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Metals in Pros Tho Don Tics
Metals in Pros Tho Don Tics
Metals form a large part of the earth on which we live, nearly 80% of
the known elements are metals, in the earths crust, most of the metallic
elements occur in compounds and not in the metallic state. A few of the rare
and least reactive metals may be found in the metallic state in the earths
crust. These metals include gold, copper, mercury and platinum. Scientists
think the earths core in mainly made up of nickel and iron in the metallic
state.
Ancient people knew a used many native metals. Gold was used for
ornaments, plates, jewellery and utensils as early as 3500 BC, gold objects
showing a high degree of culture have been excavated at the ruins of the
ancient city of ur in mesapotamia. Silver was used as early as 2400 BC.
Native copper was also used at an early date for making tools and utensils.
Since about 1000 BC iron and steel have been the chief metals of
construction.
The earliest known use of dental materials can be traced to
approximately 500 BC and the Etruscans, who used gold to make first
dental bridges.
Definition :
GPT – 7 defines “metal” as any strong and relatively ductile
substance that provides electropositive ions to corrosive environment and
that can be polished to a high lusture, characterized by metallic atomic
bonding.
In dentistry, metals present one of the four major classes of
materials used for the reconstruction of decayed, damaged or missing
teeth.
General characteristics of metals
• A metal is an element that ionizes positively in solution
• Metal have certain typical and characteristic properties that
distinguish them from non metallic elements.
The optical properties – metallic luster and high opacity
Physical properties – high ductility and
- high electrical and thermal conductivity.
The extensive use of metals and their alloys in mechanical and
structural applications in a result of good mechanical properties and
workability of many products.
Metallic bonding is responsible fore the unique properties of the
metals. Metals atoms have valance electrons that are rather loosely held and
these electron are free to more throughout the solid. This diffuse nature is
responsible for easy deformability of metals and their high thermal and
electrical conductivities.
They are opaque because the valance electron absorbs the high, and
they are lustrous because the electrons remit the high.
Grain size :
The size of the grain depends upon the number and location of the
nuclei at the time of solidification. It the nuclei are equally spaced with
reference to each other, the grains will be approximately equal in size. The
solidification can be pictured as proceeding from the nuclei in all directions
at the same time in the form of a sphere that is constantly increasing in
diameter when these spheres meet, they are flattened along various surfaces.
The grain tends to be the same diameter in all dimensions such a grain is
called equiaxed.
DEFORMATION OF METALS
The atoms within each grain are arranged in a regular three-
dimensional lattice. There are several possible arrangements such as cubic,
body-centred cubic and face-centred cubic etc.
The arrangement adopted by any one crystal depends on specific
factors such as atomic radius and charge distributions on the atoms.
although there is a tendency towards a perfect crystal structure, occasional
defects occur, such defects are called dislocations and their occurrence has
an effect on the ductility of the metal or alloy. When the material is placed
under a sufficiently high stress the dislocation is able to more through the
lattice until it reaches a grain boundary.
The plane along which the dislocation moves is called the slip plane
and the stress required to initiate moment is called the elastic limit.
Application of a stress greater than the elastic limit causes the
material to be permanently deformed as a result of movement of
dislocations.
Grain boundaries form natural barriers to the movement of
dislocation. The concentration of grain boundaries increases as the grain
size decrease metals have higher valves of elastic limit.
It is important to understand that any process that impedes dislocation
movement tends to harden a metal, raise its yield stress and often lower its
ductility.
COLD WORKING / WORK HARDENING :
A process for hardening the metal. It is the permanent deformation
that takes place on the application of sufficiently high force at room
temperature, due to the movements of dislocations along slip planes.
Any plastic deformation of the metal by hammering, drawing, cold
forging or bending processes, produce many dislocations in the metal that
cannot slip through each other as easily as the lattice becomes more
distorted.
Such cold working not only produces a change in microstructure,
with dislocation becoming concentrated at grain boundaries, but also a
change in grain shape. The grain are no longer equiaxed but take up a more
fibrous structure.
The properties of the metal are altered. The surface hardness,
strength, and proportional limit are increased, where as ductility and
resistance to corrosion are decreased by strain hardening.
In dentistry, cold working occurs when gold foil is compacted, a
denture clasp is bent, an inlay margin is burnished, or a deformed metal
layer forms on a crown during finishing and polishing.
