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INTRODUCTION
Nanotechnology research is entirely multidisciplinary and the results of such research can
be applied very quickly to real products. Nanomaterials are of great scientific and
technological interest because of their potential to exhibit new characteristics that cannot
be achieved with micromaterials (Pereira de Abreu et al., 2007). Now, at nanoscale one
enters a world where physics and chemistry meet and develop novel properties of matter.
In chemistry, this range of sizes has historically been associated with colloids, micelles,
More recently, structures such as bucky tubes, silicon nanorods, and compound
associated with quantum behavior, and the behavior of electrons and photons in
biology – from DNA and viruses to sub-cellular organelles and gap junctions can be
In material technology, nanomaterial is the most important part to develop the structure
of material that can adapt under different environmental conditions. Organic nanocrystal
can be synthetic or natural. Synthetic organic nanocrystal may include perylene and
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anthracene. Natural organic nanocrystal include cellulose, starch etc. due to sustainable
The existing challenge in the polymer fabrication is to provide a sufficiently high tensile
strength due to local stress within the nanomaterial. In other words, the response of a
material to an applied stress is strongly dependent on the nature of the bonds. The
the local stress transfer and determining the quality and properties of the nanomaterial
In addition, synthetic polymeric materials are rapidly replacing more traditional inorganic
materials, such as metals and natural polymeric materials (wood, fibers). As these
initiated a search for alternative flame-retardant additives. For this purpose, inorganic
nanoparticles have become attractive since they can simultaneously improve the physical,
decades, have become worldwide research interest for developing polymeric materials
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Organic and polymer nanocrystals, ranging in size from tens of nanometers to several
hundred nanometers, represent an intermediate phase between single molecules and the
corresponding bulk crystal. In very few systems, the nanoparticulates have been
A trend has been towards incorporating natural fibers into composites. This shift has been
Natural fillers offer a cost effective and renewable alternative to their synthetic
from cotton, flax, hemp, jute, sisal, kenaf and coir have been incorporated into polymer
composites. Other sources of cellulosic fillers include wood flour/fibers, recycled fiber-
based products like newspaper and strengthened interface agricultural residues such as
rice husks and sugarcane bagasse. These natural fibers provide several benefits over
synthetic fibers. Cellulose fibers are non-toxic, biodegradable and recyclable. Natural
plant fibers are generally of lower density and exhibit high specific strength and stiffness
that allow the production of low-density composites with higher filler concentration.
Composites made from cellulosic fibers and thermoplastic matrices have generated
interest because they promise lower environmental impact when compared with more
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Additionally, natural fibers have flexibility and are therefore less susceptible to fracture
during processing, resulting in these fibers maintaining their specific aspect ratio.
Polypropylene (PP) is one of the most important and widely used polyolefin. Its low
density, low production costs, design flexibility and recyclability make it a popular
with polar surfaces, such as cellulose, are used (Steven Spoljaric et al., 2009).
3. To test the melt flow, strength and thermal properties of the sample.
CHAPTER 2
LITERATURE REVIEW
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2.1 Organic nanocrystals
These organic nanocrystals were fabricated to investigate the effect of solvent on organic
nanocrystal were prepared by the reprecipitation method in which a dilute solution of the
compound prepared by water soluble solvent, i.e. good solvent, is injected into vigorously
stirred water as a poor medium. These nanocrystals have been the subject of much
interest in recent years due to their novel optical and electronic properties, which depend
were used as ‘good’ solvents without further purification. Ultra-pure water (18.2MΩcm)
was used as a ‘poor’ solvent. The compound was dissolved in the good solvent and the
solution (2mM, 100 µl) was injected into vigorously stirred water (10 ml) using a
nanocrystals were removed from the solution by filtration using a Millipore filter, or
deposited on a substrate using a layer-by-layer procedure, and dried in air for SEM
measurement. The crystal structure of perylene and anthracene nanocrystals was analyzed
The resulting nanocrystals are dispersed stably in water. The perylene nanocrystal growth
process showed good solvent and temperature dependence. After 20 min, it was found that
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crystal size increased gradually with time, and was also higher at elevated crystallization
temperatures. We should employ the experimental results at room temperature (298 K) for
the purpose of investigating effect of the good solvent in the reprecipitation method.
