13

th
VXY (Date: 04-03-2012) Final Test
PAPER-2
Code-A
ANSWER KEY
PHYSICS
SECTION-2
PART-A
Q.1 D
Q.2 B
Q.3 A
Q.4 C
Q.5 A
Q.6 D
Q.7 A
Q.8 B
Q.9 D
Q.10 B
Q.11 A
PART-B
Q.1 (A) P,R,T
(B) Q,T
(C) P,S
(D) Q,R,S,T
PART-C
Q.1 1250
Q.2 0270
Q.3 0005
Q.4 0002
Q.5 0002
Q.6 0009
MATHS
SECTION-1
PART-A
Q.1 C
Q.2 C
Q.3 B
Q.4 A
Q.5 B
Q.6 C
Q.7 B
Q.8 D
Q.9 C
Q.10 D
Q.11 A
PART-B
Q.1 (A) P
(B) S
(C) R
(D) T
PART-C
Q.1 0005
Q.2 0006
Q.3 0009
Q.4 0016
Q.5 0106
Q.6 0006
CHEMISTRY
SECTION-3
PART-A
Q.1 A
Q.2 A
Q.3 A
Q.4 A
Q.5 B
Q.6 C
Q.7 A
Q.8 B
Q.9 C
Q.10 B
Q.11 A
PART-B
Q.1 (A) S
(B) P
(C) T
(D) Q,R
PART-C
Instruction for Q.1 & Q.2
Partial Marks will be awarded (+2) for correct
value of 'ab' (+2) for correct value of 'cd' and
(+1) as bonus if both are correct.
Q.1 ab = 05 ; cd = 05
Q.2 ab = 20; cd = 80
Q.3 0004
Q.4 0002
Q.5 0001
Q.6 0006
Q.6 0006
MATHEMATICS
Code-A Page # 1
PART-A
Q.1
[Sol. Equation of required plane is (x + y 1) + (2y z) = 0
or x + (2 + 1) y z = 0 ........(1)
If plane (1) is perpendicular to plane x + y + 4z = 9, so
1(1) + 1(2 + 1) + 4 ( ) = 0 2 2 = 0 = 1
On putting = 1 in equation (1), we get
x + 3y z = 1. Ans.
So, on comparing we get k = 1. ]
Q.2
[Sol.
x 3
dx
dy
y x = +

} }
= dx x 2 dy y
c x
2
y
2
2
+ =
Now (1, 2) satisfy it, 2 1 = c = 1, so y
2
= 2x
2
+ 2
or 2x
2
y
2
+ 2 = 0. Ans.]
Q.3
[Sol. Given,
}
|
.
|

\
|
=
x
5
2 2
dt ) t ( ' f 3 t
5
28
) x ( f x
Differentiating both sides with respect to x, we get
x
2
f '(x) + 2x f(x) =
|
.
|

\
|
5
28
x
2
3f '(x)
Put x = 5 and using f(5) = 0, we get
25 f '(5) + 0 = 28 5 3f '(5) 28f '(5) = 28 5 f '(5) = 5. Ans.]
Q.4
[Sol. Any tangent to given hyperbola, is
1
1
tan y
4
sec 2 x
=
u

u
.........(1)
Let (x
1
, y
1
) be the middle point of the chord of ellipse.
Its equation is
1
y
4
x
1
yy
4
xx
2
1
2
1 1 1
+ = + ........(2)
As (1) and (2) are identical, so
1
y
4
x
1
y
tan
x
sec 2
2
1
2
1 1 1
+
=
u
=
u
sec u =
2
1
2
1
1
y 4 x
x 2
+
and tan u =
2
1
2
1
1
y 4 x
y 4
+

MATHEMATICS
Code-A Page # 2
As, sec
2
u tan
2
u = 1, so
( ) ( )
1
y 4 x
y 16
y 4 x
x 4
2
2
1
2
1
2
1
2
2
1
2
1
2
1
=
+

