THI TH HIDROCACBON 11 --------CHC CC BN THNH CNG----Cu 1: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t.

Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,2 mol C2H4 v 0,1 mol C2H2. C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4. (H A/2009)

Cu 2: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l A. 20%. B. 25%. C. 50%. D. 40 (C A/2009)

Cu 3: Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l A. 16,0. B. 3,2. C. 8,0. D. 32,0. (C A/2009)

Cu 4: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau o khi phn ng vi H2 (d, xc tc Ni, t ), cho cng mt sn phm l: A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis-but-2-en v xiclobutan. (C A/2009)

Cu 5: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=C(CH3)2. B. CH2=CH2. C. CH2=CH-CH2-CH3. D. CH3-CH=CH-CH3. (H B/2009)

Cu 6: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l A. 20%. B. 50%. C. 25%. D. 40%. (H B/2009)

Cu 7: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en. B. xiclopropan. C. but-2-en. D. propilen. (H B/2009)

Cu 8: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l A. 1,04 gam. B. 1,32 gam. C. 1,64 gam. D. 1,20 gam. (H A/2008) Cu 9: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l A. 20,40 gam. B. 18,60 gam. C. 18,96 gam. D. 16,80 gam. (H A/2008)

Cu 10: Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn 3 th cn V m kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) A. 358,4. B. 448,0. C. 286,7. D. 224,0. (H A/2008)

Cu 11: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A. 2. B. 3. C. 1. D. 4. (H A/2008)

Cu 12: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A. 25,8. B. 12,9. C. 22,2. D. 11,1. (C A/2008)

Cu 13: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l A. C2H2 v C4H6. B. C2H2 v C4H8. C. C3H4 v C4H8. D. C2H2 v C3H8 (H A/2007)

Cu 14: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A. C3H6. B. C3H4. C. C2H4. D. C4H8. (H A/2007)

Cu 15: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). (H A/2007)

Cu 16: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l A. C3H8. B. C3H6. C. C4H8. D. C3H4. (H A/2007) 2

Cu 17: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho th tch dung dch thay i khng ng k) A. C4H9OH v C5H11OH. B. C3H7OH v C4H9OH. C. C2H5OH v C3H7OH. D. C2H5OH v C4H9OH. (C B/2007) Cu 18: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng A. 8,96. B. 5,60. C. 11,2. D. 13,44 (C B/2007)

Cu 19: Hp cht u v cc hp cht trung gian trong qu trnh iu ch ra cao su buna (1) l : etilen (2), metan (3), ancol etylic (4), ivinyl (5), axetilen (6). Sp xp cc cht theo ng th t xy ra trong qu trnh iu ch l A. 362451. C. 263451. B. 642531 D. 463251

Cu 20: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. xiclohexan. B. xiclopropan. C. stiren. D. etilen. (H A/2009)

Cu 21: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l A. C6H14. B. C3H8. C. C4H10. D. C5H12. (H A/2008)

Cu22: Hn hp X gm hiro, hirocacbon khng no v hirocacbon no. Cho X vo bnh c Ni xc tc, un nng bnh mt thi gian ta thu c hn hp Y. Nhn xt no sau y ng: A. S mol X s mol Y = s mol hiro phn ng. B. Khi lng X = khi lng Y. C. S mol O2 tiu tn, s mol CO2 v H2O to thnh khi t chy hon ton X cng y ht khi ta t chy hon ton Y. D. C A, B, C u ng. Cu 23: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. 2-Metylpropan. C. 2,2-imetylpropan. D. etan. (C A/2008) Cu 24: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l A. 2. B. 3. C. 5. D. 4. (H A/2008) 3

Cu 25: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l A. 56,0 lt. B. 78,4 lt. C. 84,0 lt. D. 70,0 lt. (C B/2007)

Cu 26: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l A. 3-metylpentan. B. 2,3-imetylbutan. C. 2-metylpropan. D. butan. (C B/2007)

Cu 27 : Cho cc cu sau: (1) Ankaien l nhng hirocacbon khng no, mch h c 2 lin kt i trong phn t. (2) Nhng hirocacbon c 2 lin kt i trong phn t l ankaien -1,3. (3) Nhng hirocacbon c 2 lin kt i trong phn t l ankaien. (4) Nhng hirocacbon c kh nng cng hp vi 2 phn t hiro thuc loi ankaien. (5) Ankaien lin hp l nhng hirocacbon khng no, mch h, trong phn t c 2 lin kt i cnh nhau. (6) Nhng hirocacbon khng no, mch h, trong pt c 2 lin kt i cch nhau mt lin kt n gi l ankaien lin hp. Nhng cu ng l A. (1), (3), (4), (5) Cu 28: Cht B. (1), (6)
| 3 5

