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Joint Entrance Exam | IITJEE-2023
1st FEB 2023 | Morning Shift
PHYSICS
SECTION - 1
f
1.(1) Average K.E. = kBT T
2
2.(2) Acceleration due to gravity decreases as we go down below the earth’s surface.
3.(2) b = V = L3
a
V 2 = P a = P V 2 = M 1L−1T −2 .L6 = M 1L5T −2
b2 L6
= 1 5 −2 = M −1LT
1 2
a M L T
1 −1 1 2
[Compressibility] = [1/Bulk Modulus] = = M LT
−1 −2
ML T
b2
= [Compressibility]
a
4.(4)
6.(4) R = 10−3 m
4 3 4 R 10−3
R = (125) r 3 r = = m = 2 10−4 m
3 3 5 5
SE = SE f − SEi = (125) 4r 2 − 4R2
( )
= 4 125 4 10−8 −10−6 = 1610−6 = 16 3.14 0.45 10−6 J = 2.26 10−5 J
h
7.(2) Momentum = p = for both.
K .E. of proton p2 / 2m p m
= = = 4 :1
K .E. of − particle p2 / 2m m p
8.(3)
9.(1) FM frequency range starts from 88 MHz and ends at 108 MHz.
1
10.(4) S = at 2
2
1
50 = a (10) a = 1m / s 2
2
2
f net = ma
30 − k mg = ma 30 − k 50 = 5
k = 0.50
T 70
11.(1) v= = m / s = 100m / s
7 10−3
12.(1) B.E. = m.c2 = 2mp + 2mn − mHe .c2 = ( 2)(1.0073 +1.0087) − 4.0015 931.5MeV
= 0.0305 931.5MeV = 28.4MeV
13.(4) TV −1 = constant
−1
V
Tf 1
1/ 2
1 T
= i = = T f =
Ti V f 2 2 2
W=
nRT
−1
= 2R T −
T
= RT 2 − 2
2
( )
VMC | JEE Main-2023 3 Solutions | 1st FEB Morning Shift
Vidyamandir Classes: Innovating For Your Success
14.(1) Vy = 2 gh = 200 = 10 2m / s
Vx = 5m / s
( )
n I0 I0
I = I0 cos2 45 I = = 2n = 64 n=6
2n 64
M
19.(1) Mp =
9
R
Rp =
2
2GM
ve =
R
v 2GM p 4GM
Escape velocity on planet = e x= =
3 Rp 9R
ve 2 2GM ve 2
x= x= ve x = 2
3 3 R 3 3
R 3R
20.(2) Wheat stone network is balanced as =
2R 6R
9R is removed
RAB = ( R + 3R ) || ( 2R + 6R ) =
( 4R )(8R ) = 8 R
12 R 3
dR
For R to be maximum, =0
dy
2
( ) ( )
2kqq0 3/ 2 3 2 1/ 2
a + y2 −y a + y2 2 y = 0
( a2 + y 2 )
3 2
2kqq0
(a 2
+ y2 − 3y2 = 0 ) 2y 2 = a2
(a 2
+y )
2 5/ 2
a
y= x=2
2
22.(828) 13.6eV − 3.4eV = 10.2eV for 1st excited state
13.6eV −1.51eV = 12.09eV for 2nd excited state
13.6eV − 0.85eV = 12.75eV for 3rd excited state
13.6eV
13.6eV − 12.75eV
n2
1 12.75
1− 2 n2 16
n 13.60
n4 n=4
nh 4h 2
L= = = ( 4.14) 10−15 eVs
2 2
828
= 10−17 eVs
x = 828
vA =
( −20)( −45) cm = −36cm
+20 − 45
vB =
( −20)( −35) cm = − 140 cm
+20 − 35 3
140 32
length of image = − 36 cm = cm x = 32
3 3
25.(40) S = rf − ri = 3iˆ − 5 ˆj + 5kˆ
F = 5iˆ + 2 ˆj + 7kˆ
W = F.S = 15 −10 + 35 = 40J
P
26.(1) B=
V
−
V
Bwater 0.03% 3 3
= = =
Bliquid 0.01% 1 x
x =1
27.(40) R = 100
X L = 79.6
29.(2) v=
2 gh
=
( 20)( 0.6sin 30) m / s
k2 1+
1
1+ 2 2
R
20 0.3 2
v= m / s = 2m / s
3
30.(144) q = 2C
B = 4mT = 4 10−3T
V = 100 volt
R = 0.03m
mv 2mK 2mqV
R= = =
qB qB qB
( )
2
( qRB ) 2 2 10−6 0.03 4 10−3
m= = −6
kg
2qV 2 2 10 100
m = 144 10−18 kg
CHEMI
CHEMISTRY
SECTION - 1
1.(3) Dehydration of alcohol is directly proportional to the stability of carbocation.
