B GIO DC V O TO CHNH THC

( thi c 05 trang)

THI TUYN SINH I HC, CAO NG NM 2007 Mn thi: HO HC, Khi A Thi gian lm bi: 90 pht. M thi 182

H, tn th sinh:.......................................................................... S bo danh:............................................................................
PHN CHUNG CHO TT C TH SINH (44 cu, t cu 1 n cu 44): Cu 1: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12) B. C2H2 v C4H8. C. C3H4 v C4H8. D. C2H2 v C3H8. A. C2H2 v C4H6. Cu 2: Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l A. 0,04. B. 0,075. C. 0,12. D. 0,06. Cu 3: Nh t t cho n d dung dch NaOH vo dung dch AlCl3. Hin tng xy ra l A. c kt ta keo trng, sau kt ta tan. B. ch c kt ta keo trng. C. c kt ta keo trng v c kh bay ln. D. khng c kt ta, c kh bay ln. Cu 4: Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta un nng dung dch amoni nitrit bo ho. Kh X l A. NO. B. NO2. C. N2O. D. N2. + 2 2 Cu 5: Dy gm cc ion X , Y v nguyn t Z u c cu hnh electron 1s 2s 2p6 l: A. Na+, Cl-, Ar. B. Li+, F-, Ne. C. Na+, F-, Ne. D. K+, Cl-, Ar. Cu 6: Mnh khng ng l: A. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3. B. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui. C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2. D. CH3CH2COOCH=CH2 c th trng hp to polime. Cu 7: Dy cc ion xp theo chiu gim dn tnh oxi ho l (bit trong dy in ha, cp Fe3+/Fe2+ ng trc cp Ag+/Ag): A. Ag+, Cu2+, Fe3+, Fe2+. B. Fe3+, Cu2+, Ag+, Fe2+. D. Fe3+, Ag+, Cu2+, Fe2+. C. Ag+, Fe3+, Cu2+, Fe2+. 2+ Cu 8: Anion X v cation Y u c cu hnh electron lp ngoi cng l 3s23p6. V tr ca cc nguyn t trong bng tun hon cc nguyn t ha hc l: A. X c s th t 17, chu k 4, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). B. X c s th t 18, chu k 3, nhm VIA (phn nhm chnh nhm VI); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). C. X c s th t 17, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). D. X c s th t 18, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 3, nhm IIA (phn nhm chnh nhm II). Cu 9: Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16) A. C3H7N. B. C2H7N. C. C3H9N. D. C4H9N. Cu 10: Cho 15,6 gam hn hp hai ancol (ru) n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l (cho H = 1, C = 12, O = 16, Na = 23) A. C3H5OH v C4H7OH. B. C2H5OH v C3H7OH. D. CH3OH v C2H5OH. C. C3H7OH v C4H9OH.
