Chemistry 12 Solubility Test # 2

1. Consider the following experiment:

1.0 mL 0.20 M Ag
+
+ an unknown solution preipitate

1.0 mL 020 M !r
2+
+ an unknown solution no preipitate

"he unknown solution ould ontain
A 0.20 M #$
%
& 0.20 M '#(
%
C 0.20 M )#*
(%
+ 0.20 M !#*
2%

2. A ompound has a solu,ilit- of ..1 x 10
%/
M at 2/
o
C. "he ompound is
A Cu!
& Ag&r
C CaC#(
+ Ca!#*

(. A saturated solution of 'aCl ontains (0./ g of solute in 0.100 L of solution. "he solu,ilit- of the
ompound is
A 0.002 M
& 1.00 M
C (.0/ M
+ 0.2* M

*. Calulate the 1Li
+
2 in 200.0 mL of 1./ M Li2!#*.
A 0.(0 M
& 0.00 M
C 1./ M
+ (.0 M

/. "he 3sp expression for a saturated solution of Mg4#$52 is
A 3sp 6 1Mg
2+
21#$
%
2
2
1Mg4#$522
& 3sp 6 1Mg
2+
21#$
%
2
2
C 3sp 6 1Mg
2+
21#$
%
2
+ 3sp 6 1Mg
2+
212#$
%
2
2

0. Consider the following saturated solution solutions

Cu!#* &a!#* Ca!#*

"he order of ation onentration7 from highest to lowest7 is
A 1&a
2+
2 8 1Ca
2+
2 8 1Cu
2+
2
& 1Ca
2+
2 8 1Cu
2+
2 8 1&a
2+
2
C 1Cu
2+
2 8 1Ca
2+
2 8 1&a
2+
2
+ 1Cu
2+
2 8 1&a
2+
2 8 1Ca
2+
2

.. 9hen 1.0 x 10
%(
moles of CuCl24s5 are added to 1.0 L of 1.0 x 10
%(
M :#(
%
7 the

A "rial 3sp 8 3sp and a preipitate forms
& "rial 3sp ; 3sp and a preipitate forms
C "rial 3sp 8 3sp and no preipitate forms
+ "rial 3sp ; 3sp and no preipitate forms
<. "he solu,ilit- of Cd! 6 2.< x 10
%1*
. "he =alue of the 3sp is
A ..< x 10
%2<
& 2.< x 10
%1*
C /.0 x 10
%1*
+ 1.. x 10
%.

>. "he ion onentrations in 0.2/ M Al24!#*5( are
1Al
(+
2 1!#*
2%
2
A 0.2/ M 0.2/ M
& 0./0 M 0../ M
C 0../ M 0./0 M
+ 0.10 M 0.1/ M

10. 9hih of the following will not produe a preipitate when e?ual =olumes of 0.20 M solutions are
om,ined@
A 3#$ and CaCl2
& An4'#(52 and 3()#*
C !r4#$52 and 4'$*52!
+ 'a2!#* and ),4'#(52

11. Consider the following e?uili,rium: Mg4#$524s5 Mg
2+
4a?5 + 2#$
%
4a?5
A ompound that an ,e added to ause a shift to the right is
A 'a#$
& $Cl
C !r4#$52
+ Mg4#$52

12. :f the trial ion produt for Ag&r#( is alulated to ,e 1.0 x 10
%.
7 then
A a preipitate forms ,eause the trial ion produt 8 3sp
& a preipitate forms ,eause the trial ion produt ; 3sp
C no a preipitate forms ,eause the trial ion produt 8 3sp
+ no a preipitate forms ,eause the trial ion produt ; 3sp

1(. 9hih of the following will dissol=e in water to produe a moleular solution@
A CaCl2
& 'a#$
C C$(#$
+ !r4#$52

1*. :n a solu,ilit- e?uili,rium7 the
A rate of dissol=ing e?uals the rate of r-stalliBation
& neither dissol=ing or r-stalliBation ours
C onentration of solute and sol=ent are e?ual
+ mass of dissol=ed solute is greater than the mass of the solution