The temperature below which work hardening is possible is termed as
recrystallizaiton temperature.
Since metals and alloys have finite values of ductility or malleability
there is a limit to the amount of cold working which can be carried out.
Attempts to carry out further cold working beyond this limit may result in
fracture.
ANNEALING :
The effects associated with cold working such as strain hardening,
lower ductility and distorted grain can be reversed by simply heating the
metal. The process is called annealing.
The more severe the cold working, the more readily does annealing
occur.
Annealing in general comprises three stages :
Recovery, recrystallization and grain growth :
Annealing is a relative process ; the higher the melting point of the
metal, the higher is the temperature needed for annealing. A rule of thumb is
to use a temperature approximately one half that is necessary to melt the
metal.
Recovery : It is considered the stage at which the cold work properties
begin to disappear before any significant visible changes are observed under
the microscope.
During this period there is very slight decrease in tensile strength and
no change in ductility.
Recrystallizaiton : When a severely cold worked metal is annealed, than
recrystallization occurs after some recovery. This involves a rather radical
change in the microstructure. The old grains disappear completely and are
replaced by a new set of strain – free grains. These recrystallization grains
nucleate in the most severally cold – worked regions in the metal, usually at
grain boundaries, or where the lattice was most severely bent on
deformation.
On the completion of recrystalization the material essentially attains
its original soft and ductile condition.
Grain growth : The recrystallized structure has a certain grain size,
depending upon the number of nuclei. The more severe the cold working,
the greater are the number of such nuclei. Thus, the grain size for the
completely recrystallized material can range from rather fine to fairly
coarse.
If now the fine grain form is further annealed, the grains begin to
grow. This grain growth process is simply a boundary energy minimizing
process. the effect, the large grains consume the little grains. It does not
progress indefinitely to a single crystal. Rather, an ultimate coarse grain
structure is reached, and then for all practical purposes, the grain growth
stops.
Excessive annealing can lead to large grains. It should be emphasized
that the phenomenon occurs only in wrought material
ALLOYS :
An alloy is a mixture of two or more metals mixture of two metals are
called binary alloys, mixtures of three metals ternary alloys.
The term alloy systems refers to all possible compositions of an alloy.
To form an alloy, two or more metals are heated to a homogenous
liquid state. However, a few combinations of metals are not miscible in the
liquid state and will not form alloys.
When a combination of two metals is completely miscible in the
liquid state, the two metals are capable of forming an alloy. When such a
combination is cooled, one of three microstructure may form.
a) A solid solution
b) A mixture of intermetallic compound
c) An eutectic mixture s
Solid solution : When two metals are completely miscible in a liquid state,
and they remain completely mixed on solidification, the alloy formed is
called a solid solution.
When two metals are soluble in one another in the solid state, the
solvent in that metal whose space lattice persists, and the solute is the other
metal. The solvent may be defined as the metal whose atoms occupy more
than one half the total number of positions in the space lattice.
Eg : The copper and gold combination crystallizes in such a manner
that the atoms of copper are scattered throughout the crystal structure (space
lattice) of gold, resulting, in a single phase system. Such a combination is
called the solid solution because it is a solid but has the properties of a
solution. The configuration of the space lattice of solid solution may be of
several types.
- Substitutional, interstitial and ordered.
In substitution type : The atoms of the solute occupy the space lattice
positions that normally are occupied by the solvent atoms in the pure metal.
In interstitial type : The solute atoms are present in positions between the
solvent atoms.
In ordered type : The solute atoms occupy specific sites within a common
crystal lattice.
The extent of solid solubility is determined by at least 4 factors.
1) Atomic size : It the sizes of the two metallic atoms differ by less than
15% they posses a favorable size factor for solid solubility.
2) Valance : metals of the same valance and size are more likely to form
extensive solid solutions than are metals of different valancies.
3) Chemical affinity : When two metals exhibit a high degree of
chemical affinity, they tend to form an intermettalic compound on
solidification rather than a solid solution.
4) lattice type : Only metals with the same type of crystal lattice can
form a complete series of solid solutions
Intermettalic compounds :
If two metals show a particular affinity for one another they may form
intermettalic compounds with precise chemical formulation. Intermettalic
compounds are also formed on cooling liquid metal solution, in the liquid
state they have a tendency to unite and form definite chemical compounds
on solidifying. As far as the space lattice is concerned, the atom of one
metal, instead of appearing randomly in the space lattice of another metal,
occupy a definite position in every space lattice.
