You are on page 1of 23

Guru Nanak Engineering College

Ibrahimpatnam, Ranga Reddy District – 501 506 (A. P.)

COURSE FILE (2008-2009)

NAME OF THE FACULTY : B. SRINIVAS

DESIGNATION : ASSISTANT PROFESSOR

DEPARTMENT : HUMANITIES & SCIENCES

SUBJECT CODE : CM 05044

SUBJECT NAME : APPLIED CHEMISTRY

YEAR : Ist YEAR CE


1. Target:
a. First class with distinction : 15
b. First class : 30
c. Pass class : 15

2. Course plan:
a. Teaching the students in the class
b. Explain the lesson using examples
c. Explain the practical applications.
d. Presentations through OHP, LCD projector
e. Guest lecture s on industrial related topics
f. Teaching with using Experiments in lab.

3. Method of evaluation:
a. Internal examinations (Objective type)
b. Unit wise Assignments (from previous question papers)
c. Final examination (Theory/Descriptive type)
4. Course Objective:
On completion of this course the student shall be able to:

a. Understand the role of chemistry in the field of engineering.

b. Develop analytical capabilities

c. Understand the various water treatment processes

d. Characterize, transfer and use of materials in engineering and apply


knowledge in solving engineering problems.

e. Understand the quality of lubricants.

f. Understand the different polymers and their uses..

g. Understand the material is corrosion resistant.

h. Understand the concepts of cement and their applications.


2007 - 2008
TPC
+1 0 4
JNTU SYLLABUS (CM05044) APPLIED CHEMISTRY
UNIT I: Water Technology-I:
Introduction, Effect of Water on Rocks and Minerals, Types of impurities in Water, Hardness of Water –
Temporary and Permanent hardness. Units and inter conversions of Units. Estimation of hardness by
EDTA Methods. Problems on Temporary and Permanent hardnesses. Analysis of Water - Alkalinity;
Chlorides and Dissolved Oxygen. Disadvantages of Hard Water. Methods of Treatment of Water for
Domestic Purposes - Sedimentation, Coagulation, Filtration, Disinfection - Sterilization,
Chlorination,Break point chlorination, Ozonization.
UNIT II: Water Technology-II:
Water for Industrial purpose - Water for Steam Making-Boiler Troubles – Carry Over - Priming and Foaming,
Boiler Corrosion, Scales and Sludges, Caustic Embrittlement. Water Treatment: - Internal Treatment –
Colloidal, Phosphate, Calgon, Carbonate, Sodium aluminate Conditioning of Water. External Treatment - Lime-
Soda Process, Zeolite Process, Ion- Exchange Process; - Numerical Problems.
UNIT III: Science of Corrosion:
Definition, Examples, Types of Corrosion: Theories of Corrosion and Mechanism – Dry Corrosion, (Direct
Chemical attack), Wet Corrosion, (Electro Chemical Theory) Principles of Corrosion, Galvanic Series, Galvanic
Corrosion, Concentration Cell Corrosion, Mechanism of Wet Corrosion – Hydrogen evolution type, Oxygen
absorption type. Factors Influencing Corrosion. Control of Corrosion – Proper Design, Use of pure metal and
metal alloys, Passivity, Cathodic Protection – Sacrificial anode and Impressed Current. Modifying the
Environment, use of Inhibitors.
UNIT IV: Protective Coatings and their applications:
Surface Preparation: (1) Solvent Cleaning (2) Alkali Cleaning (3) Pickling and Etching (4) Sand Blasting (5)
Mechanical Cleaning.
Types of Protective Coatings: Metallic Coatings – Anodic Coatings, Galvanization, Cathodic Coatings –
Tinning, Metal Cladding, Electroplating Ex: Chromium Plating, Metal Spraying, Cementation–Sheradizing,
Colourizing, Chromizing.
Chemical Conversion Coatings: (1) Phosphate (2) Chromate (3) Anodized Coatings.
UNIT V: Polymer Science and Technology:
Polymerization Reactions – Basic concepts. Types of Polymerization – Addition and Condensation
Polymerizations. Plastics –Thermosetting and Thermoplastics – Differences. Compounding and Moulding of
Plastics – Compression, Injection, Transfer, and Extrusion molding methods. Preparation, Properties and
Engineering Uses of the Following: Polyethylene, PVC, Teflon, Bakelite, Nylon, Polyester, Polyurethane and
Silicone Resins. Rubber – Processing of Natural Rubber, Vulcanization and Compounding. Elastomers – Buna
S, Buna N, Thiokol. Polyurethane Rubber.
UNIT VI: Refractories and Insulators:
Refractories – Definition, Classification With Examples; Criteria of a Good Refractory Material; Causes for the
failure of a Refractory Material; Insulators – Definition and Classification with Examples; Characteristics of
Insulating Materials; Thermal Insulators, Electrical Insulators - Their Characteristics and Engineering
Applications.
UNIT VII: Lubricants:
Principles and function of lubricants - Types of Lubrication and Mechanism – Thick Film or Hydrodynamic
Lubrication, Thin Film or Boundary Lubrication, Extreme Pressure Lubrication. Classification and properties of
lubricants-Viscosity, flash and fire point, cloud and pour point, aniline point, Neutralization Number and
mechanical strength.

