LEMBAR PERHITUNGAN REAGEN

1. Kebutuhan Na2S2O3.5H2O 0,1 N basis 500 ml

gr 1000
N= × × valensi
Mr V
gr 1000
0,1 = × ×2
248 50 0
gr = 6,2 gr
2. Kebutuhan Na2SO3 0,033 N
Tinggi cairan : 90,5 cm
Volume reactor : 14,3 cm x 14 cm x 90,5 cm
= 18118,1 cm3
gr 1000
N= × × valensi
Mr V
gr 1000
0,03 3 = × ×2
126 18118,1
gr = 38,01 gr

Luas area riser :

14,3 cm x 8,5 cm = 121,55 cm2
Luas area downcomer :
14,3 cm x 5,5 cm = 78,65 cm2
Tinggi sparger : 10 cm
Tinggi cairan : 90,5 cm
Maka nilai z : 90,5 cm - 10 cm = 80,5 cm

B-1
 LEMBAR PERHITUNGAN

1. Penentuan Hold-up Gas

25 oC = 298 K
kg
ρ gas250 =1,4128 ( Kalogirou , 2009 )
m3
kg
ρ gas300 =1,1774 3 ( Kalogirou ,2009 )
m
X− X 1 Y −Y 1
=
X 2−X 1 Y 2−Y 1
X−1,4128 298−250
=
1,1774−1,4128 300−250
kg
X =1,1868
L
kg m3 103 gr
ρ gas298 =1,1868 3 × 6 × =0,0011868 gr /ml
m 10 ml kg

 Variabel 1
h = 90,5 cm ; Δhr = 0,3 cm ; Δhd = 0,1 cm
Z = 90,5 cm – 10 cm = 80,5 cm
( 46 , 638 4−2 0,734 ) gr
ρcairan = =1,0362 gr/ml
25 ml
ρL
ε r=
Δhr
ρ¿ × ¿
Z
1,0362 0,3
ε r= ×
1,0362−0,0011868❑ 80,5
ε r=3 , 73098 x 10−3
ρL
ε d=
Δhd
ρ¿ × ¿
Z
1,0362 0,1
ε d= ×
1,0362−0,0011868 ❑ 80,5
ε d=1,2 4366 x 10−3
Ar . ε r + Ad . ε d
ε ❑=
Ar . Ad
( 1 21,55 ×3,73098 x 10−3 ) +(78,65 ×1,24366 x 10−3)
ε tot =
1 21,55+7 8,65
ε tot =2,75381 x 10−3

 Variabel 2

B-2
 h = 90,5 cm ; Δhr = 0,5 cm ; Δhd = 0,4 cm
Z = 90,5 cm – 10 cm = 80,5 cm
( 46,566−20,734 ) gr
ρcairan = =1,0332 gr/ml
25 ml
ρL
ε r=
Δhr
ρ¿ × ¿
Z
1,03 3 2 0 ,5
ε r= ×
1,03 32−0,0011868❑ 80,5
ε r=6,21832 x 10−3
ρL
ε d=
Δhd
ρ¿ × ¿
Z
1,03 3 2 0 ,4
ε d= ×
1,03 3 2−0,0011868❑ 80,5
ε d=4,97465 x 10−3
Ar . ε r + Ad . ε d
ε ❑=
Ar . Ad
( 121,55 × 6,21832 x 10−3 ) +(78,65 × 4,97465 x 10−3 )
ε tot =
121,55+ 78,65
ε tot =5,72973 x 10−3

 Variabel 3
h = 90,5 cm ; Δhr = 1 cm ; Δhd = 0,8 cm
Z = 90,5 cm – 10 cm = 80,5 cm
( 46,563−20,734 ) gr
ρcairan = =1,0332 gr/ml
25 ml
ρL
ε r=
Δhr
ρ¿ × ¿
Z
1,0332 1
ε r= ×
1,0332−0,0011868❑ 80,5
ε r=12,43664 x 10−3
ρL
ε d=
Δhd
ρ¿ × ¿
Z
1,0332 0,8
ε d= ×
1,0332−0,0011868 ❑ 80,5
ε d=9,94931 x 10−3

