NARAYANA IIT/PMT ACADEMY

INDIA
XIIP IIT LJ(MAINS MODEL) Exam Date:01-10-2016
Time:3:00 Max Marks: 360

KEY
PHYSICS CHEMISTRY MATHEMATIC
1. 2 31. 1 61. 1
2. 2 32. 2 62. 2
3. 1 33. 1 63. 2
4. 2 34. 2 64. 1
5. 3 35. 1 65. 2
6. 2 36. 4 66. 3
7. 1 37. 4 67. 2
8. 2 38. 1 68. 1
9. 4 39. 4 69. 1
10. 2 40. 2 70. 3
11. 2 41. 4 71. 1
12. 2 42. 3 72. 1
13. 4 43. 4 73. 4
14. 1 44. 2 74. 3
15. 1 45. 2 75. 2
16. 2 46. 3 76. 2
17. 2 47. 3 77. 2
18. 3 48. 3 78. 1
19. 2 49. 2 79. 1
20. 4 50. 1 80. 1
21. 1 51. 1 81. 3
22. 3 52. 2 82. 4
23. 2 53. 2 83. 1
24. 1 54. 4 84. 2
25. 3 55. 1 85. 4
26. 1 56. 2 86. 4
27. 3 57. 2 87. 1
28. 1 58. 3 88. 2
29. 2 59. 2 89. 3
30. 3 60. 3 90. 2
 SOLUTION
PHYSICS
  m  m 2    2m 2  
1. v1   1  u1    u2
 m1  m 2   m1  m 2 
2. m1u1 – m2u2 = (m1 + m2)v
3. mu = (m + M)v
h2
4. e
h1
p12 p2
5. E  E1  E 2   2
2m1 2m 2
 
 m1u1  m 2 u 2
6. v
m1  m 2
7. d = h + 2h1 + 2h2 + ….. and hn = e2nh
8. mv0 i  3mV0 j  5mv0 k   m  m  m  v

v 

mv0 iˆ  3jˆ  5kˆ 
3m
V1 1
9. e1 : e2  3 :1; U1  2V1  e1  
U1 2
V1 V2
:  3 :1
U1 U 2
 m  em 2 
10. v1   1  u1  0
 m1  m 2 
m 1  e 
v2  0  1 u1
m1  m 2
v 22
11. Mv   M  m  v 2 ; h 
2g
12. mu = (M + m)v
4m1m 2 8
13. 2
 , find m1 and m2.
 m1  m 2  9
r v v 2r 2r 2t
14. t ; e  2 1 ; v 2  v1  eu1 and second impact, t1   
u1 u1 v 2  v1 eu1 e
vA 1  e v  vA
15.  e B .... 1
vB 1  e vA  vB
v v v  vA
We have e  2 1  B ...  2 
u1  u 2 uA  0
From (1) and (2), uA = ?
 
 m1 r1  m 2 r2
16. rcm 
m1  m 2
 m1y1  m 2 y 2
17. y cm 
m1  m 2
 
 m1 v1  m 2 v 2
18. v cm 
m1  m 2
19. Distance from shore = (10 – l + d)
m x  m2x 2
20. x cm  1 1
m1  m 2
 
 m1 r1  m 2 r2
21. rcm 
m1  m 2
m v  m2 v2
22. v cm  1 1
m1  m 2
r 2d
23. shift  
R 2  r2
L 
24. rcm  x 2cm  y cm
2
 or  rcm  cos
4 2
25. Coordinates of masses m1 = m, m2 = m, m3 = m are (40, 0), (20, –60) & (x3, y3)
respectively,
(xcm, ycm) = (0, 0)

26. x cm 

2 2 2
mx 1  2  3  ...  n l

 2

m 1  2  3  ....  n 
ad
27. ‘m’ be the mass of each part 3m  cc 2  m  cc1  or  X  a-Area of removed plate A-
A a
area of original plate d-distance between centres.
L L kx
3  L4 
xdm 0 dx  4 
28. dm 
kx 2 0
dx ; x cm  L  L  3
3L
2
L
0 dm 0 kxL dx  L  4
L

