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SOLUTIONS
of

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Mock Test 1

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(Paper-1)

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Mock Test 1 (Paper-1) - Answers & Hints

MOCK TEST - 1
(Paper - I)
ANSWERS
MATHEMATICS

CHEMISTRY

PHYSICS

(B)

21.

(D)

41.

(B)

2.

(B)

22.

(C)

42.

(C)

3.

(C)

23.

(A)

43.

(C)

4.

(B)

24.

(D)

44.

(B)

5.

(D)

25.

(D)

45.

(B)

6.

(B)

26.

(A)

46.

(C)

7.

(C)

27.

(A)

47.

(C)

8.

(D)

28.

(A)

48.

(B)

9.

(A, C)

29.

(A, B, C, D)

49.

(A, B, C)

10.

(A, B, C, D)

30.

(B, C)

50.

(B, D)

11.

(C, D)

(A, B)

51.

(B)

12.

(A, B, D)

(A, C)

52.

(A, B, D)

13.

(B)

33.

(A)

53.

(D)

14.

(A)

34.

(B)

54.

(C)

15.

(B)

35.

(D)

55.

(A)

16.

(B)

36.

(B)

56.

(C)

17.

(C)

37.

(B)

57.

(A)

18.

(B)

38.

(A)

58.

(C)

19.

A (p, q, t)

39.

A (q, s)

59.

A (p, q, r, t)

20.

.m

ye

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om

1.

31.

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://

32.

B (p, r)

B (p)

B (q, r, t)

C (p, q, t)

C (r)

C (s)

D (s)

D (t)

D (r)

A (p, r, t)

40.

A (p, r, s, t)

50.

A (q, s, t)

B (p, r)

B (q, t)

B (s)

C (p, q, r, t)

C (p, q, r, s, t)

C (q, s)

D (p, r, s)

D (p, q, r, s)

D (p)

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Mock Test 1 (Paper-1) - Answers & Hints

ANSWERS

&

HINTS

PART - I : CHEMISTRY
1.

Answer (B)

6.

Answer (B)
O

Milliequivalents of H2 O2 = Milliequivalents of K2 Cr2 O 7

(i) CH3 C CMgBr


+
(ii) H,

W
1
1000 = 10 6
17
6

C C CH3
Lindlar's H(1 eq)
2
catalyst

CH3
C

Suppose, weight of sample = x g

C
H

om

w H2O2 = 0.17g H2 O 2

CN

68
= 0.17
100

CH3

CN

ng
g.
c

x = 0.25g
Answer (B)

d [ I2 ]
dt

7.

2
2
1 d S 2 O3 d S 4O 6
=
=
2
dt
dt

If X = 0.2 & Y = 0 then


T f = i Kf m

.m

1 d I
=
= Rate of reaction.
2 dt

Answer (C)

CH3 C CLi
(1 eq)

= 1.116

w
://

ht
tp

Cl

So, observed range of Tf becomes 0.744 to 1.116.


8.

(i) NaCN (1 aq)


(ii) H

OH

Answer (A, C)

Now,
Milliequivalent of Ca 2+ = milliequivalent of K4 [Fe(CN)6 ]

CN

5.

9.

The n-factor of K 4 [Fe(CN) 6 ] is 3 because 3K + are


displaced by Ca 2+ in one mole.

CH3

H3C

4.

Answer (D)
On heating, -graphite is converted into -graphite & on
grinding -graphite is converted into -graphite.

CH3

CH3

= 0.744
T f = 3 1.86 0.2

CH3

= 2 1.86 0.2

If X = 0 & Y = 0.2 then

3.

Answer (C)

ye

2.

CN
CN

Answer (B)

W
1000 = 30 0.1 3
20

BeO is an amphoteric oxide. BeSO4 is water soluble


while Be(OH)2 is water insoluble.

WCa =

Answer (D)
On adding O 2 (g), IInd equilibrium shifts in backward
direction & 1st equilibrium shifts in forward direction.

600 0.3
= 0.18g pure calcium
1000

% purity of calcium ore =

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0.18
100 = 18%
1

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Mock Test 1 (Paper-1) - Answers & Hints

4
10. Answer (A, B, C, D)

Solution of Q13 to Q15

Cyclopentadienyl rings have aromatic character. So, it


undergoes Friedel Crafts acylation & do not give
reactions of dienes.
11.

