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Paper - 07
ANSWER KEY
PHYSICS CHEMISTRY MATHEMATICS
1. (4) 31. (2) 61. (1)
2. (2) 32. (2) 62. (2)
3. (3) 33. (3) 63. (2)
4. (2) 34. (1) 64. (1)
5. (2) 35. (1) 65. (1)
6. (3) 36. (2) 66. (4)
7. (1) 37. (2) 67. (3)
8. (2) 38. (4) 68. (4)
9. (2) 39. (3) 69. (3)
10. (3) 40. (4) 70. (1)
11. (2) 41. (2) 71. (2)
12. (2) 42. (4) 72. (1)
13. (2) 43. (2) 73. (1)
14. (2) 44. (2) 74. (4)
15. (3) 45. (4) 75. (2)
16. (3) 46. (3) 76. (3)
17. (3) 47. (3) 77. (3)
18. (1) 48. (1) 78. (2)
19. (2) 49. (2) 79. (2)
20. (4) 50. (2) 80. (2)
21. (12) 51. (366) 81. (15)
22. (3) 52. (3) 82. (330)
23. (18) 53. (2) 83. (0)
24. (7) 54. (6) 84. (18)
25. (2) 55. (9) 85. (87)
26. (3) 56. (4) 86. (1)
27. (17) 57. (3) 87. (6)
28. (5) 58. (1) 88. (5)
29. (4) 59. (6) 89. (5)
30. (8) 60. (4) 90. (1)
[1]
SECTION-I (PHYSICS)
1. (4) ES = 200 V
0 I1 0 I 2 Frequency remains same = 50 Hz
=
2x 2y
I 5. (2)
y = 2 x 1 1 1
I1 For lens − = . And on mirror the incident
v u f
2. (2) ray will be normal to the surface.
Magnetic force should balance the centrifugal
force.
q0 m
dl RB dl 2 R
2R 2R
q0 RB m2 R Using lens formula
1 1 1
q0 B
− =
m v u f
u = −12 cm, f = 10 cm
3. (3) v = 60 cm
d 2 Distance of C from mirror is 50 cm
= –2 for angular SHM
dt 2 R = 50 cm
L L L L f = 25 cm
= k + k
6 6 3 3
6. (3)
2 mL2 d 2
+ mL2 2 = – kL2 +
1 1
3 dt 36 9
F = 0
T
5mL2 d 2 5kL2 (M + m)g = (50 + 25)g = T +
2 = − 2
3 dt 36
T = 500 N
d 2 k
2
= −
dt 12 m 7. (1)
k 2
= Pressure =
12 m 2 0
1 k Considering any point on hemispherical shell
f=
2 12 m 2
Pressure =
2 0
1 k
=
4 3 m Hence force required = P A
2
= R2 (cross-sectional area)
4. (2) 20
ES N S
= 2 R2
=
EP N P 20
ES N S
=
EP N P 8. (2)
ES 5000 dQ dT
= =c
20 500 dt dt
[2]
N = 20 − T sin 37 …(2)
From (1) and (2)
m1 = 2 kg
13. (2)
dQ dT 1 1 1
=c ...(i) − =
dt dt v u f
dQ kA
= T − 0
T Point A(–2f, 2f)
...(ii)
dt t0 2 2 f = 40
From equation (i) and equation (ii) f = 20 cm
= − T − 0
dQ dT kA T
=C
dt dt t0 2 14. (2)
C T t kA g(x, t) = f((x – v(t – t0)), t)
T0
T0
dT = − dt
0 t
T− 0
2 15. (3)
− kA The ray SM after reflection undergoes a phase
T = 0
T t
change of , for maxima at P, path difference
2 1 + e Ct0
between S & S =
9. (2) 2
V0 I0 (S is virtual source producing back PM,
P= cos
2 symmetric to S)
VI Comparing with YDSE, d = 4x, D = 600x
P = 0 0 cos x.d
2 Path difference =
V0 I0 V0 I0 D
= cos x (4 x)
4 2 = x = 75
1 2 600 x
cos =
2
16. (3)
= Power, P = Area under E versus
3
4
P1 T
10. (3) = 4 = 1 T1 = T2 41/4 = T2 2
P2 T2
2
mvmax
Tmax = mg +
l 17. (3)
2
Vmax = 4gl + 2gl = 6gl If mirror rotates then angle rotated by reflected
Tmax = mg + 6mg = 7mg ray is twice of mirror rotation
Total angle rotated by reflected ray
= 20° + 10° = 30° in anticlockwise
11. (2)
Angular fringe width = 3°
18. (1)
3 = Q = U + W
180 d
Heat energy exchange,
T0 T0
12. (2) Q = nc dT = n dT
T0 T0 T
f = s N
= n ln
4
T cos37 = N …(1) Change in internal energy, U = nCv T
7
[3]
R 23. (18)
=n (T0 − T0 )
r −1 If load resistance matches with source resistance,
nRT0 then maximum power transfer happens at load
= ( − 1) resistance.
