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Paper - 06
ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (3) 31. (2) 61. (4)
2. (2) 32. (2) 62. (2)
3. (3) 33. (1) 63. (3)
4. (2) 34. (1) 64. (4)
5. (4) 35. (4) 65. (2)
6. (4) 36. (2) 66. (1)
7. (3) 37. (4) 67. (3)
8. (1) 38. (2) 68. (3)
9. (2) 39. (3) 69. (2)
10. (3) 40. (4) 70. (4)
11. (1) 41. (1) 71. (1)
12. (1) 42. (1) 72. (1)
13. (2) 43. (2) 73. (2)
14. (3) 44. (3) 74. (4)
15. (4) 45. (4) 75. (4)
16. (1) 46. (2) 76. (2)
17. (3) 47. (3) 77. (3)
18. (4) 48. (4) 78. (3)
19. (2) 49. (1) 79. (4)
20. (2) 50. (3) 80. (1)
21. (8) 51. (5) 81. (8)
22. (5) 52. (8) 82. (2)
23. (8) 53. (2) 83. (3)
24. (6) 54. (5) 84. (3)
25. (2) 55. (1) 85. (2)
26. (4) 56. (5) 86. (12)
27. (10) 57. (5) 87. (48)
28. (5) 58. (5) 88. (900)
29. (494) 59. (8) 89. (30)
30. (27) 60. (59) 90. (191)
[1]
SECTION-I (PHYSICS)
1. (3) 1
Wby gas = – 1 40 = –20 J
Two surfaces are formed in the capillary 2
Since force due to surface tension becomes twice
h = 2h 7. (3)
u = us + ui
2. (2) Total energy of the system = u1 + u2 + u12
KE = PE and pi = p f q12 q2
= + 2 + q1V2
80 a 80b
J2 1 2 J2
= kx + q12 q2 q .q
2m 2 2(5 m) = + 2 + 1 2
80 a 80b 40b
2J 2 10
x= =
5 mk 5 11000
8. (1)
2 2 Use KVL
= = m
50 5 Let a charge q flow in circuit in clockwise
direction
3. (3)
As the detector moves from Q along
x-axis, maxima are observed when x = 4, 3,
2,
7
At first minima from Q, x = By loop law,
2
q1 − q q2 − q q3 − q q4 − q
7 + + + =0
x2 + (4)2 − x = C 2C 3C 4C
2
q1 = CV, q2 = 4CV, q3 = 9CV, q4 = 16CV
15
x= 24
28 q= CV
5
q − q 19V
4. (2) V1 = 1 =
R
c 5
1 G
−4r dr q − q 2V
2
Vc = V2 = 2 =
0
r r 2c 5
R
R2 q − q 7V
M= 4 r 2
dr
1
= 4 V3 = 3 =
r 2 3c 5
0
q − q 14V
R V4 = 4 =
1 G 2GM
−(4r dr ) = − 4c 5
2
Vc =
0
r r R
9. (2)
1 dV
5. (4) =
Both voltmeters are parallel. V dT
1 dV
Both the voltmeters A and B are effectively in = , PT2 = Constant
parallel and hence give the same reading every V dT
T 3 = kV
time.
