M.

Prakash Institute
Answer Key:
Q1 Q2 Q3 Q4 Q5 Q6 Q7 Q8 Q9 Q10
B A B D A C A C C D
Q11 Q12 Q13 Q14 Q15 Q16 Q17 Q18 Q19 Q20
B B A B D D B C A C
Q21 Q22 Q23 Q24 Q25 Q26 Q27 Q28 Q29 Q30
11.2 1.00 0.23 2.33 16.00 11.00 960.00 6.00 3.00 2.00

Solutions:

1 Inside concentric spherical cavity gravitational field is zero and it is maximum on the
outer surface.
2

3
4

6
7

9
10

11

12
13

14
15

16

17

18

19
20

21

22

23

24
25

26
27

28

29

30
 Key/Solutions

Q A Q A Q A Q A Q A Q A
31 D 36 C 41 D 46 D 51 132 56 1
32 B 37 D 42 A 47 B 52 480 57 0
33 B 38 B 43 D 48 D 53 97 58 19
34 D 39 B 44 D 49 B 54 Range = 25.5-26 59 Range = 1.85-2.1
35 A 40 B 45 B 50 C 55 4 60 2

Q34)
2Ag+ + Cu ⇌ Cu2+ + 2Ag
At equilibrium ax
if V is 500 mL
( 500 )
x × 1000
x
Kc = =
( 500 )
a × 1000
2 2a2

If volume is doubled, then a becomes a /2; Let x be x′, then if V = 1000 mL

x′ 4x′
Kc = 2
= 2
(a / 2) a
x 4x′ x x
∴ = or x′ = 8
or x′ < 2
2a2 a2

[Cu ]
2+
x
Kc = 2
=
[ Ag+ ] (a) 2
x
To have K c constant [Cu2+] will be less than .
2

Q36)
Given that
XeF6( g) + H2O(g) ⇌ XeOF4( g) + 2HF(g) = K1
XeO4( g) + XeF6( g) ⇌ XeOF4( g) + XeO3 F2( g) constant = K 2
equilibrium constant for (K)
XeO4 + 2HF ⇌ XeO3 F2 + H2O (constant = K )
In terms of K1 and K 2






 [XeOF4 ][HF]
2
K1 =
[XeF6 ][H2 O]
[XeOF4 ][XeO3 F2
K2 =
[XeO4 ][XeF6
[XeO3 F2 ][H2 O]
K=
[XeO4 ][HF
2

XeOF4 [H2 O]
XeF6
= K1
[HF]2
K2
K= K1

Q38)
Cu(s) + 2Ag+(aq) ⇌ Cu2+(aq) + 2Ag(s)
The equilibrium constant expression is
[Cu (aq)][Ag(s)]
2+ 2
KC = 2
[Cu(s)][Ag+ ]

2 × 10−7 mol L−1

= 2
(1 × 10 )
−11 mol L−1

= 2 × 1015 mol L−1

Q41)

FeSO4 ⋅ 7H2O FeSO4 Fe 2O3 + SO2 SO3

(Green) (White (Brown) (μ D∗0) (μ D =0)
from 2 moles)
3SO3( g) S3O9
(μD ≠ 0)

Q42)
The degree of dissociation cannot be calculated from the vapour density data in reaction I and III
Because here the number of moles remains unchanged (Δn = 0) before and after reaching
equilibrium.

Q46)
For equilibrium: N2O4(s) ⇌ 2NO2(g)
At equilibrium (1-⍺) mole 2⍺ mole
Total moles = 1 − α + 2α = 1 + α
If p is total pressure at equilibrium therefore
 1−α 2α
p N2 O4 = 1+α
⋅ p and p NO2 = 1−α
⋅p
2
(p NO 2) 4α 2 × p
Kρ = pN O
= (1 − α)(1 + α)
2 2
If volume is halved, therefore pressure is doubled but the value of Kp is not effected with pressure.
Thus at higher pKp will be higher, but it is constant so for maintaining the constant value of Kp, a
will be lowered. Hence, Kp does not changed, but a changes.

Q48)
The relation between K c and K p is given by,
K p = K c ⋅ (RT)Δn
Δn = Number of moles of gaseous product - Number of moles of gaseous reactants.
△ n = 2 − 4 = − 2,
T = 500 + 273 = 773 K
Since, the partial pressure are measured in atmosphere the value of R will be 0.082 L-atm/mol-K
Kp 1.44 × 10−5
Kc = =
(RT )Δn (0.082 × 773)−2

Q49)
The third group solution should be treated with excess of NH 4 Cl. The presence of NH 4 Cl in excess
reduces degree of dissociation of NH 4OH to a considerable amount, and thus, [OH−] is just
sufficient to cross over the ionic concentration product of hydroxides of III group elements to their
K sp.

