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[Physics]
1. (3)
2
a = a2 = 1, = 1 T = 2, T = 6.28s
T
2. (2)
2 l 1 l T 4
t' = + 2 = 2 = sec
2 g 6 g 3 3
3. (1)
Velocity at extreme position is zero.
4. (2)
T2 2T
= 1− = 1− 2 =
T1 2T1
5. (2)
Q KA
End to end = (T1 − T2 ) …(1)
12 2L
Q K ( 2 A)
Lengthwise = (T1 − T2 ) ….(2)
t L
Equation (1) (2) then t = 3sec
6. (2)
7. (3)
Total time taken by a milk drop to come at ground is
t0 = 3t
1 2 1
h= gt0 or 20 = gt02 or 4 = t02
2 2
t0 = 2s
2
3t = 2 t =
3
The separation between fourth and second drop is
1 1 4 80
s = g ( 2t ) = 10 4 = m
2
2 2 9 9
Height of second drop
80 180 − 80 100
= 20 − = = m
9 9 9
8. (2)
v = u + at or v − u = at
or v − u = area of a − t graph
1 1
or v − ( −2) = 5 ( 2 + 3.5) − 5 0.5
2 2
v + 2 = 12.5; v = 10.5 m / s −1
9. (3)
Initial coordinate system,
F sin 37 = 6 N
( ) 1
2
= 52 + 5 2 − 2 5 5 2
2
= 25 + 50 − 50
= 25 = 5ms −2
11. (3)
Let the velocity of rain fall is vr
v 25 25
100
or vdv = 2ds +
5 10 10
s2
ds
25
s −2+1
v = 2 s 25 + 100
1 2 v
or
2 5 10
−2 + 1 10
The lower block will not move, the syst. is at rest, no friction on upper block.
14. (2)
T = mg ….(1)
2T cos = mg ….(2)
1
By equation (1) and (2) cos =
2
15. (2)
The fraction of energy lost is given by,
E mg ( h − h ') h − h '
= =
E m gh h
Given that, h = 2 meter and h ' = 1.5 meter
E 2 −1.5 1
= =
E 2 4
16. (2)
Mass of 2 litre, water = 2 kg
( x + d )2 = 3x2 x2 + d 2 + 2xd
= 3x 2
2 x2 − 2dx − d 2 = 0
d 3d
x=
2 2
(Negative sign between q and −3q is unadaptable.)
d
2
+
3d d
2
( )
= 1 + 3 to the left of q.
2
20. (1)
For (VA − VB ) = 0
1
= MB ( − cos120 + cos0) MB 1 +
2
3
= MB
2
23. (2)
1 5gx
= mgh
2 2
m
5x
=4
4
16
x = cm
5
24. (3)
The photon’s with energies equal to that required for upward transition A → X , A → B and A → C
would be absorbed, these photons shall be absent from absorption spectrum.
28. (4)
29. (3)
V = VR2 + (VL − VC )
2
V = 402 + ( 50 − 20) = 50
2
30. (3)
I 2.95
= = 0.368
I max 8
Then t = = 0.01s = 10 ms
31. (2)
32. (1)
33. (3)
34. (3)
D
The distance between nth bright fringe and ( n + 1) dark fringe is equal to half fringe width =
th
2d
35. (1)
36. (1)
0 1 1
B= i −
4 r1 r2
37. (1)
1 t t
= 1 + 2
Ceq k10 A k20 A
Q Q t1 t2
V= = +
Ceq 0 A K1 K2
38. (4)
Req = 2 + 4 = 6ohm
I = 3A
Power = VI = 18 3 = 54watt
39. (1)
40. (4)
a1v1 = a2v2
4.20 5.18 = 7.60 v2 2.86 m / s
41. (3)
Heat required = m 80 + m1100 + m 540
= m ( 720) = 1 720 = 720 Calories
42. (1)
P0 M 4 1
= He = =
PHe M O2 32 8
43. (4)
BC is isochoric. VB VA , VB = VC , VD VC
44. (1)
45. (2)
Substituting x = 0 we have given wave y = Asin wt at x = 0 other should have y = − Asin wt
equation so displacement may be zero at all the time Hence (2) is correct option.