Eg : In an alloy of silver and tin containing 73.2% of Ag and 26.8% of Sn
by weight is heated above 5000C, it is a single phase liquid system. When
the alloy is cooled, it solidifies to a compound with the formula Ag3Sn, with
silver and tin atoms occupying a definite positions in the space lattice. Such
alloy is called intermetalic compound and is used in dental amalgam alloys.
Peritectic alloys :
Limited solubility of two metals can bad to a transformation referred
to as “peritectic”
• Peritectic systems are not common in dentistry
• An example being a silver – tin alloy system
• Like the eutectic transformation, the peritectic reaction in an invariant
reaction (ie it occurs at a particular composition and temperature) the
reaction can be written as
• liquid + β → α
d) Base metals :
Although these metals have frequently been reffered to as non
precious, the preferred designation is base metal. These are non noble
elements. base metals remain invaluable components of dental casting
alloys because of their influence on physical properties, control of the
amount and type of oxidation, or their strengthening effects. Eg : chromium,
cobalt, nickel, Iron copper etc.
Desirable properties :
1) Biocompatibility
2) Ease of melting
3) Ease of casting, brazing and polishing
4) Little solidification shrinkiage
5) Minimal reactivity with the mould material
6) Good wear resistance
7) High strength and sag resistance
8) Excellent tarinsto and corrosion resistance
Chemical properties :
Co-Cr / Ni-Cr alloys have very good corrosion resistance by virtue of
the passivating effect. The alloys are covered with a tenacious layer of
chromic oxide which protects the bulk of the alloy from attack.
Chromium containing alloys are attached vigourously by chlorine;
household bleaches should not be used for cleaning appliances made from
chromium-type alloys.
Disadvantages :
Although certain physical and mechanical features of the chromium
type alloys are superior to those of partial denture golds, clinical application
of these materials may be burdened by the following occurrences.
1. Clasps cast from relatively nonductile base metal alloys can break in
service, some break within a short period of time.
2. Minor but necessary adjustments required upon the delivery of the
base metal partial denture can be made difficult by the alloys high
hardness and strength, and accompanying low elongation.
3. High hardness of the alloy can cause excessive wear of restorations
and natural teeth that they contact.
Ti-6Al-4V :
It is the most widely used alloy because of its desired proportion and
predictable productivity at room temperature Ti-6Al-4V is a two phase
(α +β ) alloy.
At approx 9750C an allotrophic phase transformation takes place,
transforming the microstructure to a single phase BCC β alloy.
Properties :
Titanium has a density of 4.5 g/cm3, which is half of the weight of
other non precious metals used in dentistry and one quarter that of gold. The
low density of titanium is advantages because it allows lightweight
prostheses to be fabricated.
The protective passive oxide film of on titanium mainly TiO2, is
stable over a wide range of pHs, potentials and temperature.
Minimum yield strength of Ti ranges between 240 to 890 MPa. It has
low modulus of elasticity 103 to 113 MPa.
And has favorable microhardness – 210 VHN.
High melting point of 17000C
Alloys have a slightly lower melting point
In theory, the light weight of titanium and its strength-to-weight ratio,
high ductility and low thermal conductivity would permit design
modifications in Ti restorations and removable prosthesis.
Casting : because of high affinity of titanium has for hydrogen, oxygen and
nitrogen, standard crucibles and investment materials cannot be used.
Dental castings are made via pressure-vaccum or centrifugal casting
methods. The metal is melted using an electric plasma arc or inductive
heating in melting chamber filled with inert gas or held in a vacuum. The
molten metal than is transferred to the refactory mould centrifngal or
pressure vaccum. Filling casting of titanium commonly are used to fabriate
crowns, bridge frameworks, and full and partial denture frameworks. The
casting machines are very expensive. Investment material such as phosphate
bonded silica and phosphate investment materials with added trace elements
are used.
Other alloys : Ti 15 V, Ti – 20 Cu, Ti 30 pd, Ti – Co, Ti – Cu.
Disadvantages :
1) High melting point 2) High reactivity 3) low roasting efficiency 4)
Inadequate expansion of investment. 5) casting porosity 6) Difficulty in
finishing this metal 7)Difficult to weld and solder 8) Expensive equipment.