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Cu 11: Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng thi khuy u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c xut hin kt ta. Biu thc lin h gia V vi a, b l: A. V = 22,4(a - b). B. V = 11,2(a - b). C. V = 11,2(a + b). D. V = 22,4(a + b). Cu 12: Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo. Hai loi axit bo l (cho H = 1, C = 12, O = 16) A. C15H31COOH v C17H35COOH. B. C17H33COOH v C15H31COOH. C. C17H31COOH v C17H33COOH. D. C17H33COOH v C17H35COOH. Cu 13: Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5) A. 3. B. 6. C. 4. D. 5. Cu 14: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40) A. 20. B. 40. C. 30. D. 10. Cu 15: Cho cc phn ng sau: b) FeS + H2SO4 (c, nng) a) FeO + HNO3 (c, nng) c) Al2O3 + HNO3 (c, nng) d) Cu + dung dch FeCl3 Ni, t o e) CH3CHO + H2 f) glucoz + AgNO3 (hoc Ag2O) trong dung dch NH3 g) C2H4 + Br2 h) glixerol (glixerin) + Cu(OH)2 Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l: A. a, b, d, e, f, h. B. a, b, d, e, f, g. C. a, b, c, d, e, h. D. a, b, c, d, e, g. Cu 16: Khi nung hn hp cc cht Fe(NO3)2, Fe(OH)3 v FeCO3 trong khng kh n khi lng khng i, thu c mt cht rn l A. Fe3O4. B. FeO. C. Fe. D. Fe2O3. Cu 17: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) B. C3H4. C. C2H4. D. C4H8. A. C3H6. Cu 18: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16) A. CH3CHO. B. HCHO. C. CH3CH2CHO. D. CH2 = CHCHO. Cu 19: Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt ( ktc) hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l (cho H = 1, N = 14, O = 16, Fe = 56, Cu = 64) A. 2,24. B. 4,48. C. 5,60. D. 3,36. Cu 20: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 21: Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt ta th cn c t l A. a : b = 1 : 4. B. a : b < 1 : 4. C. a : b = 1 : 5. D. a : b > 1 : 4. Cu 22: Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l A. 8. B. 5. C. 7. D. 6. Cu 23: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l (cho Na = 23, Ag = 108) A. HCHO. B. CH3CHO. C. OHC-CHO. D. CH3CH(OH)CHO. Cu 24: Hp th hon ton 2,688 lt kh CO2 ( ktc) vo 2,5 lt dung dch Ba(OH)2 nng a mol/l, thu c 15,76 gam kt ta. Gi tr ca a l (cho C = 12, O = 16, Ba = 137) A. 0,032. B. 0,048. C. 0,06. D. 0,04.

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Cu 25: nhn bit ba axit c, ngui: HCl, H2SO4, HNO3 ng ring bit trong ba l b mt nhn, ta dng thuc th l A. Fe. B. CuO. C. Al. D. Cu. Cu 26: Cho s Cl2 (t l mol 1:1) NaOH c (d) axit HCl C6H6 (benzen) Y Z. X o o t cao, p cao Fe, t Hai cht hu c Y, Z ln lt l: A. C6H6(OH)6, C6H6Cl6. B. C6H4(OH)2, C6H4Cl2. C. C6H5OH, C6H5Cl. D. C6H5ONa, C6H5OH. Cu 27: in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catt v mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung dch NaOH l (cho Cu = 64) A. 0,15M. B. 0,2M. C. 0,1M. D. 0,05M. Cu 28: Nilon6,6 l mt loi A. t axetat. B. t poliamit. C. polieste. D. t visco. Cu 29: Pht biu khng ng l: A. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c phenol. C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin. D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu c natri phenolat. Cu 30: Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng trnh phn ng gia Cu vi dung dch HNO3 c, nng l A. 10. B. 11. C. 8. D. 9. Cu 31: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5) A. H2NCH2COOH. B. H2NCH2CH2COOH. D. CH3CH(NH2)COOH. C. CH3CH2CH(NH2)COOH. Cu 32: Ho tan 5,6 gam Fe bng dung dch H2SO4 long (d), thu c dung dch X. Dung dch X phn ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V l (cho Fe = 56) A. 80. B. 40. C. 20. D. 60. Cu 33: Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l (cho H = 1, C = 12, O = 16, Ca = 40) A. 550. B. 810. C. 650. D. 750. Cu 34: Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l A. 3. B. 5. C. 2. D. 4. Cu 35: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23) A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam. Cu 36: Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l (cho H = 1, C = 12, O = 16) A. 10,12. B. 6,48. C. 8,10. D. 16,20. Cu 37: t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l A. HOOC-CH2-CH2-COOH. B. C2H5-COOH. C. CH3-COOH. D. HOOC-COOH.