+
Locus is (x
2
+ 4y
2
)
2
= 4(x
2
4y
2
). Ans.]
Q.5
[Sol. A A A A
1
A
2
, M M M
1
M
2
, C
1
C
2
C
3
12 fruits
A A
1
A
2
M
1
M
2
C
1
C
2
C
3
A A M M
4 4
70
! 4 ! 4
! 8
! 2
! 2 ! 4 ! 4
! 8
= =
If child C
1
receives A in the distribution of 8 fruits then he can not get A A he has to take M M
Distribution of AA & MM can be done by only 1 ways.
Hence, required number of ways = 70 1 = 70.]
Paragraph for Question no. 6 to 8
[Sol. Put z = x + iy in ( ) ( ) 0 z z 8 z z
2
= + +
y
2
= 4x ......(1)
Also, 4 1 z 1 z = + +
(6,0)
x
y
|
|
.
|

\
|
3
2 2
,
3
2
P
|
|
.
|

\
|

3
2 2
,
3
2
Q
S
O(0,0)
|
.
|

\
|
0 ,
3
2
R
|
.
|

\
|
0 ,
3
2
M
1
3
y
4
x
2 2
= +
or 3x
2
+ 4y
2
= 12 ......(2)
Note that L (x
1
, y
1
) =
|
.
|

\
|
2
3
, 1
.
(i)
( )
( ) PQR Area
PQS Area
A
A
=
( ) ( )
( ) ( ) RM PQ
2
1
SM PQ
2
1
=
3
4
3
16
3
2
3
2
3
2
6
=
+

= 4. Ans. (C) is correct.

(ii) centroid (G) of ALRS =
|
|
|
|
.
|

\
|
+ + +
3
0 0
2
3
,
3
6
3
2
1
G
L
|
.
|

\
|
2
3
, 1
S(6, 0) R |
.
|

\
|
0 ,
3
2
=
|
.
|

\
|
2
1
,
9
19
Ans. (B) is correct.
MATHEMATICS
Code-A Page # 3
(iii) Equation of normal to y
2
= 4x, is y = mx 2m m
3
. As it passes through D(3, 0) so
m = 0, 1, 1.
A(0, 0), B(1, 2), C(1, 2)
So, area of triangle ABC =
2 |
1 2 1
1 2 1
1 0 0
|
2
1
=

.
Hence, R =
2 4
4 5 5
4
abc

=
A
=
2
5
. Ans. (D) is correct.]
Paragraph for question nos. 9 to 11
[Sol. Let g"(x) = Ax, A = 0
g'(x) =
2
Ax
2
+ B
As, |
.
|

\
|
2 2
1
' g = 0 0 = |
.
|

\
|
8
1
2
A
+ B B =
16
A
g'(x) =
16
A
2
Ax
2

So, g(x) =
16
Ax
6
Ax
3
+ C
As, g(0) = 0 C = 0
g(x) =
16
Ax
6
Ax
3
.
Also, g(1) = 5 5 =
16
A
6
A

A = 48
Hence, g(x) = 8x
3
3x,
(i) g(2) = 64 6 = 58. Ans.
(ii) As, g(x) = 8x
3
3x
So, ( ) ) x ( g f = sgn (8x
3
3x) =

|
|
.
|

\
|
e
|
|
.
|

\
|
e
|
|
.
|

\
|
=
|
|
.
|

\
|
e
|
|
.
|

\
|
e
,
3
8
x ; 1
3
8
, 0 x ; 1
0 ,
3
8
x ; 0
0 ,
3
8
x ; 1
3
8
, x ; 1
x
y
|
|
.
|

\
|
8
0 ,
3
|
|
.
|

\
|
8
0 ,
3
O
Graph of y = g(x)
MATHEMATICS
Code-A Page # 4
So, area enclosed between ordinates x = o to x = o, is 2
}
o
0
dx = 2o.
O
3
8
3
8

x
y
y = 1
(0, 1)
y = 1
y = 1 y = 1 (0, 1) (iii)
dx
dy
+ g'(x) y = ( ) 1 ) x ( g + g'(x)
Integrating factor = e
g(x)
.
Also, general solution is y e
g(x)
= ( )
}
+ dx ) x ( ' g 1 ) x ( g e
) x ( g
Put g(x) = t g'(x) dx = dt
=
}
+ dt ) 1 t ( e
t
= t e
t
+ c = g(x) e
g(x)
+ C
h(x) = y = g(x) + C e
g(x)
As, h(0) = 1 1 = 0 + C C = 1
h(x) = g(x) + e
g(x)
Hence. h(1) = 5 + e
5
. Ans.]
PART-B
Q.1
Sol.
(A) 2 + sin u = x
2
+
2
x
a
. x e R {0}
1 s 2 + sin u s 3
1 s x
2
+
2
x
a
s 3 ......(1)
Let f(x) = x
2
+
2
x
a
f(x) = a 2
x
a
x
2
+
|
|
.
|