Alloys for metal-ceramic restoration
All ceramic anterior restorations can appear very natural.
Unfortunately, the ceramics used in these restoration are brittle and subject
to fracture from high tensile stresses. Conversely, all metal restoration are
strong and tough but, from an aesthetic point of view, acceptable only for
posterior restoration. Fortunately the esthetic qualities of ceramic materials
can be combined with the strength and toughness of metals to produce
restorations that have both a natural tooth like appearance and very good
mechanical properties.
A cast metal coping provides a substrate on which a ceramic coating
in fused. The ceramics used for these restorations are porcelains.
The bond between the metal and ceramic is the result of
chemisorption by diffusion between the surface oxides on the alloy and in
the ceramic. These oxides are formed during wetting of the alloy by the
ceramic and firing of the ceramic.
Noble metals, which are resistant to oxidizing, must have other, more
easily oxidizing element added such as indium and tin to form surface
oxides. The common practice of “degassing” or preoxidizing the metal
coping before ceramic application creates surface oxides that improve
bonding.
Base metal alloys contain elements, such as nickel, chromium, and
beryllium which form oxides easily during degassing.
CLASSIFICATION OF ALLOYS USED FOR METAL CERAMIC
RESTORATION
1) High noble - Gold – Platinum – Palladium (Au-pt-pd)
Gold – Palladium – Silver (Au-pd-Ag)
Gold – Palladium (Au-Pd)
2) Noble – Palladium – Gold (Pd – Au)
Palladium – Gold – Silver (Pd-Au-Ag)
Palladium – Silver (Pd-Ag)
3) Base metal – Pure Titanium
Titanium – Aluminium – Vanadium (Ti-Al-V)
Nikel – Chromium – Molybdenum (Ni-Cr-Mo)
Nikel – Chromium – Molybdenum – Berillyum (Ni-Cr-
Mo-Be)
Inspite of vastly different chemical compositions, all alloys share at least
three common features
1) They have potential to bond to dental porcelain
2) They posses co-efficient of thermal contraction compatible with those
of dental porcelain.
3) Their solidus temperature is sufficiently high to permit the application
of low-fusing porcelains.
HIGH NOBLE ALLOYS :
The high noble alloys are composed principally of gold and platinum
group metals with minor additions of tin, indium, and iron added for
strength and to promote a good porcelain bond to metal oxide.
Gold-platinum –palladium alloys :
These have a gold content ranging upto 88% with varying amounts of
Pd, Pt and small amount of base metals alloys of this type are restricted to 3-
unit spans, anterior cantilevers, or crowns.
Gold-palldium-silver alloys :
These gold based alloys contain between 39% and 77% gold and upto
35% palladium, and silver levels as high as 22%. The silver increases the
thermal contraction co-efficient, but it also has the tendency to discolor
some porcelains.
Gold-palladium alloys : -
A gold content ranging from 44% to 55% and palladium level of 35%
to 45% is present in these metal-ceramic alloys, which have remained
popular despite their relatively high costs. Yield strengths and hardness are
favourable and elastic modulus is increased significantly compared with
high gold alloys. Corrosion resistance is excellent because of high nobility.
The only recognizable disadvantage is the incompatible co-efficient of
thermal contraction with some of the porcelains with higher thermal
contractions co-efficient, due to the lack of silver though there is freedom
from silver discolouration. Alloys of this type must be used with porcelains
which have lower coefficient of thermal contraction to avoid the
development of axial and circumferential tensile stresses in porcelain during
the cooling part of the porcelain firing cycle.
NOBLE ALLOYS :
According to ADA classification of 1984, noble alloys must contain
at least 25% to 40% silver. Tin and indium are both usually added to
increase the alloys hardness and to promote oxide formation. These alloys
were developed. When the cost of Pd was considerably lower than Au ;
those conditions no longer exist. Some ceramics used with these high Ag
alloys resulted in a greenish-yellow discolouration termed as “greening”,
due to the silver vapour that escapes from the surface of these alloys during
firing of the porcelain, the silver vapour diffuses is ionic silver into the
porcelain, and is reduced to form colloidal metallic silver in the surface of
porcelain.
