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Separation Process-II
Introduction
In the field of Chemical Engineering separation process is the transfer of
any mass that converts the substance mixture into distinctive product mixtures. In some cases, a
separation may fully divide the mixture into its pure constituents. Separations are carried out based
on differences in chemical properties, or physical properties such as size, shape, mass, density, or
chemical affinity, between the constituents of a mixture, and are often classified according to the
particular differences they use to achieve separation.
In most cases one single difference is used to attain a desired separation;
however multiple processes are implemented in combination to attain the desired solution. Apart
from a few cases, compounds and elements are found naturally in an impure state and these impure
materials needs to be separated for purification. For example; crude oil that occurs naturally is a
mixture of various hydrocarbons and impurities purification process splits the mixture into
valuable natural gas, gasoline and chemical feedstock, these further need separation to render
further purer form.
Separation Process-II
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contacted and then separated. The two separated phases are assumed to be in equilibrium with each
other.
Consider a vapor and a liquid that are in contact with each other as shown
in Figure 1.2. Liquid molecules are continually vaporizing, while vapor molecules are continually
condensing. If two chemical species are present, they will, in general, condense and vaporize at
different rates. When not at equilibrium, the liquid and the vapor can be at different pressures and
temperatures and be present in different mole fractions. At equilibrium the temperatures, pressures,
and fractions of the two phases cease to change. Although molecules continue to evaporate and
condense, the rate at which each species condenses is equal to the rate at which it evaporates.
Although on a molecular scale nothing has stopped, on the macroscopic scale, where we usually
observe processes, there are no further changes in temperature, pressure, or composition.
Separation Process-II
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Liquid-Liquid Extraction
Definition:
The separation of the component of a liquid mixture by treatment with a
solvent, in which one or more of the desired component of the liquid mixture is preferentially
soluble is known as liquid-liquid extraction or solvent extraction.
Principle:
Liquid-liquid extraction is based on the solubility difference rather than the
difference in the vapor pressure of the component to be separated out. It is based on the relative
solubility in the two phases.
Separation Process-II
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Applications:
Penicillin is recover from the fermentation broth by extraction with a solvent such as butyl
acetate, after lowering the pH to get a favorable partition co-efficient. Solvent is treated
with a buffered phosphate solution to extract the penicillin from the solvent and give a
aqueous solution, from which penicillin is eventually produced by drying.
To separate acetic acid from dilute aqueous solution.
To separate petroleum product that have different chemical structure but about same
boiling point. Lube oil (boiling point 300 oC) fractions are treated with solvent such as
phenol or furfural to extract the aromatic to get paraffinic and naphthenic.
Separation of benzene, toluene and xylene from petroleum fractions.
Extraction of phenol from aqueous waste (coal carbonization plant, phenolic resin plant).
Purification of the uranium fuels.
Separation Process-II
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Feed mixture is mixed in the solvent in the mixer 1 and then extract 1 and
raffinate 1 are separated in the separator 1. Raffinate 1 is again treated similarly in mixer 2 and
separator 2.
EQUILIBRIUM DATA:
Distribution Law:
The equilibrium condition for the distribution of one solute between two
liquid phases is conveniently considered in terms of the distribution law. Thus, at equilibrium, the
ratio of the concentrations of the solute in the two phases is given by;
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