HO

1. NaOH
2. HCHO
+
3 . H3 O

CHO

CHO

HO
HO

[A]

Answer (C, D)
O
CH3 C CH3

(i) CHMgBr
3

H ,

H+

( i i ) H3 O

CH2

H 3C

H 3C

PhP
3 = CH2
Wittig Reaction

H3C

S
H3C

CH

ng
g.
c

CH

H 3C O

CH2
NH

H3C O

1
4 + 1 = 2Na +
4

H 3C

://

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HO

Number of Na + ions removed = 1Na + ion

CH

NH
C

1
1
2 = Cl ion
8
4

Number of

ions removed =

1Na +

ion

1
2 = 1Cl ion
2
Hence, stoichiometry of NaCl remains same.
Number of Cl ions removed =

13. Answer (B)


14. Answer (A)
15. Answer (B)

CH3

CH2

HO

HC
[Albuterol]

Hence, stoichiometry of NaCl does not same

Na +

CH3

OH

(C) When a body diagonal line is passed then two


corners & one body atoms are removed

(D) On passing a tetrad axis, two face atoms & 1 body


atom are removed.

CH 3

CH 3

ye

.m

CH3

H2N

Number of Cl ions removed = 4 = 2Cl


2
Hence, stoichiometry of NaCl remains same.

Number of Cl ions removed =

CH2

OH
H 3O

(B) When a rectangular plane is placed then 4 edges, 4


faces & one body atoms are removed.
Number of Na + ion removed =

H 3C O

[C]

1
1
+
= 2 + 1 = 1 Na
4
2
Number of Cl ions removed

Hence, stoichiometry of NaCl remains same.

O
CH 2

H3C O

(A) When a body diagonal plane is placed then 4


corners, 2 edges, 2 faces & one body atoms are
removed. Number of Na + ions removed

1
1
1
= 2 + 4 = 1 Cl .
2
8
2

[B]

om

12. Answer (A, B, D)

CHO

CH 3
CH 3

16. Answer (B)


Pb 3 O4 exists as 2PbO. PbO2 .
In (B) option, reaction proceeds as :

2PbO + 4HCl
2PbCl2 + 2H 2O
(Acid - base reaction)
+4

+2

PbO 2 + 4HCl
PbCl2 + 2H 2 O + Cl2
(Redox reaction)

(A) is acid base reaction, (C) is salt displacement reaction


& (D) is only redox reaction.

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Mock Test 1 (Paper-1) - Answers & Hints

17. Answer (C)

The balanced equation is

6H + + IO 3 + 5I
3I 2 + 3H 2 O
(B) PCl2 F3

So, 1 mole IO 3 produces 3 mole of I2 .

Cl

I2 reacts with Na 2 S2 O3 as follows


2NaS2 O3 + I2 Na 2 S4 O6 + 2NaI

1 mole I2 2 mole Na 2 S2 O3

Cl

3 mole I2 6 mole Na 2 S2 O3
sp3d

18. Answer (B)

hybridisation

Trigonal bipyramidal geometry

The n-factor of P4 & FeC2 O4 both are 3.

NH2
H

+ NH3

ng
g.
c

(A)

om

19. Answer A(p, q, t), B(p, r), C(p, q, t), D(s)

Stable aromatic
carbanion

Xe

(C) XeF2

ye

(B)

O + H2 O
O

linear shape

NaHCO3

dipole moment = Zero

+ HO
+ CO2
2

ht
tp

(C)

hybridisation

Trigonal bipyramidal geometry

OH

://

F
sp3d

O
H
Stabiliized by
intramolecular
Hydrogen Bonding

.m

OH

Stable

20. Answer A(p, r, t), B(p, r), C(p, q, r, t), D(p, r, s)

(D) SF 4

Cl

F
(A) PCl3 F2

Cl

sp3d hybridisation
Trigonal bipyramidal geometry

Cl

see saw shape.

sp3d

hybridisation

Trigonal bipyramidal geometry


dipole moment = Zero

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Mock Test 1 (Paper-1) - Answers & Hints

PART - II : MATHEMATICS
23. Answer (A)

21. Answer (D)

x3
x +1

xy + y = x 3

3+ y
x=
1 y

1
log 2 x 1 + log1/2 x3 + 2 > 0
2

and

Thus, f ( y ) + f y 3 = 3 + y
y
+
1

1 y

y3
3+ x
x=
1 x
y+1

.m
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://

3+ y
f
= 2 f ( y) + y
1 y

ht
tp

y 3
f
+
y +1

4y
y
f ( y) =

2
2
1 y
f ( 2) =

2 x < 4

uuur uuur
uuur
Then, XP + XR = 2 XS

Adding them, we get

0 log2 x 1 < 1

Let S and T be the mid-points of the sides PR and QR


respectively.