Actually, after 24 h crystal size became almost constant at 298 K, and this value was
defined as the pseudo equilibrium size in the present study. It was found that the average
decreased as the dielectric constant of the good solvent increased, while the size of the
the aqueous dispersion liquid. The relationship between size and solvent dielectric
constant for anthracene nanocrystals is the inverse of that found for perylene nanocrystals.
due to its availability of renewable recourses. Available nanocrystals include cellulose and
starch. The nanocomposite structure has strong potential to develop various kinds of
multifunctional materials for the energy and environment sectors. Properties which have
strength, modulus and dimensional stability, decreased permeability to gases, water and
hydrocarbons, thermal stability and heat distortion temperature, flame retardancy and
To date one of the few disadvantages associated with nanoparticles incorporation has
concerned toughness and impact performance. Some of the data presented has suggested
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performance. Clearly this is an issue which would require consideration for applications
where impact loading events are likely. In addition, further research will be necessary to,
Cellulose is one of the most abundant natural materials, typically found in the cell walls
of plants. The crystalline form of it can be derived through the hydrolysis of a variety of
biopolymers such as wood, cotton, and tunicate in sulfuric acid. This will produce either
needle or rod shaped nanocrystals with a range of aspect ratio depending on the raw
carbon nanotubes (~1 TPa). The single layer adsorption of cellulose nanocrystals was
demonstrated to be fast and produced films of very high loading. This creates a
polymer/nanocrystal film with exceptional strength. The low cost of raw material, ease of
dispersion, and adsorption quality may allow for more efficient mass production of layer-
by-layer composite films using either dipping or spraying methods (Lang Sui et al.,
2008).
The polymer/nanocrystal films are made using the layer-by-layer deposition method.
substrate to produce a thin film. The films elastic moduli were measured using Brillouin
light scattering (for films as thin as 250 nm) in the backscattering geometry. Using this
technique, elastic properties of a material are derived from the inelastic scattering of light
as it interacts with acoustic phonons. Comparison between the behaviors of surface and
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bulk acoustic modes allowed us to elucidate the effect of the thickness of individual
layers relative to the total film thickness on the overall elastic properties of the
different aspect ratios were measured using Brillouin light scattering. Short cellulose
nanocrystals with length of ~200 nm were produced from the hydrolysis of filter paper
powder in sulfuric acid. Long crystals with lengths of several microns were produced by
the bleaching and hydrolysis of tunicate using sulfuric acid. Layer-by-layer films are
chloride (PDDA) and cellulose nanocrystals. The moduli of films with long crystals are
observed to be dramatically higher than films with short crystals for both
Depending on their origin, the microfibril section ranges between 2 and 20 nm for lengths
that can reach several tens of microns. They aggregate further to form fibers. Therefore,
each natural fiber can be considered as a string of cellulose crystallites, linked along the
The nanocrystals can be used in ceramics and in biomedical applications such as artificial
plastics has advantages over the glass that is often used: Glass is heavier, harder on
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processing machinery and therefore more expensive to work with, and it stays in the
ground for centuries. The cellulose nanocrystals will break down quickly in a landfill.
Anything which is made in nature can be destroyed in nature and these cellulose particles
have a lifetime in a landfill of less than 90 days, at which time, they go back into carbon
dioxide and water. It can be reabsorbed by other plants that use it to make more cellulose
In Winter’s process, the cellulose is first purified in the laboratory as substances such as
wax and gluey lignin are removed from the biomass. The cellulose then goes through a
homogenizing process, similar to the one used with dairy products. The cellulose is
shredded into tiny particles under high pressure, rendering nanocrystals, so-called
because they are so miniscule they are measured in nanometers. The result is a viscous,
white liquid that goes into a microcompounder, where it is mixed with plastic under high
pressure. The unit produces a cord or a ribbon, depending on the die being used to shape
it of crystal-reinforced plastic that can tested for several properties. Winter’s team is
currently working on refining the surface of the crystals so they adhere better to the
plastic, and disbursing the crystals throughout the material to achieve the best results. In
the future, Winter said the process could be tied to the production of cellulosic ethanol.
