Professional Documents
Culture Documents
ABSTRACT
INTRODUCTION
310
BEM and Magnetic Field Measurement for Detection of Corrosion in Reinforced Concrete: An Overview
Ridha et. al. (2001 and 1999) has reported the identification method for
solving the above problems. However, since the existing equipments for
measuring the potential is less sensitive (about tens m-Volt), the methods still
have some limitations to precisely detect corrosion in concrete structure.
The corrosion current has an associated magnetic component. The intensities
of the associated magnetic fields should be very low since the corrosion currents
are small (about some µA/cm2). Such fields could be measured by using the
superconducting quantum interference device (SQUID), which is an extremely
sensitive magnetic field sensor (Jenks et. al. 1999, 1997, Wikswo 1996,
Bellingham et. al. 1986, Li et. al. 1988)
In this paper, the concept of inverse analysis by combining BEM and
magnetic field measurement is introduced to detect the location of steel corrosion
in concrete and also noted some challenges to refine the introduced method.
Fe → Fe 2+ + 2e (1)
At the cathode, the electrons combine with oxygen and moisture to form
hydroxide ions.
1
O 2 + H 2 O + 2e → 2OH − (2)
2
The total corrosion rate is the self-corrosion rate plus the galvanic corrosion
rate. The self-corrosion rate can be neglected since it is generally much lower
than the galvanic corrosion rate.
The corrosion rate is proportional to the density of current across the surface
of an anode, so the analysis of corrosion problem can be reduced to computing
the electro-galvanic field due to multiple anodic/cathodic interactions
An electric current flow occurs due to the above reactions. A polarization
curve given in Figure 1 shows the relationship between the current density i
across the steel surface versus electrical potential in the electrolyte near the metal
surface to a reference electrode E. These relationships between i and E for anodic
and cathodic reaction (solid curves) are not obtained individually, but only
nominal relationship E = f(i) for the two reactions (dashed curve) is measured. In
natural state, the reaction become in equilibrium at point R. The current
corresponding to RS flows from anode to the cathode due to galvanic effect.
311
A. K. Ariffin, N. A. Nik Mohamed and S. Abdullah
The potential field in the concrete domain (Ω) can be modeled mathematically by
the Laplace's equation:
∇2φ = 0 in Ω (3)
i=0 on Γs (4)
where fa(i) and fc(i) are the non-linear functions representing the experimentally
determined polarization curves for corroded and non-corroded areas on the steel
in concrete, respectively.
The minus signs on the right hand sides of Equation (6) and (7) are due to the
fact that the potential in the electrolyte near the metal surface, φ, is equal to
minus value of potential difference between the metal and the reference
electrode, such as saturated calomel electrode, SCE. It is noted that the potential
φ is defined with referring to the metal and has the inverse sign of the employed
usually in the corrosion science. The potential within the steels has been imposed
as the reference potential (i.e. zero volts) for the numerical calculations.
312
BEM and Magnetic Field Measurement for Detection of Corrosion in Reinforced Concrete: An Overview
⎧φ s ⎫ ⎧ io ⎫
⎪ ⎪
κ [H ]⎨ − f (i a ) ⎬ − [G ]⎪⎨ i a ⎪
⎬ = 0 (8)
⎪ − f (i ) ⎪ ⎪i ⎪
⎩ c ⎭ ⎩ c ⎭
where the detail expression of matrices [H] and [G] are given in references
(Brebbia 1980), and the subscripts s, a, c and m represent the quantities on Γs,
Γm1 and Γm2, respectively. The system of non-linear algebraic equation in
Equation (8) can be solved by the iterative procedures, e.g. the Newton-Raphson
method. An experimental verification of the boundary element solution is shown
in reference (Aoki et. Al. 1998).