r −1
If we open the circuit across ‘R’ then
From first law of thermodynamics
nRT0
W = Q – U = n ln – ( − 1)
r −1
For one mole, n = 1
RT
W = ln − 0 ( − 1) VTh = 3 = 12 volts
36
r −1 9
63
19. (2) And r0 = =2
Q = [(7.835 × 231) + (7.07 × 4) – (7.8 × 235)] 9
= 5.165 MeV
20. (4)
For maximum intensity, path difference = n So value of R should be 2 and I = 3 A
Path difference = 3 × 8.5 cm = 25.5 cm F(max) = I2R = 18 watt
26. (3)
T=
a +x
2
+
2
b + (c − x)
2 2
l =
Fi Li
v1 v2 AY
dT
for minimum T, =0
dx
x
a2 + x2 v1 sin 1 6
= = =3
(c − x) v2 sin 2 2
b2 + (c − x)2
[4]
F
Stress in part (1) is and stress in part (2) is
A
2F
A
2FL FL
l = +
AY AY c
3FL Fundamental frequency, f =
= 4l
AY
c
f = l −1
27. (17) 4
df d c −1 c dl
1 1 1 = l = (−1) l −2
= (n − 1) − dt dt 4 4 dt
f R1 R2
c dl −c
2 2 = − 2 = 2 (−v)
(nA − 1) = (nB − 1) 4l dt 4l
RA RB
df cv cv
nB = 1.7 = 2 = 2 where, x = 4
dt 4l xl
28. (5)
mg − NA = macm 30. (8)
mg − NA = macm 1 1 1
+ =
l v u f
acm = For 1st reflection
2
l u1 = −15, f = −10
Also A = I A mg = I
2 v1 = −30 cm
3g mg For 2nd reflection
= NA = =5N
2l 4 u2 = −(40 − 30) = −10 cm
v2 = +10 cm
29. (4)
c For 3rd reflection
Fundamental frequency, F = u3 = −(40 +10) = −50 cm, f = −10 cm
4x
v3 = −12.5 cm
SECTION-II (CHEMISTRY)
31. (2) P P
A ––––→2B +C 1
= ln 3 1
= ln 3
t=0 P0 0 0 t P 3P − P t P 3P P
− − +
t = tP0–x 2x x 3 6 3 6 6
t= 0 2P0 P0 1
ln
2P
From question: P∞ = 2P0 + P0 t 3(P 3P)
P
P0 =
3 32. (2)
and P = (P0–x) + 2x + x q =ΔU-w and from the question, q = | w | = w or
2q = ΔU
P − P0 3P − P
x= = Cv,m
2 6 2⋅n⋅Cm⋅ΔT = n Cv,m ΔT Cm =
2
Now,
1 R
1 P 1 P Or = =R
K = ln A = ln 0 2 1.5 − 1
t PA t P0 − x
[5]
33. (3) 38. (4)
N2O4 2NO2
Equilibrium 1-α 2α
2
2 39. (3)
1+ P
1
2
PNO 42 P Kp 2
Kp = 2
= = , =
p N 2O 4 1 − 1 − 2 Kp + 4P
1+ P
Kp / 4p
=
1 + Kp / 4p
34. (1)
1 1 40. (4)
z 22 2 − 2
n –I power of – F is maximum in
v2 1 n 2 1
=
v1 1 1
z12 2 − 2 41. (2)
n
1 n 2 2 C > Si > Ge > Pb > Sn (correct order of M.P. and
iH1)
1 1
32 2 − 2
