GIREESHA C, LECTURER IN CHEMISTRY

GIREESHA C,
LECTURER IN CHEMISTRY
GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038),
HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK, TUMAKURU DISTRICT - 572218
MODEL QUESTION PAPER-1
II YEAR PUC ONLY FOR -2020-21
SUBJECT CODE: 34 SUBJECT: CHEMISTRY
Q. NO. PART-A MARKS

I ANSWER ALL THE QUESTIONS. EACH QUESTION CARRIES 1 MARK. 10X1 = 10

1) What is the effect of temperature on molality of a solution?

Ans. Does not changes or Independent on temperature. 1
2) How does the size of blood cell changes when placed in an aqueous solution containing less
than 0.9% (m/v) sodium chloride?
Ans. Blood cells collapse due to loss of water by osmosis. 1
3) The resistance of a conductivity cell containing 0.001M KCl solution at 298K is 1500Ω.
What is the cell constant if conductivity of 0.001M KCl solution at 298K is 0.146X10-3 Scm-1?
Ans. 219cm-1 OR
1
Cell constant = conductivity X Resistance.= 0.146X10-3 S cm-1 X 1500Ω = 219cm-1
4) Give an example for pseudo first order reaction.
Ans. The Acid hydrolysis of ethyl acetate OR CH3COOC2H5+H2O → CH3COOH+C2H5OH OR
1
Inversion of cane Sugar OR C12 H22O11 + H2O → C6H12 O6 (any one correct answers)
5) What is adsorption isotherm?
Ans. The graph plotted on mass of gas adsorbed by adsorbent against pressure at constant
temperature. OR
1
At constant temperature, The graph plotted against the variation in the amount of gas adsorbed
by adsorbent verses pressure.
6) Noble gases have large positive values of electron gain enthalpy. Why?
Ans. Noble gasses have stable electronic configuration hence they no tendency to accept electron. 1
Complete the following equation:
7)

Ans. O2 F2 OR XeF4 +O2F2 → Xe F6 +O2 1

8) Give an example for geminal halide.
Ans. 1,1-dichloroethane OR 2,2- dibromopropane etc (OR any one correct answer) 1
9) Which type of Aldehydes does not undergo Cannizzaro’s reaction?
Ans. Aldehydes which do not have an α -hydrogen atom 1
10) What are nucleotides?
A nitrogen containing heterocylic compounds. OR
Ans. An organic molecule consisting of Nucleoside linked to a phosphate group. OR 1
Nucleotides are organic molecules consisting of a nucleoside and a phosphate.

1
GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

Q. NO. PART-B MARKS

II ANSWER ANY FIVE OF THE FOLLOWING. EACH QUESTION CARRIES 2 MARKS. 5X2 = 10

11) Give any two differences between amorphous and crystalline solids. 2
Ans. Amorphous solids. Crystalline solids.
Have irregular shape. Have definite geometrical shape
Gradually soften over a range of temperature. Have sharp and characteristic melting point.
Do not have definite heat of fusion Have definite and characteristic heat of fusion
Isotropic in nature Anisotropic in nature (any
Pseudo solids True solids two)
only short-range order long-range order 2

12) Write the overall cell reaction during the working of Daniel cell. 2

Ans. Zn(s) + Cu+2 (aq)→Zn +2 (aq) +Cu (s) E0 = 1.1V 2

13) For the reaction R → P, the concentration of reactant changes from 0.03M to 0.02M in
2
25min. Calculate the average rate of reaction in seconds.
Ans.

1 +1

14) How will you account for the following?

i) Zr and Hf sizes are almost same. 1
ii) Write the general electronic configuration of lanthanoids. 1
Ans. i) Due to Lanthanoid contraction 1
ii) [noble gas] 6s2 5d0-1 4f 1-14 1
15) Explain Friedel-Crafts acylation with equation by taking chlorobenzene as example. 2
Ans. Chlorobenzene reacts with acetyl chlorides in the presence of anhydrous AlCl3 catalyst to form
4-chloroacetophenone as a major product. 1