UNIT VIII: Inorganic Cementing Materials:


Cement: Important Parameters for Manufacturing Cement Clinkers. Chemical Constituents and Composition of
Cement. Methods of Manufacture of Cement – Wet and Dry Processes. Additives for Cement. Properties of
Cement - Setting and Hardening. Types of Portland Cement.
5. Guidelines to students:

a. They should attend all the class to understand and learn basics of this
Course.

b. They should go through different reference books, internet browsing,


Journals, news papers to acquire the best and latest knowledge of the
Subject.

c. They should learn the things in the practical approach besides theory.

d. They should gain knowledge by using internet, news papers and journals.
BOOKS/ MATERIALS/ REFERENCES:
TEXT BOOKS:
1. A text book of Engineering Chemistry by Jain & Jain, Dhanpat Rai Publishing
Company, New Delhi(15
Ediction) (2006).
2. Chemistry of Engineering Materials by C.P. Murthy, C.V. Agarwal and A. Naidu
BS Publication Hyd. 2007.

REFERENCE:
1. A text book of Engineering Chemistry by S.S. Dara, S.Chand & Co, New Delhi
(2004)

2. Engineering Chemistry by J C Kuriacose and J. Rajaram, Tata McGraw-Hill Co,


New Delhi (2004)

3. Text book of Engineering Chemistry by Shashi Chawala, Dhanpat Rai


Publishing Company, 15th edition
New Delhi (2004).

4. Laboratory Manual on Engineering Chemistry by S.K. Bhasin and Sudha Rani,


Dhanpat Rai Publishing
Company, New Delhi (2004).
5. Engineering Chemistry by R. Gopalan, D. Venkappaya and S.Nagarajan, Vikas
Publishing House, New
Delhi (2004).
6. Engineering Chemistry by R.V. Gadag A.N. Tyanand Shortly IK. International
Publishing house Pvt. Ltd.
New Delhi.

SUGGESTED WEB SITES:


WWW.CHEMISTRYMASTER.WETPAINT.COM
WWW.GURUNANAK-CHEMISTRY.BLOGSPOT.COM
WWW.CHEMISTRYMASTER.BLOGSPOT.COM
WWW.ENGINEERINGCHEMISTRY.BLOG.CO.IN
WWW.APPLIEDCHEMISTRY.BLOG.CO.IN
WWW.CHEMISTRYABOUT.COM
WWW.MSENCARTA.COM
WWW.WIKIPEDIA.COM
WWW.CHEMISTRY.CALTECH.EDU
WWW.CHEM.VT.EDU
COURSE SCHEDULE
Number of hours / Lectures available in this Year
Distribution of hour’s unit wise

Text Books (to be acquired by the Students)

Book 1 Text Book of Engineering Chemistry By Jain &Jain Publishers:Dhanpat Rai


Text Book of Engineering Chemistry By C..P.Murthy , C.V.Agrawal,and AndhraNaidu & B.S
Book2
publication.
Text Books for references
Book 3 Text book of Engineering Chemistry By S.S.Dara Publishers:Chand
Book 4 Text book of Engineering Chemistry By Shashi Chawla Publishers Dhanpat Rai & Co
Book 5 Engineering Chemistry By R.gopalan, D.Venkappaya and S.Nagarajan, Vikas publishers