 3
m i x i
29. CM of bricks, above each brick must not be beyond its edge. x cm  ; x cm  L
m i
L L L
x1  a  , x 2  2a  , x 3  3a 
2 2 2
L
(or) a 
n
30. Theoretical
CHEMISTRY
31. A + 2B  AB2
32. Unit of rate constant for zero order reaction and unit of rate of the reaction are same (i.e.,)
mol.lit–1. Sec–1.
33. Decomposition of H2O2 is example of first order reaction.
0.693
34. For first order reaction, t1/2 does not depend on the initial concentration. t1/2 
K
 1 a
35. t1/2  n 1
for n  0  t1/ 2 
ka k
36.
37. r = K[A][B]
 A   B  16K A B
r1  K   
1/ 4 1/ 4
38. Rate of reaction w.r.t NH3 = Rate of reaction w.r.t. O2
39. According to stoichiometric relation.
40. For zero order, rate remains constant with time.
41. r = K(conc)n
42. 3 = 9n
n  1/ 2
43. According to given data[A] is constant w.r.t. [B] order is 2.
3
44.  i  t 75%  t 50%
2
 ii  t100%  2t50%
45. Activation energy forward reaction is greater than that of backward reaction. Hence the
reaction is endothermic.
46. Threshold energy = activation energy + normal energy.
47. Rate = K[Y][Z]1/2
1 d  A d C
48.  
2 dt dt
49. Rate law depends upon slow step
50. Rate does not depend upon the reactant which is taken as excess quantity.
51. Units of K = mol1–n. litn–1. Sec–1.
52. Rate = K[A][B]
1 
R1  K 1    1
2
1 
R 2  K  4  1   4   8
2 
1
53. t 1  n 1
2 a
54. t 1 is 16 Min.
2
 32 Min is equal to two half lifes
55. 75% completion equal to 2 half lifes hence
t 1  15 min.
2
93.75% completion equal to 4 half lifes
56. r = K[CH3COOC2H5][NaOH] on adding, three times of water the resultant volume becomes
four times that of initial volume.
57. 2n = 4, 3n = 9
58. rate = K[X][Y]0
59. Rate = K[NO]2[O2]
d d d O2 
60. 2   N 2O5    NO 2   4
dt dt dt
 1.0 M  0.6 M (40%)

MATHEMATICS
a 1 1
61. 2 1 1  0  a  1
1/ 2 2 1
62. y1  y1  y3  y 2 and x 2  x1  x 3  x 2
y  y 2 y 2  y1
So 3  (so points are collinear)
x 3  x 2 x 2  x1
63. x 2  x1r, x 3  x1r 2 , y 2  y1r, y3  y1r 2
y1r 2  y1r y1r  y1
  Points are collinear
x 1 r 2  x1 r x 1 r  x 1
ax  by  c  0 
64.  compare them x = 3, y = 4
3a  4b  c  0 
65. Set of lines passes through intersection point of x – 2y + 1 = 0 and x + y = 0 which is
 1 1
 ,  .
 3 3
66. Lines are parallel.
11
2x  3y  5  0 and 2x  3y   0
2
mn
Let required line is 2x  3y    0,  
2
11
5
  2 1
4 4
So 8x + 12 y – 1 = 0 is required line.
1
67. Slope of given line is 
3
From figure equation of reflected ray is
1
y
3
x 3 
y axis

30 o 30o
x axis
O  3,0 
 3y  x  3
69. c1 < 0, c2 < 0 (They are of same sign) a1a2 + b1b2 = 15 + 48 > 0 so origin containing bisector
is obtuse angled bisector.
3x  4y  5 5x  12y  5

5 13
  39x + 52y – 65 = 25x + 60y – 25
 14x – 8y – 40 = 0
or 7x – 4y = 20
3
70. Slope of line OP  , let new position is Q(x, y) slope of
4
y
OQ  also x 2  y 2  OQ 2  25   OP 2 
x
y 3

