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  • Tris (2 Aminoethyl) Amine PP

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    jackactforever4
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    Original Title

    Tris(2 Aminoethyl)Amine PP

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    Attribution Non-Commercial (BY-NC)
    Download as PPTX, PDF, TXT or read online from Scribd
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    20 views5 pages

    Tris (2 Aminoethyl) Amine PP

    Uploaded by

    jackactforever4

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPTX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 5

    Jason Nguyen Thien Vu

    Properties
    Abbrev. Tren
    Neutral ligand Does not deprotonate upon binding Chelating ligand Colorless, transparent liquid Form stable complexes, especially in 2+, 3+ oxidation

    states Corrosive

    Structures
    CN=5 C3v Trigonal Bipyramidal CN=6 Cs Square bipyramidal

    Spontaneous Resolution
    cis-[Ni(NCS)2(tren)]
    Pfeiffer Effect Cotton effect

    References
    Chiral Synthesis of a Mononuclear Nickel(II)

    Complex Formed from an Achiral Tripodal Amine Ligand: Spontaneous Resolution, A. Srinivasa Rao, Abhijit Pal, Rajarshi Ghosh, and Samar K. Das , Inorganic Chemistry, 2009, 48, 1802-1804

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