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PART – A – PHYSICS
Section A
Ans: 0.4 s
Sol: 2T T
2a
8 kg 2 kg
m1 g m1 g
Ans: 640 m / s
3KT
Sol: Vrms =
M
(Vrms )O MH2 2
2
= =
(Vrms )H 2
MO2 32
(Vrms )H 2
= 4 × (Vrms )O = 4 × 160= 640 m/s
2
Ans: 1.25 V
hc
Sol: kE max = +φ
λi
hc
Or eV0 = +φ
λi
When λi = 670.5 nm; V0 = 0.48
When λi = 474.6 nm; V0 = ?
So, e(0.48 ) =
1240
+ φ − − − − − − − − − −(1)
670.5
e(V0 ) =
1240
+ φ − − − − − − − ( 2)
474.6
(2) – (1)
1 1
e(V0 − 0.48 ) = 1240 − eV
474 . 6 670 .5
670.5 − 474.6
V0 = 0.48 + 1240 Volts
474.6 × 670.5
V0 = 0.48 + 0.76
V0 = 1.24 V ≅ 1.25 V
Ans: 1 : 2 : 2
Sol:
D
VD
A C2 C3 B
V 0
C1
0 0
V
(VD – V) C2 + (VD – 0) C3 = 0
(VD – V) 6 + (VD – 0) 12 = 0
VD – V + 2VD = 0
V
VD =
3
V
q 2 = (V − VD )C 2 = V − (6µF )
3
q2 = (4V) µF
V
q3 = (VD – 0) C3 = × 12 µF = 4V µF
3
q1 = (V – 0) C1 = V (2µF)
q1 : q2 : q3 = 2 : 4 :4
q1 : q2 : q 3 = 1 : 2 : 2
Ans: µ1 − µ2
Sol:
f1 f2
1
= (µ 1 − 1)
1
f1 R
1
= (µ 2 − 1) −
1
f2 R
1
+
1
=
1 (µ − 1) − (µ 2 − 1)
= 1
f1 f 2 f eq R
1 (µ − µ 2 )
= 1
f eq R
= (µ 1 − µ 2 )
R
f eq
x2
Ans:
a2
Sol:
i0
a b i0
When x < a
i 2
B1 (2πx ) = µ 0 0 πx
πa 2
µ 0i0 x 2
B(2πx ) =
a2
µ 0i0 x
B1 = ------------------(1)
2πa 2
When a < x < b
B2(2πx) = µ0i0
µ i
B 2 = 0 0 ----------------(2)
2πx
x
µ0i0 2
B1
= 2 π a2 = x
B2 µ i
00 a 2
2πx
Ι1Ι 2
Ans: (ω1 − ω2 )2
2(Ι1 + Ι 2 )
ki − k f =
1 (Ι ω + Ι 2 ω 2 )2
Ι 1ω12 + Ι 2 ω 22 − 1 1
2 Ι1 + Ι 2
Solving above we get
1 Ι Ι
k i − k f = 1 2 (ω1 − ω2 )2
2 Ι1 + Ι 2
Ans: 7.35 m
Sol: 3
h
2 H = 9.8
1
1 2
H= gt
2
9.8 × 2
= t2
9.8
t = 2 sec
∆t: time interval between drops
1
(
h = g 2 − ∆t
2
2
)
1
(
0 = g 2 − 2∆t
2
2
)
1
∆t =
2
2
1 1 1 1 9 .8
h= g 2− = × 9.8 × = = 2.45 m
2 2 2 2 4
H – h = 9.8 – 2.45 = 7.35 m
R = 75 × 10 ± 5% of 7500
2
Sol:
R = (7500 ± 375) Ω
Ans: −4 G
Sol: A 100 kg
r 50 m
50 kg
−GM1 GM2 50 100
VA = − = − 25 G − 50 G = −4 G
r R
α
Ans: β =
1− α
ΙC Ι
Sol: α= ,β = C ; ΙE = Ι C + ΙB
ΙE ΙE
ΙC
ΙC ΙB β 1 1
α= = = + 1+ =
ΙC + ΙE ΙC β +1 β α
+1
ΙB
1 1− α
=
β α
α
β=
1− α
Ans: 2 Ω
50
Sol: Ι max == 25mA
2
V 50mV
R= = = 2Ω
Ι 25mA
Ans: 4 Ι0
Sol: Ι max = (Ι 1 + Ι2 )
2
= 4Ι0
Ans: 2 V
Ans: 605 m
Ans:
3 3Q
8 π 2 ε 0R 2
(î )
Sol: ε=
2kλ
R
θ
( )
sin − î
2
−Q −Q
λ= =
Rθ R 2π
3
−3Q
λ=
2πR
ε=
2k −3Q
R 2πR
sin(60°) − î ( )
ε=
3 3Q
8π 2 ∈0 R 2
(+ î )
Ans: 0.147°C
-4 2
Ans: [F L T ]
Ans: 15
n(n − 1) 6 × (6 − 1) 6 × 5
Sol: No. of different wavelengths = = = = 15
2 2 2
Ans: 1
π
Sol: y1 = 10 sin 3πt + ⇒ Amplitude = 10
3
(
y 2 = 5 sin 3πt + 3 cos 3πt )
1 3
y 2 = 10 sin 3πt + cos 3πt
2 2
π π
y 2 = 10 cos sin 3πt + sin cos 3πt
3 3
π
y 2 = 10 sin 3πt + ⇒ Amplitude = 10
3
10
So ratio of amplitudes = =1
10
Ans: 20
