer and micelles equilibrated to each other. The sizes of asphaltene micelles fall in colloidal range. Asphaltene flocculation occurs when oil solvency is reduced. Flocculated asphaltene could have detrimental effects on oil production, transportation and refinary process. Refractive index (RI) is a simple, readily measurable parameter for characterizing crude oil solvency with respect to asphaltene stability.