dV 3T 2 dV
3T 2 = k =
6. (4) dT k dT
2
Work done by a gas in a cyclic process is negative 3T 1 dV 3
3k= =
if P-V graph is in anticlockwise sequence. kT V dT T
[2]
10. (3) 3mg sin
x=
dr 2g k
= R
dt r
15. (4)
u= 2 gR
mv
1 2 GMm 1 2 GMm R=
mv – = mu − qB
2 r 2 R
(mv)2
2g Area(A) = R 2 =
v= R (qB)2
r
dr 2g
= R 16. (1)
dt r At equilibrium
4R t mg
x1 =
r dr = R 2 g dt k
R 0
mg
7 2R x2 =
t= 2k
3 g
mg
max. x2 = 2x2 =
k
11. (1)
q = i dt 17. (3)
−
t Use dipole
q = idt = lmax 1 − e dt
dq = 0 sin a d
0 0
| dp | = dq 2a − 2a20 sin d
l
q = max | dp | = 2a20 sin d cos iˆ + sin ˆj
e
d = dp E
12. (1)
x2 = 4y d = 2a20 d sin cos iˆ + sin 2 ˆj
2xvx = 4vy
ˆ ˆ
E0i + E0 j
vx2 + xax = 2a y
d = 2a 0 E0d sin cos − sin kˆ
At (0, 0) 2 2
ax = 0 v = 0
0
vx2
ay = = 2a20 E0 sin cos d − sin 2 d kˆ
2 0 0
sin 2
1 − cos2 ˆ
13. (2) = 2a20 E0 d − d k
Q = nCP T 0 2 0 2
= 2a20 E0 0 − kˆ = a20 E0 kˆ
2
18. (4)
Q = nCP T VyA = VyB
f 10 × sin37° = (V)sin53°
CP = + 1 R
2 3
10 = (V )
4
5 5
14. (3) 15
kx = 3mg sin V = m/s
2
kx = 3mg sin
[3]
19. (2) 2 2
Time period of motion is, T = = =
Power is zero when F.v = 0 10 5
q ˆ T
Now F = (− j ) Then, t =
= =
0 4 20
qt ˆ 20
v = v cos iˆ + v sin − j = =5
m0 4 4
qt q
F .v = v sin − . = 0 23. (8)
m0 0
vm (just before collision) = 2 2gh0
mv sin 0
t=
q vm (just before collision) = 2 2gh0
20. (2) v
Let a = maximum acceleration of A. v3m (just after collision) = m
Under no slip condition acceleration of B is also 5
a g
a3m = (Downward)
FBD of A w.r.t ground 5
H max =
( v3m )
2
4h
= 0 = 8 cm
a3m 5
24. (6)
Bvl
ΣFy = 0 i= ; F = iBl
Req
N N
= mg + Bvl 3 2 2
2 2 i= = =1A
NF N Req 12
Σ x+ = ma
2 2 F = iBl = 1 3 2 = 6 N
Solving these two equations, we get
25. (2)
1+
a = g kq
1− V=
R
kqA kqB
21. (8) + = 2V … (1)
1 R 2R
qv = K.E. and
V kqA kqB 3
+ = V … (2)
h 2R 2R 2
=
2 emV1 qA 1
From equation (1) and (2), =
h qB 2
=
3 2 em(V1 + V2 ) After B is earthed VB = 0
V1 + V2 qB = – qA
3= After earthing
V1
1 1 kqA
VA – VB = kqA − =
R 2R 2R
V1 1
=
V2 8
Putting qB = 2qA in equation (1)
kqA V V
22. (5) = ,VA − VB =
= 10 rad/s 2R 2 2
From Eqn. a = – 100x = –2x V
VB = 0 VA =
= 10 2
[4]
26. (4) 28. (5)
Li = L f (About point on horizontal surface) a
tan =
g
mR2 3
0 = 2 mR2
2 2
0
=
6
R0 mR0
Vcm = J =
6 6
(2)(1)12 a 2 1
J= = 4 kg m/s tan = = =
6 g 10 5
= tan−1 = tan−1
1 1
27. (10) 5 x
For solenoid B = 0 nI i.e. x = 5
1
Resistance R0 = (2r ) 400 29. (494)
100 Energy of incident photons
400 = 13.6 Z2
n = (no. of turns per unit length) = 100
20 = 13.6 × 22
n = 2000 = 54.4 eV
Max K.E. of photoelectrons
0 2000 E0 100 = 54.4 – 5
B=
2r 400 = 49.4 eV
1 1 400 Stopping potential = 49.4 volt
E0 = 2 −
10 100 410 2000 100
7
30. (27)
E0 = 10 volts
1 1 1
= RZ 2 2 − 2
n
1 n2
SECTION-II (CHEMISTRY)
31. (2) 34. (1)
In compound ‘Y’, 4 g of A will combine with P − P n1 1 w / 180
7 = = w = 50.5gm
12 = 28 g of B, and hence, 8 g of A will P n2 99 500 / 18
3
combine with 2 × 28 = 56 g of B.