Chapters No of Classes
Unit Topic
B-1 B-2 B-3 B-4 B-5
Water
I 1 2 1 6 18 7+1*
Technology-I
Water
II 1 2 1 6 18 9+1*
Technology-II
Science of
III Corrosion 7 8 4 17 6 9+1*
Protective
IV Coatings and 8 8,9 4 - 7 8+1*
their applications
Polymer Science
V 3 9 9 1 16 12+1*
and Technology

Refractories &
VI 11 10,1 16 8,14 11 7+1*
Insulators

VII Lubricants 10 7 5 7 13 7+1*


Inorganic
VIII Cementing 11 11 6 9 10 11+1*
Materials
Classes forCombustion
above curriculum topics 03
Descriptive tests 06
On – line tests 03
Revisions 03
Total no of classes 93

• Indicates Tutorial Class


LESSON PLAN
Name of the Unit Name of the topic No. of Cumu.
class class
Unit- I 1.1. Sources, impurities in water 1 1
Water technology-I
1.2. Water quality- hardness, units and its 1 2
determination
1.3. Estimation of hardness by EDTA methods 1 3

1.4. Problems on Hardness 1 4

1.5. Analysis of alkalinity, chlorides and D.O 1 5

1.6. Methods for treatment of water for domestic 2 7


purpose.
Unit –II 2.1. Water for industrial purpose 1 8
Water Technology –
II 2.2. Boiler problems 1 9

2.3. Water treatment- Internal treatment 1 10

2.4. External water treatment- Lime soda 2 12

2.5. Zeolite process 1 13


2.6. Ion-exchange process 1 14

2.7. Numerical problems in lime soda process 2 16

Unit-III 3.1. Introduction , Corrosion definition 1 17


Science of 3.2. Types of corrosion, Chemical 1 18
corrosion corrosion
3.3. Electrochemical corrosion 1 19

3.4. Types of electro chemicals corrosion 1 20


(Galvanic, pitting corrosion
3.5. Crevice, concentration cell, waterline 1
corrosion 21
3.6. Inter granular, Stress, Underground 1 22
corrosion
3.7. Microbiological, erosion corrosion 1 23

3.8. Factors affecting corrosion


Sacrificial anodic, Impressed current 2 25
cathodic protection
Unit-IV 4.1. (1) Solvent Cleaning (2) Alkali Cleaning (3)
Protective Pickling and Etching(4) Sand Blasting (5) 2 27
coatings and their Mechanical Cleaning.
application
4.2. Types Of Protective Coatings: Metallic
Coatings – Anodic Coating Galvanization, 2 29

4.3. Cathodic Coating – Tinning, Metal Cladding,


Electroplating Ex: Chromium 2 31
Plating, Metal Spraying, Cementation–
Sheradizing, Colourizing, Chromizing

4.4. Chemical Conversion Coatings: (1) Phosphate


(2) Chromate 1 32

4.5. (3) Anodized Coatings.


1 33
Unit-V 5.1. Polymerization 1 34
Polymer Science 5.2. Types of polymerization- additional
and Technology polymerization

5.3. Step growth polymerization 1 35


Chain growth polymerization

5.4. Plastics- Definition, classification 1 36

5.5. Thermo and Thermosetting plastics 1 37


Compounding plastics

5.6. fabrication plastics 1 38

5.7. Composition, properties, engineering 1 39


uses of Poly-ehylene
5.8. PVC, Bekalite, 1 40

5.8. Nylon, poly ester 1 41

5.9. polyurethane, Silicon resins, 1 42

5.10. Processing of natural rubber 1 43


Vulcanization of rubber
5.11. Compounding of rubber

5.12. Elastomers- 1 44
Buna-S, Buna-N ,

5.13. Thiokol, . polyurethane rubber 1 45


Unit-VI 6.1. Refractories- Definition, Classification 1 46
Refractories and
Insulators 6.2. Criteria for a good refractory material 2 48

