Sr. No.

Cw

Time(s) Vol used (mL)

1
600
0.1
2
1200
0.9
3
1800
1.2

0.001
0.009
0.012

C
Ln (1-Cw/C)
0.0452 -0.022372298
0.0452 -0.222037968
0.0452 -0.308547211

-0.02237
600
Calculating
slope
-0.22204
-0.30855

1200
1800

2000
1800
1600

f(x) = - 3985.4521480236x + 465.4014600763

1400
1200
1000

time (s)

800
600
400
200
-0.35

-0.3

-0.25

-0.2

-0.15

ln(1-Cw/C)

-0.1

-0.05

Bottle

Initial

Vol of NaOH

[CH3COOH]

Wt. of CH3COOH

No.

conc (Co)

used (V)

after adsorption

adsorbed

C=V*0.1/10

X=(Co-C)60Mc/1000

1
2
3
4
5
6

0.6
0.5
0.4
0.3
0.2
0.1

32.5
29.0
18.0
14.5
8.0
5.0

0.325
0.290
0.180
0.145
0.080
0.050

0.990
0.756
0.792
0.558
0.432
0.180

Log C

Log (x/m)

-0.488117
-0.537602
-0.744727
-0.838632
-1.09691
-1.30103

-0.481486
-0.598599
-0.578396
-0.730487
-0.841638
-1.221849

Freundlich isotherm
-1.4

-1.2

-1

-0.8

-0.6

-0.4

-0.2

0
0
-0.2
-0.4
-0.6

log (x/m)

-0.8
-1
-1.2
-1.4
log C

Bottle
No.

Initial
conc (Co)

1
2
3
4
5
6

0.6
0.5
0.4
0.3
0.2
0.1

Vol of NaOH
used (V)

Conc of Oxalic acid

after adsorption

Wt. of oxalic acid

adsorbed

C=V*0.1/4

X=(Co-C)60Mc/1000

17.7
14.9
10.7
7.7
4.9
1.6

0.443
0.373
0.268
0.193
0.123
0.040

0.851
0.689
0.716
0.581
0.419
0.324

Freundlich isotherm
-1.6

-1.4

-1.2

-1

-0.8

log (x/m)

log C

-0.6

-0.4

Log C

Log (x/m)

-0.354086725
-0.4288737229
-0.5726762136
-0.7155692662
-0.9118639113
-1.3979400087

-0.5474469368
-0.6392173101
-0.6225116166
-0.7133190306
-0.8554257924
-0.9665762445

m
-0.6

-0.4

-0.2
0
-0.2
-0.4
-0.6
-0.8
-1
-1.2

Heating
Time

Thermometer
reading
0
18
3.7
40
5.1
50
6
60
7.7
70
10.6
80
12.8
85
15.9
89
17.3
91
20.1
93
22.2
94
26
95
32.3
96
40
96.5
55.6
97

Step-input response to h
120
100
80
Temp. (0C)

60
40
20
0
0

10

20

30

40

50

Time (s)

Cooling
Thermometer
reading
0
95
5.9
80
8.5
75
11.7
70
16.4
65
19
63
22.1
61
23.5
60
26.7
58
29.8
56
34.2
54
38.2
52
44.5
49
53.9
45
72
39
101.5
34
111.5
32
129.1
30
181.5
25
216.3
23
276.1
21

Time

Step-input response to c
100
80
60
Temp. (0C)

40
20
0
0

50

100 150 200 250 300 350 4

Time (s)

329.2
407.5

20
19.5

response to heating

13112037

20

30

40

50

60

Time (s)

response to cooling

13112037

150 200 250 300 350 400 450

Time (s)

Vol NaOH
N2=(N1XV1)/V2
Time, Ti (s) used, V2 (mL) eq/L)
20
0.3
40
0.4
60
0.5
80
7.6
100
5.9
120
3.5
140
1.7
160
0.5
180
0.5
200
0.5
220
0.7
240
0.8
260
0.9
280
0.8
300
0.6
Total

Conc (mol/L)

20
40
0.04
60
80
0.03
100
120
0.02
140
0.01
160
180
0
0 200
220
240
260
280
300

(gm

Ci=N2/2
TixCi (mol
(mol/L)
s/L)
0.003
0.0015
0.03
0.004
0.002
0.08
0.005
0.0025
0.15
0.076
0.038
3.04
0.059
0.0295
2.95
0.035
0.0175
2.10
0.017
0.0085
1.19
0.005
0.0025
0.40
0.005
0.0025
0.45
0.005
0.0025
0.50
0.007
0.0035
0.77
0.008
0.004
0.96
0.009
0.0045
1.17
0.008
0.004
1.12
0.006
0.003
0.90
0.126
15.81

C-curve

0.0015
0.002
0.0025
0.038
0.0295
0.0175
0.0085
0.0025
0.0025
100
0.0025
0.0035
0.004
0.0045
0.004
0.003

50

150

200

250

300

350

time (s)

E-curve

0.020000
0.015000
E

0.010000
0.005000
0.000000
0

50

100

150
time (s)

200

250

300

350

0.000000
0

50

100

150
time (s)

200

250

300

350

CixTi2 (mol
s2/L)
E
0.6
3.2
9.0
243.2
295.0
252.0
166.6
64.0
81.0
100.0
169.4
230.4
304.2
313.6
270.0
2502.2

250

250

300

300

0.000599
0.000799
0.000999
0.015187
0.011790
0.006994
0.003397
0.000999
0.000999
0.000999
0.001399
0.001599
0.001798
0.001599
0.001199

350

350

250

300

350