35. (1)
32. (2)
1
z
Vn,z = 2.188 106 m / s Hg2Cl2 ( s ) + e− → Hg ( l ) + Cl− ( aq )
n 2
z
Or, 1094 × 103 = 2.188 × 106 z = 2
4 36. (2)
+
He ion 4C3H6 + 6NO→ 4C3H3N + 6H2O + N2
420
33. (1) nC3H6 = = 10 moles
For minimum work in compression, the 42
process must be reversible. 4 moles C3H6 = 4moles C3H3N
P 16 1.01325 103 10 moles C3H6 = 10 moles C3H6N
w = −nRT.ln 1 = − 8.3 300 ln
P2 32 1.01325 105 = 10 × 53 = 530 kg.
= + 2727 J
[5]
37. (4) 45. (4)
n eq H2O2 = n eq KMnO4 Molecule having almost negligible tendency to
form hydrogen bonds is HI as hydrogen bonding
x
1 depends on two factors:
or 100 2 = x N N = 0.588
34 1000 (i) Higher electronegativity of X in HX
(ii) Small size of X
Electronegativity of I is low and its size is also
38. (2)
large. Therefore, both the factors fail here. Hence,
Apply Fajans' rule.
no hydrogen bonding is present in HII.
Covalent character:
4+ 3+ 2+
C Cl4 BCl3 BeCl2 LiCl 46. (2)
Both are enantiomers.
39. (3)
In N2, there is one unpaired electron in bonding 47. (3)
MO (i.e., s 2p1z )
40. (4)
Lesser is the positive charge, higher is the radius.
Moreover the size increases down the group. 48. (4)
Therefore, Maltose is composed of two units of a-D glucose
Na Li Mg2+ Be2+ which are joined through C1 – C4 glycosidic
Na+= 102 pm linkage.
Li+ = 76 pm
Mg2+ = 72 pm
Be2+ = 31pm
41. (1)
E2 reaction
49. (1)
42. (1)
44. (3)
51. (5)
160 2 n
= n = 10 Oxidation state of Br
96 2 + n
in unknown product = 5
[6]
52. (8)
63
Heat released by mole haemoglobin
64000
= 25 4.2 0.03 = 3.15 J
Heat released per mole haemoglobin
3 15 64000
= = 32000 J It has sp3 d2 hybridization with octahedral
63 geometry according to CFT, e–distribution is as
Heat released per mole follow:
32000
O2 = = 8000 J
4
53. (2)
ΔTf = Kf m
Hg(CN)2 + mCN− Hg(CN)m−
m+2
0.1 mole 0.2 mole 0 57. (5)
Final 0 (0.2−0.1 m) mole 0.1 mole (i), (ii), (iii), (iv) and (v)
For KCN solution: 0.80 = Kf × 0.2 × 2
Final effective molality = (0.2−0.1 m) + 0.1 + 0.2
= 0.5−0.1 m
Now, 0.60 = Kf × (0.5−0.1 m)
58. (5)
From (1) and (2): m =2
54. (5)
59. (8)
• • •
55. (1) H3C − CH = CH − CH = CH − CH = CH − Ph
Carbon 1 is anomeric carbon. Total stereoisomer =23 = 8
60. (59)
56. (5) K = Ae–Ea/RT
2+
0 +1 2K1 Ea 1 1
Fe H2O NO ln
5 K1 R 300 309
0.3 8.3 2.3 300 309
Fe+1 = 3d6 4s1 Ea 59 kJ mol–1
9
Since (NO) is strong ligand, so one pairing
occurs.