46. (4)
47. (4)
48. (1)
W = FS cos , if = 90 then W = 0
49. (3)
When fiction is absent
a1 = g sin
1
s2 = a1t12 …(i)
2
When friction is present
a2 = g sin − g cos
1
s2 = a2t22 ….(ii)
2
From Eq. (i) and (ii)
1 2 1 2
a1t1 = a2t2
2 2
or a1t1 = a2 ( nt1 ) ( t2 = nt1 )
2 2
or a1 = n2a2
a2 g sin −g cos 1
or = = 2
a1 g sin n
g sin 45 − g cos 45 1
or = 2
g sin 45 n
1 1
or 1 − k = 2 or k = 1 −
n n2
50. (1)
FBC = FAD
FAB FCD
[Chemistry]
51. (3)
Rate = K A
x
R → 2R
If A = 4time
R = K A
x
….(1)
2R = K 4A
x
….(2)
During (1) by (2)
K A
x
R
=
2R K 4Ax
x
1 1
=
2 4
x = 1/ 2
52. (2)
Cu ( OH)2 Cu 2+ + 2OH
2
Ksp = Cu 2+ OH
2
1×10–19 = Cu 2+ OH
pH=14= –log H+
H+ = 10−14
OH– OH+ = 10−14
OH– = 1 Ksp = Cu2+
0.0591
Ecell = Ecell
0
− log Q
n
Cu2+ + 2e− ⎯⎯ →Cu
1
n = 2, Q =
Cu 2+
0.0591 1
Ecell = 0.34 − log −19 = −0.22V.
2 10
53. (3)
− − +
Each Cs + ion is surrounded by 8Cl ion and each Cl is surrounded by 8Cs ion.
54. (2)
In fcc , No. of atoms = 4
i = 1 + ( n −1)
i = 1 + 0.8 (5 −1)
i = 4.2
56. (3)
V2 = 125m3
% increase = 25%.
57. (3)
1
→ O2 + 2e− + H2
H2O ⎯⎯
2
2 faradays of charge is required for 1 mole.
2 96500C
2 96500 = 3t
t = 64333.34sec
64333.34
t=
60 60
t = 17.87 = 18hours
58. (2)
no.of e− in no.of e− in
−
bonding MO ABMO
Bond order =
2
9−4
= = 2.5
2
59. (4)
BrF3
60. (1)
Ba ( OH)2 ⎯⎯
→ Ba 2+ + 2OH−
OH− = 10−2 2 = 2 10−2
( )
pOH = − log 2 10−2 = 1.7
pH + pOH = 14
pH = 14 −1.7
pH = 12.3
61. (3)
Common ion effect is the suppression of Ionization of an electrolyte when another electrolyte (Which
contains a common ion is added).
HCN is a weak acid so its ionization suppresses when HCl is added (common ion is H+ )
62. (2)
Permanent Hardness is removed by permuted process in which zeolite is used.
63. (2)
The Ortho and para hydrogen differ in the nature of spin of proton. In ortho hydrogen, the spin of the
proton are in the same direction, while in para-hydrogen the spin of the proton are in opposite
direction.
64. (3)
CH3 — C — NH — C6H5
||
O
68. (3)
Boric acid is a lewis acid as it accepts electrons from a hydroxyl ion.
69. (4)
Path in dependent function are temperature, internal energy and pressure all because the value of
these properties do not depent upon the path taken by the system
70. (3)
Enthalpy of formation is defined as the enthalpy change during formation of ‘mole of a substance
from it elements in their thermodynamically most stable state.
