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SECTION-B
Q.1 [3] Q.2 [4.86] Q.3 [0002] Q.4 [8] Q.5 [8] Q.6 [12] Q.7[100] Q.8 [5] Q.9 [7] Q.10 [4]
CHEMISTRY
SECTION -A
Q.1 (4) Q.2 (4) Q.3 (2) Q.4 (2) Q.5 (1) Q.6 (2) Q.7 (1) Q.8 (1) Q.9 (2) Q.10 (2)
Q.11 (4) Q.12 (2) Q.13 (2) Q.14 (3) Q.15 (3) Q.16 (3) Q.17 (2) Q.18 (3) Q.19 (1) Q.20 (1)
SECTION - B
Q.1 [18] Q.2 [0008] Q.3 [5440] Q.4 [3, 2] Q.5[169] Q.6[25] Q.7 [0112] Q.8 [41.56] Q.9 [5] Q.10 [3]
MATHEMATICS
SECTION-A
Q.1 (2) Q.2 (3) Q.3(2) Q.4 (3) Q.5 (4) Q.6 (3) Q.7 (3) Q.8 (1) Q.9 (1) Q.10 (2)
Q.11 (1) Q.12 (2) Q.13 (2) Q.14 (3) Q.15 (2) Q.16 (2) Q.17 (2) Q.18 (2) Q.19 (3) Q.20 (2)
SECTION-B
Q.1 [0002] Q.2 [0004] Q.3 [0039] Q.4 [0011] Q.5 [0002] Q.6 [0032] Q.7 [0055] Q.8 [0002] Q.9 [0039] Q.10 [0002]
2n + m = 1 ....(i) =
–n + 2m = 1 ....(ii) 4 1 2 cos
–––––––––––– 3(1 + 2cos)2 = 16sin2
3(1 + 4cos2 + 4cos) = 16(1 – cos2)
1 3 3 + 12cos2 + 12cos = 16 – 16cos2
Sovling n= ,m= 28cos2 + 12cos – 13 = 0
5 5
cos = 1/2, –0.92
AITS/JEE-Main/PT-001
Q.8 (3) h 1
ut at 2
A1 3 A2 5 A1 A 2 5 3 2
2 2 1 2 h
gt ut 0
A1 A 2 A1 A 2 2 A1 A 2 cos 2 3
1 h
5 9 25 2 3 5cos u u 2 4. g
t 2 3
9 3 g
cos =
2 3 5 10
4
(2A1 3A 2 ).(3A1 2A 2 ) 2
t1 3 3 2
6 | A1 |2 9A1 .A 2 4A1A 2 6 | A 2 |2 t2 4 3 2
2
3
3
= 54 + 5 × 3 × 5 – 6 × 25
10 Q.13 (4)
45 V, = 2 km/h
= 54 – 150 – = – 118.5 Vmt = 4 km/h
2
4 cos
Q.9 (4) 4 sin
40 60 For swimmer to cross the river straight
A 6l B l C 1
4 sin = 2 sin = = 30º
2
7l So, angle with direction of river flow = 90º + = 120º
<v> = = 42
6l l Option (4)
40 60
Q.14 (2)
Relative velocity = 144 km/h
Q.10 (2)
= 40 m/s
H 1 Length = 40 m/s × 8 s
L= = g sin × t2 = 320 m
sin 2
Q.15 (1)
Q.11 (2)
v = constant slope of x – t graph = constant. ] r Sx î S y ĵ
40 = Sx = V cos × t
Q.12 (3)
Using v2 = u2 + 2as 1 2
0 = u2 – 2gh 50 = Sy = V sin t – gt
2
u= 2gh t = 2 given
1 2
at
7
Now using, s = ut +
2 = tan–1
4
v=0
Q.16 (2)
5 3
10
h
60°
h 5
u 30°
3
a t
a=g=10
AITS/JEE-Main/PT-001
at t = 1 Q.20 (2)
ux = 5, uy = 5 3 dv dv
a= = k – bv = dt
vy = 5 3 – 10 ; vx = 5 dt k bv
tan = – (2 – 3 ) = – 30° –bn (k – bv) = t + c
t = 0, v = 0 c = –blnk
v2 102 10 20
2
a 10 cos 30
m
k bv
R= = t k
n = – v = 1 et / b
3 3
k b b
2
5 10 5 3
2
200 100 3
= 2.8 m
10 cos 10 0.965 SECTION - B
INTEGERTYPEQUESTION
Q.17 (2) Q.1 [3]
2 2sin15º 2.43 + 4.1 + 4.1 + 2.43
t=
g cos 30º ~ 13.1 3 significant digits.