Palladium-copper alloys :
First introduced to dental profession in 1982 ; they are comparable in
cost to Pd-Ag alloys. They are usually composed of 74-80% palladium and
2-15% copper. They cause none of the porcelain colour problems associated
with silver. High hardness value in some of the alloys are offset by a
relatively low elastic modulus, resulting in better working characteristics
than would be expected with a high hardness value. Strength is good, and in
some alloys extremely high yield strengths are found. Some Pd-Cu alloys
have a rather heavy oxide that is difficult to cover with opaque porcelain.
They are susceptible to creep deformation at elevated firing temperatures,
tending to contraindicate their use in large-span fixed partial dentures.
Palladium-cobalt alloys :
These alloys contain around 88% palladium and 4-5% cobalt this
groups is the most sag resistant of the noble metal alloys. These alloys have
good handling characteristics. They tend to have relatively high thermal
contraction coefficient and would be expected to be more compatible with
higher-expansion porcelain. However, the main disadvantage is the
formation of a dark oxide that may be difficult to mask at thin margins.
Palladium-gallium-silver and palladium-gallium-silver-gold alloys :
These alloys are the most recent of the noble metals. This group of
alloys was introduced because they tend to have a slightly lighter-coloured
oxide than that of Pd-Cu or Pd-Co alloys, and they are thermally compatible
with lower expansion porcelains. The silver content is relatively low (5%)
and is inadequate to cause porcelain greening.
Physical properties of high noble and noble metal alloys :
1) The metal ceramic alloys must have a high melting range so that the
metal is solid well above the porcelain sintering temperature to
minimize distortion of casting during porcelain application.
2) Must have considerably low fusing temperature
3) Good corrosion resistance
4) High modulus of elasticity
BASE METAL ALLOYS FOR METAL CERAMIC RESTORATION :
Developed in the 1970s, most of the base metal alloys are based on
nickel and chromium, but a few cobalt-chromium based alloys are also
available.
Composition :
Ni – Cr → 61-81 wt / nickel
11-27% chromium
2-5% molybdenum
Co-Cr → 53-67% cobalt
25-32% chromium
2-6% molybdenum
These alloys contain one or more of the following elements ;
aluminum, beryllium, boron, carbon, cobalt, copper, cerium, gallium, iron,
manganese, niobium, silicon, tin, and zirconium.
Properties of Ni-Cr, Ni-Cr-Be and Co-Cr alloys :
The base metal alloys have different physical properties than the
noble metal alloys. The most significant are high hardness, high yield
strength, high elastic modulus. Elongations is about the same as for the gold
alloys but is negated by the high yield strength which makes it difficult to
work the metal.
The elastic modulus of base metal alloys in as much as two times
greater than the value of noble metal alloys which decreases the flexibility
to a significant degree. The flexibility of a FPD framework constructed of
Ni-Cr is less than half that of a framework of the same dimensions made
from a high-gold alloy. This property would enhance the application of base
metal alloys for long-span bridges. In a similar manner, the high modulus of
elasticity may be used to permit thinner castings.
- The creep resistance of nickel-based alloys at porcelain firing
temperature is considered to be for superior to the resistance of gold and
palladium based alloys under the similar conditions. It is particularly
important in long span bridges where the porcelain firing temperature
may cause the unsupported structure to deform permanently under
controlled condition it has been found that base metal alloy deforms less
than 25 µ m, whereas a noble metal alloy deforms 225 µ m.
- In general, the high hardness and high strength of base metal alloys
contribute to certain difficulties in clinical practice grinding and
polishing of fixed restorations to achieve proper occlusion occasionally
require more chair side time.
- They have high casting temperature and they have much lower
densities (7 to 8gm /C3) thus on the basis of the lower density and low
intrinsic value of the component metals, the cost difference between
base metal and noble metal alloys can be substantial. The disadvantage
is adequate casting compensation is at a times a problem, as in the fit of
the coping.
- The addition of beryllium to some Ni-Cr alloys results in more
favourable properties. Beryllium increases the fluidity, and improves
casting performance. Be, also controls surface oxidation and results in
more reliable, less technique sensitive porcelain metal bonds.
DENTAL IMPLANT MATERIALS :
Most commonly, metals and alloys are used for dental implants.
Initially, surgical grade stainless steel and Co-Cr alloys were used because
of their acceptable physical properties and relatively good corrosion
resistance and biocompatibility. However, it is currently more common to
use implants made of pure titanium or titanium alloys, because of the
excellent biocompatibility of titanium.