\
|
( )
. min
) x ( f = 2 a , at x =
x
a
x
2
= a
But 2 a > 1 a >
2
1
a >
4
1
......(2)
Now, maximum of
|
.
|

\
|
+
2
2
x
a
x = 3.
A.M. > G.M.
2
x
a
x
2
2
|
.
|

\
|
+
>
|
.
|

\
|
2
2
x
a
x
2
3
> a a s
4
9
a e
(

4
9
,
4
1
. Ans.]
MATHEMATICS
Code-A Page # 5
(B) Given,
dx
dy
= 1 2x
On integrating, we get
y = x x
2
+ c
As (2, 2) lies on it, so c = 0
y = x x
2
For point of intersection, ox = x x
2
x = 0, 1 m
Now,
area =
( ) ( )
3
32
dx mx x x
m 1
0
2
=
}

( )
m 1
0
3 2
3
x
2
x
m 1

|
|
.
|

\
|

=
3
32

( ) ( )
3
32
3
m 1
2
m 1
3 3
=

(1 m)
3
= 64 = ( 4)
3
m = 3, 5. Ans.
(C) On squaring, we get
(1 sin x) = (1 sin x)
2
(1 sin x) (1 (1 sin x)) = 0
Either sin x = 0 or sin x = 1
x = nt or x = (4m + 1)
2
t
, where n, m e I.
But only x =
2
t
, t, 2t,
2
5t
satisfy the condition | x t | s
2
3t
]
(D)

We have h(x) = ( ) ( ) ) x ( f g f
h'(x) = ( ) ( ) ) x ( f g ' f g'(f (x)) f '(x)
Now, h'(2) = f '(g(f (2))) g'(f (2) f '(2) = f '(g(1)) g'(1) f '(2) =
( )
2
) 2 ( ' f
g'(1) = (4)
2
4 = 64
Hence ) 2 ( ' h =
64
= 8. Ans.]
PART-C
Q.1
[Sol. ABC = | | 1 5 3
1
b
2
x 0 2
5 x 1
2 0 3
2 (
(

(
(

=
| | 1 5 3
4 x
3 bx
2 6
2 (
(

=
(
(

4 x . .
. 15 bx 5 .
. . 24
2
Tr(ABC) = 24 + 5bx 15 x
2
4 = x
2
+ 5bx 43
Tr(ABC) s 18 x e R
x
2
+ 5bx 43 s 18 x e R
x
2
+ 5bx 25 s 10 x e R
D s 0 25b
2
4 ( 1) ( 25) s 0
b
2
4 s 0
b e [2, 2]
Number of integral values of b are 5. Ans.]
MATHEMATICS
Code-A Page # 6
Q.2
Sol. I =
}
|
.
|

\
|
+
3
1
2
2
dx ) x 1 ( n
x
1
l
I = ( )
}
+
3
1
2
2
dx x 1 n
x
1
2
1
l
2I =
( )
}
+
+
(

(
+
3
1
2
3
1
2
dx
x
1
x 1
x 2
x
x 1 n l
2I =
( )
| |
3
1
1
x tan 2 ) 2 ( n
3
4 n

+ + l
l
2I = ln 2
6 3
2
1
t
+ |
.
|

\
|

I = ln 2
12 3
1
2
1 t
+ |
.
|

\
|
. Ans.]
Q.3
[Sol. Given that p
1
, q
1
, p
2
q
2
are in A.P.
(p
2
p
1
)
2
= (q
2
q
1
)
2
(p
2
+ p
1
)
2
4p
1
p
2
= (q
2
+ q
1
)
2
4q
1
q
2
|
.
|