OR

2
GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

16) Explain Kolbe’s reaction. 2

Ans. Sodium phenoxide undergoes electrophilic substitution reaction with weak electrophiles carbon
dioxide followed by acid hydrolysis gives (Salicylic acid) 2-hydroxybenzoic acid. 1

OR
O
R

17) Give the preparation of phenol from cumene. 2

Ans. When cumene (Isopropyl benzene) is oxidised in the presence of air, it gives cumene hydroperoxide
which on treated with dilute acid gives phenol and acetone. 1

OR
Or

(self explanatory equation)

18) Explain carbylamine reaction with an example. 2
Ans. Aliphatic and aromatic primary amines on heating with chloroform and ethanolic potassium
hydroxide form isocyanides or carbylamines. 1

R-NH2 + CHCl3 + 3 KOH R-NC + 3KCl+ 3H2O 1

OR
Or

(self explanatory equation)

3
GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

Q. NO. PART-C MARKS

III ANSWER ANY FIVE OF THE FOLLOWING. EACH QUESTION CARRIES 3MARKS. 5 X 3 = 15

Discuss the principle involved in the manufacture of ammonia by Haber’s process along
19) 3
with the chemical equation.
Ans. according to Le Chaterlier’s principle, the forward reaction is favored by
1. Low Temperature (≈700K).
2. High Pressure (≈200atm) (Any
3. Iron (Fe) Catalyst two)
4. K2O & Al2O3 are promoter. 2

20. Give any three reasons for the anomalous behaviour of oxygen. 3
Ans. 1. Small size.
(Any
2. High ionization enthalpy
three)
3. High electronegativity
3
4. Absence of ‘d’- orbitals
21) i) What is aqua regia? 1
ii) Write the structure of chlorous acid. 1
iii) Complete the equation: Br2 + 5F2(excess) → _______ 1
Ans. i) The mixture of three parts of conc. HCl and one part of conc.HNO3 is called aqua regia. 1
OR
ii) 3:1part of conc. HCl and conc. HNO3.
1

iii) 1

22) i) Many copper (I) compounds are unstable in aqueous solution and undergo
disproportionation. Explain. 2
ii) What are interstitial compounds? 1
Ans. i) Because
1. The stability of Cu+2(aq) is more than Cu+(aq) ion. 1
2. More negative ∆hydH of Cu (aq) ion than
- +2
Cu+(aq) ion, which more than compensates for the
second ionization enthalpy of Cu. 1
ii) Interstitial compounds are those which are formed when small atoms like H, C, or N are
1
trapped inside the crystal lattice of metals

4
GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

23) a) Write general valence shell electronic configuration of d-block elements. 2

b) d-Block elements act as good catalysts. Give any two reasons. 1
Ans. a) [noble gas] (n-1)d1-10 ns1-2 where n= 4, 5, 6, 7….. 1
b) 1. Ability to adapt to multiple oxidation state. (any
2. Form complexes with reactant molecules using vacant d-orbital. two)
3. Due to presence of large surface area. 1+1
24) Give any three postulates of Werner’s theory of coordination compounds 3
Ans. 1. The central metal atom or ion in a complex possesses two types of valences (linkages):
Namely a) Primary valency b) secondary valency.
2. Primary valency is ionisable and Secondary valency is non-ionisable
3. Primary valency is satisfied only by anions (negatively charged ions) and secondary valency
is satisfied by either anions or neutral molecules or both. 3
4. The primary valency corresponds to the oxidation state of central metal and the secondary valency (any three
corresponds to the co-ordination number of the metal (remains fixed for a metal). correct
5. The secondary valences are directional. Hence they show isomerism. answers)
6. The primary valency of the metal is variable; the secondary valency has a fixed value.
25) Based on VBT, Explain the formation of [Ni(CN)4]2-. 3
2
Ans. Hybridisation: dsp
Geometry : Square planar 1
Magnetic property: Diamagnetic 1

26) i) Write the structure of decacarbonyldimanganese(0), Mn 2(CO)10. 1

ii) What are homoleptic complexes? Give an example. 2
Ans. a)
1

b)
1
Complexes in which a central metal atom/ion is bound to only one kind of donor groups are 1
known as homoleptic complexes.
Example: [Ti(H2O)6]3+ , [Co(CN)6]3−, [Cu(H2O)4]2+, [Ni(CN)4]2−, [NiCl4]2−, [Co(en)3]3+ etc
(any three correct answers)