[7]
SECTION-III (MATHEMATICS)
4 − 10 − a 0 dx
−25
25 + 4a 0 a , −6 tx = 3x2e x dx
3
4
5
2 −x 3
2 = ex + c
y
64. (4) Alternate solution
r ( r + 1)( 2r + 1) 4 2 ( 2r + 1) 2 1
ydx − xdy x3
y2
+ e d x3 = 0 ( )
1
tr = = = +
6r 2 ( r + 1)
2 3r ( r + 1) 3 r r + 1 x x3
+e =c
y
( −1)r +
2 n 1 1
Sn =
3 r =1
r r +1
67. (3)
x −1 1
2 1 1 1 1 1 I = dx
S = −1 + − + ... + − + − + ... x + 1 x2
3 2 3 2 3 4 1 dx
2 Put = cos2 − 2 = −2sin 2d
= −1 x x
3
1 − cos 2
I = 2sin d
1 + cos 2
[8]
= 4sin2 d = 2 (1 − cos2) d 71. (1)
x3 + 1 x2 y x2 z x3 x2 y x2 z
1 1
= 2 − sin 2 + C = cos−1 − 1 − 2 + C xy 2 y3 + 1 y 2 z = xy 2 y3 + 1 y2 z
x x
xz 2 yz 2 z3 + 1 xz 2 yz 2 z3 + 1
68. (3)
lim tan x
x→
2
( 2sin x + 3sin x + 4 − sin x + 6sin x + 2
2 2
) 1
+ 0 y3 + 1
x2 y x2 z
y2 z
2
(
2sin 2 x + 3sin x + 4 − sin 2 x + 6sin x + 2
= lim tan x 2 ) 0 yz 2 z3 + 1
x→
2sin 2
x + 3sin x + 4 + sin 2
x + 6sin x + 2
2 x2 x2 y x2 z
= lim
1 (
sin 2 x − 3sin x + 2 ) = x y2 y3 + 1 ( )( )
y 2 z + y3 + 1 z 3 + 1 − y3 z 3
x→
cos2 x 2 + 3 + 4 + 1 + 6 + 2 z 2
yz 2
z +1
3
2
+ +
2 2 2
+ +
3 3 3
4 + 4 + 4 73. (2)
2 f (x) = sgn (x – x4 + x7 – x8 – 1)
1 1 1
For x (0, 1); x – 1 < 0, x7 – x4 < 0
= ( − ) ( − ) ( − )
2 2 2
=
x – x4 + x7 – x8 – 1 < 0
2 2 2 For x (1, ); x < x4, x7 < x8
x – x4 + x7 – x8 – 1 < 0]
70. (4) Also for x = 1; x – x4 + x7 – x8 – 1 = –1
Total n-digit numbers using 1, 2 or 3 = 3n Thus x – x4 + x7 – x8 – 1 < 0 for all x R+
total n-digit numbers using any two digits out of Hence sgn (x – x4 + x7 – x8 – 1) = –1 x R+
1, 2 or 3 = 3C2 × 2n – 6 = 3 × 2n – 6 Therefore f (x) is many-one and into
total n-digit numbers using only one digit of 1, 2
or 3 = 3 74. (4)
the numbers containing all three of the digits
(1 − sin x ) (8x3 − 3 ) cos x
1, 2 and 3 at least once = 3n – (3 × 2n – 6) – 3 lim
= 3 n – 3 2n + 3 x→
2
( − 2 x )4
[9]
( 2
)
1 − cos 2 − x ( 2 x − ) 4 x + + 2x sin 2 − x
2
(
Position vector of N −c + 2b )
= lim
x→
2
16 − x
4
equation of line BC is r = b + b − c ( )
2
equation of line AB is r = 0 + b
(1 − cos h )( −2h ) sin h lim
= lim
h→0 16h4 x→
( 4x 2
+ + 2x
2
) equation of line MN is r =
c 4c
+ t − 2b
2 3 3
(1 − cos h )( −2h ) sin h lim
= lim
h→0 16h 4
x→
( 4x 2
+ 2 + 2x ) 1 4
= −2t , 0 = + t
3 3
2
1
(1 − cos h ) 4 2 + 2 + 2 Which gives =
= lim 2
h→0 8h2 2 2
b
Position vector of X is .