Sol: When unregulated voltage is 14 V voltage across zener diode must be 10V so potential difference
across resistor ∆VRs = 4V
And Pzener = 2W
VΙ = 2
2
Ι= = 0 .2 A
10
∆VRs = Ι Rs
40
4 × 0.2 Rs ⇒ Rs = = 20 Ω
2
Ans: 50
T1max
Sol: B.S1 = ⇒ T1max = 8 × 1.25 × 100 = 1000 N
8 × 10 − 7
T2 max
B.S 2 = ⇒ T2 max = 4 × 1.25 × 100 = 500 N
4 × 10 − 7
1000 − 500
m= = 50 kg
10
Ans: 34
Sol:
l
λ
= l ⇒ λ = 4l
4
V V
f= =
λ 4l
340
⇒ 250 =
4l
34
⇒l= = 0.34 m
4 × 25
l = 34 cm
Ans: 2
E 6
Sol: B = = = 2 × 10-8 T
C 3 × 10 8
∴x=2
Ans: 500
Ans: 9
3R
Sol: R eq open =
2
R × 2R 4R
R eq closed = 2× =
3R 3
R eq open 3R 3 9
= × =
R eq colsed 2 4R 8
∴x=9
Ans: 1
Sol: XL Xc = 2R
R XL = 3R R
~ ~
R R
cos φ = cos φ' =
R + 3R
2 2
R + R2
2
1 1
= =
10 2
cos φ 10 5
= =
cos φ' 2 1
∴x=1
Ans: 400
Sol:
0.5 m
10 g
Vmin = V
Section A
3− 2− − + 2+
Ans: P > S > Cl > K > Ca
Sol: All the given species are isoelectronic. Among isoelectronic species, as atomic number increases,
ionic radii decreases.
+
Ans: CH3CH2CH2Br + Mg, CO2 dry ether / H3O
O
CH3−CH2−CH2−Br CH3−CH2−CH2MgBr CH3−CH2−CH2−C−MgBr
Mg CO2
Sol:
Dry ether
O
H 3 O+
CH3−CH2−CH2−C−OH
B utano ic acid
Ans:
OH O−
O
Sol: B ase S N2 r eaction
+ Br
Sol: In the lyophilic colloids, the colloidal particles are extensively solvated.
Ans: (b) only
NO2
OH
Sol: shows intramolecular H-bonding
H
N CH3
shows intermolecular H-bonding
O
HO
Ans: Among the alkali metal halides, LiF is least soluble in water
Sol: * For alkali metal fluoride the solubility in water increases from Lithium to Caesium. LiF is least
soluble in water.
* In CsI, lattice energy is less, but Cs+ is having less hydration enthalpy due to which it is less soluble
in water.
* Standard enthalpy of formation for LiF is most negative among alkali metal fluorides.
* Standard enthalpy formation for alkali metal bromide becomes more negative on descending the
group
Ans:
Sol: Histamine stimulates secretion of HCl in stomach leading to irritation and pain. Structure of Histamine
is
H
CH3−CH2−C−CH2−Br CH3−CH2−C=CH 2
CH 3O− / CH 3OH
Sol:
A
Major produ ct
Ans: α-Black phosphorus
Sol: When red phosphorus is heated in a sealed tube at 803 K, α-black phosphorus is formed
∆
Sol: 2 KMnO 4
→ K 2MnO 4 + MnO2 + O2
513 K
Green Black
K2MnO4 has one unpaired electron hence it is paramagnetic
Ans:
OH OH OH
O O
H2 / P d
Sol:
C2H 5OH
NO 2 NH2 NH CH3
(B ) O
(Majo r pr oduct)
O
H−C≡C−CH2−CH2−C−O−CH2−CH3
CH 3Mg Br (3 moles)
Sol:
−CH3CH 2OMgBr
− +
OMgBr OH
+ −
Br−MgC≡C−CH2−CH2−C−CH3 HC≡C−CH2−CH2−C−CH3
H 2O
CH3 CH3
It consumes 3 moles of Grignard reagent so statement 2 is false
Ans: O2F2
Sol: O2F2 oxidises plutonium to PuF6 and the reaction is used in removing plutonium as PuF6 from spent
nuclear fuel.