1 Q.2 [ 4.86]
S = 2 cos 15º × t – g sin30ºt2
2 LC = 0.01 mm
Put values and solve five error = 40 × 0.01 mm = 0.4 mm
S = 20 cm Reading = 5 + 26 × 0.01 – 0.4 = 4.86 mm]
5m/s A = Se A
[A] = [S] = L
4m/s [LT 2 ] [t x ]
= L° x=2
L
10m/s
Q.4 [8]
20 2
t= = 2s a 2î 3ˆj
10
1 b̂ î ˆj
4 22 = 18 m
y0 = 5 × 2 +
2
a b î 4ˆj
Q.19 (2)
dy
a .b .c 8
For ymax = – 2x = 0
dx Q.5 [8 ]
vA 24 m/s
x=
2
x 180 m
2
vB = 21 m/s
ymax = Hmax = –
2 2 1 2
x = 24t – at
2
2 2
2
= – = 4
2 4
1 2
180 – x = 25t – at
2u sin cos 2
2
= 2x = R = =
g
1
u sin
2 2 2 180 = 45t – (a + a )t2
H= = 2 1 2
4 2g 0 = 24 – at
tan = 0 = 21 – at
q = tan–1 () 0 = 45 – (a1 + a2) t
AITS/JEE-Main/PT-001
Q.6 [12] Q.10 [4]
kt
P log e
x
kt
The dimensions of is M 0 L0 T 0
x
Q.3 (2)
1 1
1100m
= RH CZ2 2 – 2
total distance moved by car n1 n2
For first line of Balmer series
72 1000
= ( + 1100) = 60 n1 = 2 ; n2 = 3 & Z = 1
3600
1 1
+ 1100 = 1200 0 = RHC –
= 100 m 4 9
5
Q.8 [5] 0 = R C ……….. (1)
36 H
+
vy For He atom Z = 2
tan 37° = 5
24 = 4 × R C or = 4 0
36 H
3 vy
Q.4 (2)
4 24 According to Aufbau principle atomic orbitals are
filled in order of increasing energies.
32 37° Q.5 (1)
vy
53° n = 1, = 1, m = 1, s = + ½ is not possible Because for
n=1 =0
24
vy = 18 Q.6 (2)
v y + u y + ay y h
– 18 = 32 – 10 t = mV
10 t = 50 P
t = 5 sec Vc 3 108
Vp = = = 3 × 106
Q.9 [7] 100 100
M = 1.67 × 10–27 kg
1
M(u) 2 6.62 10 34
KE pop 2 4 =
= 1 2 =
1.67 10 27 3 10 6
KE top M(u cos30) 3 = 1.33 × 10–13 m
2
= 1.33 × 10-–3 Å
AITS/JEE-Main/PT-001
Q.7 (1) Q.12 (2)
Shortest wavelength of H-atom
n1 = 1 n2 = Z=1 9.81
= 0.15
moles of Zn =
65.39
1 1 1 hc
= RH × 1 × E =
1 1.8 10 23
moles of Cr = = 0.3
1 1 6.023 10 23
= RH = x
, RH moles of O = 0.6
so whole molar ratio
1 1 1 = 0.15 : 0.3 : 0.6 = 1 : 2 : 4
longest wavelength = RH × 2 2 ×
4 9 Hence, formula = ZnCr2O4
1 5 1 5 9x
= RH × 4 × = == Q.13 (2)
36 x 9 5 PCl3 + 3H2O H3PO3 + 3HCl
0.5 0.6
Q.8 (1) Limiting reagent = H2O
Mass of H2SO4
112
× 12.5 ; n H3PO3 (exp ected) 0.2
100
12.3
Moles of H2SO4
112 12.5
n H3PO3 (actual) 0.15
100 98 82
112 12.5 0.15
Moles of H+ 2 ; % yield = 100 = 75 %
100 98 0.2
112 12.5 2 2 Q.14 (3)
[H+] =
100 98 100 100 AB C
A + 2B + 3C 2 3
Q.10 (2)
0.036
(I) 0.5 mole of O3 mass = 0.5 × 48 = 24 gm 0.036 mole of C will form
(II) 0.5 gm molecule of N2 mass = 0.5 × 28 = 14 gm 3
(III) 3.011 × 1023 molecules of O2 mass = 0.5 × 32 = = 0.012 mol of AB2C3.