2.(2)
List I List II
Test Functional group/Class of compound
(A) Molisch’s Test (II) Carbohydrate
(B) Biuret Test (I) Peptide
(C) Carbylamine Test (III) Primary amine
(D) Schiff s Test (IV) Aldehyde
3.(2) No pollution occurs by combustion of hydrogen and very low density of hydrogen.
4.(4) Initially lone pair electron of −NH2 attack on electrophilic carbon, after then lone pair electron of
oxygen attacks leading to formation of cyclic compound.
5.(3) Resonating structure are hypothetical and resonance hybrid is real structure which is weighted average
of all the resonating structures.
6.(1) Fact
7.(1) Fact
8.(1) 2C (s ) + O2 ( g ) → 2CO ( g )
rS is +ve, r G = r H − TrS; thus slope is negative
As temperature increases r G becomes more negative thus it has lower tendency to get decomposed.
9.(2) By Haworth structure of mannose.
10.(1) By using catalytic convertors.
3
11.(1) Adsorption vanderwaal attraction forces Zc = for all real gases
8
12.(2)
SECTION – 2
21.(2) As per the language of given question, the best possible isomeric structure is
Ph − CH = CH − O − CH3 (cis and trans). So, the answer is 2.
22.(3) KCl + AgNO3 → AgCl + KNO3
V = 25ml V = 20ml
M = 1M
At equivalence point, mmole of KCl = mmole of AgNO3 = 20 mmole
Volume of solution = 25 ml
Mass of solution = 25 gm
Mass of solvent = 25 – mass of solute
me = 9 10−31 kg
h 6 10−34
= = −
= 666.67 10−9 m = 666.67nm
mv 9 10 1000
31
Mn 2+
E=E −
0.059
0
log
8
5 MnO−4 H+
0.059 10−3
1.282 = 1.54 − log 8
5 10−1 H+
By solving this H+ = 10−3 Hence, pH = 3
26.(12) HBrO3 (Bromic acid)
Ox. State of Br = + 5
HBrO4 (per bromic acid)
Ox. State of Br = + 7
Sum of Ox. State = 12
27.(15) At = A0 e−kt
ln 2 ln 2
For A : Let At be y and A0 be x; k = =
t1/ 2 15min
ln 2
− t
−kt
y = xe = xe 15
ln 2 ln 2
Let Bt = y; B0 = 4x; k = =
t1/ 2 5min
ln 2
− t
y = 4xe 5
ln 2 ln 2
− t − t
xe 15 = 4xe 5
ln 2 ln 2
t −
e 5 15 =4
ln 2 ln 2
t − = ln 4
5 15
1 1
t ln 2 − = 2ln 2
5 15
t = 15min
Initial moles n – –
At equilibrium n −n n n
Ptotal = p1
1 p1 1 + p1
k p1 =
1−
p
1+ 1
2 p
3= 1
(1 + ) (1 − )
2p1
3=
1 − 2
(ii) A (g) 2B ( g ) k p2 = 1
Initial moles n –
At equilibrium x −n 2n Ptotal = p2
2
2
p2
= 1−
2
k p2
1−
p
1+ 2
42 p2
1=
1 − 2
k p1 p
= 1
k p2 4p2
H2 ( g ) → 2H +436kJ mol−1
_________________________________________________
MATHEMATICS
SECTION - 1
f ( 3) g ( 3)
2.(4) Equation of the pair of angle bisector for the homogenous equation ax2 + 2hxy + by 2 = 0 is given as
x2 − y 2 xy
=
a −b h
1
Here a = 2, h = and b = −3
2
x 2 − y 2 xy
Equation will become =
2 − ( 3) 1/ 2
x2 − y 2 = 10xy
x2 − y2 −10xy = 0
1 1
3.(3) 1 1 =0
1 1
1 1 1
( + 2) 1 1 = 0
1 1
so ( −2
2
)
+ −2 = 6
( )
26 26
1 1
( 2r −1)!( (51)!− (2r −1) )! 51C( 2r −1) 51! = 51!
51 1 50
4.(4) = 51
C1 + 51C3 + ... + 51C51 = 2
r =1 r =1 51!