Section B
Ans: 16
Ans: 3
Ans: 964
∆ r H°
Sol: Teqbm =
∆ r S°
[ ][
∆rH° = ∆ f H(oFe ) + ∆ f H(oCO ) − ∆ f H(oFeO ) + ∆ f H(ographite ) ]
= [0 − 110.5] − [−266.3 + 0]
= 155.8 kJ mol−1
[ ][
∆r S° = ∆S(oFe ) + ∆S(oCO ) − ∆S(oFeO ) + ∆S(ographite ) ]
= [27.28 + 197.6] − [57.49 + 5.74] = 161.65 J mol K−1
155.8 × 10 3
Teqbm = = 963.8 K ≈ 964
161.65
Since ∆rH° and ∆rS° are positive, the reaction is spontaneous if T > 963.8 K
Therefore the minimum temp at which the reaction becomes spontaneous is 964 K
Ans: 50
Sol: E = nhν
nhc
E= P = 1mW = 1 × 10 −3 J / s
λ
For 1s → E = 10−3 J
∴0.1 s → E = 10−4 J
−10
Eλ 1× 10 −4 × 1000 × 10 −9 10
n= = −
=
hc 6.63 × 10 × 3 × 10 19.89 × 10 − 26
34 8
= 0.050 × 1016
= 50 × 1013
∴ x = 50
Ans: 6
Ans: 19
Ans: 271
Ans: 760
1000 κ 1 l 1
Sol: Λm = κ= × = × 1.14 = 0.00076
M R A 1500
1000 × 0.00076 0.76 0.76
Λm = = = = 0.76 × 103 = 760 S cm2 mol −1
0.001 0.001 10 −3
Ans: 2
3+ ox 3+
ox
Sol: ox Cr Cr ox
ox ox
Ans: 84
PART – C – MATHEMATICS
Section A
π
Ans:
2
Ans: 3 − 2 2
π
Sol: sinx + cosx = 2 sin x x +
4
[ ] π
⇒ sin x + cos x ∈ 1, 2 for x ∈ 0,
2
π
f (x ) = tan −1 (sin x + cos x ) ∈ , tan −1 2
4
π 2 −1 2 −1
tan tan −1 2 − = × =3−2 2
4 1+ 2 2 −1
Ans: [62, 63)
[x + 1] [x + 2] [x + 3]
Sol: [x] [x + 3] [x + 3] = 192
[x] [x + 2] [x + 4]
R1 → R1 − R 2 & R 2 → R 2 − R 3
1 0 −1
0 1 − 1 = 192
[x ] [x] + 2 [x] + 4
2[x ] + 6 + [x ] = 192 ⇒ [x ] = 62
Ans: R
1 1 1
Sol: ∆= 3 2 5 = −24 − [λ ] + 15 = −[λ ] − 9 ≠ 0
9 4 28 + [λ ]
If [λ ] +9 ≠ 0 then unique solution
If [λ ] + 9 = 0 then ∆1 = ∆ 2 = ∆ 3 = 0
∴ λ can be any real number
d2 y
Ans: 11 = 10
dx 2
3(2) + 4(− 3 ) − 5 11
Sol: Latus rectum = =
5 5
(x − h)2 11
= (y − k )
5
Differentiate with respect to x
2(x − h) =
11 dy
5 dx
Differentiating again,
11 d 2 y
2−
5 dx 2
d2 y
11 = 10
dx 2
5
Ans:
16
Sol:
0 1 2 3
No. of heads
1 1 1 3 3 9 3 3 9 1 1 1
P (same) × = × = × = × =
8 8 64 8 8 64 8 8 64 8 8 64
1 9 9 1 5
Total probability = + + + =
64 64 64 64 16
Ans: y 5 − y 2 − 1 = 0
Rearranging, we get
dx 2
⇒ + x = 10 y 2
dy y
2 2 ln ( y )
∫ y dy =e =y2
I.F = e
Solution of D.E is
∴ x.y = ∫ (10y )y .dy
2 2
10 y 5
xy 2 = + C ⇒ xy 2 = 2y 5 + C
5
Since it passes through (0, 1); 0 = 2 + C ⇒ C = −2