5
GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

Q. NO. PART-D MARKS

IV ANSWER ANY THREE OF THE FOLLOWING. EACH QUESTION CARRIES 5 MARKS. 3X5 = 15

27) a) Calculate the packing efficiency in a cubic close packed (ccp) structure. 3
b) Metallic iron crystallizes in a particular type of cubic unit cell. The unit cell edge length
is 287pm. The density of iron is 7.87gcm-3. Calculate the number of iron atoms per unit 2
cell. [Given: Atomic mass of Fe is 56 & NA = 6.023 X 1023].
Ans. Let the edge length be ‘a’ and face diagonal AC be ‘b’.
a) Let ‘r’ be the radius of the atom.
From ΔABC, we have

But
∴ Total Volume of the unit cell, 1
The number of atoms per unit cell of FCC is 4.

Volume occupied by four spheres in the unit cell =

1

Ans.
b) 1
OR
1
Z=2
28) a) Addition of 0.643g of a compound to 50mL of a liquid (density=0.879g/mL) lowers the
3
freezing point from 5.510C to 5.030C. Calculate the molar mass of the compound. (Kf
for benzene = 5.12KKgmol-1)
2
b) Give any two differences between ideal and non-ideal solutions.
Ans. a)
Depression of freezing point = = 5.510C – 5.030C = 0.480C
1
mass of solvent = density x volume = 0.879g/mL X 50mL = 43.95g

OR

= 1000 X 0.643 X 5.12

0.48 X 43.95
1
-1
M2 = 156gmol

6
GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

b) Ideal Solution Non-Ideal Solutions

Solutions which obey Raoult’s law over the Solutions which do not obey Raoult’s (Any
entire range of concentrations law over the entire range of concentration
two)
Enthalpy of mixing of the pure components Enthalpy of mixing of the pure components
2
to form the solution, Δmix H = 0 to form the solution, Δmix H ≠ 0
Volume of mixing, Δmix V = 0 Volume of mixing, Δmix V ≠0
29) a) The standard electrode potential for Daniel cell is 1.1V. Calculate the standard Gibbs
3
energy change for the reaction;
Zn(s) + Cu2+(aq) → Zn2+(aq) +Cu(s)
2
b) Write any two factors affecting ionic conductance.

Ans. a) For this equation : n=2

1
= -2 X 96487 X 1.1 1
= -212271.4 Jmol-1 = = -212.27 KJmol-1 1
b) 1. Nature of electrolyte.
2. Size of ions produced & their solvent. (Any
3. Nature of the solvent & its viscosity. two)
4. Concentration of electrolyte 2
5. temperature (Increase with the increase of temperature)
30) a) Derive integrated rate equation for a first order reaction. 4
b) Which step of the reaction mechanism decides the order of reaction in complex reactions? 1
Ans. a) Consider a first order reaction, R → P

Integrating this equation, ln [R] = − kt + I …(ii) (I or C= Integration constant) 1

When t = 0, [R] = [R]0 ([R]0 = Initial concentration of the reactant)
Substituting [R] = [R]0 in equation (ii), ln [R]0 = − k × 0 + I
ln [R]0 = I
Substituting the value of I in equation (ii),
ln[R] = − kt + ln[R]0 …(iii) 1

b) Slow step 1

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GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

31) a) How does free energy and entropy changes during adsorption? 2
b) What is coagulating value? The coagulating value of A and B will be 2.4X10-3 millimole 2
per litre and 1.2 X 10-2millimole per litre, which one has higher coagulating power?
c) What is Craft temperature (Tk) 1
Ans a) Free energy change during adsorption: ΔH decreases or ΔH < 0 or ΔH = -ve 1
Entropy change during adsorption: ΔS decreases or ΔS < 0 or ΔS = -ve 1
b) The minimum concetration of an electrolyte in millimoles per litre required to cause
precipitation of a sol in two hours is called coagulating value. 1
‘A’ has higher coagulating power. (Because smaller the quatity of coagulating value, higher
will be the quatity of coagulating power of ion). 1

c) The formation of micelles takes place only above a particular temperature is called as Critical
temperature (Tk). OR 1
The particular temperature only above which formation of micelles takes place are called as
Critical temperature (Tk).
V ANSWER ANY FOUR OF THE FOLLOWING. EACH QUESTION CARRIES 5MARKS. 4X5 =20