When hemicellulose is removed from wood for fermentation into ethanol, it leaves
behind cellulose that can be treated with enzymes and reduced to the nanocrystals uses in
the lab. The value of those crystals in industrial uses represents a significant reduction in
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2.2 Polypropylene
between that of low density polyethylene (LDPE) and high density polyethylene (HDPE);
its Young's modulus is also intermediate. PP is normally tough and flexible, especially
economical, and can be made translucent when uncolored but is not as readily made
scanning calorimetry (DSC). The MFR (Melt Flow Rate) or MFI (Melt Flow Index) is a
measure of PP's molecular weight. This helps to determine how easily the molten raw
material will flow during processing. Higher MFR PPs fill the plastic mold more easily
during the injection or blow molding production process. As the melt flow increases,
There are three general types of PP: homopolymer, random copolymer and block
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2.2.2 Degradation of Polypropylene
Carbon black also provides some protection from UV attack. The polymer can also be
oxidants are normally added to prevent polymer degradation. The activation energy
estimated for the polypropylene degradation at 250-300°C was not significantly different
Cavitation results in generation of hot spots as well as turbulence associated with liquid
circulation which can result in degradation of polymeric compounds. In the present work
cavitation generated using ultrasound has been utilized for degradation of polypropylene
and effect of different operating parameters on the extent of degradation has been
investigated. It was found that extent of degradation increases with a decrease in reaction
degradation. It was also observed that a constant solution viscosity is reached beyond
which ultrasonic irradiation could not further degrade polypropylene. The limiting
viscosity was also observed to depend on the volume and concentration of polypropylene
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It is a linear structure based on the monomer CnH2n. It is manufactured from propylene
polyethylene (LDPE) and high density polyethylene (HDPE); On the other hand PP has
exposure to heat, shear and light. They broaden the property and application range by
Pigments provide solutions of high technical standard and are most suitable for
broaden and demand excellent processing properties like heat resistance or dispersibility
In general homopolymers (i.e. with only one type of monomer) can be used for housing,
housewares, packaging, cassette holders and fibers, monofilaments and film tapes;
copolymers (i.e. different monomers are involved) are preferred for all applications
exposed to cold and they are widely used for pipes, containers, boat hulls, seat shells and
automotive parts e.g. battery cases and bumpers. Polypropylene can be manufactured to a
high degree of purity to be used for the semiconductor industry. Its resistance to bacterial
of our nonwoven fabrics such as rope used in a variety of industries, including fishing
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and agriculture. PP can be used for flexible packaging applications (e.g. yogurt
containers, syrup bottles, straws, etc.), construction sector (e.g. drainage pipes, pumps,
and properties.
silicone oil, stearic acid or alkyltitanate coupling agent to promote matrix–filler dispersion
and compatibility. The aim was to prepare and characterize PP–microcrystalline cellulose
(MCC) composites, through modification of fiber surface and the addition of PP-g-MA as
a compatibilising agent. Surface treatment of the MCC involved the use of a fatty acid, a
silane coupling agent and an alkyltitanate. The objectives were to characterize the thermal
stability and morphology of the resulting composites and to evaluate the effect of the
The extent of effectiveness for each treatment on the cellulose fibers was evaluated to
identify its impact on the composite performance (Steven Spoljaric et al., 2009).
The thermal stability of PP was marginally (~2 oC) enhanced by increasing the MCC
incorporation of the cellulose fibers into the PP matrix. PP-g-MA increased the thermal
stability of PP by 10 oC and lowered the mass loss rate resulting in degradation occurring
over a broader and higher temperature range. MCC increased the crystallization
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PP-g-MA further increased the Tg of the composites by 2 oC, verifying that PP had
increasing MCC content. This was attributed to the MCC having cellulose II form that does
The modulus (E) of the composites increased with MCC content, confirming effective filler
coupling agents and PP-g-MA that provided enhanced compatibility and allowed greater
stress transfer. Creep deformation decreased and permanent strain increased with MCC
content. This was due to adsorption of the matrix onto MCC, restricting molecular motions
of the PP chains.
CHAPTER 3
METHODOLOGY
3.1 Materials
Polypropylene
Kenaf fiber
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3.2 Formulating by varying ratio of PP.MCC and PP.NCC and kenaf fiber
Before we prepare the sample, we must make a formulating the composition to produce a
sample. We use the various ratio of composition is aim to compare the different ability of
the sample during testing. The formulating composition is shown in the table. Table 3.1
shows the composition of the polypropylene with the microcrystalline cellulose; table 3.2
shows the composition of the polypropylene with the nanocrystalline cellulose: table 3.3
F1 1000 10
F2 1000 20
F3 1000 30
F4 1000 40
F1 1000 0.2
F2 1000 0.5
F3 1000 1.0
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F4 1000 1.5
F3 100 20 - 200
This formulating ratio will use to prepare the sample by using twin screw extruder. Twin screw
The flexibility of twin screw extrusion equipment allows this operation to be designed
specifically for the formulation being processed. For example, the two screws may be co-
elements, reverse conveying elements, kneading blocks, and other designs in order to
achieve particular mixing characteristics. The extruder has two zones that the first zone is
feed zone having uniform screw root diameter and the compression zone with continuously
increasing root diameter. The temperature was measured by using a PT-100 precision
thermocouple and the screw speed was measured by using a proximity switch. One
temperatures below the melting point. The degree of orientation in such polymers is
indicated by the increase in tensile modulus of the oriented polymer over the tensile
modulus of the unoriented polymer. GRP was extruded at a constant feed rate of
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50cm/min and the extrudate has been designated as extrusion processed polypropylene
powder.