∴ Curve is xy 2 = 2y 5 − 2
Given it passes through (2, β )
2β 2 = 2β 5 − 2 ⇒ β 5 − β 2 − 1 = 0
∴ β is root of an equation y 5 − y 2 − 1 = 0
1
Ans: 1, −
2
Sol: lim x 2 − x + 1 − ax = b (∞, − ∞ )
x →∞
⇒a>0
⇒ lim
(x 2
− x + 1 − a2 x 2 )=b
x →∞
x 2 − x + 1 + ax
lim
(1− a )x 2 2
− x +1
=b
x →∞
x − x + 1 + ax
2
lim
(1 − a )x
− x +1 2
=b
2
x →∞ 1 1
x 1− + +a
x x2
⇒ 1− a2 = 0 ⇒ a = 1
−x + 1
Also, lim =b
x →∞ 1 1
x 1− + +a
x x2
−1 1
⇒ =b⇒b=−
1+ a 2
1
(a, b) = 1, −
2
r
( )
Ans: r . ĵ − 3k̂ + 6 = 0
Ans: 9
Sol: When y = 3 ⇒ x = 2
∴Point is (2, 3)
Differentiating (y −2)2 = x − 1 with respect to x
2 (y – 2) y' = 1
1
⇒ y' =
2(y − 2)
1
At (2, 3), y' =
2
y−3 1
⇒ = ⇒ x − 2y + 4 = 0
x−2 2
∫ ((y − 2) )
3
Area = 2
+ 1 − (2y − 4 ) dy = 9 sq. units
0
1
Ans: −
2
x x x x
cos 2 + sin 2 + sin 2 − cos 2
Sol: y(x ) = cot −1
cos x + sin x − sin x + cos x
2 2 2 2
x π x
y(x ) = cot −1 tan = −
2 2 2
y' (x ) = −
1
2
1 2
Ans: e
2
1 1
Sol: y = 1 − x 2 + 1 − x 3 + .......
2 3
(
= x 2 + x 3 + x 4 + .... − )
x2 x3 x4
2
+ +
+ .... =
x2
+ x − x +
x2 x2
+
+ ....
3 4 1− x 2 3
1
x = ⇒ y = 1 − ln 2
2
e2
e1+ y = e1+1−ln 2 = e 2−ln 2 =
2
Ans: 25
Sol: (x – 2 )2 + y2 ≤ 4
x2+ y2 ≤ 4
No. of points common in A & B is 5.
(0, 0), (1, 0), (2, 0), (1, 1), (1, –1)
Similarly in B & C is 5
No. of relations = 25×5 = 225
5
Ans: 1,
2
Sol: (3x 2
+ 4x + 3 )
2
( )( ) (
− (k + 1) 3 x 2 + 4 x + 3 3 x 2 + 4 x + 2 + k 3 x 2 + 4 x + 2 )
2
=0
Let 3 x + 4 x + 3 = a and b = 3 x + 4 x + 2 = b ⇒ b = a – 1
2 2
Sol:
C
θ α
b
α
B D
x
1
tan θ =
2
tan(θ + α ) =
x x
, tan α =
b a+b
1 x
+
⇒ 2 a+b =
x
1 x b
1− ×
2 a+b
Rearranging
⇒ x 2 − 2ax + ab + b 2 = 0
a + b − a 2 + b 2 − ab
Ans:
6
Sol: V = (a − 2x )(b − 2x )x
dV (x )
⇒ = 12 x 2 − 4(a + b )x + ab
dx
dV (x )
= 0 ⇒ 12 x 2 − 4(a + b )x + ab = 0
dx
Solving, x =
(a + b) ± a 2 + b 2 − ab
6
Let x =
(a + b) + a 2 + b 2 − ab
6
or
(a + b) −
a 2 + b 2 − ab
6
We can see that the maximum point is
a + b − a2 + b2 − ab
∴x =
b
Ans: x + 1 = 0
Ans: (p ∧ q) ⇒ (r ∧ q)
Sol: (p ∧ q) ⇒ ((r ∧ q) ∧ p)
~ (p ∧ q) ∨ ((r ∧ q) ∧ p )
~ (p ∧ q) ∨ ((r ∧ q) ∧ (p ∧ q))
⇒ [~ (p ∧ q) ∨ (p ∧ q)] ∧ (~ (p ∧ q) ∨ (r ∧ p ))
⇒ T ∧ [~ (p ∧ q) ∨ (r ∧ p )]
⇒ ~ (p ∧ q) ∨ (r ∧ p )
⇒ (p ∧ q) ⇒ (r ∧ q)
π 3