o
tan 45  x 4  1  4y  3x
3y 4x  3y
1
4x
4x  3y  4y  3x or  4x  3y  4y  3x
1
x y ...  i 
7
x  7y ... ii 
1
Correct relation is x  y as new point must lies in 1st quadrant.
7
1 7
x 2  49x 2  25  x  ,y 
2 2
x  4  r cos  o
71.  r  2 and   45
y  3  r sin  
72. Line (i) and line (ii) are perpendicular, so their intersection point is orthocenter.
On solving the equation of line (i) and (ii), then we get the co-ordinate of orthocenter, i.e.,
(1, 0).
74. (i) Reflection of (4, 1) about y = x is (1, 4).
(ii) Translation along x-axis by 2 units, so point’s position is (3, 4) now
 1 7 
(iii) Rotation about origin (similar to problem number 27) it’s new position is   , .
 2 2
x y X Y
75.   1,   1 is same line in two different frames with same origin, distance of line
a b p q
from origin will remain same in both cartesian system.
1 1

1 1 1 1
2
 2 
a b p2 q2
1 1 1 1
 2 2  2 2
a b p q
76. R is mid-point of PT
P a, x  T b, y 
Q R S

 5a  3b 5x  3y 
Point  ,  divides PT in the ratio 3 : 5 and that is mid point of QR.
 8 8 
77. Incentre is on the line y = x (Angle bisector of OA and OB)
Angle bisector of y = 0 and 3x + 4y = 12
 5y = 3x + 4y – 12
 y axis

B 0, 3

x axis
O A 4, 0 

 3x + 9y = 12
and 3x – y = 12
Here 3x + 9y = 12 internal bisector.
So intersection point of y = x and 3x + 9y = 12 is incentre.
78. In a right angled triangle mid-point of hypotenuse is circumcentre, therefore circumcentre is
3 
 ,2 .
2 
79. X = x – h, Y=y–k
0 = 7 – h, 0 = –4 – k  h = 7, k = –4
Hence, X = x – 7 and Y = y + 4 is (x, y) is (4, 5), then (X, Y) is (–3, 9).
80. The line y = 3x passes through the origin. Therefore, it can be written as
x 0 y0
 r
1 3
2 2
 r 3r 
Where r is the distance of any point (x, y) on y = 3x from (0, 0) i.e.,  ,  will always
2 2 
lie on the line y = 3x at a distance r from (0, 0)
Since it cut curve
x 3  y3  3xy  5x 2  3y 2  4x  5y  1  0
r 3 3 3r 3 3 3r 2 5r 2 9 2 5 3r
We have     r  2r  1  0
8 8 4 4 4 2

r3
1  3 3   r
2
...  r ...  1  0
8
This is a cubic in r which shows that y = 3x cuts the curve at 3 points.
1 4
 OA. OB. OC =
1 3 3

.8 
13

3 3 1

81. Length of perpendicular from origin to

x sec   y cos ec  a 2  0 is
a cos  sin 
p  a sin  cos 
sin 2   cos 2 
and length of perpendicular from origin to
x cos   y sin   a cos 2 is
a cos 2
p'   a cos 2
cos 2   sin 2 
Now, 4p 2  p '2  4a 2 sin 2  cos 2   a 2 cos2 2
 = 4a 2 sin 2  cos 2   a 2 cos 2 2
= a 2  sin 2 2  cos 2 2   a 2
 ax  bx 2  cx 3 ay1  by 2  cy3 
82. Incentre   ,
 abc a  b  c 
y axis

0, b 

x axis
O a, 0
where (x1, y1), (x2, y2) and (x3, y3) are vertices and a, b, c are lengths of sides.
Here vertices are  0, 0  ,  a, 0  and  0, b  and length of sides is a 2  b 2 , b, a so incentre.
 0  ab  0 0  0  ab   ab ab 
 ,   , 
2 2 2 2 2 2 2 2
a b a b ab a b  a b a b a b a b 
83. C is mid point of AB.
So A  (2x1, 0)
and B  (0, 2y1)
y axis

B
C x 1 , y1 

x axis
O A
x y
So line is  1
2x1 2y1
x y
  2
x1 y1

84. Verification
85. m = –1
86. Find the distance between
x  7y  3 2  0 and x  7y  7 2  0
87. Solve 3x – 2y – 1 = 0, x – 3y + 9 = 0
2 3 4
88.  
 k 2
|c c |
89. d 1 2
a 2  b2
k 4 2
90. 1 3 5  0
2 7 3