16 gm
Weight
(IV) 11.35 L of CO2 at STP mass = 0.5 × 44 = 22 gm Mole of AB2C3 = Molecular weight
Q.11 (4)
4.8
22.2 0.012
grams of H2O = × 126 Molecular weight of AB2 C3
77.8
So, molecular wt. of AB2C3 = 400
= 35.95
Atomic mass of A + 2 × Atomic mass of B + 3 Atomic
35.95 mass of C = 400
no. of molecules of H2O = 2
18 ~ 60 + 2B + 3 × 80 = 400
Hence, hydrate is Na2SO3 . 2H2O Atomic mass of B = 50 amu
AITS/JEE-Main/PT-001
Q.15 (3) Q.19 (1)
N2(g) + 3H2(g) 2NH3(g)
(1) 0.5 mol 2 mol
(LR)
(2) 1 mol 3 mol (completion)
(3) 2 mol 5 mol
(LR) (balanced skelton) 2CrCl3 + 3H2O2 2Na2CrO4 +
(4) 1.25 mol 4 mol 6H2O
(LR)
+ 6NaCl (Chloride balance)
Q.16 (3) + 10NaOH
6 1 1 –2 6 2 1 1 1 (Sodium balance)
(a) XeF6 H 2 O
XeOF4 2HF
No change in oxidation numbers, hence, no redox + 2H2O (Oxygen balance)
reaction occurs.
6 1 1 –2 6 2 1 1 1
______________________________________________________________________
(b) XeF6 2H2O
XeO2 F2 4HF 2CrCl3 + 3H2O2 + 10NaOH 2Na2CrO4 + 6NaCl +
8H2O
No change in oxidation numbers, hence, no redox
a=2 b=3 and c = 10]
reaction occurs.
Decrease in O. No. Q.20 (1)
(Reduction)
MnO4¯ + Fe2+ Mn2+ + Fe3+
0 n-factor n-factor =1
+4–1 +1–1 +6–1
number of equivalents of MnO 4 ¯ = number of
(c) XeF 4 + O 2 F2 XeF 6+ O 2 + equivalents of Fe2+
(Oxidation)
0.01 × V × 5 = 60 × 0.1 × 1
Increase in O. No.
6
Hence, it is a redox reaction. V= 120 ml
+2 –1 +5 –1
0.05
+2 –1 +5 –1
(d) XeF + PF [XeF] + PF –
2 5 6
Q.8 [41.56]
Out of 6 electron in 2p & 3p must have one electron Meq. of CaCO3 = Meq. of MgSO4
1 w 5
with m = –1 and s = but in 3d subshell an orbital
100 / 2
× 10–3 =
120 / 2
× 10–3 w = 4.156 g
2
4.156
1 ppm of CaCO3 =
having m = –1 may have spin quantum no.
× 106 = 41.56
or 100 103
2
1 Q.9 [5]
The balanced eq’s is –
2
5C2O42– + 16H+ + 2MnO4–
therefore maximum possible value is = 3 10CO2 + 8H2O + 2Mn2+
therefore minimum possible value is = 2 ] Nows 2 moles of MnO4 requires C2O4–2 = 5 mol
–
Q.5 [169] 5
1 mol of MnO4– mol.
2
10
moles of H2SO4 = = 0.102 ;
98 Q.10 [3]
2N3– (N2)° + 6e–
40 2 mole of NH3 = 1 mole N2
moles of SO3 = = 0.5
80 Thus equivalents
2×n=1×6
0.102
mole fraction of H2SO4 = = 0.169 M 17
0.602 n = 6/2 = 3 Eq.wt. = =
3 3
= 169 × 10–3
AITS/JEE-Main/PT-001
Q.3 (2) Q.7 (3)
(x3 – 1) – k (x – 1) = 0 540 = 1 + (n – 1)d
(x – 1) [x2 + x + 1 – k] = 0 (n – 1)d = 539 = 72 × 11
x = 1 or x2 + x + (1 – k) = 0 For the minimum sum, n – 1 = 7 and d = 77
For exactly two distinct real solutions, Required number of terms = 8
either D = 0 1 – 4 (1 – k) = 0 1 – 4 + 4k = 0
3 Q.8 (1)
k= Let A.P. be a 1, a 2, a 3 …… a 100 with common
4 differentiation d
1 (one root)
or x2 + x + (1 – k) = 0 100
–2 (other root) (a + a ) = –1
3 – k = 0 k = 3.