6.3. Causes for the failure of a refractory 2 50


material

6.4. Insulators- Thermal insulators 1 51

6.5. Electrical Insulators 1 52

Unit- VII 7.1.Pinciples and factions of lubricants - Types of 2 54


Lubricants Lubrication and Classification
7.2. Lubricants Mechanism – Thick Film or 1 55
Hydrodynamic Lubrication,
7.3. Lubricants Thin Film or Boundary Lubrication, 1 56
Extreme Pressure Lubrication.
7.4. properties of Lubricants – Viscosity – Flash 1 57
and Fire points –
7.5. Cloud and Pour points 1 58

7.6. Aniline-Point-Neutralization number and 1 59


Mechanical strength.
Unit-VIII 8.1cement: parameters for manufacturing cement 1 60
Inorganic clinkers
cementing 8.2Chemical constituents and composition of 1 61
materials. cement
8.3Methods manufacture of cement – wet process 2 63

8.4.Dry process 2 65

8.5.Additives for cement 1 66

8.6.Properties of cement- setting 1 67

8.7.hardening 1 68

8.8.Types of Portland cement 2 70


TOPIC WISE COVARAGE
UNIT – I

Hour Date Topic References


No.
01 1.1. Introduction, impurities in water 1,2,3,4,5

02 1.2. Water quality- hardness, units and its


determination
03 1.3. Estimation of hardness by EDTA methods
04 1.4. Problems on Hardness

05 1.5. Analysis of alkalinity, chlorides and D.O

06 1.6. Methods for treatment of water for domestic


purpose.
07 Methods for treatment of water for domestic purpose.

REVISION

UNIT – II

Hour Date Topic References


No.
08 2.1. Water for industrial purpose 1,2,3,4,5

09 2.2. Boiler problems

10 Scales and sludge, carry over

11 2.3. Water treatment- Internal treatment

12 2.4. External water treatment- Lime soda

13 Hot and cold process of lime soda

14 2.5. Zeolite process

15 2.6. Ion-exchange process

16 2.7. Numerical problems in lime soda process

REVISION
UNIT – III

Hour Date Topic References


No.
17 3.1. Introduction , Corrosion definition 1,2,3,4,5

18 3.2. Types of corrosion, Chemical corrosion

19 3.3. Electrochemical corrosion

20 3.4. Types of electro chemicals corrosion


(Galvanic, pitting corrosion
21 3.5. Crevice, concentration cell, waterline
corrosion
22 3.6. Inter granular, Stress, Underground corrosion
23
3.7. Microbiological, erosion corrosion
24 3.8. Factors affecting corrosion

25 Sacrificial anodic, Impressed current cathodic


protection
REVISION

UNIT – IV

Hour Date Topic References


No.
26 4.1. (1) Solvent Cleaning (2) Alkali Cleaning (3) 1,2,3,4,
Pickling and Etching
27 (4) Sand Blasting (5) Mechanical Cleaning.

28 4.2. Types Of Protective Coatings: Metallic Coatings –


Anodic Coating
29 Galvanization,

30 4.3.Cathodic Coating – Tinning, Metal Cladding,


Electroplating Ex: Chromium Plating, Metal Spraying,
31 Cementation–Sheradizing, Colorizing, Chromizing

32 4.4. Chemical Conversion Coatings: (1) Phosphate (2)


Chromate.
33 (3) Anodized Coatings

REVISION
UNIT – V
Hour Date Topic References
No.
34 5.1. Polymerization 1,2,3,4,5
5.2. Types of polymerization- additional polymerization
35 5.3. Step growth polymerization
Chain growth polymerization
36 5.4. Plastics- Definition, classification
37 5.5. Thermo and Thermosetting plastics
Compounding plastics
38 5.6. fabrication plastics

39 5.8. Composition, properties, engineering


uses of Poly-ethylene
40 5.9. P V C and Teflon

41 5.10. Bakelite, Nylon, poly ester

42 5.11. polyurethane, Silicon resins,

43 5.12. Processing of natural rubber


Vulcanization of rubber
5.13. Compounding of rubber
44 5.14. Elastomers- Buna-S, Buna-N