5.(4) The solution of D.E.: y (sec x ) = x tan x − ln (sec x ) + c
3 3 3
At x = ,y= + ln +
6 12 2 2 2
1
1 + x dx n(1 + x0 =
1
n2
x − 2 y +1 z − 3
7.(2) Equation of line PM = = =
1 2 −1
any point on line = ( + 2, 2 −1, − + 3)
1
for point M ( + 2) + 2 ( 2 −1) − (3 − ) = 0 =
2
1 1 −1 5 5
point M + 2, 2 −1, + 3 = ,0,
2 2 2 2 2
+ 2 5 −1 +3 5
For Image Q ( , , ) = , = 0, =
2 2 2 2 2
Q : (3,1, 2)
3 ( 3) + 2 (1) + 2 + 29
d=
32 + 22 + 12
42
d= = 3 14
14
8.(2) ( q (( q) p) )
= q (( q ) p ) = q ( q p ) = ( q q ) ( q p ) = ( q p )
9.(4) ( x − 2 ) 2 + y 2 = 2 ( x − 3) 2 + y 2
= x2 + y2 − 4x + 4 = 4x2 + 4 y2 − 24x + 36 = 3x2 + 3 y 2 − 20x + 32 = 0
20 32 10
= x2 + y 2 − x + = 0 = ( , ) = ,0
3 3 3
100 32 4 2
= − = =
9 3 9 3
10 2
3 ( , , ) = 3 + = 12
3 3
10.(4) As 3 ( a − a ) + 7 = 7 which belongs to relation so relation is reflexive
7
Check for symmetric: Take a = ,b = 0
3
Now (a, b) R but ( b, a ) R
7
Check for transitivity: Take ( a, b ) as
3 ,1
2 7
and ( b, c ) as 1,
3
So now ( a, b ) R and (b, c ) R but ( a, c ) R which means relation is not transitive.
dy x + a
11.(4) + =0
dx y − 2
dy x + a
=
dx 2 − y
− y x2
( 2 − y ) dy = ( x + a ) dx 2y = + ax + c
2 2
1
a + c = − as y (1) = 0
2
x2 + y2 + 2ax − 4 y −1 − 2a = 0
r 2 = 4
r2 = 4
4 = a2 + 4 + 1 + 2a
( a + 1)2 = 0
(
P, Q = 0, 2 3 )
Equation of normal at P, Q are y − 2 = 3 ( x − 1)
y − 2 = − 3 ( x − 1)
2
R = 1 − ,0
3
2
S = 1 + ,0
3
4 3
RS = =4
3 3
x − x1 y − y1 z − z1 x − x2 y − y2 z − z2
12.(2) Shortest distance between two lines = = & = = is given
a1 a2 a3 b1 b2 b3
x1 − x2 y1 − y2 z1 − z2
a1 a2 a3
b1 b2 b3
as
( a1b3 − a3b2 )2 + ( a1b3 − a3b1 )2 + ( a1b2 − a2b1 )2
16 + 14 + 6 36 36 18
= = = = =6 3
12 12 2 3 3
1+ 3 + 5 + a + b
13.(2) =5
5
a + b = 16 … (1)
x12 x
2
2
= −
5
5
12 + 32 + 52 + a2 + b2
8= − 25
5
a2 + b2 = 130 ….(2)
by (1), (2)
a = 7, b = 9 or a = 9, b = 7
14.(4) If cos2 A + cos2B + cos2C is minimum then A = B = C = 60°
MD r 6
So ABC we have tan30 = = =
BD a / 2 a
1
1/ 3 = =a=6 3
a
Perimeter of ABC = 18 3
3 2
Area of ABC = a = 27 3
4
15.(3) np + npq = 5, ( np )( npq ) = 6
np (1 + q ) = 5, n2 p2q = 6
n2 p2 (1 + q ) = 25, n2 p2q = 6
2
6
(1 + q )2 = 25
q
6q2 + 12q + 6 = 25q
6q2 −13q + 6 = 0
6q2 − 9q − 4q + 6 = 0
(3q − 2)( 2q − 3) = 0
3 2 2
q = , , q = is accepted
2 3 3
1 1 1 2
p = n. + n. . = 5
3 3 3 3
3n + 2n
=5
9
n=9
1 2
So 6 ( n + p − q ) = 6 9 + − = 52
3 3