h 2
2sin 2
( )
= − 3 lim
2
h→0 h 2
2
32 78. (3)
4
32
=−
16
75. (4)
f ( x ) = 2 1 − x , x 0
2
0, x0
x y z
Clearly, f (x) is discontinuous, hence non- = = …..(i)
differentiable at x = 0. 2 3 5
x y z
= = ….(ii)
76. (2) 1 2 3
3
cos ( A − B ) = & tan A tan B = 2 2iˆ + 3 ˆj + 5kˆ iˆ + 2 ˆj + 3kˆ
5 aˆ + bˆ = +
38 14
3
cos A cos B + sin Asin B = (A) and (B) will be incorrect
5
Let the dr's of line ⊥ to (1) and (2) be a, b, c
3
(1 + tanA tanB) cos A cos B = 2a + 3b + 5c = 0 ….(iii) and
5
a + 2b + 3c = 0 …..(iv)
3
(1 + 2) cos A cos B = a b c
5 = =
1 9 − 10 5 − 6 4 − 3
cos A cos B = a b c
5 = =
3 1 2 −1 −1 1
sin Asin B = − =
5 5 5 a b c
= =
1 2 −1 1 1 −1
cos(A + B) = cosA cosB – sinA sinB = − =
5 5 5 equation of line passing through (0, 0, 0) and
is ⊥r to the lines (1) and (2) is
77. (3) x y z
Let position vector of A be origin = =
1 1 −1
c
Position vector of M
3
[10]
79. (4) 82. (2)
1 − cos x dx x2 x
I = dx + − +1 = 0
cos − cos x dy y 2 y
0<α<x<π
Put x = vy
x
2 sin dx dx dv
= 2 =v+ y
dy dy
x
2cos2 − 1 − 2cos2 + 1 dv 2
2 2 v+ y + v − v +1 = 0
x dy
sin dx
=
2
x
−y
dv
dy
(
= 1 + v2 )
cos2 − cos2
2 2 dv dy
x 1 x =−
Put cos = t − sin dx = dt v +1
2 y
2 2 2 Integrating
x tan–1 v + c = –ln y
cos
−2dt
I = = −2sin −1 2 +C
x
cos tan −1 + ln y + c = 0
cos2 − t 2 y
2 2
Where c is arbitrary constant
80. (1)
The equation of required hyperbola is 83. (3)
2
2x − y + 4 x + 2 y − 3
2 Let b = iˆ + ˆj + kˆ, a b = ˆj − kˆ
iˆ ˆj kˆ
5 − 5
=1
2
2
1
2 1 1 1 = ˆj − kˆ
2 3
x2 − 4xy − 2 y2 + 10x + 4 y = 0 β – γ = 0, α – γ = 1, α – β = 1
Since centre of hyperbola is intersection of axis β = γ, α = 1 + γ, α = 1 + β, a b = 1
C (–1, 2) and foci lies on T.A. at a distance ae α + β + γ = 1, β + 1 + β + β = 1
from centre β=0
focus ((–1 ae cos θ), (2 ae sin θ)) α = 1, γ = 0,
transverse axis slope = −
1 b = iˆ
2
−2 1
We get cos = ,sin = 84. (3)
5 5 Eliminating n we have (l2 + m2) – (l + m)2 = 0
2 1 2lm = 0
−1 ,2
6 6 When l = 0 then m + n = 0
l m m
= = …(1)
81. (8) 0 1 −1
Solving given curves When m = 0 then l + n = 0
x2 + 2 = 2 |x| – cosπ x l m n
= = …..(2)
x2 – 2 |x| + 2 = – cos π x 1 0 −1
