LEMBAR PERHITUNGAN REAGEN

Tinggi cairan
Luas Area Riser (Ar)
Luas Area Downcomer (Ad)
Luas alas reactor
BM Na2SO3
BM Na2S2O3.5H2O
Na2S2O3.5H2O 0,1 N
m x 1000 x val
N=
BM x V
0,1=

= 90 cm
= (8,2 cm x 14 cm) = 114,8 cm2
= (5,6 cm x 14 cm) = 78,4 cm2
= (114,8 cm2 + 78,4 cm2)
= 193,2 cm2= 17,581 dm3
= 128 gr/mol
= 248,15 gr/mol

m x 1000 x 2
248,15 x 500

m=6,203 75 gram

Na2SO3 0,03 N
1. Variabel 1= tinggi cairan 90 cm
Volume Reaktor
= Luas alas total x tinggi cairan
= (114,8 cm + 78,4 cm) x 90 cm
= 17352 cm3 = 17,352 dm3
N=

m x 1000 x val
BM x V

0,03=

m x 1000 x 2
128 x 17352

m=33,316 gram
2. Variabel 2= tinggi cairan 92 cm
Volume Reaktor
= Luas alas total x tinggi cairan
= (114,8 cm + 78,4 cm) x 92 cm
= 17774,4 cm3 = 17,7744 dm3
N=

m x 1000 x val
BM x V

0,03=

m x 1000 x 2
128 x 17774,4

m=34,127 gram

3. Variabel 3= tinggi cairan 94 cm

Volume Reaktor
= Luas alas total x tinggi cairan
= (114,8 cm + 78,4 cm) x 94 cm
= 18160,8 cm3 = 18,1608 dm3

N=

m x 1000 x val
BM x V

0,03=

m x 1000 x 2
128 x 1 8160,8

m=34,869 gram

LEMBAR PERHITUNGAN
A. Menghitung densitas cairan dalam reaktor
Variabel 1
M pikno (m0)
= 31,085 gram
M pikno+air (m1)
= 80,276 gram
Volume picnometer = 50 ml
air
= 1 gr/cm3
=
=

m1m0
v

80,27631,085
50

=0,958 3 gr /ml

Variabel 2
M pikno (m0)
M pikno+air (m1)

= 31,085 gram
= 81,442 gram

Volume picnometer
air

= 50 ml
= 1 gr/cm3
=
=

m1m0
v

81,44231,085
50

=1,007 gr /ml

Variabel 3
M pikno (m0)
M pikno+air (m1)
Volume picnometer
air

= 31,085 gram
= 81,462 gram
= 50 ml
= 1 gr/cm3
=
=

m1m0
v

81,46231,085
50

=1,008 gr /ml

B. Hold Up Gas
gas
Panjang riser
Panjang downcomer
Lebar
Luas riser (Ar)

=
=
=
=

=
=
=
Luas downcomer (Ad) =
=
=

0,0012 gram/ml
8,2 cm
5,6 cm
14 cm
panjang riser x lebar
8,2 cm x 14 cm
114,8 cm2
panjang downcomer x lebar
5,6 cm x 14 cm
78,4 cm2