45 5.15.POLYURETHANE , Thiokol,

REVISION

UNIT – VI
Hour Date Topic References
No.
46 6.1. Refractories- Definition, Classification 1,2,3,4,5

47 6.2. Criteria for a good refractory material

48 Criteria for a good refractory material

49 6.3. Causes for the failure of a refractory material

50 Causes for the failure of a refractory material

51 6.4. Insulators- Thermal insulators

52 6.5. Electrical Insulators

REVISION
UNIT – VII

Hour Date Topic References


No.
53 7.1.Pinciples and factions of lubricants - 1,2,3,4,5

54 Types of Lubrication and Classification

55 7.2. Lubricants Mechanism – Thick Film or


Hydrodynamic Lubrication,
56 7.3. Lubricants Thin Film or Boundary Lubrication,
Extreme Pressure Lubrication.
57 7.4. properties of Lubricants – Viscosity –
Flash and Fire points –
58 7.5. Cloud and Pour points Aniline-Point-,

59 7.6. Neutralization number and Mechanical strength.

REVISION

UNIT - VIII
Hour Date Topic References
No.
60 8.1cement: parameters for manufacturing cement 1,2,3,4,5
clinkers
61 8.2Chemical constituents and composition of cement

62 8.3Methods manufacture of cement – wet process

63 8.3Methods manufacture of cement – wet process

64 8.4Methods manufacture of cement – DRY process

65 8.4Methods manufacture of cement – DRY process

66 8.5.Additives for cement

67 8.6.Properties of cement- setting

68 8.7.hardening

69 8.8.Types of Portland cement

70 Types of Portland cement

REVISION
Actual Date of Unit Completion and Remarks

UNIT – I Water Technology-I


Actual Date :
Completion Date :
Remarks: Total classes held :
As per Teaching Schedule Total No. of Hours: 7

UNIT – II Water Technology-II


Actual Date :
Completion Date :
Remarks: Total classes held :
As per Teaching Schedule Total No. of Hours: 9

UNIT – III Science of Corrosion

Actual Date :
Completion Date :
Remarks: Total classes held :
As per Teaching Schedule Total No. of Hours: 9

UNIT – IV Protective Coatings and their applications


Actual Date :
Completion Date :

Remarks: Total classes held :


As per Teaching Schedule Total No. of Hours: 8
UNIT – V Polymer Science and Technology
Actual Date :
Completion Date :

Remarks: Total classes held :


As per Teaching Schedule Total No. of Hours: 12

UNIT - VI Refractories & Insulators


Actual Date :
Completion Date :

Remarks: Total classes held :


As per Teaching Schedule Total No. of Hours: 7

UNIT - VII Lubricants


Actual Date :
Completion Date :
Remarks: : Total classes held :
As per Teaching Schedule Total No. of Hours: 7

UNIT – VIII Inorganic cementing materials

Actual Date :

Completion Date :

Remarks: Total classes held :


As per Teaching Schedule Total No. of Hours: 11
Assignments
UNIT-I Water Technology - I
1. a) What is meant by “hardness” of water. And what are the disadvantages of hard
Week -1 water.? b) Distinguish between temporary and permanent hardness of water. C) What
are its units? D) How do you express the hardness of water?
2. (a) What is the principle of EDTA method? Explain the estimation of hardness of
water by complex metric method.
(b) Mention the dis-advantages of using hard water for industrial purpose.
3. (a) Explain the terms temporary and permanent hardness of water. (b) How do you
estimate the temporary hardness of water by EDTA method? (c) 50 ml of a sample of
hardwater was titrated against 0.01 M EDTA, required 48 ml of EDTA for titration.
50 ml of the same hardwater after boiling and filtering etc. required 35ml of the
EDTA for titration. Calculate the total and temporary hardness of water in degree
Clark.
1. (a) Estimation of free chlorine in water samples.
(b) Discuss the impurities in water and their effects.
c. Explain the sedimentation process for the treatment of municipal water
Week-2 2. Write a short notes on the following: (a) Break - point chlorination (b) Dissolved
oxygen (c) Hardness of water (d) Sedimentation and coagulation.
3. Distinguish the following: [4+4+4+4] (a) Hard water and soft water (b) carbonate
and non-carbonate hardness (c) mg/litre and ppm (d) Sedimentation and filtration.
1. What is meant by disinfection? What is its significance? Explain the different
methods used for disinfection of surface water.
2. (a) Why is sterilization of water necessary? Discuss any two methods of
sterilisation. (b) 0.5 g of CaCO3 was dissolved in dil.HCl and diluted to 1000 mL. 50
mL of this solution required 48 mL of EDTA solution for titration. 50 mL of hard
water sample required 15 mL of EDTA solution for titration. 50 mL of same water
sample on boiling, filtering etc, required 10 mL of EDTA solution. Calculate
Week-3 the different kinds of hardness in ppm.
3. Write short notes on the following: [4+4+4+4] (a) Units of hardness of water
(b) Break point chlorination (c) Filtration of water (d) Impurities in water