3+ y
y3
We have f
+ f ( y) =
y +1
1 y

24. Answer (D)

x 3 3 + y
=
x +1 1 y

8y
= 2 f ( y) +
1 y2

log2 x 1 0

by solving (i) we get

ye

and

8
8
11
1 = 1 =
14
3
3

and

uuur uuur
uuur
2 XQ + XR = 4 XT

uuur
uuur
uuur
uuur
uuur uur
XP + 2 XQ + 3 XR = 2 XS + 2 XT = 0

uuuur
uuur
uuuur
uuur
XS and X T are collinear and XS = 2 X T

ar ( PQR) 3 2
ar PTS 3
= and
=
=3
ar PB 2
ar ( PR )
2

x2 4x + 3 < 0

x (1, 3)

Let the positive vector of P, Q, R with respect to X b e


r r r
a, b , c respectively

g(3) 0
4 k 1

Area of PQR =

1 r r r r r r
| a b+ b c+ c a
2

r
r
r
but a + 2b + 3c = 0

Let f(x) = 21x + k, g(x) = x2 2(k + 7)x + 5


When 1 < x < 3, the images of f(x) and g(x) are both
below the x-axis and since A B, f(x) is decreasing and
g(x) is quadratic function. A B iff f(1) 0, g(1) 0 and

Alternate Solution

22. Answer (C)

...(i)

ng
g.
c

Similarly for y =

3
3 1
log2 x 1 log2 x + + > 0
2
2 2

om

Putting y =

The domain of the given function is the set of values


of x satisfying

r r
r r
2 a b = 3c a
r
r r b cr
b

c
=
and
2

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...(i)

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Mock Test 1 (Paper-1) - Answers & Hints

Area of PQR =

1 3r r 1r r r r
ca + c a+ c a
2 2
2

3 r r
c a
2

x2 2x + 1 = 1 + k

x =1 1+ k

RS 2 = ( x1 x2 ) 2 + ( y1 y2 ) 2 = 5( x2 x1 ) 2 = 20( k + 1)

Similarly area of PXR =

1 r r
c a
2

Let us pick a point (6, 5) on y = 2x 17 and the


distance from the point to the line y = 2x + k is a

ratio = 3

25. Answer (D)

0<
sin


2 < 3 <
2
2 2

k 1 = 3, k 2 = 63

a 2 = 80 or a 2 = 1280

Min (a 2 ) = 80

om

2+ 3 >

=2 5

(k + 1)

a=

27. Answer (A)

2 > sin 3

ng
g.
c

We have

17 + k

15

Required probability =

cos 2 > 0,cos 3 < 0

cos 2 cos 3 > 0

) (

Now, sin 2 sin 3 cos 2 cos 3

2+ 3
2 3
.sin
+ <0
2
2
4

://

= 2 2sin

sin 2 sin 3 < cos 2 cos 3

The foci lie on the y-axis

ht
tp

26. Answer (A)

R (x1, y1)

(x2, y2)
S

(x) = ke x

(0) = 1 = ke0 k = 1

(x) = e x

(x) = x2 ex

0 ( x ) ( x ) dx = 0 ( x e
1

Hence

(2
x
=

2 x

f(x) is non-negative x R

f(x) 0, x R

64a 2 16a 0

a(4a 1) 0

1
a 0,
4

Integral value of a = 0
f(0) < 0 a < 0

e 2 x dx

1
1
e 2x
e2 3
= x 2 e x 2 xe x dx
= e

0
0
2 2
2 0

17
)

29. Answer (A, B, C, D)

Let R(x 1 , y 1 ) and S (x 2 , y2 ) lie on the parabola


y = x2 and the equation of RS be y = 2x + k

y = (2 x + k)

C3

We have '(x) = (x)

Hence the curve represented by the equation is an ellipse

15

28. Answer (A)

ye

0<

.m

2<


, < 3<
2 2

and

C3 15 11C1 15

For distinct roots in (0, 1)

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55
91

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Mock Test 1 (Paper-1) - Answers & Hints

8
>0

a(4a 1) > 0

If , are the roots

T1
+
<1 0< a < 1
then 0 <
2
f(0) > 0

a>0

f(1) > 0

4 7a > 0

(2, 0)
T2

4
a<
7
Let (a, 0) be the centre of the circle and the radius be r.

