TUITION TEST :: CHEMISTRY :: GOC

Full Marks: 15

Time: 20 minutes

1. What is meant by the term structural isomer? Give example.

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2. Draw the three structural isomers of the alkene which has the molecular formula C4H8 . 1
3. CH3CH = CCl2 is a structural isomer of CH3CCl = CHCl but it does not exhibit
4.
5.
6.
7.

geometrical isomerism. Account for this difference.

What type of structural isomerism is shown by alkanes?
Can propane show chain isomerism? Why?
Write the conditions necessary for geometrical isomerism.
Which one of the following does not show geometrical isomerism?
CHCl = CHCl ; CCl2 = CHCl

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1
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1
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8. Why alkynes do not show geometrical isomerism? Explain.

9. What are tautomerism and metamerism? Give an example each.

10. Draw the possible stereoisomers of tartaric acid.

11. What are optical isomers?

12. Which of the following compounds will exhibit geometrical isomerism?

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(1) 1 phenyl 2 butene
(2) 3 phenyl 1 butene
(3) 2 phenyl 1 butene
(4) 1, 1 diphenyl 1 propane
13. Give the correct IUPAC name of the following compound:

14. How many chiral carbons are there in Resepine (an antipsychotic drug)?

O
O

N
H3C

CH3

O
N
H

CH3

CH3
O

CH3

H3C
O

(A) 9

(B) 8

(C) 7

15. Which of the following is incorrect relation between given pairs?

(D) 6
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