2 1 100
3 15 1
Hence sum of possible values of k = 3 + = . a1 + a`100 =
4 4 50
a2 + a4 + a6 + …… a100 = 1
Q.4 (3)
sin4x – 2cos2x + a2 = 0 50
sin4x + 2sin2x + a2 – 2 = 0 (a + a ) = 1
2 2 100
Put sin2x = y, y [0, 1]
y2 + 2y + a2 – 2 = 0 ....(1) 1
for solution, D0 a1 + a100 + d =
4 – 4 (a2 – 2) 0
25
1 – a2 + 2 0 a2 3 1 1 3
Solution of equation (1), +d= d=
50 25 50
2 4 4(a 2 2)
y= = – 1 ± 3 a2 1
2 a1 + a100 =
50
But, 0 y 1 0 – 1 ± 3 a2 1
1
1 ± 3 a 2 2 1 3 – a2 4 a1 + a1 + 99d =
50
– 2 – a2 +1 – 1 a2 2
a 2
2
1 3 149
2a1 = – 99 × a1 =
a [ 2, 2] 50 50 50
Number of integral values = 3. 50th term = a50 = a1 + 49d
149 147 1
Q.5 (4)
= =
q r 50 50 25
+ = p ; = p
Q.9 (1)
Also, 2q = p + r
2, 6, 2(k – 1) are in G.P.
2q r k = 10.
p =1+ p now x2 – x – 6 > 0
– 2 ( + ) = 1 + = 1 + 99 = 100 (x – 3)(x + 2) > 0 ....(1)
( + ) = – 50. and | x | < 100
– 100 < x < 100 ....(2)
Q.6 (3)
19
S19 = [2a1 + 18d1] = 171
2
a1 + 9d1 = 9 .....(1)
Let 2nd A.P. be a2, a2 + d2 , a2 + 2d2, ........... from (1) and (2)
x (– 100, – 2) (3, 100)
a1
Given a2 = and d2 = d1 number of integers
9 – 99 to – 3 and 4 to 99
Put in equation (1), we get i.e. 97 + 96 = 193
9a2 + 9d2 = 9 a2 + d 2 = 1
AITS/JEE-Main/PT-001
Q.10 (2) Q.13 (2)
x2 – p |x – 1| – 2x + 2p2 – 7 = 0 x2 – 3ax + 2a2 – 1 = 0 (a > 0)
(x – 1)2 – p |x – 1| + 2p2 – 8 = 0 2a2 – 1 = 7 D0
|x – 1| = t, t2 – pt + 2p2 – 8 = 0 a = ±2 9a2 – 4 (2a2 – 1) 0
For exactly three distinct real solutions, one of the a – 2 (a > 0) a2 + 4 0
values of t should be zero and other should be positive a = 2.
2p2 – 8 = 0 p = ±2
For p = –2, t (t + 2) = 0 t = 0, t = –2 (rejected) Q.14 (3)
p = 2 is only the solution 2
a x1 + bx1 + c = 0 x1 (ax1 + b) = – c
Q.11 (1)
c ly c
ax1 + b = ; ||| ax2 + b =
S (n) =
n
2a (n 1) d x1 x2
2
x1 x 2 b a
S (2n) =
2n
2a (2n 1) d Sum of roots = – c
x1 x 2
=–c = b
a c
2
S (3n) =
3n
2a (3n 1) d Product of roots =
c2
=
c2 · a
= ac
2 x1 x 2 c
S (2n) – S (n)
Equation is x2 – bx + ac = 0.
=
2n
2a (2n 1) d n 2a (n 1) d Q.15 (2)
2 2
The above series in an infinite G.P., whose first term =
=
n
4a 2(2n 1) d 2a (n 1) d 1
and common ratio =
(1 x )
2 1 x (1 x )
=
n
2a d (4n 2 n 1) 1
2
S = 1 x =
1
=
1 3n
2a (3n 1) d = 1 S (3n) 1 x
1
2
2 2 3 1 x
S (3n )
= 3.
S ( 2n ) S ( n ) Q.16 (2)
x
=5
Q.12 (2) 1 r
D>0
x = 5 – 5r
64 – 4 (k – 2) (k + 4) > 0
5r = 5 – x
16 – (k2 + 2k – 8) > 0
k2 + 2k – 24 < 0 5 x
(k + 6) (k – 4) < 0 r= | R | < 1 for G.P.
5
k (– 6, 4) …….(1)
8 5 x
–1< <1
sum of root =
2 (2 k ) < 0 5
2–k<0 5 x
product of root > 0 > – 1 or 5–x<5
5
k4 5 – x > – 5 or –x<0
>0 – x + 10 > 0 or x>0
k2 x < 10
k (– , – 4) (2, ) 0 < x < 10.
