Ti liu n thi H-C 2010

Chuyn :

B. TRC NGHIM BI TP AMIN - AMINO AXIT V PROTEIN.

Cu 47 : Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l
A. 8,15 gam
B. 0,85 gam
C. 7,65 gam
D. 8,10 gam
Cu 48 : Th tch nc brom 3% (d = 1,3g/ml) cn dng iu ch 4,4g tribormanilin l
A. 164,1ml.
B. 49,23ml.
C 146,1ml.
D. 16,41ml.
Cu 49 : Khi lng anilin cn dng tc dng vi nc brom thu c 6,6g kt ta trng l
A. 1,86g.
B. 18,6g.
C. 8,61g.
D. 6,81g.
Cu 50 : Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu
c 15,06 gam mui. X c th l :
A. axit glutamic.
B. valin.
C. glixin
D. alanin.
Cu 51 : 1 mol -aminoaxit X tc dng va ht vi 1 mol HCl to ra mui Y c hm lng clo l 28,287%. CTCT ca
X l
A. CH3 CH(NH2) COOH.
B. H2N CH2 CH2 COOH.
C. NH2 CH2 COOH.
D. H2N CH2 CH(NH2) COOH.
Cu 52 : Khi trng ngng 13,1g axit -aminocaproic vi hiu sut 80%, ngoi aminoaxit cn d ngi ta thu c m
gam polime v 1,44g nc. Gi tr m l
A. 10,41g.
B. 9,04g.
C. 11,02g.
D. 8,43g.
Cu 53 : Mt amin n chc cha 19,718% nit v khi lng. CTPT ca amin l
A. C4H5N.
B. C4H7N.
C. C4H9N.
D. C4H11N.
Cu 54 : t chy hon ton mt amin no n chc thu c VH2O = 1,5VCO2. CTPT ca amin l
A. C2H7N.
B. C3H9N.
C. C4H11N.
D. C5H13N.
Cu 55 : Cho 3,04g hn hp A gm 2 amin no n chc tc dng va vi 400ml dd HCl 0,2M c 5,96g mui.
Tm th tch N2 (ktc) sinh ra khi t ht hn hp A trn ?
A. 0,224 lt.
B. 0,448 lt.
C. 0,672 lt.
D. 0,896 lt.
Cu 56 : Cho 17,7g mt ankylamin tc dng vi dd FeCl3 d thu c 10,7g kt ta. CTPT ca ankylamin l
A. C2H7N.
B. C3H9N.
C. C4H11N.
D. CH5N.
Cu 57. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M,
ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit?
A. 100ml
B. 50ml
C. 200ml
D. 320ml
Cu 58 : Cho 0,01 mol aminoaxit X tc dng va vi 80ml dd HCl 0,125M, sau c cn dd thu c 1,835g mui.
Phn t khi ca X l
A. 174.
B. 147.
C. 197.
D. 187
Cu 59. Cho 10 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M,
ri c cn dung dch th thu c 15,84 gam hn hp mui. Nu trn 3 amin trn theo t l mol 1 : 10 : 5 theo th t
phn t khi tng dn th cng thc phn t ca 3 amin l p n no sau y?
A. CH5N, C2H7N, C3H7NH2
B. C2H7N, C3H9N, C4H11N
C. C3H9N, C4H11N, C5H11N
D. C3H7N, C4H9N, C5H11N
Cu 60. t chy hon ton 6,2 gam mt amin no, n chc phi dng ht 10,08 lt kh oxi (ktc). Cng thc ca amin
l cng thc no sau y?
A. C2H5NH2
B. CH3NH2
C. C4H9NH2
D. C3H7NH2
Cu 61. Hp cht hu c to bi cc nguyn t C, H, N l cht lng, khng mu, rt c, t tan trong nc, d tc dng
vi cc axit HCl, HNO2 v c th tc dng vi nc brom to kt ta. Hp cht o c cng thc phn t nh th no?
A. C2H7N
B. C6H13N
C. C6H7N
D. C4H12N2
Cu 62. t chy hon ton 100ml hn hp gm imetylamin v hai hirocacbon ng ng k tip thu c 140ml
CO2 v 250ml hi nc (cc th tch o cng iu kin). Cng thc phn t ca hai hirocacbon l p n no?
A. C2H4 v C3H6
B. C2H2 v C3H4
C. CH4 v C2H6
D. C2H6 v C3H8
Cu 63. Trung ha 3,1 gam mt amin n chc X cn 100ml dung dch HCl 1M. Cng thc phn t ca X l p n
no?
A. C2H5N
B. CH5N
C. C3H9N
D. C3H7N
Cu 64. t chy hon ton hn hp hai amin no n chc ng ng lin tip, ta thu c hn hp sn phm kh vi t
l nCO2: nH2O = 8 : 17. Cng thc ca hai amin l p n no?
A. C2H5NH2, C3H7NH2
B. C3H7NH2, C4H9NH2
C. CH3NH2, C2H5NH2
D. C4H9NH2, C5H11NH2
Cu 65. t chy hon ton mt amin n chc cha no c mt lin kt i mch cacbon ta thu c CO 2 v H2O
theo t l mol = 8:9. Vy cng thc phn t ca amin l cng thc no?
A. C3H6N
B. C4H9N
C. C4H8N
D. C3H7N
Cu 66. Cho 1,52 gam hn hp hai amin no n chc (c trn vi s mol bng nhau) tc dng va vi 200ml
dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc.
A. Nng mol ca dung dch HCl bng 0,2M.
B. S mol ca mi cht l 0,02mol

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Ti liu n thi H-C 2010

Chuyn :