Date of submission

Date of valuation of Assignment


UNIT-II Water Technology – II
1. Write short notes on the following:
a) Carry over b) Phosphate conditioning (c) Caustic embrittlement
2. a) Write short notes on Internal treatment methods
b) State the disadvantages of scale formation in boilers.
Week-4 3. Distinguish between the following: (a) Scales and Sludges (b) Soft water and
dematerialized water. (c) Lime soda process and demineralization of water.
4. What are boiler scales? How their compositions effect the boiler? What are their ill
effects? Discuss the measures for their prevention. (b) Compare the lime soda process
with zeolite process of water softening. [8+8]
1. (a) Describe the demineralisation of water by ion - exchange method.
(b) Mention the disadvantages of using hard water for any two industries
2. Explain the Ion-exchange method for the removal of dissolved impurities and its
advantages over lime soda process
3. (a) Explain the cold lime soda process and hot lime soda process. What are the
Week-5 advantages of lime soda process? (b) 100 ml of a water sample contains hardness
equivalent to 25 ml of 0.08 N MgSO4. [8+8]
i. What is the hardness of water sample in ppm? ii. What is the amount of lime and
soda required for the treatment of the water sample?
3. Explain the Ion-exchange method for the removal of dissolved impurities and its
Advantages over lime soda process. [16]
1) a) What is the chemical composition of Zeolite? How are they classified? Explain
the mechanism of the treatment of hard water by Zeolites.
b) A Zeolite softener was exhausted and regenerated by passing 100 liters of NaCl
solution containing 585 gms per liter. Calculate the total hardness of the water sample
in ppm, if the Zeolite softener can soften 1000 liters of water before regeneration.
2) Write a comparative statement on lime soda & Zeolite process.
3) Calculate the lime and soda needed for softening 50,000 litres of water containing
the following salts: CaSO4 = 136 mg/lit; MgCl2 = 95 mg/lit; Mg(HCO3)2 = 73 mg/lit;
Ca(HCO3)2= 162 mg/lit. Given that the molar mass of Ca(HCO3)2 is 162 and that of
MgCl2 is 95
Week-6 4) Determine the amount of soda and lime required in Kg’s to soften 5000 lit of water
containing the following salts MgCl2 = 15.5 ppm, Ca(Hco3)2 = 32.5 ppm, Ca(No3)2 =
22.4 ppm, NaCl = 50 ppm, KCl = 22.5 ppm.

Date of submission

Date of valuation of Assignment


UNIT-III Science of Corrosion
1) Explain the process of wet corrosion by evolution of hydrogen and absorption of
oxygen (or) Describe the electrochemical theory of corrosion.
2) Differentiate the following with suitable examples. a) Galvanic series and
Week-7 electrochemical series. b) Pitting corrosion ad stress corrosion.
3)(a) What is meant by differential aeration corrosion? Illustrate with suitable
examples. (b) How is rate of corrosion influenced by i. Nature of corrosion product ii.
Relative anodic to cathodic areas iii. Temperature and moisture.
4) (a) What is oxidation corrosion and how does it take place? Describe the
mechanism of oxidation corrosion. (b) Describe the various factors influencing the
rate of chemical corrosion.
5) Write down the equation for the hydrogen evolution in an electro chemical
Week-8
corrosion reaction?
6. (a) What is oxidation corrosion and how does it take place? Describe the
mechanism of oxidation corrosion. (b) Describe the various factors influencing the
rate of chemical corrosion.
Week-9 1. What are the factors effecting corrosion?
2. a) Explain the following factors influencing the rate of corrosion. i. Nature of
corrosion product ii. Position in electrochemical series iii. pH. (b) Differentiate
between dry corrosion and wet corrosion
3. Define corrosion? Explain any 4 factors that affect the rate of corrosion & explain
any 4 corrosion control methods.
1. Explain how corrosion control can be brought about by the following methods.
a) Modifying the environment b) Cathodic protection.
2. Write a short note on Inhibitors & Cathode protection.

