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Abstract
The eect of curing conditions on properties of mortars with and without ground granulated blast furnace slag (GGBFS) was studied.
In the present work, cement was replaced by ground granulated blast furnace slag 0% (control), 30%, and 60% by weight, and mortars
were produced. One of the two groups of mortars was kept in water at 20 C standard conditions, and the other was kept in moisture
cabinet at 40 C temperature and approximately at 100% relative humidity (RH). Flexural strength, compressive strength, ultrasonic
pulse velocity, capillarity coecient, and volumetric water absorption were investigated at the ages of 7, 28, 56, 90, and 180 days.
The results obtained indicate that elevated temperature increases performance of mortar at early ages but decreases at later-age, and this
aect is more signicant at slag replaced mortars.
2006 Elsevier Ltd. All rights reserved.
Keywords: Curing condition; Ground granulated blast furnace slag; Mechanical properties, Physical properties
1. Introduction
Concrete is the most important element of the infrastructure and well-designed concrete can be a durable construction material. However, the environmental aspects of
Portland cement are a growing concern, as cement manufacturing is responsible for about 2.5% of total worldwide
emissions from industrial sources [1]. One of the eective
ways to reduce the environmental impact is to use mineral
admixtures, as a partial cement replacement. This strategy
will have the potential to reduce costs, conserve energy,
and waste minimization [1,2]. Mineral admixtures such as
ground granulated blast furnace slag, y ash, and silica
fume are silica-based pozzolanic materials so they can partially replace Portland cement [1]. The use of mineral
admixtures improve the compressive strength, pore structure, and permeability of the mortars and concretes with
309
2. Experimental procedure
2.1. Materials
Experimental study was carried out on mortars with and
without ground granulated blast furnace slag (GGBFS).
An ordinary Portland cement (CEM I 42.5) [10], a siliceous
sand according to the RILEM guidelines and GGBFS were
used for the mortar mixtures. Cement and GGBFS properties are indicated in Table 1. A modify polycarboxylatebased superplasticizer (SP) was used to adjust the ow
within 105115 mm. Density of SP was 1.10 kg/l and its
pH was 7.3.
2.2. Mix proportion and curing
Table 2 presents the mix designs for three dierent mortars. The sand/cementitious ratio was 3, and water/cementitious material ratio was 0.5. Cement was replaced by
GGBFS 0% (0), 30% (3), and 60% (6) by weight. Bulk densities of the fresh mortars are also presented in Table 2.
After production of mortars, the molded specimens were
covered with a plastic sheet and left in the casting room for
24 h. Then the specimens were demolded and divided into
two groups. First group specimens were stored in lime-saturated water (W) at 20 2 C, and second group specimens were put into temperature and humidity controlled
Table 1
Chemical and mechanical test results of OPC and slag
Chemical composition (%)
GGBFS
CaO
SiO2
Al2O3
Fe2O3
MgO
SO3
Cl
Na2O/K2O
Sulphur
Loss on ignition
Insoluble residue (max)
Specic gravity (g/cm3)
64.01
20.01
5.28
3.65
1.21
2.47
0.033
0.25/0.81
2.27
0.32
3.14
33.48
41.43
10.28
3.48
6.05
3570
Initial
Final
145
180
Mechanical properties
7 days
28 days
0.012
0.41/1.72
1.64
0.61
2.89
4730
Table 2
Mix proportions
Group
SP (by weight)
0
3
6
1
0.70
0.40
0
0.30
0.60
0.5
0
0.028
0.028
2410
2310
2280
310
Table 3
Physical and mechanical properties at 7 day
Properties
0W
3W
6W
0H
3H
6H
33.7
6.8
20.4
4.6
3733
31.0
6.5
19.4
3.8
3600
26.3
6.0
18.6
3.2
3575
36.9
7.0
19.0
5.4
4033
34.1
6.3
18.2
5.0
3800
32.6
6.1
17.0
4.2
3633
80
70
60
50
40
30
0W
0H
3W
3H
6W
6H
0W
0H
3W
3H
6W
6H
20
0
28
56
84
112
140
168
196
10
311
0W
0H
3W
3H
6W
6H
0W
0H
3W
3H
6W
6H
0W
0H
3W
3H
6W
6H
0W
0H
3W
3H
6W
6H
8
7
2
6
5
0
28
56
84
112
140
168
196
24
21
R = 0.9932
2
18
15
12
0
28
56
84
112
140
168
196
8.E-06
0W
0H
3W
3H
6W
6H
3.E-06
0W
0H
2.E-06
3W
3H
6W
6H
7.E-06
6.E-06
5.E-06
4.E-06
1.E-06
0.E+00
0
28
56
84
112
140
168
196
4750
4500
4250
4000
3750
0W
0H
3W
3H
6W
6H
0W
0H
3W
3H
6W
6H
R = 0.8083
2
R = 0.8862
R = 0.9953
3500
0
28
56
84
112
140
168
196
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strength show similar behaviour at the 7 day and laterages. It can be seen from Fig. 2 that increases with time
in all specimens for both curing conditions. The exural
strengths of slag replaced groups are lower than the control
groups.