71. (2)
72. (2)
73. (2)
When an alkylbenzene is treated with KMnO4 then it results in oxidation to give benzoic acid
irrespective of the carbon chain length
74. (2)
N2O3 2x + 3( −2) = 0
x = +3
x = 6/ 2
HN3
1+ 3x = 0
x = −1/ 3
H−C N x = −3
(by electronegativity difference b / w C& N )
75. (3)
Propene and propyne can be distinguished by Tollen’s reagent because propyne has an acidic
hydrogen due to which it readily reacts with Ammoniacal silver nitrate (Toller’s reagent) to give white
precipitate. However, Propene doesn’t have acidic hydrogen so it does not react with Toller’s reagent.
76. (2)
The given reaction is decarboxylation reaction. In this, sodium salt of carboxylic acids are treated
with soda-lime ( CaO + NaOHmix ) to give an alkane containing one carbon atom less and evolves
carbon dioxide.
CH3CH2COO− Na + + NaOH
CaO
⎯⎯⎯ → CH3 — CH3
(ethane)
77. (2)
Packing efficiency of FCC unit cell is 74%
no.of atoms Vol.of 1atom
Packing efficiency =
Vol.of unit cell
4
4 r3
= 3 2a = 4r
a3
packingefficency = 74%
78. (4)
When calcium salts of carboxylic acids are heated then they give either aldehyde or ketone depending
upon their structures. The product in this reaction is propan-2-one.
79. (2)
80. (2)
This reaction proceeds through the formation of a benzyne intermediate and the incoming
substituent gets attached to the adjacent carbon.
81. (2)
Caprolactam is the monomer of nylon-6
82. (2)
D-Glucose and D-mannose are C-2epimers because these 2 sugars differ from each other by
configuration of atoms at 2-carbon.
83. (4)
Because intermolecular interactions between pure solution and mixture are nearly equal
84. (3)
XeF2 ⎯⎯
→ It has 3 lone pair so, it has maximum lene lone pair repletion
85. (1)
Product X is an alkane nitrate. When this alkane nitrile is reduced then it gives an aldehyde(y).
R − Br ⎯⎯⎯→
NaCN
R −C N
(X)
DIBAL−H
⎯⎯⎯⎯⎯
H O
→R − C − H
2
O
(Y)
86. (4)
Volume at STP
No of moles =
22.4L
11.2
= = 0.5moles
22.4
Mass of 1 mole of NH3 = 17g / mol
Mass of 0.5 mole of NH3 = 17 0.5 = 8.5g
87. (3)
A + 2B → 3C
1 mole of A requires 2 moles of B
So, 2 mole of A requires 4 moles of B
But only 3 moles of B have been given so, B is a limiting reagent here.
2 moles of Bgive → 3 moles of C
3
3 moles of Bgive → 3
2
9
= 4.5moles
2
88. (1)
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p1
−
No. of e in p subshell = 6 + 6 +1 = 13
89. (3)
Cr +3
no.of unpairede− = 3.
90. (3)
When aniline is treated with chloroform and KOH (carbylamine reaction) then it gives benzene
isocyanide while on further reduction, then it gives N-methylaniline.
91. (4)
BeCl2 ⎯⎯
→ Cl − Be − Cl
Be 1s2 2s2
H = 2+2 = 2 = sp
1
2 Geometry=linear
92. (3)
Most electronegative element is ‘O’.
( F O N)
93. (1)
MnO is antiferromagnetic
94. (2)
d a d a c a
b M c c M b d M b
3 geometrical isomers
98. (0)
0.97g
Moles of ZnS = = 0.01mol
97g / mol
No. of atoms = 0.01 NA
1 unit cell contains 4 atoms
1
0.01 NA atoms are contained in 0.01NA
4
= 2.5 10−3 NA
Unit cells
99. (4)
Cu +2 and Ti3+
Cu+2 Ar 4s0 3d9
M = n ( n + 2)
n =1
m = 1(1 + 2) = 1.73BM