Q51) CrO5 = 132

Q52)
The reaction can be represented as N2O4 ⇌ 2NO2
Initial mole 1 0
Mole at equilibrium 1-⍺ 2⍺
The equilibrium constant can be given by

(nNO2)
2

( nT )
Δng
pT
Kp =
(nN2 O4)

1 − α(1 + α)
1
4α 2 pT
But, Kp is given by Kp =

Substituting Kp = 640 and pT = 160 mmHg, we get

4α 2
4= ⇒ α = 0.707
1−α
or percentage dissociation = 70.7%.
If α = 0.5, then the expression is
4 × (0.5)2 p
640 = × T ⇒ pT = 480 mmHg
0.5 1.5
Q53) ZnS = 97

Q54)
Reaction: PCl5 ⇄ PCl3 + Cl2
Initially: 1 0 0
EQM : (1-x) x x
Total moles at equilibrium = 1 − x + x + x = (1 + x)
( 1 + x ⋅ p)( 1 + x ⋅ p)
x x
p PCl ⋅ pCl
3 2
Kp = = .
( 1 + x ⋅ p)
p PCl 1−x
5

}
moles of species
{ partial pressure of a species = × total pressure
total moles
x2
Kp = ⋅ p.
1 − x2
Substituting the values of Kp and p
x2
0.202 = × 1.5; x = 0.343 .
1 − x2
∴ moles of Cl2 at equilibrium = 0.343
and total moles at equilibrium = 1 + x
= 1 + 0.343
= 1.343 .
∴ volume percentage of chlorine = mole percent of chlorine
moles of Cl2
= × 100
total moles
0.343
= 1.343
× 100
= 25.5% .

Q55)
X ⇒ (NH 4 )3PO4 . 12MoO3 (Canary yellow ppt is produced by both, phosphate and arsenate ions!)
15th group and sp 3 hybridized atoms in X = 4 (3, N-atoms +1P-atom)

Q56)
NH2 COONH 4( s) ⇋ 2NH3( g) + CO2( g)
Let α = degree of dissociation of Ammonium carbamate
Let D = density of ammonium carbamate
mol ⋅ wt
∵D=
2
where molecular wt. of NH2 COONH 4 = 14 + 2 + 12 + 32 + 14 + 4 = 78
78
Then D = = 39
2
Give vapour density d = 13
D−d
α=
(n − 1)d
where n = no of products = 3
39 − 13 26
α= = =1
(3 − 1) × 13 (2) × 13
➠∴α =1
Q59)
CASE I:
N2O4( g) ⇌ 2NO2( g)
At equilibrium (1-x) 2x
(1 − x) 2x
p N2 O4 = (1 + x) × P; p NO2 = (1 + x) × P
2
( (1 + x) ⋅ P)
2x
4x2 P
Kp = =
( (1 + x) ⋅ P)
(1 − x) 1 − x2

Given x = 0.503 and P = 1

∴ K p = 1.3548

CASE II:
N2O4( g) ⇌ 2NO2( g)
At equilibrium (1-x) 2x

1−x 1
given = ☞ x = 0.8
2x 8
Let the new pressure be P atm
4X2 P
Kp = 2
= 1.3548
1−X
P = 0.19 atm
11th std. Batch - F1 Mains Date –13/01/2024

Answer Key:

Q.61 Q.62 Q.62 Q.64 Q.65 Q.66 Q.67 Q.68 Q.69 Q.70
B D A A D D A A C B
Q.71 Q.72 Q.73 Q.74 Q.75 Q.76 Q.77 Q.78 Q.79 Q.80
B C A B C C A A A D
Q.81 Q.82 Q.83 Q.84 Q.85 Q.86 Q.87 Q.88 Q.89 Q.90
9 3 3 3 5 8410 9802 1928 3439 8728

Maths Solutions:

61. B

62. D

63. A
64. A

65. D

66. D

67. A

68. A

69. C
70. B

71. B

72. C

73. A

74. B

75. C

76. C

77. A

78. A
79. A

80. D

81. 9

82. 3

83. 3

84. 3
85. 5

86.

87.

88.

89.
90.