The samples will bring to test with tensile and impact testing. Tensile test is probably the
most fundamental type of mechanical test you can perform on material. First of all, the
sample must be form into dumbbell shape or straight shape to perform in tensile test
machine. The rate at which a sample is pulled apart in the test can range from 0.2 to 20
inches per minute and will influence the results. As the material is being pulled, you will
The impact then will be implementing to measure a materials resistance to impact from a
swinging pendulum. The specimen is clamped into the pendulum impact test fixture with
the notched side facing the striking edge of the pendulum. The pendulum is released and
allowed to strike through the specimen. If breakage does not occur, a heavier hammer is
used until failure occurs. Since many materials (especially thermoplastics) exhibit lower
temperatures that simulate the intended end user environment. The standard specimen for
ASTM is 64 x 12.7 x 3.2 mm (2½ x ½ x 1/8 inch). The most common specimen thickness
is 3.2 mm (0.125 inch), but the preferred thickness is 6.4 mm (0.25 inch) because it is not
as likely to bend or crush. The depth under the notch of the specimen is 10.2 mm (0.4
inches).
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3.3.2 Melt flow index
Then the samples are bringing to melt flow indexer to test a measure of the ease of flow
temperatures. The method is given in ASTM D1238 and ISO 1133. The samples are
Differential scanning calorimetry will operate to study what happens to polymers when
they are heated. There are two pans. In one pan, the sample pan, you put your polymer
sample. The other one is the reference pan. You leave it empty. Each pan sits on top of a
heater. Then you tell the nifty computer to turn on the heaters. So the computer turns on
the heaters, and tells it to heat the two pans at a specific rate, usually something like 10 oC
per minute. The computer makes absolutely sure that the heating the rate stays exactly the
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Then the sample is carrying out with TGA to measure the weight changes in the sample.
The temperature programme means the heating or cooling at a linear rate and isothermal
measurements. It also can be combinations of heating, cooling and isothermal stages and
other more modern approaches in which the temperature profile is modified according to
3.5 Morphology
This study also interest to know the morphology of the sample that will carry out by
using scanning electron microscopy (SEM). The SEM is a microscope that uses electrons
instead of light to form an image. The SEM is an instrument that produces a largely
electrons is produced at the top of the microscope by an electron gun. The electron beam
follows a vertical path through the microscope, which is held within a vacuum. The
beam travels through electromagnetic fields and lenses, which focus the beam down
toward the sample. Once the beam hits the sample, electrons and X-rays are ejected from
the sample.
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CITED REFERENCES
Vaibhav Desai, Mohan A., Shenoy, Parag R., Gogate (2008). Degradation of polypropylene
using ultrasound-induced acoustic cavitation. Department of Polymer Engineering
Technology, Institute of Chemical Technology, Matunga, Mumbai 40019, India
Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai
40019, India, 140, 483-487.
Hae-Ryong Chung, Eunsang Kwon, Hidetoshi Oikawa, Hitoshi Kasai, Hachiro Nakanishi
(2006). Effect of solvent on organic nanocrystal growth using the reprecipitation method.
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1
Katahira, Aoba-ku, Sendai 980-8577, Japan, 294, 459–463.
Zhanhu Guo, Ta Y. Kim, Kenny Lei, Tony Pereira, Jonathan G. Sugar, H. Thomas Hahn (2008).
Strengthening and thermal stabilization of polyurethane nanocomposites with silicon
carbide nanoparticles by a surface-initiated-polymerization approach. Mechanical and
Aerospace Engineering Department and Materials Science and Engineering Department,
University of California Los Angeles, Los Angeles, CA 90095, United States, 68, 164–
170.
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D.A. Pereira de Abreu, P. Paseiro Losada, I. Angulo, J.M. Cruz (2007). Development of new
polyolefin films with nanoclays for application in food packaging. Department of
Analytical Chemistry, Nutrition and Bromatology, Faculty of Pharmacy, University of
Santiago de Compostela, 15782-Santiago de Compostela, Spain GAIKER Technological
Centre, 48170 Zamudio, Bilbao, Spain, 43, 2229–2243.
Aparecido Junior de Menezes, Gilberto Siqueira , Antonio A.S. Curvelo, Alain Dufresne (2009).
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polyethylene nanocomposites. Grenoble Institute of Technology, The International
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Studies of Cellulose Nanocrystals-Polymer Composite Thin Films .Materials Science and
Engineering, University of Michigan, 3062 HH Dow, Ann Arbor, MI 48107, Chemical
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