32) a) Write SN2 mechanism and mention the order of this reaction. 3
b) What are Grignard reagents? Write its general formula. 2
Ans. a) The reaction between methyl chloride and hydroxide ion to yield methanol and chloride ion
follows a second order kinetics and involves only one step. The product (methanol) formed 1
has the inverted configuration as compared to the reactant (Methyl chloride).
1

1
Second order reaction.
b) Haloalkanes react with magnesium metal in dry ether to form alkyl magnesium halides called
as Grignard reagents. OR Grignard reagent is an oranomagnesium halide compounds. 1
R-Mg-X OR RMgX 1
33) a) Explain the mechanism of dehydration ethanol to ethene. 3
b) Explain Williamson’s synthesis with an example. 2
Ans. a) Step1: Formation of protonated alcohol:
1

Step2: Formation of carbocation:

Step3: Elimination of proton:

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GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

b) When alkyl halides are allowed to react with sodium alkoxide gives ethers. 1
1
OR
OR

(self explanatory equation)

34) a) Lower members of aldehydes and ketones are miscible with water. Give reason 1
b) Complete the following reactions:
i)
ii)

c) How acetaldehyde does react with hydrazine? Give equation. 2

Ans. a) Because lower member of aldehydes and ketones form hydrogen bond with water. 1

b) 1
i)

ii) 1

When acetaldehyde reacts with hydrazine gives acetaldehyde hydrozone.

1
c)
1

35) a) What is Hell-Volhard-Zelinsky reaction? Give an example 2

b) Explain the effect of electron withdrawing groups on acidity of carboxylic acid. 1
c) Explain decarboxylation of benzoic acid with equation. 2
Ans. a) Carboxylic acids having an α-hydrogen on treated with chlorine or bromine in the presence of 1
red Phosphorus gives α-halocarboxylic acid. 1

9
GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

b) Electron Withdrawing Group increases the acidic strength of carboxylic acid.

(Electron Withdrawing Group stabilises the carboxylate ion due to inductive effect). 1

OR
OR

Benzoic acids lose carbon dioxide to form benzene when their sodium salts are heated with
c) 1
sodalime (3:1 ratio NaOH and CaO).

OR
OR

(self explanatory equation)

36) a) Write the equation and IUPAC name of the product formed when aniline reacts with
2
b) bromine water at room temperature.
Write the increasing order of basicity of the following amines in aqueous solution.
1
c) NH3, (C2H5)3N, C2H5NH2, (C2H5)2NH
2
How do you prepare primary amine by Gabriel’s phthalimide synthesis? Give equation.
Ans. a) When aniline reacts with bromine water at room temperature gives 2,4,6,-tribromoaniline. 1

OR
OR

(self explanatory equation)

b) 1
(C2H5)2NH > (C2H5)3N > C2H5NH2 > NH3

10
GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218
 GIREESHA C, LECTURER IN CHEMISTRY

c) Phthalimide on treatment with ethanolic KOH forms potassium salt of phthalimide on heating with
alkyl halide followed by alkaline hydrolysis produces primary amine. 1

OR OR

37) a) Write the Haworth structure of α -D-(+)glucopyranose.

2
b) What are fibrous proteins? Give an example.
2
c) Name the base which forms hydrogen bond with adenine in double stranded helix structure
1
of DNA.
Ans. a)

b) The proteins in which polypeptide chains run parallel and are held together by hydrogen and 1
disulphide bonds are called as fibrous proteins. 1
Example: keratin, myosin, etc (Any one correct answer)
c) Thymine (T) 1

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GOVERNMENT PRE-UNIVERSITY COLLEGE (UU0038), HULIYAR-KENKERE, CHIKKANAYAKANAHALLI TALUK,
TUMAKURU DISTRICT - 572218