Professional Documents
Culture Documents
determining the dissolved oxygen (DO) at the beginning and at the end
of a 5-day period in a sealed sample. The BOD gives the measure of
oxygen utilized or consumed in the period as a result of oxidation of
dissolved organic matter present in the water sample.
Threshold limit value (TLV):
This value indicates the permissible level of a toxic pollutant in
atmosphere to which a healthy industrial worker can be exposed during
an eight-hour day without any adverse effect. TLV of a pollutant is
found by experimentation on animals, medical knowledge and
experience and environmental studies.
Now let us discuss the various segments of our environment in detail
one by one. In the first instance let us discuss about the atmosphere and
atmospheric chemistry.
Measurement of total organic carbon (TOC):
Both BOD and COD give indications of the oxidisability and oxygen
demand of water samples. Neither, however, measures the total organic
content of water. When this is required a determination of total organic
carbon (TOC) is made. This is done by quantitatively oxidising all the
organic matter in the sample to carbon-di-oxide soon after acidification
to remove interference from carbonates or bicarbonates. Oxidation in a
gas stream passing through a heated tube or wet oxidation with
potassium peroxodisulphate have both been used. The latter is less
convenient, but more sensitive and can be used at low levels below 1
-3
mgdm . The carbondioxide produced is measured either by
conductivity after absorption in solution or by catalytic conversion to
methane which is then passed to a flame ionisation detector as used in
gas chromatography.
The TOC test can be performed in a relatively short period of time (few
minutes) compared to BOD and COD measurements and, hence offers a
valuable supplement to BOD and COD estimations.
TURBIDITY
Water that is not clear but is dirty, in the sense that light transmission
is inhibited, is known as turbid water. Many materials can cause
turbidity, including clays and other tiny inorganic particles, algae, and
organic matter. In the drinking water treatment process, turbidity is of
great importance, partly because turbid water is aesthetically
displeasing, and also because the presence of tiny colloidal particles
makes it more difficult to remove or inactivate pathogenic organisms.
Turbidity is measured using a turbidimeter. Turbidimeters are
photometers that measure the intensity of scattered light. Opaque
particles scatter light, so scattered light measured at right angles to a
beam of incident light is proportional to the turbidity. Formazin polymer
is currently used as the primary standard for calibrating turbidimeters,
and the results are reported as nephelometric turbidity units (NTU).
5.3-7.4
Hard water
7.6-8.8
Sea water
8.2-9.2
In coagulation, the forces responsible for keeping the particles apart after
they contact, are reduced. Flocculation brings the de-established
colloidal particles together and they form large aggregates. Both these
techniques are employed in the treatment of water. Thus, we can
understand the process of coagulation and flocculation with the help of
examples derived from water treatment techniques.
Water may contain colloidal solids like non-settleable organic matter,
clay particles, bacteria, plankton, small particles of decayed plant
material, etc. Thus, coagulation and flocculation techniques are
employed for separating these impurities from water.
Coagulation is achieved by neutralizing the particles and thus, the
repelling force between the particles is greatly reduced. After employing
the flocculation process, the coagulated particles form a large
agglomeration, which is also known as floc.
the order of 4000 to 7000 kN/m are required. Fig.1b represents the
principle of operation of the reverse osmosis unit.
-Electrodialysis:
Electrodialysis uses ion-selective membranes and an electrical
potential difference to separate anions and cations in solution.
chemical additives and has low energy requirements and as such it can
be an economically feasible means of demineralisation.
Disinfection:
Disinfection, using chemical and physical methods is the final step in
drinking water purification. The finished water is disinfected often with
chlorine. It kills the remaining microorganisms in the water, some of
which will be pathogenic. It is a very efficient oxidising, bleaching and
disinfecting agent. In water chlorine reacts as follows:
Together, HOCl and OCl are called the free available chlorine.
A principal advantage of chlorination over other forms of disinfection is
that a chlorine residual is created that can protect the treated water after
leaving the treatment plant. This is guard against possible contamination
that might occur in water distribution system. To increase the lifetime of
the residual, some systems add ammonia to the treated water, forming
chloramines.
PARAM UNITS
ETERS
DRINKING
WATER
WHO Standard
HDL
MPL
Experim
ental
Values
(Range)
Tempera 0C
ture
---
-----
22-30
Turbidity NTU
10
18-470
pH value -
6.5 to 8.5 No
8.4- 8.9
relaxatio
n
4
Total
mg/l
hardness
(as
CaCO3)
300
600
122-212
Iron
mg/l
0.3
1.0
0.2-0.8
Chloride mg/l
s
250
1000
7-26
Dissolve mg/l
d Solids
500
2000
256-500
Calcium
75
200
28-48
Sulphate mg/l
200
400
50-91
10
Nitrate
mg/l
50
No
0-1.772
relaxatio
n
11
Fluoride
mg/l
1.0
1.5
0-0.4
12
Total
mg/l
Alkalinit
y
200
600
13-246
13
Magnesi
um
mg/l
30
150
9.2326.24
14
Oxygen mg/l
Observe
d from
KMnO4
at 370C
in 3 hrs.
3.0
No
2.4-7.8
relaxatio
n
mg/l
15
Suspend mg/l
ed Solids
20
150
70-280
Electrostatic Precipitator:
An electrostatic precipitator (ESP) is a particulate collection device that
removes particles from a flowing gaseous stream (such as air) using the
force of an induced electrostatic charge.
ESP can be operated at high temperature and pressures, and its power
requirement is low.
For these reasons the electrostatic precipitation is often the preferred
method of collection where high efficiency is required with small
particles.
Steps in Electrostatic Precipitation
1. Generation of Electric field high voltage Direct current 20-80kv.
2. Generation of electric charges
3. Transfer of electric charge to a dust particle.
4. Movement of the charge dust particle in an electric field to the
collection electrodes.
5. Adhesion of the charge dust particle to the surface of the collection
electrode.
6. Dislodging of dust layer from collection electrode
7. Collection of dust layer in a hopper
8. Removal of the dust from the hopper.
PRINCIPLE OF ESP
Principle of ESP has four distinct phases as follows:
(I) Ionization or corona generation: When the potential difference
between the wire and electrode increases, a voltage is reached where an
electrical breakdown of the gas occurs near the wire. This electrical
break down or ion discharge is known as corona formation and thereby
gas is transformed from insulating to conducting state.
Two types of corona discharge can be generated which are:
(a) Negative corona: In negative corona, discharge electrode is of
negative polarity and the process of electron generation occurs at narrow
region