B-3
 Ar . ε r + Ad . ε d
ε ❑=
Ar . Ad
( 121,55 × 12,43664 x 10−3 ) +(78,65 ×9,94931 x 10−3 )
ε tot =
121,55+ 78,65
ε tot =11,45947 x 10−3

Laju alir εr εd ε❑
L/menit
4 3,73098 x 10−3 1,24366 x 10−3 2,75381 x 10−3
6 6,21832 x 10−3 4,97465 x 10−3 5,72973 x 10−3
8 12,43664 x 10−3 9,94931 x 10−3 11,45947 x 10−3

2. Perhitungan Laju Sirkulasi

Lc
Uld=
tc
Ad
Ulr=Uld x
Ar
Lc = 30 cm
 Variabel 1
Laju alir = 4 L/menit ; tc = 3 s
30 cm
Uld= =10 cm/s
3s
cm 7 8,65 cm2
Ulr=10 x =6 , 47058 cm/ s
s 1 21,55 cm2
 Variabel 2
Laju alir = 6 L/menit ; tc = 2,1 s
30 cm
Uld= =1 4,28571cm/ s
2,1s
cm 78,65 cm2
Ulr=14,28571 x =9,24369 cm/ s
s 121,55 cm2
 Variabel 3
Laju alir = 8 L/menit ; tc = 1 s
30 cm
Uld= =30 cm/s
1s
cm 78,65 cm2
Ulr=30 x =1 9 , 41176 cm/s
s 121,55 cm 2
Laju alir L/menit Uld (cm/s) Ulr (cm/s)
4 10 6,47058

B-4
 6 14,28571 9,24369
8 30 19,41176

2. Perhitungan Koefisien Transfer Massa Gas-Cair (KLa)

N Na 2 S O 3
a. Mol N a2 S O 3 mula mula= ×v reaktor
eq
N KI
b. Mol I 2 excess= × V KI
eq

1 N Na2 S 2 O3
c. Mol N a2 S O3 sisa=b−
2 ( eq )
×V Na2 S2 O3

1
d. Mol O 2 yang bereaksi= × ( a−c )
2
d × BM O2
e. O 2 yang masuk reaktor =
t × 60
e
Koefisien transfer massa gas-cair (KLa) K La=
0,008
 Variabel 1 ( Laju alir = 4 L/menit )
t V titran a b c e
d (mmol) KLa
(menit) (ml) (mmol) (mmol) (mmol) (mgr/s)
0 7,5 298,948 0,5 0,3125 149,3175 0 0
5 6,5 298,948 0,5 0,3375 149,3052 15,925 1990,62
10 6 298,948 0,5 0,35 149,299 7,962 995,25
15 6 298,948 0,5 0,35 149,299 5,308 663,5
20 6 298,948 0,5 0,35 149,299 3,981 497,663
KLa rata-rata 829,407

 Variabel 2 (Laju alir = 6 L/menit)

t V titran a b c e
d (mmol) KLa
(menit) (ml) (mmol) (mmol) (mmol) (mgr/s)
0 5 298,948 0,5 0,375 149,286 0 0
5 4,5 298,948 0,5 0,3875 149,280 15,923 1990,375
10 4,5 298,948 0,5 0,3875 149,280 7,961 995,125
15 4,5 298,948 0,5 0,3875 149,280 5,307 663,375
KLa rata-rata 912,218

 Variabel 3 (Laju alir = 8 L/menit)

t V titran a b c
d (mmol) e (mgr/s) KLa
(menit) (ml) (mmol) (mmol) (mmol)
0 4 298,948 0,5 0,4 149,274 0 0
5 4 298,948 0,5 0,4 149,274 15,922 1990,31
10 4 298,948 0,5 0,4 149,274 7,961 995,125
KLa rata-rata 995,145

B-5
B-6