a+2
2

1
, min f(x) = 0
4

a 2
1

30. Answer (B, C)


We have on squaring and adding

a 2 + 4a + 4 = 2(a 2 4a + 4)

a 2 12a + 4 = 0

a=

12 8 2
= 6 4 2
2

ye

4 + 9 + 12 sin ( + ) = 25

radius = |a 2| = 4

+ = ( 4n +1) , n Z
2

) (

2 1 , 4

2 +1

w
w

The given lines are coplanar if

2$i + 5k$

w
://

=
2
2

5 sin = 3 sin =

32. Answer (A, C)

ht
tp

When + =

.m

sin( + ) = 1 = sin
2

= radius of the circle = r

ng
g.
c

When a =

Then

om

1 4
Hence a ,
4 7

2 0 5
1 1 = 0
1 2

3
4
or cos =
5
5

3
4
Also cos = andsin =
5
5

$i $j + k$ $i + j$ + 2k$ = 0

5 + 33 5 33
,
4
4

33. Answer (A)

Hence >

34. Answer (B)

31. Answer (A, B)

35. Answer (D)

Since the point P(2, 0) lies on the directrix of the

and
2
the equations of PT 1 a n d PT 2 are y = x + 2 and
x + y + 2 = 0 respectively. The equation of T1 T 2 is
x2=0
parabola, hence the angle between the tangents is

Q.33 to Q35 Solution


The equation of the tangents to the given curve
y = (x) and y = (x) at points with equal abscissae x
are
Y (x) = '(x) (X x)

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Mock Test 1 (Paper-1) - Answers & Hints

and Y (x) = '(x) (X x)

which will intersect on y-axis if


Y (x) = x '(x)
Y (x) = x '(x)
(x) (x) = x

d
{ (x ) (x )}
dx

d ( ( x ) ( x ))

( x ) ( x)

ln((x) (x)) = lncx

(x) (x) = cx

ln (1 + a ) + c, at a = 0, c = 0
2

I=

ln (1 + a )
2

ng
g.
c

2a

1
1

dx

a 2 b 2 0 1 + b 2 x2 1 + a 2 x 2
2ab 1 1

=
2
a b 2 b a b ( a + b)
2

.m

ye

I=

ln ( a + b ) + c
b

Using a = 0, I = 0 K = ln b
2

hence

(x) =

(x) + (x) =

://

I=

These normal intersect on x-axis,


X = x + (x) '(x) and X = x + (x) '(x)

((x))2 ((x))2 = k

...(i)

1
and Y ( x ) =
( X x)
'( x )

a2

1
Y ( x) =
( X x)
'( x )

(x)'(x) = (x)'(x)

dI
1
1
=
.2ax2 .
dx
2 2
da 0 1 + a x
1 + b 2x 2

The equations of normals at the points with equal


abscissae x to the given curves are given by

dx =
) 1 + x 2 1+ a 2 x 2 2 (1+ a )

37. Answer (B)

dx
x

om

1
1a2

a +b
ln

b b

38. Answer (A)

ht
tp

k
cx

Hence I =

sin mx
dx
x
0

I=

1
K
1
K
cx + , ( x ) = cx
2
cx
2
cx

Since curve passes throgh (1, 1) and (2, 3),

dI
sin mx
= cos mxdx =
, which is not defined
dm 0
m 0

39. Answer A(q, s), B(p), C(r), D(t)

2
2
Hence (x) = x +
, (x) = x +
x
x
36. Answer (B)

A.

The no. of shortest routes that must pass through


the junction A = 5 C2 8 C3

B.

The no. of routes that must pass through the street


AB = 5 C2 7 C3

C.

The no. of routes that pass through junctions A


and C = 5 C2 4 C1 4 C2

D.

When street AB is closed, the number of possible


routes = 13 C5 5 C2 7 C3

We have

I=
0

tan 1 ax
dI
1
dx
=
dx
2
2 2
da
x 1+ x
1+ x2
0 1+ a x

)(

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Mock Test 1 (Paper-1) - Answers & Hints

10
40. Answer A(p, r, s, t), B(q, t), C(p, q, r, s, t), D(p, q,
r, s)
B.

C.

We have

ar

ar
a2

a 2 r2

r4

r2

1=0

r2 =

r2 =

where a = 2

10ar = 4a + 4ar2

2r2 5r + 2 = 0

(r 2) (2r 1) = 0

r = 2,

r=

1
, but r 2
2

1
, a = 40
2

1
We have a2 = 9 + 4 2.2.3. = 13 + 6 = 19
2

1 5
2

120 3
60

om

D.