313
A. K. Ariffin, N. A. Nik Mohamed and S. Abdullah
µ o ⎡ i ( P ) d Ω ( P ) × r (Q , P )
4π ⎣⎢ Ω∫
B (Q ) = ⎢ 3
r (Q , P )
(9)
Nm⎛ I ( S ) dL ( S ) × r (Q , S ) ⎞ ⎤
+ ∑⎜ ∫ ⎟⎥
⎜ r ( Q , S )
3
⎟⎥
⎝
k =1 L mk
⎠⎦
where B is the magnetic flux density (in Tesla). i(P) is the current density at
point P in Ω. r is the vector of distance between source and observation points.
I(S) is the current that flows through a steel at point S.
Current
Suply
I SQUID
Magnetometer Controller
Dewar
Data
SQUID Acquisition
Concrete SQUID pickup
surface (Γn ) CE coils
Q
rPQ
Reinforcing P rPS
steel S
Noncorroded area(Γm2 )
φ=0
2
− φ 2 = f m2 (i)
314
BEM and Magnetic Field Measurement for Detection of Corrosion in Reinforced Concrete: An Overview
No X (m) B
(pTesla)
1 1.19 142
2 1.23 159
3 1.27 171
4 1.31 184
5 1.35 201
Figure 3 shows the convergence of the inverse analysis result for detection of
the corrosion location in concrete. In the figure, Ridha et. al. (2006) shows that
the estimated location of corrosion was X = 1.2859375 m (the exact location, i.e.
X=1.30 m).
The research conducting by Ridha et. al. (2006 and 2005) has shown the
effectiveness the method for identification of reinforced concrete corrosion.
However, there are still many limitations that have to overcome in refining the
method. Some assumptions that made earlier need to be reviewed again since it is
the properties of material such as ferromagnetic of steel and magnetic
permeability of concrete.
In addition, there are some possibilities to improve the accuracy in detection
of corrosion using BEM and magnetic measurement. The type of element used in
the analysis can be improved into higher order element i.e. two- and three-
dimensional element. The need to reduce time consumption during simulation
can be fulfilled by applied post- and pre-processor into the program.
315
A. K. Ariffin, N. A. Nik Mohamed and S. Abdullah
CONCLUSIONS
REFERENCES
Aoki, S., Amaya, K., and Miyasaka, M. 1998. Boundary Element Analysis on
Corrosion Problems, Shokabo, Tokyo: 24-25 (in Japanese).
Bellingham, J.G., MacVicar, M.L.A., Nisenoff, M., and Searson, P.C. 1986,
Detection of Magnetic Field Generated by Electrochemical Corrosion, J of
Electrochemical Society, Vol 133: 1753.
316
BEM and Magnetic Field Measurement for Detection of Corrosion in Reinforced Concrete: An Overview
Hertlein B.H. 1992. Assessing the Role of Steel Corrosion in the Deterioration of
Concrete in the National Infrastructure: A Review of the Causes of
Corrosion and Current Diagnostic Techniques, Corrosion Forms and
Control for Infrastructure, ASTM STP 1137, Ed. by V. Chaker, p.356.
Jenks W.G., Thomas, I.M., and J.P. Wikswo Jr., J.P. 1997, SQUIDS,
Encyclopedia of Applied Physics, Vol 19(3): 457.
Jenks, W.G., Sadeghi, S.S.H., and J.P. Wikswo Jr., J.P. 1999, SQUIDs for
Nondestructive Evaluation, J. Physics D: Applied Physics, Vol 30: 293.
Li, D., Ma, Y., Flanagan, W.F., and J.P. Wikswo Jr., J.P., 1998 Detection of
Hidden Corrosion of Aircraft Aluminum Alloys by Magnetometry Using a
Super-conducting Quantum Interference Device, Corrosion, Vol 53(2): 93-
98.
Press, W.H., Teukolsky, S.A., Vetterling, W.T., Flannery, B.P. 1992. Numerical
Recipes in Fortran 77 - The Art of Scientific Computing, 2nd Ed., Cambridge
University Press, England: 402.
Wikswo Jr., J.P., 1996, The Magnetic Inverse Problem for NDE, in SQUIDs
Sensors: Fundamental, Fabrication and Application, eds H. Weinstock,
Kluwer Academic Publishe, Nederland: 629.
317