\
|

|
.
|

\
|

9
c
4
9
b
2
= |
.
|

\
|

|
.
|

\
|
c
9
4
c
b
2

81
9 c 4
81
b
2

+ =
2
+
c
c 36
c
b
2
2

81
c 36 b
2
+
=
2
+
c
c 36 b
2
c
2
= 81
c = 9 (As c = 9 reject) think!. ]
Q.4
[Sol. We have f(x) = e + (1 x)
}
+
|
.
|

\
|
x
1
dt ) t ( f
e
x
n l .......(1)
Differentiate both sides with respect to x, we get
f '(x) = (1 x) |
.
|

\
|
+
e
x
n
x
1
l (1) + f(x) f '(x) f(x) =
|
|
.
|

\
|
|
.
|

\
|

e
x
n 1
x
1
l
Multiplying both sides with e
x
, we get
e
x
f '(x) e
x
f(x) = e
x

|
|
.
|

\
|
|
.
|

\
|

e
x
n 1
x
1
l

( ) ) x ( f e
dx
d
x
= e
x

|
|
.
|

\
|
|
.
|

\
|

e
x
n 1
x
1
l
MATHEMATICS
Code-A Page # 7
On integrating both sides with respect to x, we get e
x
f(x) = e
x

} |
|
.
|

\
|

|
.
|

\
|

dx
x
1
e
x
n e
x
l
= e
x
+ e
x

|
.
|

\
|
e
x
n l + f(x) = 1 +
|
.
|

\
|
e
x
n l + e
x
.......(2)
Now, putting x = 1 in equation (1), we get f(1) = e .......(3)
Using (3) and (2), we get = 1.
Thus, f(x) = 1 + e
x
+
|
.
|

\
|
e
x
n l or f(x) = e
x
+ ln x.
1
O
x
y
Hence g(x) = x ln x ; Now A =
}
1
0
dx x n xl =
4
1
A
2
=
2
4
1

|
.
|

\
|
= 16. Ans.]
Q.5
[Sol. Two balls transferred from I to II can be 1 W and 1 B or both W or both B.
B
1
: 1 W and 1 B From I II
2 5 II Bag
3 4 I Bag
B W Balls

P(B
1
) =
2
7
1
3
1
4
C
C C
=
21
12
=
7
4
B
2
: 2W from I II
P(B
2
) =
2
7
2
4
C
C
=
21
6
=
7
2
B
3
: 2 B from I II
P(B
3
) =
2
7
2
3
C
C
=
21
3
=
7
1
Now, P (ball drawn from II is white) = |
.
|

\
| 4
9
6
7
=
63
24

63
43
=

+
9
7
7
2
|
.
|

\
|
=
63
14
+
9
5

7
1
|
.
|

\
|
=
63
5
. ]
MATHEMATICS
Code-A Page # 8
Q.6
[Sol. C
1
: 1
4
) 2 y (
9
) 3 x (
2 2
=

A
1
(6, 2) and A
2
(0, 2)
A (0,2)
2 A (6,2)
1
(3,2)
2 3 PA PA
2 1
= .
Clearly, locus of P is a hyperbola whose A
1
A
2
= 2ae = 6 foci are A
1
and A
2
and 2a =
2 3
.
e =
2
Locus of P is a rectangular hyperbola
a = b =
2
3
.
Equation of conic C
2
is (x 3)
2
(y 2)
2
=
2
9
.
D
1
: Distance between foci of the conic is A
1
A
2
= 6.
D
2
: A
1
, A
2
are the foci of the conic C
2
Product of the perpendicular from A
1
and A
2
upon its any tangent is equal to b
2
i.e.,
2
9
.
D
3
: L =
2
9
9
=
2
3
.
3 2
L
3
Hence
|
|
.
|

