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ELECTRICAL ENGINEERING
Prashantkumar Koradia ,ManageEssar Oil Ltd. ,Refinery Site, 39 KM, JamnagarOkha Highway , Vadinar - 361305
2
Prof. M. N. Bhusavalwala M.E.. Associate Professor, Head Of The Department ,S V
National Institute of Technology (SVNIT), Surat
Prashantkumar.Koradia@essar.com, mnb@eed.svnit.ac.in
ABSTRACT Cathodic protection is technique used to protect steel materials against corrosion i.e.
underground vessels, pipelines, storage tank bottoms etc. buried underground or in sea water against corrosion.
The condition monitoring of cathodic Protection systems have received considerable attention in recent years
because corrosion may lead to spillage of oil and leakage of gases from storage tanks and Pipelines. Routine
measurements of CP level are required to comply with regulatory safety standards. In most of cases, the length
of pipelines for which CP level are to be measured are in lengths of kilometers. This paper includes the method
of condition monitoring of cathodic protection system in petroleum refinery using GSM based remote
monitoring unit (RMU).
Keyword:- Corrosion, Cathodic Protection, Condition Monitoring, GSM Based Remote Monitoring System,
Pipe To Soil Potential And Tank To Soil Potential.
I.
INTRODUCTION
In petrolieum refineries and petrochemical plants,
steel tanks and underground vessels for the storage
of crude oil and products as well as pipelines for
transferring the crude and products from crude
distrillation plant to storage area and then to product
storage & dispatch area are among the most parts of
the fixed plant facilities. Corrossion leads to not only
lossess of the metal and disconnection of the tank and
pipelines from the regular plant operation, but also
lossess of the product and severe environment
problems. Corrossion was a factor in 21.5% (28/128)
of all accidents in refineries reported to the MARS
database. Since 1980, 3 accidents account for the
majority of 60 deaths and 370 injuries arising from
these events (if BP Texas city -2005 is included). An
accident in Germany in 2006 estimated 9.5 million
in environmental damage.
Cathodic Protection is a technique to reduce the
corrosion of a metal surface by making that surface
the cathode of that electrochemical cell.[1]
In 1971 Galvani noticed that when two metals having
different energy level or potential are coupled
together current will flow. The direction of positive
current flow will be from the metal with more
negative potential through the electrolyte to that
which is more positive. Corrosion will occur at the
point where positive current leaves the metal surface.
Corrosion is degradation of a metal by its chemical
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1.
Electrolytic corrosion.
Electrolytic corrossion is a result of direct current
from outside sources entering and then leaving a
particular metallic structure by way of electrolyte.
When current enters the structure, that part is usually
unaffected or is provided with some degree of
protection but when the current leaves the structure,
corrossion occurs. In underground work, this type of
corrossion is usually reffered as stray current
corrossion. This type of corrossion usually results due
to current entering the soil from sources of DC like
DC motors or DC powerhouse.
2.
Galvanic corrossion.
All metals have specific relative electrical potential.
When metals of different electrical potential are in
contact in the presence of moisture, a low energy
electric current flows from the metal having the
higher position in the galvanic series. This is called
"galvanic action." Galvanic corrosion is a form of
electrochemical corrosion that occurs when two
dissimilar metals come together in the presence of an
electrolyte to form an electrical couple, known as a
galvanic couple. The more noble or cationic the
metal, the less likely it will corrode relative to the
other metal with which it is in contact. The more
active, or anodic, metal corrodes rapidly while the
more noble, or cathodic, metal is not damaged. The
difference in potential can arise from the coupling of
two dissimilar metals, variation of electrolytes, nonhomogeneity of the metal, or a combination of the
above.[6]
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IV.
CATHODIC PROTECTION
Cathodic protection is a technique to reduce the
corrosion of a metal surface by making that surface
the cathode of that electrochemical cell. [1]
The concept of CP has been around for quite some
time. Marine vessels have used CP for almost 200
years The first recorded use of CP occurred in the
early 1800s. In 1824, Sir Humphry Davy was
consulted by the British Admiralty, which was
concerned about the rapid decay of the copper
sheeting of His Majestys ships of war and the
uncertainty of the time of its duration. Davy
proposed the attachment of a small piece of zinc to
nullify electrochemical action on the copper
sheathing. Davy also investigated this action using an
impressed current system [7].
Currently, CP is mandatory for underground, metallic
pipelines of hazardous gas and liquids [8], [9], and
for water storage tanks with a 250,000 gallon
capacity or greater [10]. Cathodic protection also is
recommended for underground piping systems
located within ten feet of steel reinforced concrete.
Galvanic corrosion will occur between the steel rebar
and the pipeline if the two systems are too close [10],
[11].
V.
TYPE OF CATHODIC PROTECTION
There are basically two methods of applying cathodic
protection.[12]
1)Sacrificial Anode Cathodic Protection.
2)Impressed Current Cathodic Protection
A)
Sacrificial Anode Cathodic Protection
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DIFFICULTIES
IN
CATHODIC PROTECTION
READINGS
Page 93
Page 94
CP = Cathodic Protection.
CM = Condition monitoring.
http://www.wbdg.org/ccb/ARMYCOE/PWTB/pwtb_
420_49_37.pdf
[4]
Roberge, Pierre R, Handbook of Corrosion
Engineering 1999.
[5]
Cathodic Protection [Online]. Available:
cpcorrosion.blogspot.com/2009/08/corrosionmechanism.html
[6]
Matthew
Stuart,
Dissimilar
metal
corrosion
[Online].
Available:
http://www.pdhonline.org/courses/s118/s118.htm
[7]
Sir H. Davy, On the corrosion of copper
sheeting by seawater, and on methods of preventing
this effect, and on their application to ships of war
and other ships, Proc. R. Soc. Lond., vol. 114, no.
1824, pp. 151246 and vol. 115, no. 1825, pp. 328
346.
[8]
Department of Transportation, Washington,
DC, Transportation of Natural Gas and other Gas by
Pipeline. 49 CFR, Part 192.
[9]
Department of Transportation, Washington,
DC, Transportation of Hazardous Liquids by
Pipeline, 49 CFR, Part 195.
[10]
Department of the Army, Washington DC,
Maintenance of Mechanical and Electrical Equipment
at Command, Control, Communications, Computers,
Intelligence, Surveillance, and Reconnaissance
(C4ISR) Facilities, TM 5-692-2, Chapter 31, Apr. 15,
2001.
[11]
Department of the Army, Washington DC,
Electrical Design, Cathodic Protection,
[12]
J. Paul Gayer, An Introduction to cathodic
protection, El Macero CA, 2009.
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