C. Cng thc thc ca hai amin l CH5N v C2H7N

D. Tn gi hai amin l metylamin v etylamin
Cu 67. Ngi ta iu ch anilin bng cch nitro ha 500g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu
c l bao nhiu, bit hiu sut mi giai on 78%?
A. 346,7gam
B. 362,7gam
C. 463,4gam
D. 358,7 gam
Cu 68. Cho lng d anilin phn ng hon ton vi dung dch cha 0,05mol H2SO4 long. Khi lng mui thu c
bng bao nhiu gam?
A. 7,1gam
B. 14,2gam
C. 19,1gam
D. 28,4 gam
Cu 69. Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol
HCl. A cng phn ng vi vi 0,075 mol Br2 to kt ta. Lng cc cht NH3, C6H5NH2 v C6H5OH ln lt bng
bao nhiu?
A. 0,01 mol; 0,005mol v 0,02mol
B. 0,005 mol; 0,005mol v 0,02mol
C. 0,05 mol; 0,002mol v 0,05mol.
D. 0,01 mol; 0,005mol v 0,02mol
Cu 70. t chy hon ton 100ml hn hp gm imetylamin v 2 hirocacbon ng ng k tip thu c 140ml CO2
v 250ml hi nc (cc th tch o cng iu kin). Thnh phn % th tch ca ba cht trong hn hp theo tng
phn t khi ln lt bng bao nhiu?
A. 20%; 20% v 60%
B. 25%; 25% v 50%
C. 30%; 30% v 40%
D. 60%; 20% v 20%
Cu 71. Este X c iu ch t aminoaxit v ru etylic. T khi hi ca X so vi hiro 51,5 . t chy hon ton
10,3 gam X thu c 17,6gam kh CO2, 8,1gam nc v 1,12 lt nit (ktc). Cng thc cu to thu gn ca X l cng
thc no sau y?
A. H2N- CH2 - COO-C2H5.
B. H2N- CH(CH3) - COOC. H2N- CH2 CH(CH3) - COOH
D. H2N-CH2 -COO-CH3
Cu 72. X l mt aminoaxit no ch cha 1 nhm - NH2 v 1 nhm COOH. Cho 0,89 gam X tc dng vi HCl va
to r a 1,255 gam mui. Cng thc cu to ca X l cng thc no sau y?
A. H2N- CH2-COOH
B. CH3- CH(NH2)-COOH.
C. CH3-CH(NH2)-CH2-COOH.
D. C3H7-CH(NH2)-COOH
Cu 73. X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 15,1 gam X tc dng vi HCl d thu
c 18,75 gam mui. Cng thc cu to ca X l cng thc no?
A. C6H5- CH(NH2)-COOH
B. CH3- CH(NH2)-COO
C. CH3-CH(NH2)-CH2-COOH
D. C3H7CH(NH2)CH2COOH
Cu 74. X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 23 gam X tc dng vi HCl d thu
c 30,3 gam mui. Cng thc cu to thu gn ca X l cng thc no?
A. CH3-CH(NH2)-COOH
B. H2N-CH2-COOH
C. H2N-CH2CH2 -COOH
D.CH2=C(CH3)CH(NH2)COOH
Cu 75. Cht A c % khi lng cc nguyn t C, H, O, N ln lt l 32%, 6,67% 42,66%, 18,67%. T khi hi ca A
so vi khng kh nh hn 3. A va tc dng NaOH va tc dng dd HCl, A c cng thc cu to nh th no?
A. CH3-CH(NH2)-COOH
B. H2N-(CH2)2-COOH
C. H2N-CH2-COOH
D. H2N-(CH2)3-COOH
Cu 76 Cht A c thnh phn % cc nguyn t C, H, N ln lt l 40,45%, 7,86%, 15,73% cn li l oxi. Khi lng
mol phn t ca A <100 g/mol. A tc dng c vi NaOH v vi HCl, c ngun gc t thin nhin, A c CTCT nh
th no.
A. CH3-CH(NH2)-COOH
B. H2N-(CH2)2-COOH
C. H2N-CH2-COOH
D. H2N-(CH2)3-COOH
Cu 77 : Este A c iu ch t aminoaxit B (ch cha C, H, O, N) v ancol metylic. T khi hi ca A so vi H 2 l
44,5. CTCT ca A l
A. H2N CH2 CH2 COOCH3.
B. H2N CH2 COOCH3.
C. H2N CH2 CH(NH2) COOCH3.
D. CH3 CH(NH2) COOCH3.
Cu 78 : DD X gm HCl v H2SO4 c pH=2. trung ho hon ton 0,58g hn hp 2 amin no n chc bc 1 (c s
ngt C nh hn hoc bng 4) phi dng 1 lt dd X. Cng thc ca 2 amin c th l
A. CH3NH2 v C4H9NH2.
B. C2H5NH2 v C4H9NH2.
C. C3H7NH2 v C4H9NH2.
D. C A v B.
Cu 79: t chy hon ton ng ng X ca axit aminoaxetic, thu c t l s mol CO2 : H2O l 6 : 7. Cc CTCT c
th c ca X l
A. CH3CH(NH2)COOH ; H2NCH2CH2COOH
B. CH3CH2CH(NH2)COOH ; H2NCH2CH2CH2COOH.
C. CH3CH2CH2CH(NH2)COOH ; H2N[CH2]4COOH.
D. CH3[CH2]3CH(NH2)COOH ; H2N[CH2]5COOH.
Cu 80 : t chy hon ton a mol aminoaxit A thu c 2a mol CO2 v a/2 mol N2. Aminoaxit A l
A. H2NCH2COOH.
B. H2N[CH2]2COOH.
C. H2N[CH2]3COOH.
D. H2NCH(COOH)2.
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