(|x| – 1)2 + 1 = – cos π x D.R.'s are 0, 1, –1 and 1, 0, –1
x=1 0.1 + 1.0 + 1 1
Required Area = cos = =
1+1 1+1 2
(x )
1
2
+ 2 − 2 x + cos x dx =
8
3 =
−1 3
[11]
85. (2)
Equation of AU is
0 − y1
y − y1 = ( x − x1 )
3 − x1 α + β + x2 = –7, αβ + βx2 + αx2 = p ….(2)
3 y1 αβ + βx1 + αx1 = p
So that the coordinates of C are 0,
(3 − x1 )
+ x2 + x2 = p
( x1 − x2 ) + ( x1 − x2 ) = 0
6 y1
Similarly, the coordinates of D are 0, (x1 – x2) (α – β) = 0 [x1 x2]
( 6 − x1 )
α+β=0
x y ( 6 − x1 )
Now, equation of AD is + = 1 …(i) x1 = –5
3 6 y1
x2 = –7
and equation of OU is y1x = x1y …(ii)
87. (48)
2x − 1
f ( x ) = − log x+4 log 2
3 + x
2
2x − 1
For domain : log x+ 4 log 2 0
Solving (i) and (ii), we get 3 + x
2
x1 y y ( 6 − x1 )
+ =1 x+4
3 y1 6 y1 Case I 0 1
2
y (2x1 + 6 – x1) = 6y1 –4 < x < –2 ……A
6 y1 6 x1
y= x= 2x − 1
6 + x1 6 + x1 then log x+ 4 log 2 0
3 + x
2
6 x1 6 y1
Hence, the coordinates of V are , 2x − 1
6 + x1 6 + x1 log 2 1
3+ x
Therefore, equation of CV is
2x − 1
6 y1
−
3 y1 2
3 y1 6 + x1 3 − x1 3+ x
y− = ( x − 0) x < –3 …..B
3 − x1 6 x1
−0
6 + x1 on A B x (–4, –3) …..(i)
3 y1 9 x1 y1 Case-II
y= − x
3 − x1 6 x1 ( 3 − x1 ) x+4
1 or x > –2 …..A
2
3 y1 x
y= 1−
3 − x1 2
log x+4 log 2
2x − 1
0
3 + x
Which passes through the point (2, 0) for all 2
values of (x1, y1) 2x −1
0 log2 1
3+ x
86. (12) 2x − 1
1 2
3+ x
x (4, ) ….(ii)
(i) (ii)
α + β + x1 = –5, αβ + β x1 + α x1 = p
…..(1) Domain x (–4, –3) (4, )
[12]
88. (900) 1
= t dt
a1 + a5 + a10 + a15 + a20 + a24 = 225 t
3 (a1 + a24) = 225 2
= t = x x = 24 − 1 = 15
2
(sum of terms equidistant from beginning and
1
end are equal) a1 + a24 = 75
24
Now a1 + a2 + ........ + a23 + a24 = [a1 + a24] 90. (191)
2 Let No. of children of John & Angelina = y
= 12 × 75 = 900
x + (x + 1) + y = 24
89. (30) y = 23 – 2x
2 Number of fights
x x (1 + 2ln x ) dx
2
x F = x(x + 1) + x(23 – 2x) + (x + 1) (23 – 2x)
1 F = – 3x2 + 45x + 23
2 dF
xx = t = 0 – 6x + 45 = 0
dx
x2 lnx = lnt
x = 7.5
2 1 1
x x + ln x 2 x dx = t dt But 'x' will be integral.
check x = 8 or x = 7
1
( x + 2ln x ) dx = dt F = 191
t
PW Web/App - https://smart.link/7wwosivoicgd4
Library- https://smart.link/sdfez8ejd80if
[13]