Flexural strength gain of control mortars which cured in
water (0 W) is 7%, and 21%, strength gains of slag replaced
mortars 3 W groups are 8% and 23%; 6 W groups are 13%
and 25% at 28 and 180 days, respectively, if 7 day specimens are compared to 28 and 180 days. The aect of slag
increases with time similar to compressive strength, and it
becomes more signicant with the increase of slag replacement ratio. The exural strength of mortars cured in moisture cabinet increase by 3%, and 7% in 0 H group, increase
by 8% and 13% in 3 H group, and increase by 7% and 15%
in 6 H group at 28 and 180 days, respectively. Slag replaced
mortars exural strengths are negatively aected at elevated temperature and lower humidity condition. The exural strength of mortars produced with Portland cement
and cured in water at 40 C temperature is lower than the
exural strength of mortars cured in water at 20 C temperature [16].
It can be seen from the equations of Fig. 2 that the increment ratio of exural strength with time in control and slag
replaced mortars cured in water are higher with respect to
the specimens cured in moisture cabinet, and this situation
is more signicant in slag replaced groups. According to
the experimental data, the aects of curing conditions on
compressive and exural strength are seen with time on
mortars especially as those of slag replaced mortars.
3.3. Appearing porosity
The appearing porosity (AP) of the specimens cured in
water is higher than those of cured in moisture cabinet at
7 day (Table 3). This indicates that, at the beginning, the
degree of hydration of cement becomes higher with the
increment of temperature. It can be seen in Fig. 3 that
appearing porosity values decreases in all specimens with
time for both curing conditions. The appearing porosity
of the slag replaced mortars is lower than the control mortars. Decrement in AP of the mortars cured in water is 8%
and 21% in control group (0 W), 9% and 23% in the slag
replaced mortars 3 W group, and 12% and 25% in 6W
group at 28 and 180 days, respectively. Porosity of the mortars decreases with slag replacement. This situation connote that slag lls the pores and decreases the capillarity,
thus, durability of mortars increases. Decrements in
appearing porosity of the mortars cured in moisture cabinet are, 4% and 12% in 0 H group, 7% and 13% in 3H
group, and 5% and 9% in 6 H group.
According to the results, the appearing porosity decrement of control and slag replaced specimens cured in water
with time is higher compared to those of cured in moisture
cabinet. These results conrm that higher degree of hydration due to the increased temperature is not continual, and
the hydration products occurred is also porous [5,15].
313
tars and pointed out that the porosity of the mortars containing slag is higher compared to control Portland cement
mortars at 7 days and 28 days but their pore size distribution is similar to each other. They also indicated that when
the pore structure at the age of three years is considered,
the porosity decreases considerably; the volume of pores
is just only 50% of that at 28 days, and the radius of medium pore size is decreased and the harmful pore (>100 nm)
has almost disappeared after three years curing. This situation is explained as the improvement of the pore structure
due to the late hydration, which means that the hydration
products gradually ll up the free space of cement stone.
4. Conclusions
This experimental study has investigated the physical
and mechanical properties of mortars with and without
ground granulated blast furnace slag according to curing
temperature, curing humidity and aging. The following
conclusion can be drawn from this study:
The exural and compressive strength of slag replaced
mortars are lower than the exural and compressive
strength of control mortars for both curing conditions.
The exural and compressive strength of specimens
exposed to elevated temperature and lower relative
humidity leads to higher early-age strength but eventually lower later-age strength compared to specimens
cured in water. As a summary, it is observed that the
eects of elevated temperature and lower relative humidity conditions are more signicant especially in slag
replaced mortars.
The appearing porosity and capillarity coecient of slag
replaced mortars are lower than control mortars for
both curing conditions but the decrease in the capillarity
coecient and the appearing porosity of slag replaced
mortars cured in water are higher than slag replaced
mortars cured in humidity cabinet. Use of ground granulated blast furnace slag in producing mortar decreases
the porosity and capillary, thus, improves the durability
against water and aggressive solutions.
As a result, eects of environmental conditions as temperature and relative humidity on concrete have to be
taken into account, especially curing conditions of concretes containing slag should be taken pains over.
References
[1] Aldea CM, Young F, Wang K, Shah SP. Eects of curing conditions
on properties of concrete using slag replacement. Cem Concr Res
2000;30(3):46572.
[2] Escalante-Garcia JI, Sharp JH. The microstructure and mechanical
properties of blended cements hydrated at various temperatures. Cem
Concr Res 2001;31(5):695702.
[3] Bagel L. Strength and pore structure of ternary blended cement
mortars containing blast furnace slag and silica fume. Cem Concr Res
1998;28(7):101120.
314