= 3 5
v2
42. (4)
2.5 105 42 1 − 1
2
2 32 Ga In Tl (correct order of stablity)
SiF4 > SiCl4 > SiBr4 > Sil4
v2 = 7.2 104 cm−1 (correct order of stablity)
[6]
H2S 2 2
lp-lp 92° 52. (3)
lp-bp Final excited state = 5th orbit
NH3 1 3 Bp-bp 107° As only two wavelengths are longer than
lp-bp absorbed radiation initial excited state = 3rd orbit
bp-bp
BF3 0 3 Bp-bp 120° 53. (2)
SiH4 0 4 bp-bp 109°28° +7 +5
Hence, bond angle H2S < NH3 < SiH4 < BF3 An + + MnO−4 → A O3− + Mn 2+
Number of lost electrons = Number of Gained
47. (3) electrons
Chlorine being the group 17 clement has 5 × 1.5 × 10–3 = 2.5 × 10–3 × (5–n)
maximum electronegativity. 'N' has zero electron
(5–n) = 7.5 = 3
affinity because extra stability is associated with 2.5
exactly half-filled orbitals. Sulphur has more n=2
electron affinity than 'O' because the effect of
small size of O atom is more than offset by the 54. (6)
repulsion of electrons already present in 2p-
orbirlas of O atom. MnO 2− 2−
4 ,Cr2O7 ,CrO4
(They have 3d0 configuration yet they are
48. (1) coloured due to charge transfer theory)
Element X can lose its first two outermost Cu2 (3d9 ),Fe2 (3d6 ),Fe3 (3d5 ), all are
electrons easily. It is most likely bivalent. By
coloured dur to the presence of unpaired
similar reasoning element Y is tetravalent.
electrons.
Therefore, the compound may be X2Y.
Colourless ions are:
49. (2) ( ) ( ) ( )
Sc3+ 3d0 ,Ti4+ 3d0 , Zn 2+ 3d10
The correct order of boiling point
PH3 < AsH3 < NH3 < SbH3
55. (9)
50. (2)
K 1000 2.3 10 6 1000
S o
AgCl (61.9 76.3)
5
1.66 10 M
51. (366)
In first case
Tb = Kb × m 56. (4)
1.22
0.17 1.7 3
x 100 10
x = 122
In 2nd case
1.22
0.13 2.6 3
y 100 10
y = 244
In 2nd case it exist as dimer.
[7]
57. (3) 2.14 12
= 1 + 2 Na2S2O3 required = = 6 10−2 mole
214 2
0.693
= = 1 + 2 10 3
M 60 6 10 2
20
1 4 6 10 2
96 M 1
2 60 10 3
2 = 24 1
0.693
25 1 59. (6)
20
CrO5 have butterfly structure
0.693
1
20 25
60. (4)
1 = 1.386 × 10–3
N=4
58. (1) Metal ion is Hg2+.
