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JR MPC: (PRE-FINAL-II) (CHEMISTRY) IPE Q P EX.DT.

17-04-2021

TELANGANA STATE
SEC: JR.MPC (CIO, CAO & CEO) & NEET EXAM DATE:17-04-2021
PRE-FINAL – II EXAMINATION
Time: 3Hr. IPE MODEL EXAM Max. Marks: 60 M

CHEMISTRY
Note: This question paper consists of three sections A, B, and C
SECTION – A
I. Very Short Answer Questions 10 × 2 = 20 M
i) Answer ALL questions
ii) Each question carries TWO marks.
1. What type of bonds present in NH 4Cl ? Write its structure.
2. What is heterogeneous equilibrium? Give two examples.
3. Give the relation between the partial pressure of a gas and its mole fraction.
4. Calculate the equivalent weight of the Na2CO3 .
5. What do you mean by autoprotolysis? Give the equation to prevent the autoprotolysis of water.
6. Why does potassium carbonate can’t be prepared in Solvay process?
7. Boran is unable to form BF63 ion. Explain
8. CCl4 is not dissolved in water, but SiCl4 dissolves. Why? Give reason.
9. What is the type of hybridization of each carbon in the following compound?
HC  C  CH  CH 2
10. What is diagonal relationship? Give example.
SECTION - B
II. Short Answer Questions 6 × 4 = 24M
i) Answer any SIX questions
ii) Each Question carries FOUR marks.
11. Write the postulates of Kinetic molecular theory of gases.
12. 360 cm3 of CH 4 gas diffused through porous membrane in 15 minutes, under similar conditions,
120cm3 of another gas diffused in 10 minutes. Find the molar mass of the gas.
13. Balance the following redox equation by ion-electron method taking place in basic medium.

OH
P4   PH 3  H 2 PO2
14. Calculate the mass of Na2CO3 required to prepare 250ml of 0.5 N solution.
15. a) What is standard enthalpy of formation? Example.
b) What is standard enthalpy of sublimation? Example.

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JR MPC: (PRE-FINAL-II) (CHEMISTRY) IPE Q P EX.DT. 17-04-2021
16. Derive the relation between K C and K P for equilibrium reaction
2 SO2( g )  O2( g )  2 SO3( g )
17. What is conjugate acid-base pair? Write the conjugate acid-bases for the following species.
i) HCO3 ii) OH  iii) HSO4

18. Explain the following with suitable examples.


(a) Electron deficient hydride
(b) Electron rich hydrides
19. Complete the following reaction and name the products A, B and C
H 2O hot metal tube AlCl3  CH 3Cl
CaC2   A   B  C
20. What are electron deficient compounds? Is BCl3 electron deficient species? Explain.
21. Explain the difference in properties of diamond and graphite on the basis of their structure.
22. Explain the difference between emission and absorption spectra.
SECTION - C
III. Long Answer Questions 2 × 8 = 16 M
i) Answer any TWO Questions
ii) Each Question carries EIGHT marks
23. What are the postulates of Bohr’s model of hydrogen atom? Discuss the importance of this model to
explain various series of line spectra in hydrogen atom.
24. What is a periodic property? How the following properties vary in a group and in a period? Explain
a) Atomic radius b) IE c) EN d) Nature of oxides
25. (a) What is hydrogen bond? Explain the different types of hydrogen bonds with examples.
(b) Even through nitrogen in ammonia is in sp 3 hybridization, the bond angle deviate from 1090 28' .
Explain.
26. Describe any two methods of preparation of benzene. Explain the halogenation, alkylation, acylation,
nitration and sulphonation of benzene.

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PAPER SETTER :: TANUKU–WG


CHEMISTRY: J. Nagarjuna Rao, 9052852626

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