Week-10
Date of submission

Date of valuation of Assignment

UNIT-IV Protective Coatings and their Applications

Explain the protective coatings you would choose for steel; cast iron and concrete
pipe. Give reasons for your answer.
Week-11
2. (a) Write short notes on chromizing (b) How pH of an electrolyte affects
electrodeposit? (c) Explain the method of coating for protection of furnace parts
1.(a) Describe the mechanism of drying of conjugated oils. (b) Name any four
important drying oils. (c) Define the following:i. Acid value of an oil ii.
Saponification Value iii. Iodine Value.
2. Write notes on Surface preparation.
Week-12
3. (a) Discuss how the surface of a metal is prepared prior to the application of a
protective coating.
(b) Write the important applications of protective coating.
(c) Why is moderate current density employed during electroplating?
What is metallic coating? Name the metallic coating methods.
2. (a) Describe the process of sheradizing? Mention its applications?(b) Distinguish
between anodizing and electroplating. (c) Define Anodizing
Week-13
3. (a) List the differences between anodic coating and cathodic coating. (b) How zinc
coated on iron prevents corrosion? (c) Explain sand blasting method of surface
preparation?
1. Explain in detail the various methods of Chemical conversion coatings
2. (a) Explain the following: i. Alkali Cleaning ii. Mechanical cleaning. (b)
Describe the principles involved in electro plating. (c) Anodized coating is
preferred for Aluminium - Give Reasons.

Week-14
Date of submission

Date of valuation of Assignment


UNIT-V Polymer Science & Technology
1. Write the differences between a) compression-Injection moulding b) additional
polymerization-condensation polymerization c) thermoset-thermoplasts.
Week-15
2. Explain any one of the mechanism of additional polymerization, using suitable
example. .
1. Write a note on thermo setting plastics? Write a note on properties and uses of
Teflon.
2.Describe the manufacture , properties ,uses of a)polyethylene
Week-16
b) Teflon c) Thiokol d) PVC
3.(a) How is HDPE is prepared? Give its properties and uses? (b) Explain the
injection moulding process with a neat diagram? Mention its advantages.
1.What is moulding of plastics? Explain compression moulding technique in detail.
2.How is Bakelite manufactured? Discuss its important uses and properties.
3. Identify the thermosets & thermoplasts among the following: PVC, polyethylene,
Week-17 silicon, polyester fiber, bakelite. What is Bakelite? How is it manufactured and
mention its uses.
4. (a) Differentiate between LDPE & HDPE. (b) What are the drawbacks of raw
rubber?(c) Write the repeating unit for the following: i. Nylon 6,6 ii. PVC
1.Describe the preparation, properties and engineering uses of Polythylene.
2. (a) Explain the preparation, properties and uses of Bakelite.
(b) Describe with a neat sketch, the process of compression moulding
Week-18
3. (a) How will you synthesis nylon 6,6 from 1,3 butadiene?
(b) Describe the method of preparation of polyester and mention its properties
and uses. (c) What is the repeating unit of [6+6+4] i. natural rubber ii. Teflon.
1. (a) What are elastomers? Give the preparation, properties and uses of Buna S. (b)
Describe a method for moulding of thermoplastic resin
2. (a) Differentiate between elastomer and plastic. (b) Which rubbers are used in the
preparation of automobile parts? Discuss their manufacture and vulcanization.
3 Write preparation, properties and uses of nylon, polyester, and polyurethanes. (a)
Why are Silicones called inorganic polymers? Discuss the synthesis of linear chain
Week-19 Silicones. (b) Why Bakelite can’t be remoulded and write its repeating unit? (c)
Describe condensation polymerization with an example