1/. "he maximum 1!#*
2%
2 that an exist in 1.0 x 10
%(
M Ca4'#(52 without a preipitate forming is
A ..1 x 10
%/
M
& 1.0 x 10
%(
M
C <.* x 10
%(
M
+ ..1 x 10
%2
M

10. 9hen e?ual =olumes of 0.20 M Cu!#*4a?5 and 020 M Li2!4a?5 are om,ined7 the omplete ioni
e?uation is
A Cu
2+
4a?5 + !
2%
4a?5 Cu!4s5
& Cu!#*4a?5 + Li2!4a?5 Cu!4s5 + Li2!#*4s5
C Cu
2+
4a?5 + !#*
2%
4a?5 + 2Li
+
4a?5 + !
2%
4a?5 Li2!#*4a?5 + Cu!4s5
+ Cu
2+
4a?5 + !#*
2%
4a?5 + 2Li4a?5 + !
2%
4a?5 Cu!4s5 + 2Li
+
4a?5 + !
#
*
2%
4a?5

1.. Consider the solu,ilit- e?uili,rium: CaC#(4a?5 Ca
2+
4a?5 + C#(
2%
4a?5
An additional piee of solid CaC#( is added to the e?uili,rium a,o=e. "he rate of dissol=ing and
the rate of r-stalliBation ha=e

Cate of +issol=ing Cate of r-stalliBation
A inreases inreases
& inreases not hanged
C not hanged inreased
+ not hanged not hanged

1<. At 2/
o
C7 whih of the following ompounds would dissol=e to form a saturated solution with the
greatest 1),
2+
2@
A ),:2
& ),Cl2
C ),&r2
+ ),4:#(52

1>. Consider the following anions:
: 10.0 mL of 0.20 M Cl
%
:: 10.0 mL of 0.20 M #$
%
::: 10.0 mL of 0.20 M !#(
2%

9hen 10.0 mL of 0.20 M ),4'#(52 are added to eah of the a,o=e7 preipitates form in

A : and :: onl-
& : and ::: onl-
C :: and ::: onl-
+ :7 ::7 and :::

20. 9hih of the following units ould ,e used to desri,e solu,ilit-@
A gDs
& gDL
C MDL
+ molDs

21. "he solu,ilit- of !n! is (.2 x 10
%(
M. "he =alue of the 3sp is
A 1.0 x 10
%/
& (.2 x 10
%(
C 0.* x 10
%(
+ /.. x 10
%2

22. !il=er hloride7 AgCl7 would ,e least solu,le in
A 1.0 M $Cl
& 1.0 M 'a'#(
C 1.0 M AnCl2
+ 1.0 M Ag'#(

2(. "he solu,ilit- of !rE2 is
A *.( x 10
%>
& 0.0 x 10
%/
C 1.0 x 10
%(
+ 1.0 x 10
%(



2*. "he 3sp expression for a saturated solution of AgC#( is
A 3sp 6 1Ag2
+
21C#(
2%
2
& 3sp 6 1Ag
+
2
2
1C#(
2%
2
C 3sp 6 12Ag
+
21C#(
2%
2
+ 3sp 6 12Ag
+
2
2
1C#(
2%
2

2/. $ow man- moles of solute are dissol=ed in 200.0 mL of a saturated solution of Ee!@
A 1.2 x 10
%1>
& 0.0 x 10
%1>
C 1./ x 10
%10
+ ... x 10
%10

20. A solution ontains ,oth Ag
+
and Mg
2+
ions. +uring seleti=e preipitation7 these ions are remo=ed
one at a time ,- adding
A :
%
followed ,- #$
%
& #$
%
followed ,- !
2%
C !#*
2%
followed ,- Cl
%
+ '#(
%
followed ,- )#*
(%