1. Variabel 1
=0,9583 gr /ml
Tinggi fluida
hr
hd
Z

=
=
=
=

90 cm
1,4 cm
0,35 cm
90 cm 9,5 cm = 80,5 cm

Hold Up Gas Riser

L
hr
r =

L g
Z
r =

Hold Up Gas Downcomer

L
hd
d =

L g
Z
r =

0,9583 gr /ml
1,4 cm

=0,0174
0,9583 gr /ml0,0012 cm 80,5 cm

0,9583 gr /ml
0,35 cm

=0,00435
0,9583 gr /ml0,0012 cm 80,5 cm

Hold Up Gas Total

=

A r r A d d
Ar+ Ad

114,8 0,0174+78,4 0,00435

=0,0121
114,8+78,4

2. Variabel 2
Tinggi fluida
hr
hd
Z

=
=
=
=

92 cm
1,3 cm
0,5 cm
92 cm 9,5 cm = 82,5 cm

Hold Up Gas Riser

L
hr
r =

L g
Z
r =

=1,007 gr /ml

1,007 gr /ml
1,3 cm

=0,0158
1,007 gr /ml0,0012 cm 82 , 5 cm

Hold Up Gas Downcomer

L
hd
d =

L g
Z

r =

1,007 gr /ml
0, 5 cm

=0,0 0607
1,007 gr /ml0,0012 cm 82 , 5 cm

Hold Up Gas Total

=

A r r A d d
Ar+ Ad

114,8 0,0158+ 78,4 0,00 60 7

=0,01 18
114,8 +78,4

3. Variabel 3
Tinggi fluida
hr
hd
Z

94 cm
0,7 cm
0,4 cm
94 cm 9,5 cm = 84,5 cm

1,008 gr /ml
0,7 cm

=0,0162
1,008 gr /ml0,0012 cm 84,5 cm

Hold Up Gas Downcomer

L
hd
d =

L g
Z
r =

=
=
=
=

Hold Up Gas Riser

L
hr
r =

L g
Z
r =

=1,008 gr /ml

1,008 gr /ml
0, 4 cm

=0,00 474
1,008 gr /ml0,0012 cm 84 ,5 cm

Hold Up Gas Total

=

A r r A d d
Ar+ Ad

114,8 0,0162+78,4 0,00 474

=0,01 15
114,8+78,4

C. Laju Sirkulasi

Panjang lintasan (Lc) = 30 cm

a Variabel 1
tc = 2,1 s
L
Uld = c
tc
Uld =

30 cm
cm
=14,3
2,1 s
s

Ulr Ar =Ul d A d
Ulr =

Ul d Ad
Ar
14,3

Ulr =

Variabel 2
tc = 2 s
L
Uld = c
tc
Uld =

30 cm
cm
=1 5
2s
s

Ulr =

Ul d Ad
Ar
15

Ulr =

cm
2
78,4 cm
s
=9,756 cm/s
114,8 cm2

cm
78,4 cm2
s
=10,244 cm/s
114,8 cm2

Variabel 3
tc = 1,9 s
L
Uld = c
tc
Uld =

30 cm
cm
=15,8
1,9 s
s

Ulr =

Ul d Ad
Ar

15,8
Ulr =

cm
2
78,4 cm
s
=10,783 cm/ s
114,8 cm2

D. Koefisien transfer massa gas-cair (KLa)

Reaksi dalam reaktor:
Na2SO3 + 0,5 O2Na2SO4 +Na2SO3(sisa)
Reaksi saat analisa:
Na2SO3(sisa) + KI + KIO3 Na2SO4 + 2KIO2 + I2(sisa)
I2 (sisa) + 2 Na2S2O3 Na2S4O6 +2NaI

Mol N a2 S O 3 mula mula=

Mol I 2 excess=

N Na 2 S O3
v reakor
valensi

(a)

N KI
V KI
valensi

Mol N a2 S O 3 sisa=b

(b)

1 N Na 2 S2 O3
v Na 2 S2 O3
2
valensi

1
Mol O2 yang bereaksi= ( ac )
2
O2 yang masuk reaktor =
K La=

(c)

(d)

d BM O2
t 60

(e)

e
0,008

Variabel 1
Mol Na2SO3 mula-mula (a)
N Na2 S O3

Vreakor
valensi

t
(menit)

0,03 N
17352 ml=260,28 mmol
2

V
Na2S2O3.5H2O

Kla

(ml)

(mmol)

(mmol) (mmol)

(mmol)

(mgr/s)

(L/s)

22

260,28

0,5

0,335

129,97

20,1

260,28

0,5

0,349

129,97

13,863

1,73287
5

10

14

260,28

0,5

0,395

129,94

6,9301

0,76162
6

15

15,4

260,28

0,5

0,385

129,95

4,6204

0,57755

20

15,2

260,28

0,5

0,386

129,95

3,4653

0,43316
2

25

15,2

260,28

0,5

0,386

129,95

2,7723

0,34653
8

KLa rata rata = 0,77035 L/s

Variabel 2
Mol Na2SO3 mula-mula (a)

N Na2 S O3
Vreako r
valensi

0,03 N
17774,4 ml=266 ,62 mmo l
2

t
(menit)

V
Na2S2O3.5H2O
(ml)

a
(mmol)

b
(mmol)

c
(mmol)

21.3

266.62

0.5

0.34025

18.3

266.62

0.5

10

16.2

266.62

0.5

15

16.3

266.62

0.5

20

16.2

266.62

0.5

25

16.3

266.62

0.5

KLa rata rata = 0.675482 L/s

d
(mmol)

133.139
9
133.128
0.36275
6
133.120
0.3785
8
0.37775 133.1211
133.120
0.3785
8
0.37775 133.1211

e
(mgr/s)

Kla
(L/s)

14.20039

1.775048

7.099773

0.887472

4.733196

0.591649

3.549887

0.443736

2.839917

0.35499

 Variabel 3
Mol Na2SO3 mula-mula (a)
N Na2 S O3

Vreako r
valensi

0,03 N
1 8160,8 ml=272 , 41 mmo l
2

V
Na2S2O3.5H2O
t (menit) (ml)
0
5
10
15
20
25
30

25.7
17.9
17.8
18.5
19
18.8
19

(mmol)

(mmol)

(mmol)

(mmol)

(mgr/s)

0.5

0.3072
5

136.056
4

0.5

0.3657
5

136.027
1

14.50956

1.813695

0.5

0.3665

136.026
8

7.25476

0.906845

0.5

0.3612
5

136.029
4

4.8366

0.604575

0.3575

136.031
3

3.6275

0.453438

0.359

136.030
5

2.901984

0.362748

0.3575

136.031
3

2.418333

0.302292

272.42
272.42
272.42
272.42
272.42
272.42
272.42

KLa rata rata = 0.690217 L/s

0.5
0.5
0.5

Kla
(L/s)