\
|
2
3
2 1
D
D D
= 6. Ans.]
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. mv
2
L
=
12
1
ML
2
e
2
.......(i)
mv = MV
0
.......(ii)
V 0
0 2 / L v
0

e +
= 1 .......(iii) ]
Q.2
[Sol. t =
80
T
t =
80
27 . 1
cm = 0.015875 cm = 0.15875 mm
t = 0.159 mm ]
Q.3
[Sol. W =
}
pdV =
}
dV V C
3 / 2
P = CV
2/3
=
5
C 3
V
5/3
=
5
3
(P
2
V
2
P
1
V
1
)
=
5
3
nR (T
2
T
1
) =
5
3
1
3
25
30 = 150 J ]
Q.4
[Sol. E goes from higher potential to lower potential
E =
x
V
A
A
=
05 . 0
V V
0 3

V
3
= 400 0.05 = 20V ]
Q.5
[Sol.
2
x
=
l
l
1
x
2
=
) 2 . 0 ( 1
2 . 0
+
+
l
l
=
l
l

+
8 . 0
2 . 0
) 8 . 0 )( 1 (
) 2 . 0 (
l l
l l

+
= 1
l
2
+ 0.2 l = 0.8 + l
2
0.8 l l
2l = 0.8
l = 0.4 m
2
x
=
6 . 0
4 . 0
x =
3
4
x
2
=
) 2 . 0 ( 1
2 . 0


l
l
=
l
l

2 . 1
2 . 0
PHYSICS
Code-A Page # 2
1 =
) 2 . 1 )( 1 (
) 2 . 0 (
l l
l l


l
2
0.2 l = 1.2 + l
2
2.2 l
2l = 1.2
l = 0.6
x =
4 . 0
6 . 0 2
= 3O ]
Paragraph for question nos. 6 to 8
[Sol. Case-I :
TF
Rest
OSC
Rest
Case-II :
TF OSC
Rest
v
Case-III :
TF OSC
Rest
u
(6) For P
A
& P
C
K
A
= K
C
belong to case-I or case-III
For case-III, frequency is more.
P
A
belongs to case-III
P
C
belongs to case-I
P
B
belongs to case-II
I-C, II-B, III-A
(7) C = 320 m/s f = 248 Hz
f ' =
V C
C

f
256 =
V 320
320

248 V = 10 m/s
(8) f'' =
C
u C+
f
2
527
=
320
u 320 +
248 u = 20 m/s ]
Q.10
[Sol.
2
1
v
r
2
> AE
2
1
2
m
(v 0)
2
> 0.5

2
1
mv
2
> 1 MeV ]
PHYSICS
Code-A Page # 3
Q.11
[Sol. Q = (m
T
+ m
H
2m
D
)C
2
4 = (m
T
+ 1.0078 2 2.0141) 931.5
4.294 10
3
= m
T
+ 1.0078 4.0282
4.0282 1.0078 0.0043 = m
T
= 3.0161 amu ]
PART-C
Q.1
[Sol. | = B tr
2
=
R 2
I
0
tr
2
=
R 2

0

R 2t
c
tr
2
=
2
2
0
r
R 4

c
c
ind
=
2
2
0
R 4
r

dt
dc
i
ind
=
) r 2 (
ind
t
c
=
t

2
0
8
r
dt
dc
= 1.25 AA ]
Q.2
[Sol.
30
4
+
60
1
+
=
30
1
3
4

=
90
1
60
30 R
v 3
4
=
90
1

60
1
v 3
4
=
60
3 2
v = 240 cm ]
Q.3
[Sol. r =
2 1
2
2
2
1
v v
E E
+
+
=
o
+
o
(

o
+
(

o
sin d
kq
cos d
kq
) sin d (
kq
) cos d (
kq
2
2
2
2
=
(

o o
o + o
o o
o + o
cos sin
cos sin
d
cos sin
cos sin
4 4
4 4
=
o o o + o
o + o
4
cos sin ] cos [sin d
cos sin
4
= 5 ]
PHYSICS
Code-A Page # 4
Q.4
[Sol. P = P
0
+
A
mg
mg
P A
0
PA
Q = nc
p
AT =
|
|
.
|