Hg2+ + Co2+ + 4SCN– → Co[Hg(SCN)4] deep blue
2KIO3 10KI 12Na 2S2O3 12HCl
12KCl 12NaI 6Na 2S4O6 6H2O
SECTION-III (MATHEMATICS)
61. (1) 63. (2)
(i) Let P be perimeter x2 + y2 – 10x + λ (2x – y) = 0....(i)
P = 2x + 2y ; A = xy x2 + y2 + 2x (λ – 5) – λy = 0
dP dx dy
=2 +2 Centre − ( − 5) ,
dt dt dt 2
dA dx dy
= y + x = −6 + 4 = −2 Using on y = 2x
dt dt dt 5
(ii) Let A be area = −2 ( − 5) = 10
2 2
A = xy
Putting λ = 4
dA dx dy
= y+x x2 + y2 – 2x – 4y = 0
dt dt dt
= – 18 + 20 = 2
64. (1)
62. (2) z −1 + 4
log 1 1
21−r r
3 z − 1 − 2
2
a 3 b 3
Tr +1 =21 Cr z −1 + 4 1
b a 0
21−r r r 21−r 3 z −1 − 2 2
− −
= Cr
21
a 3 6 3
b 3 |z – 1| = t
42−3r 2r −21 t+4 1
=21 Cr a 2 b 3 0
3t − 2 2
14−r 2r −21
t+4 1
= Cr
21
a 2 b 3 0
3t − 2 2
14 − r r − 21
= t > 10 So true
2 3
42 – 3r = 4r – 42
65. (1)
7r = 84
x + 3y − 3
r = 12 ( x − 3) 2 + ( y − 4 ) 2 =
⇒ 13th term 1+ 9
[8]
10 {(x2 + 9 – 6x) + [y2 + 16 – 8y]} = (x + 3y – 71. (2)
3)2 3 2
P ( A) = ; P ( B ) = ; P (C ) = ?
= x2 + 9y2 + 9 + 6xy – 6xy – 6x – 18y 11 7
9x2 + y2 – 6xy – 54x – 62y + 241 = 0 P ( A) + P ( B ) + P ( C ) = 1
34
66. (4) P (C ) =
77
(z – i) (z2 + 2iz – 2) = 0
z = i, 1 – i, –1 – i 72. (1)
1 −1 1 We, know that a + b > c, b + c > a and c + a > b
Area of ABC = = 2 square units.
2 2 2 c – a < b, a – b < c, b – c < a
squaring on both sides and adding (c – a)2 + (a –
b)2 + (b – c)2 < a2 + b2 + c2
67. (3)
a2 + b2 + c2 – 2(ab + bc + ca) < 0
a124 = 111….1 (124 times)
(a + b + c)2 – 4(ab + bc + ca) < 0
= 1 + 10 + 102 + 10123
The remainder when 1, 10, 102, 103, 104 are
( a + b + c )2
4 ….(i)
divided by 271 ab + bc + ca
Are respectively 1, 10, 100, 187, 244 Now roots of equation
These are only possible remainders when x2 + 2(a + b + c) x + 3λ (ab + bc + ca) = 0 are real,
10k (k W) is divided by 271. then D ≥ 0
Required remainder = Remainder of {24 (1 +10 4 (a + b + c)2 – 4 3λ (ab + bc + ca) ≥ 0
+ 100 + 187 + 244) + (1 + 10 + 100 + 187)} = 27
( a + b + c )2 3
ab + bc + ca
68. (4)
So 3
( a + b + c )2 4
Choose any three elements from set A such that
ab + bc + ca
f (x) = y1 by 7C3 ways, and rest 4 elements of
4
set A and 3 elements of set B can arranged by 34 –
3
3(24) + 3 ways. So total number of functions are
7
C3 (34 – 3.24 + 3) = 1260.
