LEMBAR PERHITUNGAN REAGEN

Luas area downcomer

: 71.4 cm

Luas area riser

2
:113.4 cm

BM Na2SO3

: 126 gr/mol

BM Na2S2O3.5H2O

: 248.15 gr/mol

Tinggi cairan

: 90 cm

Na2 S O3

0,035 N basis volume reaktor

Volume reactor

= L alas total x tinggi cairan

= (71.4 + 113.4) x 90
= 16632 cm

gr

Na2 S O3=

= 16.632 dm

N
BM Vreaktor
eq
=

0.035
126 16.632
2

= 36.674 gr
2

Gr

Na 2 S2 O3. 5 H 2 O

0.1 N
BM 0.5
2

0.1
248.15 0.5
2

= 6.204 gr
3

KI 0.1 N, 5 ml

Amilum 6 gr dalam 100 ml aquadest

LEMBAR PERHITUNGAN
1

Penentuan Hold Up Gas ()

gas=0.012 12

gr
ml

Tinggi sparger = 10.1 cm

Massa picno = 22.456 gr
Massa picno+aquadest = 46.292 gr
Massa picno+sampel = 46.625 gr

Vpicno=

46.29222.456
= 23.883 ml
0.998

sampel=

46.62522.456
23.883

= 1.012 gr/ml

Variabel 1 laju alir 6 L/m

hr =0.8 cm
hd=0.4 cm

z=9010.1=79.9 cm
riser =

L
hr

L g
z

1.012
0.8

1.0120.0 1212 79.9

= 0.0101

 downcomer =

L
hd

L g
z

1.012
0.4

1.0120.0 1212 79.9

= 5,067 x10-3
total =

A r r + A d d
Ar+ Ad

( 113.4 ) ( 0.01 01 )+ ( 71.4 ) ( 5,067 x 103 )

=
113.4 +71.4
3
= 6,4 x 10

Variabel 2 laju alir 8 L/m

hr =0.8 cm
hd=0.8 cm

z=9010.1=79.9 cm
riser =

L
hr

L g
z

1.012
0.8

1.0120.0 1212 79.9

= 0.0101
downcomer =

L
hd

L g
z

1.012
0.8

1.0120.0 1212 79.9

= 0.0101
total =

A r r + A d d
Ar+ Ad

( 113.4 ) ( 0.01 01 )+ ( 71.4 ) ( 0.0101 )

113.4+ 71.4

= 0. 0101
c

Variabel 3 laju alir 10 L/m

hr =1 cm

hd=0.5 cm
z=9010.1=79.9 cm

riser =

L
hr

L g
z

1.012
1

1.0120.0 1212 79.9

= 0.01267
downcomer =

L
hd

L g
z

1.012
0.5

1.0120.01212 79.9

= 6,334
total =

x 10

A r r + A d d
( 113.4 ) ( 0.01267 ) + ( 71.4 ) ( 6,334 x 103 )
=
= 0.01 02
Ar+ Ad
113.4+71.4

Perhitungan Laju Sirkulasi

Lc =3 0 cm
ULd =

Lc
tc

ULr =UL d
a

Ad
Ar

Variabel 1 (laju alir 6 L/m)

ULd =

Lc 3 0
=
=17.647
t c 1.7

cm/s

ULr =UL d
b

Lc 30
=
=23.077 cm/s
t c 1.3

ULr =UL d

Ad
71.4
=23.077
Ar
113.4

=14.53cm/s

Variabel 3 (laju alir 10 L/m)

ULd =

Lc 30
= =3 0 cm/s
tc 1

ULr =UL d

=11.11 cm/s

Variabel 2 (laju alir 8 L/m)

ULd =

Ad
71.4
=17.647
Ar
113.4

Ad
71.4
=30
Ar
113.4

=18,89 cm/s

K La

Perhitungan

Reaksi dalam reactor

Na 2 SO 3+ 0.5O2 Na 2 SO 4 + Na 2 SO 3 ( sisa )
Reaksi saat analisa
Na2 SO 3 ( sisa )+ KI + KIO 3 Na2 SO 4 +2 KIO 2+ I 2 ( sisa )
I 2 ( sisa )+2 Na 2 S2 O3 Na 2 S4 O6 +2 NaI

Mol

Na 2 SO 3 mulamula

Mol

I 2 excess ( b )

Mol

Na 2 SO 3

sisa (c)

(a)

N Na2 SO 3
v reaktor
eq

N KI
v KI
eq
=

1 N Na2 SO3
v Na 2 SO 3
2
eq

Mol

O2

yang bereaksi (d)

= x (a-c)

b-

O2 yang masuk reaktor

(e)

=
K La

Koefisien transfer massa gas-cair(

d BM O 2
t .60
e
0.008

)=

Variabel 1 (Laju Alir 6 L/m)

V titran

kLa

(menit)

(ml)

(mmol

(mmol)

(mmol)

(mmol)

(mgr/s)

(L/s)

)
0

9,8

291,06

0,5

0,255

145,4025

291,06

0,5

0,275

145,3925

15,50853

1,938567

10

8,4

291,06

0,5

0,29

145,385

7,753867

0,969233

15

291,06

0,5

0,3

145,38

5,169067

0,646133

20

7,9

291,06

0,5

0,3025

145,3788

3,876767

0,484596

KLa rata-rata = 0.807706 L/s

b

Variabel 2 (Laju Alir 8 L/m)

kLa

(menit

titran

(mmol

(mmol

(mmol

(mmol)

(mgr/s)

(L/s)

(ml)

9,6

291,06

0,5

0,26

145,4

9,4

291,06

0,5

0,265

145,397
5

15,5090
7

1,93863
3

10

8,7

291,06

0,5

0,2825

145,388
8

7,75406
7

0,96925
8

15

8,6

291,06

0,5

0,285

145,387
5

5,16933
3

0,64616
7

20

291,06

0,5

0,3

145,38

3,8768

0,4846

KLa rata-rata = 0.807732 L/s

c

Variabel 3 (Laju Alir 10 L/m)

kLa

(menit

titran

(mmol

(mmol

(mmol

(mmol)

(mgr/s)

(L/s)

(ml)

9,6

291,06

0,5

0,26

145,4

8,6

291,06

0,5

0,285

145,387
5

15,508

1,9385

10

7,8

291,06

0,5

0,305

145,377
5

7,75346
7

0,96918
3

15

7,6

291,06

0,5

0,31

145,375

5,16888
9

0,64611
1

20

7,5

291,06

0,5

0,3125

145,373
8

3,87663
3

0,48527
9

KLa rata-rata = 0.8078146 L/s