\
|
A

V P
1
Power =
1

PAvv
i
2
R =
1

(P
0
A + mg)v
v =
7
2

10 10 10 10 10
350 ) 2 . 0 (
4 5
2
+

m/s = 2 cm/s ]
Q.5
[Sol. T = 2t
g

nT
T nA
=
l
l
2
A
T 100
T
=
l
l
2
A
l
l A
=
100
200
= 2 ]
Q.6
[Sol. AE =
2
1

5 . 0 1
5 . 0 1
+

(1 (0.5))
2

|
.
|

\
|

4
1
1
=
3
5 . 0
1.5
2
1.5
4
3
=
16
5 . 4
J
1 1000 AT =
2 16
5 . 4

AT =
64
9
10
3
C ]
CHEMISTRY
Code-A Page # 1
PART-A
Q.1
[Sol. Given E
n
E
1
= 108.9 eV
eV 9 . 108
1
Z
6 . 13
n
Z
6 . 13
2
2
2
2
=
|
|
.
|

\
|

|
|
.
|

\
|

13.6 Z
2

(

2
n
1
1
= 108.9 eV ....(i)
Given
n

1
= 2tr
1
2
1
1 n
r 2 2
1
r 2
n
r 2
t =
|
.
|

\
| t

t
(by 2tr
n
= n)
1 1
2
1
r 4 r 2
n
n r 2
t = t
t
n 1 = 2
n = 3
Putting n back in eq. (i)
Z = 3 ]
Q.2
[Sol. Co(CO)
4
EAN = 27 +2(4) = 35
(i) Co(CO)
4


duction Re
| |

4
) CO ( Co EAN = 27 (1) + 2(4) = 28 + 8 = 36
(ii) Co(CO)
4


Dimerises
Co
2
(CO)
8
EAN =
2
) bond to due ( 2 ) 8 ( 2 2 27 o + +
= 36
(iii) Co(CO)
4


Oxidation
| |

4
) CO ( Co EAN = 27 1 + 2(4) = 34
Not gain extra stability by oxidation ]
Q.3
[Sol. (A) N
2
is evolved on heating (B) gives red colour as it is having N as well as S (D) Inorganic compound
do not give Lassaigne's test for nitrogen ]
Q.4
[Sol. [Cr(H
2
O)
5
NO
2
] Br
2

Isomer
linkage
[Cr(H
2
O)
5
ONO] Br
2
Pentaaquanitrito-'O' chromium (III) bromide.]
Q.5
[Sol. Na 4[Fe(CN)
5
NOS]
Fe
+2
d
6
sys.
Hybridisation of Fe in complex is d
2
sp
3
]
CHEMISTRY
Code-A Page # 2
Q.6
[Sol. Cr
2
O
7
2
+ Fe
2+
Fe
3+
+ Cr
+3
E = +ve
Cr
2
O
7
2
+ C
2
O
4
2
Cr
3+
+ CO
2
E = +ve
MnO
4
+ Fe
+2
Mn
+2
+ Fe
+3
E = +ve
MnO
4
+ C
2
O
4
2
Mn
+2
+ CO
2
E = +ve
Cr
2
O
7
2
+ Cl Cr
3+
+ Cl
2
E = ve
MnO
4
+ Cl Mn
+2
+ Cl
2
E = +ve
MnO
4
can't be used to estimate FeC
2
O
4
in presence of dil.HCl as it will also oxidise Cl to Cl
2
.]
Q.7
[Sol. (n
f
= 6) (n
f
= 3)
Cr
2
O
7
2
+ FeC
2
O
4
Cr
3+
+ Fe
3+
+ CO
2
50 ml
0.1 M
5 millimoles
5 6 Milliequivalents
M
eq
of Cr
2
O
7
2
= M
eq
of feC
2
O
4
= 30
Millimoles of FeC
2
O
4
=
3
30
= 10 ]
Q.8
[Sol. Millimoles of KMnO
4
used = 50 0.1 = 5
M
eq
of KMnO
4
used = 5 5 = 25 = M
eq
of Cl + M
eq
of FeC
2
O
4
(n
f
= 5)

M
eq
of Cl = M
eq
of Cl
2
= 3.5 2 = 7
(n
f
= 2)
M
eq
of FeC
2
O
4
= 25 7 = 18
(n
f
= 3)
Millimoles of FeC
2
O
4
=
3
18
= 6 ]
Q.9
[Sol. Stability of radical = c > a > b
Bond energy = b > a > c]
Q.10
[Sol. Stability h > g > d
N sp of
C sp of
3
EN EN >
Acidic strength = h > g > d ]
CHEMISTRY
Code-A Page # 3
Q.11
[Sol. K
b
f > e > d ]
PART-C
Q.1
[Sol.