Stainless steel :
Surgical austenitic steel is an iron-carbon (0.05%) alloy with
approximately 18% chromium to impart corrosion resistance and 8% nickel
to stabilize the austenitic structure.
Because nickel is present, its use in patients allergic to nickel is
contraindicated.
The alloys is most frequently used in a wrought and heat-treated
condition. It has high strength and ductility, thus it is resistant to brittle
fracture.
Surface passivation is required to maximize corrosion- biocorrosion
resistance of all alloys, this one is the most subject to crevice and pitting
corrosion. Therefore, care must be taken to use and retain the passivated
(oxide) surface.
Cobalt-chromium-molybdenum alloy :
These alloys are most often used in an as cast or cast and annealed
condition. This permits the fabrication of custom designs, such as
subperiosteal frames.
Their composition is approximately 63% cobalt, 30% chromium and
5% molybdenum and they contain small concentrations of carbon,
manganese and nickel.
Molybdenum – stabilizes the structure
Carbon – acts as a hardener
These alloys posses outstanding resistance to corrosion and they have
a high modulus.
However they are the least ductile of all the alloys systems and
bending must be avoided.
When proper quality control is ensured, this alloys group exists
excellent biocompatibility.
Because of the requirement of low cost and long-term clinical
success, but stainless steel and Co-Cr alloys have been used extensively in
many areas of surgery and dentistry.
Titanium and titanium-aluminium-vandalium (Ti-6A-4V) alloy :
Commercially pure titanium (Cp Ti) has become one of the materials
of choice because of its predictable interaction with the biologic
environment.
Titanium is a highly reactive metal it oxidizes (passivates) on contact
with air or normal tissue fluids. This reactivity is favourable for implant
devices because it minimizes biocorrosion. An oxide layer 10 A0 thick
forms on the cut surface of pure titanium within a millisecond. Thus any
scratch or nick in the oxide coating is essentially self healing.
Ti 6Al 4V alloy :
In its most common alloyed form it contains 90 wt % titanium, 9 wt
% aluminium and 4 wt % vanadium.
- Density : 4.5g/cm3, making it 40% lighter than steel.
- The metal posses a high strength : weight ratio
- Ti has modulus of elasticity approx. one half that of stainless steel or
Co-Cr alloys. However it is still 5-10 times higher than that of bone.
- Few titanium substructures are plasma sprayed or coated with a thin
layer of calcium phosphate ceramic.
The rationale for coating the implant with tricalcium phosphate or
hydroxyapatite, both rich in calcium and phosphorous into produce a
bioactive surface that promotes bone growth and induces a direct bond
between the implant and hard tissue.
The rationale of a plasma sprayed surface is to provide a roughened,
though biologically acceptable, surface for bone in growth to ensure
anchorage in the jaw.
Other metals and alloys :
Many other metals and alloys have been used for dental implant
device fabrication. Early implants extra made of gold, palladium, tantalum,
platinum, iridium and alloys of these metals.
More recently, devices made from zirconium, hafnium and tungsten
have been evaluated.
CONCLUSION :
As a wide range of metals and alloys combination are now available,
it is necessary for us to have the knowledge about the composition,
properties and biocompatibility of the constituent metals of the alloys, to be
able to choose them for the required applications. The decision is not an
easy one, as it will have financial, technical and patient satisfaction
consequences. In may ways the decision is philosophical, based on the
drawbacks of using a particular alloy versus its known clinical benefits.
REFERENCES :
7) JADA ; 128 : 37 – 45
• Introduction
• History of metals
• Definition
• General characteristics of metals
• Structure and properties of metals
• Deformation of metals
• Cold working
• Annealing
• Alloys
o Solid solutions
o Intermetallic compound
o Eutectic formation
o Perictectic formation
• Classification of metals
• Dental casting alloys
o Uses
o Desirable properties
• Noble metal casting alloys
• Base metal casting alloys
• Alloys for metal – ceramic restoration
• Implant materials
• Biocompatibility of metals
• Conclusion
• References
COLLEGE OF DENTAL SCINECES
DEPARTMENT OF PROSTHODONTICS
INCLUDING
SEMINAR
ON
METALS
IN
PROSTHODONTICS
PRESENTED BY :
DR. SUNEEL G. PATIL