Ans: 1−
8 2
1
x
Sol: I= ∫ (1 + x )(1 + 3x )(3 + x ) dx
0
t (2t )
1
I= ∫ (t 2 + 1)(1 + 3t 2 )(3 + t 2 ) dt
0
Simplifying, we get
1
( ) ( ( ))
1 1 1
tan −1 (t ) 0 −
1 dt 3 dt 3 dt 1 1 3 tan −1 t − 3 tan −1 3 t 1
=
2 ∫ (1 + t 2 ) −
8 ∫ (t 2 + 3) −
8 ∫ (1 + 3t 2 ) =
2 8 3
3
0 8 3
0
0 0 0
1π 3 π 3 π π 3
= − − = 1−
24 8 6 8 3 8 2
− 2b 2
Ans:
b +1
a 0 1
1
Sol: b 2b + 1 1 = 1
2
0 b 1
a 0 1
⇒ b 2b + 1 1 = ±2
0 b 1
(
⇒ a(2b + 1 − b ) − 0 + 1 b 2 − 0 = ±2 )
±2−b 2
⇒a =
b +1
2 − b2 2 − b2
∴a = and a = −
b +1 b +1
− 2b2
Sum of possible values of ‘a’ is =
b +1
Ans: 7
Sol: ( ) (
2e x + 3e − x = A 4e x + 7e − x + B 4e x − 7e − x )
Equating coefficient of ex and e−x on both sides
2 = 4 A + 4B; 3 = 7 A − 7B
13 1
Solving, we get A = ,B= \
28 28
i.e., Required integral is
13 1 4e x − 7e − x
∫ 28 dx + 28 ∫ 4ex + 7e− x dx
13 1
Comparing, u = ,v=
2 2
⇒ u + v= 7
Ans: 72
Ans: 6
Sol: |z – 3| = Re(z)
Put z = x + iy
Simplifying we get y2 = 6x – 9
3
⇒ y2 = 6 x −
2
Given z1 and z2 lie on|z − 3| = Rez
π
and Arg (z1 – z2) =
4
⇒Slope of line joining z1 and z2 is 1
3 3 3 3
Let z1 + t12 , 3t1 and z 2 + t 22 , 3t 2
2 2 2 2
2
⇒ =1
t2 + t2
⇒t2 + t1 = 2
Imaginary(z1 – z2) = 3t 1 + 3t 2 = 3(t 1 + t 2 ) = 3(2) = 6
Ans: 30
Sol: ∑ P(X) = 1 ⇒ k + 2k + 2k + 3k + k = 1
1
⇒k =
9
2
1< X < 4 P(X = 2) 9 2
Now, p = P = = =
X < 3 P (X < 3 ) 1
+
2 3
9 9
2
⇒p =
3
Given 5p = λk
10 λ
=
3 9
⇒ λ = 30
Ans: 15
Ans: 80
Ans: 25
Sol: σ boys
2
=2 n1 = no. of boys
x boys = 12
σ 2girls = 2
50 × 15 − 12 × σ boys 750 − 12 × 20
x girls = = = 17 = µ
30 30
Variance of combined series
n1σ boys
2
+ n 2 σ 2girls
σ2 = +
n1.n 2
(x boys − x girls )2
n1 + n 2 (n1 + n 2 )2
20 × 2 + 30 × 2 20 × 30
σ2 = + (12 − 17 )2
20 + 30 (20 + 30 )2
σ2 = 8
⇒ µ + σ2 = 17 + 8 = 25
Ans: 40
4
Sol: Slope of line joining centres of circles = = tan θ
3
Using this
3 4
⇒ cos θ = , sin θ =
5 5
parametric form is given by
x −1 y − 2
= = ±5
cos θ sin θ
Comparing, (x, y ) = (1 + 5 cos θ,2 + 5 sin θ)
⇒ (α, β ) = (4,6 )
(x, y ) = (γ, δ) = (1 − 5 cos θ,2 − 5 sin θ)
⇒ (γ, s ) = (−2,2)
∴| (α + β )(γ + δ ) |=| 10 x − 4 |= 40
Ans: 56
⇒θ= 0
Similarly, since B lie on the hyperbola, we will get φ = 0.
π
But θ + φ =
2
Impossible so no answer