after adding of NaOH to weak monoprotic acid, pH is in the acidic medium i.e. NaOH added is
quite lesser
After addition of 50 ml NaoH 0.1 M
HA + NaOH NaA + H
2
O
(50 ml, xM) (50 ml, 0.1 M)
50 x millimoles 5 millimoles
Left mmoles in solution (50x 5) 0 5
pH = pK
a
+ log
] HA [
] A [
4.699 = pK
a
+ log
|
.
|

\
|
5 x 50
5
....(i)
After adding of 75 ml NaOH 0.1 M
Left millimoles of HA = 50 x 7.5
Millimoles of NaA formed = 7.5
pH = pK
a
+ log
] HA [
] A [
5 = pK
a
+ log
|
.
|

\
|
5 . 7 x 50
5 . 7
....(ii)
On subtracting (ii) (i)
0.3010 = log
|
.
|

\
|

5
) 5 x 50 (
5 . 7 x 50
5 . 7
= log 2
on solving x = 0.3
pK
a
= 5 ab = 05
On adding 7.5 millimoles of HCl
NaA + HCl NaCl + HA
15 Millimioles 7.5 Millimoles
7.5 Millimoles 0 7.5 Millimoles
pH = pK
a
+ log
] HA [
] A [
= pK
a
+ log
5 . 7
5 . 7
pH = pK
a
= 5 cd = 05 ]
CHEMISTRY
Code-A Page # 4
Q.2
[Sol. A
2
B
3
(aq) 2A
+3
(aq) + 3B
2
(aq)
Initial conc. a 0 0
at time t = 10 min ax 2x 3x
a 2
1 + 4x 6
3
a
x 4 a
=
+
a = 2x x =
2
a
t
1/2
= 10 min. t
3/4
= 2 t
1/2
= 20 min.
ab = 20
at t = 20 min
A
2
B
3
(aq) 2A
+3
(aq) + 3B
2
(aq)
a
t = 20 min
4
a

2
a 3
4
a 9
= 2 t
1/2
a 2

8 a 4
4
a 9
2
a 3
4
a
= + +
at t = 20 min osomotic rise = 8 mm of Solution
t = h g = 8 10
3
1 10
3
10
= 80 Pascal
cd = 80 ]
Q.3
[Sol. [Cr(NH
3
)
6
]Cl
3
[Cr(NH
3
)
6
]
3+
+ 3Cl

One complex cation + 3 simple anion

Total = 4 ]
Q.4
[Sol.
ideal
=
3
A
0
a
N
M
Z
24
24
3 10
A
10 125
10 67 . 1 25 . 31 4
) 10 500 (
N
25 . 31
4

= 1.67 g/ml

actual
= 1.6075 g/ml
Differenve due to Schottkey effect = 1.67 1.6075 0.0625 g/ml
= 0.0625 10
3
g/L
= 62.5 g/L
CHEMISTRY
Code-A Page # 5
=
L / Mole
25 . 31
5 . 62
= 2 mole/L ]
Q.5
[Sol. [Cr(H
2
O)
6
]
3+
Cr
3+
4s
0
3d
3
Hund's rule is not followed then unpaired electron is one

]
Q.6
[Sol. [M(AB)a
2
bc]
n

c by replace b
[M(AB)a
2
c
2
]
n
m
a
b
a
A
B
c

m
a
b
a
A
B
c
m
a
c
a
A
B
c

m
c
a
a
A
B
c
m
b
c
a
A
B
a

m
b
c
a
A
B
a
m
c
a
A
B
a
c

m
a
c
A
B
c
a
m
a
c
a
A
B
b

m
c
a
a
A
B
b
m
a
b
A
B
c
a
G. I. 4 S.I. = 6
7 G.I. Total change in
12 S.I.
R
e
d
u
c
e
d
n
o
. o
f
G
.I. iso
m
e
rs
b
y
th
e
se
S.I. = 12 6 = 0006 ]