(1) (2) (3)
k (2, 4).
AITS/JEE-Main/PT-001
Q.17 (2) Q.20 (2)
a b c A.P. : 1, 1 + d, 1 + 2d, .............
, , G.P. : 2, 2r, 2r2, ..........
a1 b1 c1 in A.P
d
b a c b r= (given)
So, = = d (say) 2
b1 a1 c1 b1 E = a4b1 + a3b2 + 2a1 b3
Since both equation have common root E = (1 + 3d)2 + (1 + 2d) 2r + 2(1) (2r2)
2 1 d2
E = 2(1 + 3d) + (1 + 2d)d + 2(1) 2 ·
4
= =
2bc1 2b1c ca1 ac1 2ab1 2ba1
2bc1 2b1c ca1 ac1 E = 3d2 + 7d + 2
ca1 ac1 =
2ab1 2ba1 4 (bc1 – b1c) 2
7 25
(ab1 – a1b) = (ca1 – ac1 )2 E = 3 d –
6 12
b c a b
4 b 1 c1 · a b = a 2 c 2 25
b1 c1 1 1 a1 b1 1 1
Emin = Ans.
12
2
c a SECTION-B
INTEGERTYPEQUESTIONS
c1 a1 Q.1 [0002]
4 b12 · (– d) (– d) = a1c1 (2d)2 Sn1 3n 1 n / 2[2a1 (n – 1)d1 ]
b12 = a1 c1
a1, b1 and c1 in G.P. Sn 2 2n – 10 n / 2[2a 2 (n – 1)d 2 ]
a b 5 a 2 1 a1 10d1 3 21 1 64
or So 2 :1
b a 2 b 1 2 a 2 10d 2 2 21 – 10 32
a : b = 4 : 1 or 1: 4 So k = 2.
Q.19 (3)
Q.2 [0004]
1 = b1 + b2 = b1 + b1r = b1 (1 + r)
Let t = log3(x – 1)
1 1 1
b1 =
1 r
, so bk = =
(1 r ) (1 r ) 1 r
1
Hence, t = 2 + 2 – 2t 3t =
2t 2 1
k 1
t t2
1 1 2 3t3 – 2t2 – 1 = 0 (t – 1) (3t2 + t + 1) = 0
1 – r2 = r2 = r=± . Hence, t = 1 log3(x – 1) = 1 x = 4.
2 2 2
If b1 < 0, then the sum would be negative, so
Q.3 [0039]
b1 > 0 r = 0 3, A1, A2 .... Am, 243
As 243 = 3 + (m + 1)d
1 1 2
b1 = = = =2+ 2 . 240
1 r 2 2 2 d = (m 1)
1
2 Also 3, G1, G2, G3 , 243
AITS/JEE-Main/PT-001
Q.7 [0055]
As G 22 = 243 × 3
Let term be 25, 25 + d, 25 + 2d
G2 = 243 3 27 25, 5 + d, 21 + 2d G.P.
(5 + d)2 = 25(21 + 2d)
960 d2 – 40d – 500 = 0 (d – 50) (d + 10) = 0
Now, A4 = 3 + 4d = 3 + (m 1)
d = 50 or d = –10
As A5 = G2 maximum value of second term of G.P. = 5 + 50 = 55
Q.5 [0002] 1 18 8 9
So, a7g19 = 2 6 (2 r ) = ·2 · = 12
b c 9 3 4
–3=– and –3 =
a a 1
Now a19 g28 = 2 18 (2 r27) = 27
c b 9
and +5=– and 5 =
a a Hence, (a7 a19 + a19 g28) = 12 + 27 = 39.
– 3 + 5 = 0
+ 5 = 3 ...(i)
and –3 + + 5 = 0 Q.10 [0002]
–3 + = –5 ...(ii)
1
from (i) × 3 + (ii) x = log 5 = – 2log52
1 7 2
16 = 4 = = 2 log5 2
4 4 k2 = 5 =4k=2
= 2
Q.6 [0032]
a + ar + ar2 + ar3 + ar4 = 40 and
1 1 1 1 1
2 3 4 = 10
a ar ar ar ar
1
(ar4 + ar3 + ar2 + ar + a) = 10
a 2r 4
(ar2)2 = 4 ar2 = ± 2.
| s | = | (ar2)5 | = 32.
AITS/JEE-Main/PT-001