=
(r 2
) (
+ r +1 − r2 − r +1 )
( )
16.(1) Tr
2 r 4 + r 2 +1
1 1 1
Tr = 2 − 2
2 r − r + 1 r + r + 1
1 1 1
T1 = −
2 1 3
1 1 1
T2 = −
2 3 7
1 1 1
T3 = −
2 2 13
1 1 1
T10 = −
2 91 111
10
1 1 55
Tr = 2 1 − 11 = 11
r =1
17.(4)
Here ( m ) BH ( m ) AC = −1
− 3 1
− 2 −2 = −1
1 cos2 x sin 2 x
f ( x ) = ( 2 + sin 2 x ) 1 1 + cos x 2
sin 2 x
1 cos2 x 1 + sin 2 x
R2 → R2 − R1
R3 → R3 − R1
1 cos2 x sin 2 x
f ( x ) = (2 + sin 2 x) 0 1 0 = ( 2 + sin 2 x )(1) = 2 + sin 2 x
0 0 1
3
= sin 2 x ,1
2
3
Hence 2 + sin 2 x 2 + ,3
2
((
cos−1 ( 2x ) − cos−1 2 1 − x2 −1 = ) )
(
cos−1 ( 2x ) − cos−1 1 − 2 x2 = )
( )
− cos−1 1 − 2 x2 = − cos−1 ( 2 x )
(
Taking cos both sides we get cos − cos−1 1 − 2x2 ( )) = cos ( − cos −1
( 2x ))
1 − 2 x2 = −2 x
2 x2 − 2 x − 1 = 0
1− 3 1+ 3
On solving, x = ,
2 2
1+ 3
As x = −1/ 2,1/ 2 , x = = rejected
2
− 3 −2
So x =
1− 3
2
(
x2 −1 = − 3 / 2 = 2sin −1 x2 −1 = 2sin −1
2
)
=
3
( )
x2 −4
20.(4) Let 3+ 2 =t
1
t + = 10
t
( )
x2 −4
t = 5 + 2 6,5 − 2 6 3+ 2 = 5 + 2 6,5 − 2 6
x2 − 4 = 2, −2 or x2 = 6, 2 x = 2, 6
SECTION – 2
21.(754) a1 + a2 + a3 + a4 = 50
32 + 6d = 50 d =3
and, an−3 + an−2 + an−1 + an = 170
32 + ( 4n −10).3 = 170 n = 14
a7 = 26, a8 = 29 a7 .a8 = 754
f ( x ) = 2x + g (1)
f ( x) = 2
g ( x ) = 2 f (1) x + 4x + g (1)
g ( x ) = 2 f (1) + 4
g ( x ) = 0
2 f (1) + 4 = 0
f (1) = −2 −2 = 1 + g (1) = g (1) = −3
So, f ( x ) = 2x − 3
f ( x ) = x2 − 3x + c
c=0
f ( x ) = x2 − 3x
g ( x ) = −3x + 2
f ( 4) − g ( 4) = 14
23.(3501) uvw = u.(v w)
min.( u v w cos ) = − 3401
cos = −1
u = (Given) v w = 3401
iˆ ˆj kˆ
v w = 2 −3
2 1 −1
iˆ ˆj kˆ
v w = 2 −3
2 1 −1
v w = iˆ − 5ˆj − 3kˆ
342 = 3400
2 = 100
= 10 (as 0 )
( )
so, u = iˆ − 5 ˆj − 3kˆ
2 = 2 (1 + 252 + 92 )
(x )( )
1/ 7
24.(63) 20
+ x13 + x6 2 x21 + 3x14 + 6 x7 dx
2 x21 + 3x14 + 6 x7 = t
( )
42 x20 + x13 + x6 dx = dt
11 1 11
t 8/ 7 1
( )
1 1 8/ 7 11 1
(11)8/ 7
42 0
t dt = = =
8/ 7 42
7 t
48 0 48
0
l = 48, m = 8, n = 7
l + m + n = 63.
( ) ( )
0 2
25.(18) A = x 2 − 3x dx + 3x − x 2 dx
−1 0
0 2
x3 3x2 3x2 x3 11 10 31
A= − + − A= + =
3 2 −1
2 3 6 3 6
0
12 A = 62
dy
26.(1) +y=k
dx
y.e x = e x + c
f ( 0) = e−2
c = e−2 − k
(
y = k + e−2 − k e− x )
(k + (e ) )
2
−2
Now k = − k e− x dx
0
k = e−2 − 1
(
y = e−2 − 1 + e− x)
f ( 2) = 2e−2 −1, f ( 0) = e−2
2 f ( 0) − f ( 2) = 1
1
Area = BD AC = 18
2
iˆ ˆj kˆ
AC BD = 0 −3 −3 = ( 3 + 15) iˆ − ˆj ( −24) + kˆ ( −24)
8 5 −