2.. 9hih of the following does not define solu,ilit-@
A the onentration of solute in a saturated solution
& the moles of solute dissol=ed in a gi=en amount of solution
C the maximum mass of solute that an dissol=e in a gi=en amount of solution
+ the minimum amount of solute re?uired to produe one litre of saturated solution

2<. "he ion onentrations in 0.2/ M Al24!#*5( are
1Al
(+
2 1!#*
2%
2
A 0.2/ M 0.2/ M
& 0./0 M 0../ M
C 0../ M 0./0 M
+ 0.10 M 0.1/ M

2>. 9hih of the following will not produe a preipitate when e?ual =olumes of 0.20 M solutions are
om,ined@
A 3#$ and !rCl2
& An4#$52 and 3()#*
C An4#$52 and 4'$*52!
+ 'a2!#* and ),4'#(52

(0. 9hat is o,ser=ed when $2!#* is added to a saturated solution of Ca!#*@
A Ca!#*4s5 dissol=es
& the 1Ca
2+
2 inreases
C ,u,,les of $2 are gi=en off
+ additional Ca!#* preipitates
(1. "he solu,ilit- of Cd! is 2.< x 10
%1*
M. "he =alue of the 3sp is
A ..< x 10
%2<
& 2.< x 10
%1*
C /.0 x 10
%1*
+ 1.. x 10
%.

(2. Consider the following solutions: 0.10 M Cl
%
7 0.10 M &r
%
7 0.10 M :#(
%
7 0.10 M &r#(
%

F?ual moles of Ag'#( are added to eah solution. :t is o,ser=ed that a preipitate forms in all ,ut
one solution. 9hih solution does not form a preipitate@
A Cl
%
& &r
%
C :#(
%
+ &r#(
%

((. Consider the following e?uili,rium: 2#(4g5 (#24g5 3e? 6 0/
:nitiall-7 0.10 mole #( and 0.10 mole of #2 are plaed in a 1.0 L ontainer. 9hih of the following
desri,es the hanges in onentrations as the reation proeeds to e?uili,rium@
1#(2 1#22
A dereases dereases
& dereases inreases
C inreases dereases
+ inreases inreases

(*. Consider the following potential energ- diagram for the re=ersi,le reation.












Ati=ation Fnerg- 4kG5 H$ 4kG5
A 10 %20
& 10 %(0
C (0 +10
+ 20 +(0

(/. :nreasing the temperature of a reation inreases the rate ,-
: inreasing fre?uen- of ollision
:: inreasing the kineti energ- of ollision
::: dereasing the potential energ- of ollision
A : onl-
& : and :: onl-
C :: and ::: onl-
+ :7 ::7 and :::

)F
43G5
)rogress of the reation
1*0
1(0
110
(0. 9hat is the 3e? expression for the following e?uili,rium@
Ee 4s5 + *$2#4g5 Ee(#*4s5 + *$24g5
A 3e? 6 1$22
*
& 3e? 6 1$22
1$2#2
C 3e? 6 1$22
*
1$2#2
*
+ 3e? 6 1Ee(#*21$22
*
1Ee2
(
1$2#2
*

!u,Ieti=e

1. 9rite the net ioni e?uation representing the reation that ours when /0.0 mL of 0.20 M An!#*
and /0.0 mL 0.20 M &a! are om,ined.






2. A 100.0 mL sample of 0.000M Ca4'#(52 is diluted ,- adding *00.0 mL of water. Calulate the
onentrations of all of the ions.














(. 9hen 1.00 L of CaE2 was e=aporated to dr-ness7 2.00 x 10
%2
g of residue was formed. Calulate
the 3sp.


















*. A maximum of 0.00 g ),4'#(52 an ,e added to 1./ L of 'a&r4a?5 without forming a preipitate.
Calulate the 1'a&r2.







/. Consider the following solutions at 2/
o
C












!aturated AgCl4a?5 !aturated Ag2C#(4a?5

Jsing alulations7 identif- the solution with the greater 1Ag
+
2.