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Cu 38: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l (cho H = 1, C = 12, N = 14, O = 16, Na = 23) A. 16,5 gam. B. 14,3 gam. C. 8,9 gam. D. 15,7 gam. Cu 39: Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai dung dch tng ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li) A. y = 100x. B. y = 2x. C. y = x - 2. D. y = x + 2. Cu 40: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y c pH l A. 1. B. 6. C. 7. D. 2. Cu 41: Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao. Sau phn ng hn hp rn cn li l: A. Cu, Fe, Zn, MgO. B. Cu, Fe, ZnO, MgO. C. Cu, Fe, Zn, Mg. D. Cu, FeO, ZnO, MgO. Cu 42: chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch glucoz phn ng vi A. kim loi Na. B. AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. C. Cu(OH)2 trong NaOH, un nng. D. Cu(OH)2 nhit thng. Cu 43: Trong phng th nghim, ngi ta thng iu ch clo bng cch A. in phn nng chy NaCl. B. cho dung dch HCl c tc dng vi MnO2, un nng. C. in phn dung dch NaCl c mng ngn. D. cho F2 y Cl2 ra khi dung dch NaCl. Cu 44: Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh ba anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l A. (CH3)3COH. B. CH3OCH2CH2CH3. C. CH3CH(OH)CH2CH3. D. CH3CH(CH3)CH2OH. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II) Phn I. Theo chng trnh KHNG phn ban (6 cu, t cu 45 n cu 50): Cu 45: Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M (va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l (cho H = 1, O = 16, Mg = 24, S = 32, Fe = 56, Zn = 65) A. 6,81 gam. B. 4,81 gam. C. 3,81 gam. D. 5,81 gam. Cu 46: Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp cht nng chy ca chng, l: A. Na, Ca, Al. B. Na, Ca, Zn. C. Na, Cu, Al. D. Fe, Ca, Al. Cu 47: Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l: A. anehit axetic, butin-1, etilen. B. anehit axetic, axetilen, butin-2. C. axit fomic, vinylaxetilen, propin. D. anehit fomic, axetilen, etilen. Cu 48: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16) B. C3H6. C. C4H8. D. C3H4. A. C3H8. Cu 49: Mnh khng ng l: A. Fe2+ oxi ho c Cu. B. Fe kh c Cu2+ trong dung dch. C. Fe3+ c tnh oxi ha mnh hn Cu2+. D. Tnh oxi ha ca cc ion tng theo th t: Fe2+, H+, Cu2+, Ag+.
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Cu 50: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16) A. H2N-CH2-COO-C3H7. B. H2N-CH2-COO-CH3. C. H2N-CH2-CH2-COOH. D. H2N-CH2-COO-C2H5. Phn II. Theo chng trnh phn ban (6 cu, t cu 51 n cu 56): Cu 51: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 0,342. B. 2,925. C. 2,412. D. 0,456. Cu 52: Pht biu khng ng l: A. Hp cht Cr(II) c tnh kh c trng cn hp cht Cr(VI) c tnh oxi ho mnh. B. Cc hp cht Cr2O3, Cr(OH)3, CrO, Cr(OH)2 u c tnh cht lng tnh. C. Cc hp cht CrO, Cr(OH)2 tc dng c vi dung dch HCl cn CrO3 tc dng c vi dung dch NaOH. D. Thm dung dch kim vo mui icromat, mui ny chuyn thnh mui cromat. Cu 53: thu ly Ag tinh khit t hn hp X (gm a mol Al2O3, b mol CuO, c mol Ag2O), ngi ta ho tan X bi dung dch cha (6a + 2b + 2c) mol HNO3 c dung dch Y, sau thm (gi thit hiu sut cc phn ng u l 100%) A. c mol bt Al vo Y. B. c mol bt Cu vo Y. C. 2c mol bt Al vo Y. D. 2c mol bt Cu vo Y. Cu 54: Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn ng c vi (CH3)2CO l A. 2. B. 4. C. 1. D. 3. Cu 55: C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) ri thm tip dung dch NH3 (d) vo 4 dung dch trn th s cht kt ta thu c l A. 4. B. 1. C. 3. D. 2. Cu 56: Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca este l B. HCOO-C(CH3)=CH2. A. CH2=CH-COO-CH3. C. HCOO-CH=CH-CH3. D. CH3COO-CH=CH2.
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