Date of submission

Date of valuation of Assignment


UNIT-VI Refractories & Insulators
1. Discuss any FOUR essential properties of a good refractory in detail.
2. What are electrical insulators? Discuss their characteristics & engineering
Week-20 applications.
3. What are thermal insulators? Discuss their engineering applications and
characteristics
1. (a) What are refractories? How important are the properties – refractoriness under
load and thermal conductivity for industrial applications? (b) Compare acidic and
Week-21 basic refractories with examples
2.What do you understand by ‘refractoriness’. Explain its measurement.Write a note
on ‘refractoriness-under-load (RUL)’.
1. (a) Define Refractories and what are the criteria of a good refractory? (b) Give the
classification of refractories with suitable examples
2. (a) What is pyrometric cone equivalent? How it is determined for a refractory?
What is its significance?(b) Write a short note on: i. porosity ii. Thermal Conductivity
Week-22 iii. Dimensional Stability. Iv. Strength

Date of submission

Date of valuation of Assignment


UNIT-VII Lubricants
1. Write a short note on principle and function of Lubricants
2. (a) Give the functions of lubricants. (b) Describe the mechanism of extreme
Week-23 pressure lubrication. C) How a viscous lubricant is converted into grease?
3. Write a note on lubricants with special reference to their classification, mode of
action, examples and uses.
1. Explain the various mechanisms of lubrication in detail.
2.Explain the following two theories for the mechanism of the lubricants.
Week-24 a) Boundary lubrication b) Extreme pressure lubrication
3. (a) Give the functions of lubricants. (b) Describe the mechanism of extreme
pressure lubrication. C) How a viscous lubricant is converted into grease?
1. Define lubricant. Discuss the Classification and important properties of the
lubricats.

Week-25
Date of submission

Date of valuation of Assignment


UNIT-VIII Inorganic Cementing Materials
1. What are the chemical constituents of Cement? Discuss the function of each
Week-26
constituent.
1. (a) Why cements are called hydraulic cements? [6] (b) By writing the various
Week-27
chemical reactions involved explain the setting and hardening of cement.
1. (a) Discuss the chemical and physical changes that occur during the setting of
Week-28 cement with relevant chemical equations. (b) Write a note on types of Portland
cements.
1. What is Portland cement? Give its composition. What are the raw materials
required for its manufacture? b) Discuss the chemistry of setting and hardening of
Week-29 cement.
2. a. Write a short note on Additives for cement.
b. Write a note on type of Portland cement.
1. With the help of flow diagram explain the manufacture of Portland cement by
dry and wet process.

Week-30
Date of submission

Date of valuation of Assignment


A LIST OF TUTORIAL/REVISION CLASSES

S.NO TUTORIAL/REVISION CLASSES

I Estimation hardness by EDTA method.

2 To study about external treatment of water

3 To study about factors influencing the corrosion

4 To study about types of protective coatings.

5 Preparation and properties of polyethylene, pvc, and bakelite.

6 To study about Criteria of a good refractory materials.

7 To study the properties of the lubricants.

8 To study in detailed manufacturing of cement

9 To study about plastics and elastomers

10 Explain the following two theories for the mechanism of the


lubricants.
a) Boundary lubrication b) Extreme pressure lubrication
Tutorial [as many planned per unit]

UNIT-I
WATER TECHNOLOGY-I
1. Estimation hardness by EDTA method
UNIT-II
WATER TECHNOLOGY-II
1. To study about external treatment of water
UNIT-III
SCIENCE OF CORROSION
1. To study about factors influencing the corrosion & Control methods
UNIT-IV
PROTECTIVE COATINGS ANF THEIR APPLICATIONS
1. To study about types of protective coatings & applications.
UNIT-V

POLYMER SCIENCE AND TECHNOLOGY


1
Preparation and properties of polyethylene, pvc, and
bakelite and moulding techniques
UNIT-VI
Refractories & Insulators
1. To study about Criteria of a good refractory materials

UNIT-VII
LUBRICANTS
1. To study the properties of the lubricants
UNIT-VIII
Inorganic cementing materials
1. To study in detailed manufacturing of cement

You might also like