1+ 5
2

a2

ye

5 +1
= ar 2 = 2
= 5 + 1 = 1+ 5
2

.m

= a + b a = 1, b = 5

and

b 2 = 4 + 9 2.3.2.

b= 7

Perimeter = 2

19 + 7

1
= 7
2

a + b = 19 + 7 = 26

a 2 + b 2 = 26

= 19 a = 19

ng
g.
c

(ar2 )2

We have a + ar + ar2 = 70

PART - III : PHYSICS

pE =

ht
tp

By conservation of energy

://

41. Answer (B)

17 2 2 7
mr = mv 2
2 5
10

10 pE
=v
7m

k 0.6 g
= +
= 2
R
m

k 0.6 g
100 0.8 10
+
=
+
= 256 = 16 rad/s
m
R
0.5
3/28

46. Answer (C)

U =

= 3

43. Answer (C)

tan =

= (kR2 + 0.6 mgR)

F is equals to gravitational force at different points

r
r
vcm = 4i + 8 j v A,cm = 2i 4 j
cm

Restoring torque on small displacement

45. Answer (B)

42. Answer (C)

A,

44. Answer (B)

4r
r
in critical case and tan37 =
tan = 3
h
h

1 2
Li
2
di
= iV
dt

U = Li

U et / (1 e t / )

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Mock Test 1 (Paper-1) - Answers & Hints

11

47. Answer (C)

52. Answer (A, B, D)

Initial pressure in bubble = P +

4s
r

Linear momentum is conserved if particle strikes at

x=

1
4s

Final pressure = 8 P + , as volume becomes th


8
r

and T is constant.

2L
as in this case reaction at hinge is zero.
3

r
As about hinge is zero, L = constant about hinge.
53. Answer (D)

4s 4s
3s

Outside pressure = 8 P +
= 8 P +
r
r
/
2
r

FBD of body is as shown.

48. Answer (B)

acmcos

1
1 1 1
= (1.5 1)
=
f
5 10 20

By = I about instantaneous axis at O

vobject/meniscus = 1.4 m/s (upward)

vimage/meniscus = m2 vobject/meniscus

ye

= 4 1.4 = 5.6 m/s (upward)


vimage = 5.6 + 1.4 = 7 m/s

For refraction at AB, 1 sin90 = 2 cos

...(i)

For refraction at AC, 3 sin90 = 2 sin

.m

49. Answer (A, B, C)

...(ii)

Eq (i) & (ii)

ht
tp

://

For emergence of ray from AC, C at the face

for T.I.R > C

g
6R

a x = acm cos
= .OB cos
=

g
2R
. 5R .
6R
5R

g
3

54. Answer (C)

f = m.a x =

1 2 + 3 2 < 2 2
Orbital speed and orbital angular momentum independent
of mass of revolving particle

By conservation of energy

2 MgR =

51. Answer (B)

r
r
v
As | v1 | = |v2 |, v =
2
r
r
Angle between v1 and v2 = = 60
a= 3

2Mg
3

55. Answer (A)

50. Answer (B, D)

ng
g.
c

vmeniscus = 2 gh = 2 9.8 0.1 = 1.4 m/s (down)

1
sin 3
2

acm acm sin

v
=2
u

1 2 + 3 2 = 2 2

om

m=

R
R
and b =
a = 3b
2
2

1
2
2
(4MR ) =
2

g
R

56. Answer (C)


For any point P on surface A if |S2 P S1 P| = constant,
locus of P is circle.
For any point P on surface B if |S 2 P S 1 P| = constant,
locus of P is hyperbola.

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Mock Test 1 (Paper-1) - Answers & Hints

12
57. Answer (A)

60. Answer A(q, s, t), B(s), C(q, s), D(p)

For maxima, path difference = n

(p) Energy is lost due to friction

For maxima path difference = (2n 1)

(q) Resistance =

58. Answer (C)

(r)

r
.v
v i
v fringe = vj
i = vj
3
3

v fringe

l
l2
=
A volume

(s)

Use Bernoull's theorem


Direction of r (about O) charges as particle moves
from A to B

(t)

Internal energy increase on dissociation as n

10v
=
3

becomes double while f becomes

59. Answer A (p, q, r, t), B(q, r, t), C(s), D(r)


r
r
r d r dL
v2

=
,

=
Use
and aradial =
dt
dt
r

U =

6
U
5

om

ht
tp

://

.m

ye

ng
g.
c

By PV = nRT, P increases

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3
th
5

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