C. (1), (2), (4), (6) c tn gi l: C. 3-metyl hexen

C. Tt c cc cu trn

CH 3-CH= CH-CH-CH CH
2

A. 4-etyl pent-2-en

B. 3-metyl hex-4-en

D. 4-metyl hex-2-en

Cu 29: Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca A. anken. B. ankin. C. ankaien. D. ankan. (C A/2008) Cu 30: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l A. 35% v 65%. B. 75% v 25%. C. 20% v 80%. D. 50% v 50%. (C A/2008)

Cu 31 Etilen tc dng vi kh Cl2 5000C to sn phm hu cl: A. 1,2-icloetan B. Vinylclorua C. Etylclorua D. hiroclorua

Cu 32: C th s dng cp thuc th no trong s cc cp thuc th sau phn bit 4 cht lng: n-hexan, hexen-2, dung dch NaCl v dung dch NH3 ng trong cc l mt nhn ? A. Qu tm, dung dch AgNO3. C. Dung dch HCl, dung dch Br2. B. Dung dch AgNO3, dung dch Br2. D. Kh Cl2, dung dch KMnO4.

Cu 33: Ho tan hn hp rn gm CaC2, Al4C3, Ca vo nc, thu c 2,24 lt (kc) hn hp kh X c

d X / H 2 = 10 . Dn X qua bnh cha Ni nung nng thu c hn hp kh Y; tip tc cho Y qua bnh ng Br 2 th

thu c 0,56 lt kh Z (kc) c d Z / H 2 = 13 . Khi lng bnh ng Br2 tng ln A. 1,35 gam B. 1,55 gam C. 0,89 gam D. Kt qu khc.

Cu 34:

phn bit cc kh C2H4, CH4, C2H2 v butadien-1,3 cha trong cc l mt nhn, c th s dng B. Dung dch AgNO3/NH3(d), dung dch Br2. D. Dung dch Ca(OH)2, dung dch AgNO3/NH3(d).

nhng thuc th l A. Dung dch Br2, dung dch KMnO4. C. Kh Cl2, dung dch Br2.

Cu 35: t chy hon ton hrocacbon A c

VC O : VH O = 2, ( 5 2 2

cng iu kin). Bit MA <100. TmCTCT

ca A, bit: 6,4 gam A phn ng vi AgNO3/NH3 c 27,8 gam kt ta. A. CH2=C=CH-C CH C. CH3C CCH2C CH B. CH CCH2C CH D. CH3C CCH2C CH

Cu 36: Pht biu no sau y ng vi quy tc cng Maccopnhicop ? Trong phn ng cng mt tc nhn HA vo ni i ca mt anken bt i xng: A. Phn dng in ca tc nhn gn vo C c nhiu hiro hn. B. Phn dng in ca tc nhn nh vo C mang ni i c bc cao hn. C. Hiro ca tc nhn nh vo C mang ni i c nhiu hiro hn. D. Hiro ca tc nhn gn vo C c tng i t hiro hn. Cu 37 Trn 2 th tch bng nhau ca C3H8 v O2 ri em t. Sau khi cho hi nc ngng t, a tr v iu B. V < Vs C. V > Vs 5 D. V = Vs kin ban u. Nhn xt g v Vhn hp trc p (V) v Vhh. sau p (Vs) ? A. V : Vs = 3

Cu 38 Hai anken c CTPT C3H6 v C4H8 khi phn ng vi HBr thu c 3 sn phm, vy 2 anken l: A. Propilen v buten-1 C. Propen v buten-2 B. Propen-1 v buten-2 D. Propilen v iso-butilen

Cu 39:

t hon ton hn hp 2 hirocacbon ( X v Y) c khi lng phn t hn km nhau 14 vC, thu B. Trong hn hp c t nht mt ankan D. (X), (Y) l 2 ankan k tip nhau.

c m (gam) H2O v 2m (gam) CO2. Pht biu no sau y chnh xc nht ? A. (X), (Y) thuc cng mt dy ng ng C. (X), (Y) l 2 anken k tip nhau.

Cu 40:

Cho cc ankan C2H6, C3H8, C4H10, C5H12, C6H14, C7H16, C8H18. Ankan no tn ti ng phn khi tc B. C5H12, C6H14, C7H16 D. C2H6, C5H12, C8H18.

dng vi Cl2 theo t l mol 1:1 to ra dn xut monoclo ankan duy nht? A. C2H6, C3H8, C4H10, C5H12 C. C6H14, C7H16, C8H18