69. (3)
4 3 3 4 1 1
+
5 4 4 5 4 4
4 3 3 4 1 1 1 3 1 1 1 3
+ + + 73. (1)
5 4 4 5 4 4 5 4 4 5 4 4
x2
36 + 4 20 − for x 0
= =
36 + 4 + 6 23 Given f ( x ) = 2
n 1
x sin x for x 0
70. (1)
According to the given condition, and f (x) is continuous at x = 0 clearly f (0) = 0
− x2
Now L.H.L. = lim f ( x ) = lim = 0
( 6 − a )2 + ( 6 − b )2 + ( 6 − 8)2 + ( 6 − 5)2 + ( 6 − 10 )2 x→0− x→0−
2
6.80 =
1
and R.H.L. = lim f ( x ) = lim xn sin
5
+ +
34 = (6 – a)2 + (6 – b)2 + 4 + 1 + 16 x→0 x→0 x
(6 – a)2 + (6 – b)2 = 13 = 9 + 4 = 32 + 22 For continuity at x = 0
a = 3, b = 4 lim f ( x ) = lim f ( x ) = f ( 0)
x→0+ x→0−
[9]
1 1 + x1 + x2
lim xn sin = 0 =4 ….(iii)
x→0 +
x 3
limit is defined only when n > 0 ….(i) y + y2 + 2
and 1 = 1 ….(iv)
since f (x) is non-differentiable at x = 0, 3
L.H.D. R.H.D Solving above equations, we get B & C.
Now
f ( 0 − h ) − f ( 0)
( )
L.H.D = f ' 0− = lim
h→0+ −h
76. (3)
f (x + 1) = x + f (x)
h2 ef (x + 1) = ex + f (x) = ex × ef(x)
− −0
= lim 2 =0 g (x + 1) = ex × g (x)
h→0+ −h ln (g (x + 1)) = x + ln (g (x))
and R.H.D =
g ' ( x + 1) g ' ( x )
f ( 0 + h ) − f ( 0) − =1
( )
+
f' 0 = lim
h→0+ h
g ( x + 1) g ( x )
1 1
1
hn sin g ' + 1 g '
h = lim hn−1 sin 1 2 − 2 =1
= lim
+ h→0+ 1 1
h→0 h h g + 1 g
Now L.H.D. R.H.D 2 2
1 1 1
= lim hn−1 sin 0, which is possible g ' + 2 g ' 1 +
h→0+
h 2 − 2 =1
only when n – 1 0 1 1
g + 2 g 1 +
n1 …(ii) 2 2
from equation (i) and (ii) n (0, 1]
1 1
g ' n + g ' n −
74. (4) 2 − 2
=1
Given, x1 + x2 + ….. + x10 = 12 1 1
gn + gn −
And x12 + x22 + ..... + x10
2
= 18 2 2
1 1
1 1 18 12
2 2
g ' n + g '
= x2 − x = −
2
Adding
2
− =n
2
n n 10 10 1 1
gn + g
9 36 9 2 2
= − =
5 25 25
3
SD = 77. (3)
5
u = x2 + 16
75. (2) du 2x x
= =
x1 + y1 = 5 ….(i) dx 2 x + 16
2
x + 16
2
x2 = 4 ….(ii)
x
v=
x −1
dv −1
=
dx ( x − 1)2
du du / dx −12
= =
co-ordinates of G are (4, 1) dv dv / dx 5
[10]
78. (2) 82. (330)
We have (x – 41)49 + (x – 49)41 + (x – 2009)2009 = n (A) = 40% of 10,000 = 4,000
0 n(B) = 20% of 10,000 = 2,000
Let f (x) = (x – 41)49 + (x – 49)41 + (x – 2009)2009 n(C) = 10% of 10,000 = 1,000
f ' (x) = 49 (x – 41)48 + 41 (x – 49)40 + 2009 (x n(A B) = 5% of 10,000 = 500
– 2009)48 > 0 n(B C) = 3% of 10,000 = 300
Hence, f (x) will cut x-axis only once 1 real n(C A) = 4% of 10,000 = 400
root n(A B C) = 2% of 10,000 = 200
n(A Bc Cc) = n[A (B C)c]
79. (2) = n(A) – n[A (B C)] = n(A) – n [(A B)
I =
(ex + cos x + 1) − (ex + sin x + x ) dx (A C)]
e x + sin x + x = n (A) – [n (A B) + n (A C) – n (A B C)]
