Unit Test-2

Chemistry

Section-I (5 1) = 5 1. Bohr atomic model can explain (a) The spectrum of hydrogen atom only (b) Spectrum of an atom or ion containing one electron only (c) The spectrum of hydrogen molecule (d) The solar spectrum The principal quantum number of an atom is related to the (a) Size of the shell (b) Spin angular momentum (c) Orbital angular momentum (d) Orientation of the orbital in space The correct set of quantum numbers for the unpaired electron of chlorine atom is (in the order as n, l, m) (a) 2, 1, 0 (b) 2, 1, 1 (c) 3, 1, 1 (d) 3, 0, 0 The orbital diagram in which Aufbau principle is violated is
2s 2px 2py 2pz

2.

3.

4.

2s

2px 2py 2pz 2px 2py 2pz

(a)
2s 2px 2py 2pz

(b)
2s

(c) 5.

(d)

How many unpaired electrons are there in Ni2+? (a) 0 (b) 2 (c) 4 Section-II (3 2) = 6

(d) 6

6. 7.

Calculate the wave number for the longest wavelength transition in the Balmer series of atomic hydrogen. If the photon of the wavelength 150 pm strikes an atom and one of its inner bound electrons is ejected out with a velocity of 1.5 107 ms1, calculate the energy with which it is bound to the nucleus. The quantum numbers of six electrons are given below. Arrange them in order of increasing energies. If any of these combination(s) has/have the same energy lists 1. n = 4, l = 2, ml = -2, ms = 1/2 2. n = 3, l = 2, ml = 1, ms = +1/2 3. n = 4, l = 1, ml = 0, ms = +1/2 4. n = 3, l = 2, ml = 2, ms = 1/2 5. n = 3, l = 1, ml = 1, ms = +1/2 6. n = 4, l = 1, ml = 0, ms = +1/2 Section-III (3 3) = 9

8.

9. 10.

A microscope using suitable photons is employed to locate an electron in an atom within a distance of 0.1 . What is the uncertainty involved in the measurement of its velocity? (i) (ii) (iii) Write the electronic configurations of the following ions : (a) H (b) Na+ (c) O2 (d) F What are the atomic numbers of elements whose outermost electrons are represented by (a) 3s1 (b) 2p3 and (c) 3p5? Which atoms are indicated by the following configurations? (a) [He] 2s1 (b) [Ne] 3s2 3p3 (c) [Ar] 4s2 3d5

11.

Neon gas is generally used in the sign boards. If it emits strongly at 616 nm, calculate (a) the frequency of emission (b) distance traveled by this radiation in 30 s (c) energy of quantum and (d) number of quanta present if it produces 2 J of energy. Section-IV (1 5) = 5

12.

(a) Explain briefly about Aufbau principle, pauli exclusion principle and Hunds Rule with examples? (b) Give the structure and shapes of s, p, d, f orbitals? (c) Write the electronic configuration for Cu and Cr?