= 4000 – [500 + 400 – 200] = 4000 – 700 = 3300
= loge (ex + sinx + x) – x + c
f (x) = ex + sinx + x and g(x) = –x
83. (0)
f (x) + g (x) = ex + sinx
a a3 a 4 − 1
80. (2) b b3 b4 − 1 = 0
a
I = ln ( cot a + tan x ) dx c c3 c4 − 1
0
a a3 a4 a a3 1
a
cos ( a − x )
= ln dx b b3 b 4 = b b3 1
0
sin a cos x
c c3 c4 c c3 1
a
cos x
I = ln dx abc (a – b) (b – c) (c – a) (ab + bc + ca) = (a – b)
0
sin a cos ( a − x )
(b – c) (c – a) (a + b + c)
1
a abc (ab + bc + ca) = (a + b + c)
Adding (1) and (2) we get 2I = ln 2 dx
0 sin a
84. (18)
a
= −2 ln ( sin a ) dx Case-Ι If B is right on A
0 Subcase -Ι C is right on B
= –2 a ln (sin a) then no. of ways = (4 –1)! = 6 Subcase- ΙΙ If D is
right on B then no. of ways = (4 –1)! = 6
81. (15) Case-ΙΙ If C is right on A D must be right on
If x = α + i β is a root then B = (4 – 1)! = 3! = 6
Hence total no. of ways is 6 + 6 + 6 = 18
A12 A22 An2
+ + ..... + =K
− a1 + i − a2 + i − an + i
& taking conjugate
A12 A22 An2
+ + ..... + =K
− a1 − i − a2 − i − an − i
Substracting
2A12 2A22 2An2 85. (87)
+ + .... + =0
( − a1 ) 2
+
2
( − a2 ) 2
+ 2
( − an ) 2
+
2 Let A1 → Ball drawn from urn A is red and ball
6 5
β=0 returned is also red, P(A1) =
10 11
x=α+i0
Which is purely real.
[11]
B1 → Ball drawn from urn A is red but ball
6 6
returned to it is black, P(B1) =
10 11
C1 → Ball drawn from urn A is black and ball of
4 7
same colour is returned, P(C1) =
10 11
D1 → Ball drawn from urn A is black and ball
4 4
returned is red, P(D1) = Clearly, SZ is perpendicular to PT.
10 11
R Now, SZ = a2 + a2t 2 = a 1 + t 2
Required probability P ( R ) = P ( A1 ) P +
A1 SP = a + at2 and AS = a
SZ = a2 (1 + t2) and AS SP = a2 (t2 + 1)
R R R
P ( B1 ) P + P ( C1 ) P + P ( D1 ) P Clearly, SZ2 = AS SP
B1 C1 D1
So, from the figure, we have
6 5 6 6 6 5 4 7 SZ2 = (4)(9) SZ = 6
= + +
10 11 10 10 11 10 10 11
6 4 4 7 32 88. (5)
+ =
10 10 11 10 55 Let ( 4cos + 4, 3sin + 3) be any point on the
[12]
10 + 3 tan2x – 5 (1 + tan2x) = 0 x y z
= + +
2tan2x = 5 1+ x 1+ y 1+ z
5 [where x = tan2α, y = tan2β, z = tan2γ]
tan 2 x =
2
=
( x + y + z ) + ( xy + yz + zx + 2xyz ) + xy + yz + zx + xyz
(1 + x )(1 + y )(1 + z )
90. (1) 1 + x + y + z + xy + yz + zx + xyz
sin2α + sin2β + sin2γ = =1
(1 + x )(1 + y )(1 + z )
tan 2 tan 2 tan 2
= + + xy + yz + zx + 2 xyz = 1
1 + tan 2 1 + tan 2 1 + tan 2
PW Web/App - https://smart.link/7wwosivoicgd4
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[13]